Theses and Dissertations
This collection includes both ASU Theses and Dissertations, submitted by graduate students, and the Barrett, Honors College theses submitted by undergraduate students.
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- All Subjects: Phase change materials
- Creators: Phelan, Patrick
Description
The rapid progress of solution-phase synthesis has led colloidal nanocrystals one of the most versatile nanoscale materials, provided opportunities to tailor material's properties, and boosted related technological innovations. Colloidal nanocrystal-based materials have been demonstrated success in a variety of applications, such as LEDs, electronics, solar cells and thermoelectrics. In each of these applications, the thermal transport property plays a big role. An undesirable temperature rise due to inefficient heat dissipation could lead to deleterious effects on devices' performance and lifetime. Hence, the first project is focused on investigating the thermal transport in colloidal nanocrystal solids. This study answers the question that how the molecular structure of nanocrystals affect the thermal transport, and provides insights for future device designs. In particular, PbS nanocrystals is used as a monitoring system, and the core diameter, ligand length and ligand binding group are systematically varied to study the corresponding effect on thermal transport.
Next, a fundamental study is presented on the phase stability and solid-liquid transformation of metallic (In, Sn and Bi) colloidal nanocrystals. Although the phase change of nanoparticles has been a long-standing research topic, the melting behavior of colloidal nanocrytstals is largely unexplored. In addition, this study is of practical importance to nanocrystal-based applications that operate at elevated temperatures. Embedding colloidal nanocrystals into thermally-stable polymer matrices allows preserving nanocrystal size throughout melt-freeze cycles, and therefore enabling observation of stable melting features. Size-dependent melting temperature, melting enthalpy and melting entropy have all been measured and discussed.
In the next two chapters, focus has been switched to developing colloidal nanocrystal-based phase change composites for thermal energy storage applications. In Chapter 4, a polymer matrix phase change nanocomposite has been created. In this composite, the melting temperature and energy density could be independently controlled by tuning nanocrystal diameter and volume fractions. In Chapter 5, a solution-phase synthesis on metal matrix-metal nanocrytal composite is presented. This approach enables excellent morphological control over nanocrystals and demonstrated a phase change composite with a thermal conductivity 2 - 3 orders of magnitude greater than typical phase change materials, such as organics and molten salts.
Next, a fundamental study is presented on the phase stability and solid-liquid transformation of metallic (In, Sn and Bi) colloidal nanocrystals. Although the phase change of nanoparticles has been a long-standing research topic, the melting behavior of colloidal nanocrytstals is largely unexplored. In addition, this study is of practical importance to nanocrystal-based applications that operate at elevated temperatures. Embedding colloidal nanocrystals into thermally-stable polymer matrices allows preserving nanocrystal size throughout melt-freeze cycles, and therefore enabling observation of stable melting features. Size-dependent melting temperature, melting enthalpy and melting entropy have all been measured and discussed.
In the next two chapters, focus has been switched to developing colloidal nanocrystal-based phase change composites for thermal energy storage applications. In Chapter 4, a polymer matrix phase change nanocomposite has been created. In this composite, the melting temperature and energy density could be independently controlled by tuning nanocrystal diameter and volume fractions. In Chapter 5, a solution-phase synthesis on metal matrix-metal nanocrytal composite is presented. This approach enables excellent morphological control over nanocrystals and demonstrated a phase change composite with a thermal conductivity 2 - 3 orders of magnitude greater than typical phase change materials, such as organics and molten salts.
ContributorsLiu, Minglu (Author) / Wang, Robert Y (Thesis advisor) / Wang, Liping (Committee member) / Rykaczewski, Konrad (Committee member) / Phelan, Patrick (Committee member) / Dai, Lenore (Committee member) / Arizona State University (Publisher)
Created2015
Description
In recent years, 40% of the total world energy consumption and greenhouse gas emissions is because of buildings. Out of that 60% of building energy consumption is due to HVAC systems. Under current trends these values will increase in coming years. So, it is important to identify passive cooling or heating technologies to meet this need. The concept of thermal energy storage (TES), as noted by many authors, is a promising way to rectify indoor temperature fluctuations. Due to its high energy density and the use of latent energy, Phase Change Materials (PCMs) are an efficient choice to use as TES. A question that has not satisfactorily been addressed, however, is the optimum location of PCM. In other words, given a constant PCM mass, where is the best location for it in a building? This thesis addresses this question by positioning PCM to obtain maximum energy savings and peak time delay. This study is divided into three parts. The first part is to understand the thermal behavior of building surfaces, using EnergyPlus software. For analysis, a commercial prototype building model for a small office in Phoenix, provided by the U.S. Department of Energy, is applied and the weather location file for Phoenix, Arizona is also used. The second part is to justify the best location, which is obtained from EnergyPlus, using a transient grey box building model. For that we have developed a Resistance-Capacitance (RC) thermal network and studied the thermal profile of a building in Phoenix. The final part is to find the best location for PCMs in buildings using EnergyPlus software. In this part, the mass of PCM used in each location remains unchanged. This part also includes the impact of the PCM mass on the optimized location and how the peak shift varies. From the analysis, it is observed that the ceiling is the best location to install PCM for yielding the maximum reduction in HVAC energy consumption for a hot, arid climate like Phoenix.
ContributorsPrem Anand Jayaprabha, Jyothis Anand (Author) / Phelan, Patrick (Thesis advisor) / Wang, Robert (Committee member) / Parrish, Kristen (Committee member) / Arizona State University (Publisher)
Created2018