Theses and Dissertations
This collection includes both ASU Theses and Dissertations, submitted by graduate students, and the Barrett, Honors College theses submitted by undergraduate students.
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- Creators: Aguayo, Matthew Joseph
- Creators: Hall, Asha
Description
Phase change materials (PCMs) are combined sensible-and-latent thermal energy storage materials that can be used to store and dissipate energy in the form of heat. PCMs incorporated into wall-element systems have been well-studied with respect to energy efficiency of building envelopes. New applications of PCMs in infrastructural concrete, e.g., for mitigating early-age cracking and freeze-and-thaw induced damage, have also been proposed. Hence, the focus of this dissertation is to develop a detailed understanding of the physic-chemical and thermo-mechanical characteristics of cementitious systems and novel coating systems for wall-elements containing PCM. The initial phase of this work assesses the influence of interface properties and inter-inclusion interactions between microencapsulated PCM, macroencapsulated PCM, and the cementitious matrix. The fact that these inclusions within the composites are by themselves heterogeneous, and contain multiple components necessitate careful application of models to predict the thermal properties. The next phase observes the influence of PCM inclusions on the fracture and fatigue behavior of PCM-cementitious composites. The compliant nature of the inclusion creates less variability in the fatigue life for these composites subjected to cyclic loading. The incorporation of small amounts of PCM is found to slightly improve the fracture properties compared to PCM free cementitious composites. Inelastic deformations at the crack-tip in the direction of crack opening are influenced by the microscale PCM inclusions. After initial laboratory characterization of the microstructure and evaluation of the thermo-mechanical performance of these systems, field scale applicability and performance were evaluated. Wireless temperature and strain sensors for smart monitoring were embedded within a conventional portland cement concrete pavement (PCCP) and a thermal control smart concrete pavement (TCSCP) containing PCM. The TCSCP exhibited enhanced thermal performance over multiple heating and cooling cycles. PCCP showed significant shrinkage behavior as a result of compressive strains in the reinforcement that were twice that of the TCSCP. For building applications, novel PCM-composites coatings were developed to improve and extend the thermal efficiency. These coatings demonstrated a delay in temperature by up to four hours and were found to be more cost-effective than traditional building insulating materials.
The results of this work prove the feasibility of PCMs as a temperature-regulating technology. Not only do PCMs reduce and control the temperature within cementitious systems without affecting the rate of early property development but they can also be used as an auto-adaptive technology capable of improving the thermal performance of building envelopes.
The results of this work prove the feasibility of PCMs as a temperature-regulating technology. Not only do PCMs reduce and control the temperature within cementitious systems without affecting the rate of early property development but they can also be used as an auto-adaptive technology capable of improving the thermal performance of building envelopes.
ContributorsAguayo, Matthew Joseph (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Underwood, Benjamin (Committee member) / Liu, Yongming (Committee member) / Arizona State University (Publisher)
Created2018
Description
Fiber reinforced composites are rapidly replacing conventional metallic or polymeric materials as materials of choice in a myriad of applications across a wide range of industries. The relatively low weight, high strength, high stiffness, and a variety of thermal and mechanical environmental and loading capabilities are in part what make composite materials so appealing to material experts and design engineers. Additionally, fiber reinforced composites are highly tailorable and customized composite materials and structures can be readily designed for specific applications including those requiring particular directional material properties, fatigue resistance, damage tolerance, high temperature capabilities, or resistance to environmental degradation due to humidity and oxidation. The desirable properties of fiber reinforced composites arise from the strategic combination of multiple constituents to form a new composite material. However, the significant material anisotropy that occurs as a result of combining multiple constituents, each with different directional thermal and mechanical properties, complicates material analysis and remains a major impediment to fully understanding composite deformation and damage behavior. As a result, composite materials, especially specialized composites such as ceramic matrix composites and various multifunctional composites, are not utilized to their fullest potential. In the research presented in this dissertation, the deformation and damage behavior of several fiber reinforced composite systems were investigated. The damage accumulation and propagation behavior of carbon fiber reinforced polymer (CFRP) composites under complex in-phase biaxial fatigue loading conditions was investigated and the early stage damage and microscale damage were correlated to the eventual fatigue failure behavior and macroscale damage mechanisms. The temperature-dependent deformation and damage response of woven ceramic matrix composites (CMCs) reinforced with carbon and silicon carbide fibers was also studied. A fracture mechanics-informed continuum damage model was developed to capture the brittle damage behavior of the ceramic matrix. A multiscale thermomechanical simulation framework, consisting of cooldown simulations to capture a realistic material initial state and subsequent mechanical loading simulations to capture the temperature-dependent nonlinear stress-strain behavior, was also developed. The methodologies and results presented in this research represent substantial progress toward increasing understanding of the deformation and damage behavior of some key fiber reinforced composite materials.
ContributorsSkinner, Travis Dale (Author) / Chattopadhyay, Aditi (Thesis advisor) / Hall, Asha (Committee member) / Liu, Yongming (Committee member) / Jiao, Yang (Committee member) / Yekani-Fard, Masoud (Committee member) / Arizona State University (Publisher)
Created2021