Theses and Dissertations
This collection includes both ASU Theses and Dissertations, submitted by graduate students, and the Barrett, Honors College theses submitted by undergraduate students.
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- Creators: Phelan, Patrick
Description
The concept of this thesis came up as a part of the efforts being devoted around the world to reduce energy consumption, CO2 emissions, global warming and ozone layer depletion. In the United States, HVAC units in residential buildings consumed about 350 billion kWh in 2017 [1],[2]. Although HVAC manufacturers are investing in new technologies and more efficient products to reduce energy consumption, there is still room for further improvement.
One way of reducing cooling and heating energy in residential buildings is by allowing the centralized HVAC unit to supply conditioned air to only occupied portions of the house by applying smart HVAC zoning. According to the United States Energy Information Administration [3], the percentage of houses equipped with centralized HVAC units is over 70%, which makes this thesis applicable to the majority of houses in the United States. This thesis proposes to implement HVAC zoning in a smart way to eliminate all human errors, such as leaving the AC unit on all day, which turns out to be causing a serious amount of energy to be wasted.
The total amount of energy that could be saved by implementing the concepts presented in this thesis in all single-family houses in the U.S. is estimated to be about 156 billion kWh annually. This amount of energy reduction is proportional to the electricity bills and the amount of dollars paid annually on energy that is technically being wasted.
One way of reducing cooling and heating energy in residential buildings is by allowing the centralized HVAC unit to supply conditioned air to only occupied portions of the house by applying smart HVAC zoning. According to the United States Energy Information Administration [3], the percentage of houses equipped with centralized HVAC units is over 70%, which makes this thesis applicable to the majority of houses in the United States. This thesis proposes to implement HVAC zoning in a smart way to eliminate all human errors, such as leaving the AC unit on all day, which turns out to be causing a serious amount of energy to be wasted.
The total amount of energy that could be saved by implementing the concepts presented in this thesis in all single-family houses in the U.S. is estimated to be about 156 billion kWh annually. This amount of energy reduction is proportional to the electricity bills and the amount of dollars paid annually on energy that is technically being wasted.
ContributorsFairag, Amr (Author) / Phelan, Patrick (Thesis advisor) / Bocanegra, Luis (Committee member) / Shuaib, Abdelrahman (Committee member) / Arizona State University (Publisher)
Created2018
Description
This work aimed to characterize and optimize the variables that influence the Gas Diffusion Layer (GDL) preparation using design of experiment (DOE) approach. In the process of GDL preparation, the quantity of carbon support and Teflon were found to have significant influence on the Proton Exchange Membrane Fuel Cell (PEMFC). Characterization methods like surface roughness, wetting characteristics, microstructure surface morphology, pore size distribution, thermal conductivity of GDLs were examined using laser interferometer, Goniometer, SEM, porosimetry and thermal conductivity analyzer respectively. The GDLs were evaluated in single cell PEMFC under various operating conditions of temperature and relative humidity (RH) using air as oxidant. Electrodes were prepared with different PUREBLACK® and poly-tetrafluoroethylene (PTFE) content in the diffusion layer and maintaining catalytic layer with a Pt-loading (0.4 mg cm-2). In the study, a 73.16 wt.% level of PB and 34 wt.% level of PTFE was the optimal compositions for GDL at 70 °C for 70% RH under air atmosphere.
For most electrochemical processes the oxygen reduction is very vita reaction. Pt loading in the electrocatalyst contributes towards the total cost of electrochemical devices. Reducing the Pt loading in electrocatalysts with high efficiency is important for the development of fuel cell technologies. To this end, this thesis work reports the approach to lower down the Pt loading in electrocatalyst based on N-doped carbon nanotubes derived from Zeolitic Imidazolate Frameworks (ZIF-67) for oxygen reduction. This electrocatalyst perform with higher electrocatalytic activity and stability for oxygen reduction in fuel cell testing. The electrochemical properties are mainly due to the synergistic effect from N-doped carbon nanotubes derived from ZIF and Pt loading. The strategy with low Pt loading forecasts in emerging highly active and less expensive electrocatalysts in electrochemical energy devices.
This thesis focuses on: (i) methods to obtain greater power density by optimizing content of wet-proofing agent (PTFE) and fine-grained, hydrophobic, microporous layer (MPL); (ii) modeling full factorial analysis of PEMFC for evaluation with experimental results and predicting further improvements in performance; (iii) methods to obtain high levels of performance with low Pt loading electrodes based on N-doped carbon nanotubes derived from ZIF-67 and Pt.
For most electrochemical processes the oxygen reduction is very vita reaction. Pt loading in the electrocatalyst contributes towards the total cost of electrochemical devices. Reducing the Pt loading in electrocatalysts with high efficiency is important for the development of fuel cell technologies. To this end, this thesis work reports the approach to lower down the Pt loading in electrocatalyst based on N-doped carbon nanotubes derived from Zeolitic Imidazolate Frameworks (ZIF-67) for oxygen reduction. This electrocatalyst perform with higher electrocatalytic activity and stability for oxygen reduction in fuel cell testing. The electrochemical properties are mainly due to the synergistic effect from N-doped carbon nanotubes derived from ZIF and Pt loading. The strategy with low Pt loading forecasts in emerging highly active and less expensive electrocatalysts in electrochemical energy devices.
This thesis focuses on: (i) methods to obtain greater power density by optimizing content of wet-proofing agent (PTFE) and fine-grained, hydrophobic, microporous layer (MPL); (ii) modeling full factorial analysis of PEMFC for evaluation with experimental results and predicting further improvements in performance; (iii) methods to obtain high levels of performance with low Pt loading electrodes based on N-doped carbon nanotubes derived from ZIF-67 and Pt.
ContributorsKasat, Harshal Anil (Author) / Kannan, Arunachalana (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Arizona State University (Publisher)
Created2016
Description
Concentrating solar thermal power systems gained a wide interest for a long time to serve as a renewable and sustainable alternate source of energy. While the optimization and modification are ongoing, focused generally on solar power systems to provide solar-electrical energy or solar-thermal energy, the production process of Ordinary Portland Cement (OPC) has not changed over the past century. A linear refractive Fresnel lens application in cement production process is investigated in this research to provide the thermal power required to raise the temperature of lime up to 623 K (350C) with zero carbon emissions for stage two in a new proposed two-stage production process. The location is considered to be Phoenix, Arizona, with a linear refractive Fresnel lens facing south, tilted 33.45 equaling the location latitude, and concentrating solar beam radiation on an evacuated tube collector with tracking system continuously rotating about the north-south axis. The mathematical analysis showed promising results based on averaged monthly values representing an average hourly useful thermal power and receiver temperature during day-light hours for each month throughout the year. The maximum average hourly useful thermal power throughout the year was obtained for June as 33 kWth m-2 with a maximum receiver temperature achieved of 786 K (513C), and the minimum useful thermal power obtained during the month of December with 27 kWth m-2 and a minimum receiver temperature of 701 K (428C).
ContributorsAlkhuwaiteem, Mohammad (Author) / Phelan, Patrick (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2021
Description
In this study, the stereolithography (SLA) 3D printing method is used to manufacture honeycomb-shaped flat sorbents that can capture CO2 from the air. The 3D-printed sorbents were synthesized using polyvinyl alcohol (PVA), propylene glycol, photopolymer resin, and an ion exchange resin (IER). The one-factor-at-a-time (OFAT) design-of-experiment approach was employed to determine the best combination ratio of materials to achieve high moisture swing and a good turnout of printed sorbents. The maximum load limit of the liquid photopolymer resin to enable printability of sorbents was found to be 44%. A series of moisture swing experiments was conducted to investigate the adsorption and desorption performance of the 3D-printed sorbents and compare them with the performance of IER samples prepared by a conventional approach. Results from these experiments conducted indicate that the printed sorbents showed less CO2 adsorptive characteristics compared to the conventional IER sample. It is proposed for future research that a liquid photopolymer resin made up of an IER be synthesized in order to improve the CO2-capturing ability of manufactured sorbents.
ContributorsObeng-Ampomah, Terry (Author) / Phelan, Patrick (Thesis advisor) / Lackner, Klaus (Committee member) / Shuaib, Abdelrahman (Committee member) / Arizona State University (Publisher)
Created2020
Description
About 20-50% of industrial processes energy is lost as waste heat in their operations. The thermal hydraulic engine relies on the thermodynamic properties of supercritical carbon dioxide (CO2) to efficiently perform work. Carbon dioxide possesses great properties that makes it a safe working fluid for the engine’s applications. This research aims to preliminarily investigate the actual efficiency which can be obtained through experimental data and compare that to the Carnot or theoretical maximum efficiency. The actual efficiency is investigated through three approaches. However, only the efficiency results from the second method are validated since the other approaches are based on a complete actual cycle which was not achieved for the engine. The efficiency of the thermal hydraulic engine is found to be in the range of 0.5% to 2.2% based on the second method which relies on the boundary work by the piston. The heating and cooling phases of the engine’s operation are viewed on both the T-s (temperature-entropy) and p-v (pressure-volume) diagrams. The Carnot efficiency is also found to be 13.7% from a temperature difference of 46.20C based on the measured experimental data. It is recommended that the thermodynamic cycle and efficiency investigation be repeated using an improved heat exchanger design to reduce energy losses and gains during both the heating and cooling phases. The temperature of CO2 can be measured through direct contact with the thermocouple and pressure measurements can be improved using a digital pressure transducer for the thermodynamic cycle investigation.
ContributorsManford, David (Author) / Phelan, Patrick (Thesis advisor) / Calhoun, Ronald (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Arizona State University (Publisher)
Created2020