Theses and Dissertations
This collection includes both ASU Theses and Dissertations, submitted by graduate students, and the Barrett, Honors College theses submitted by undergraduate students.
Filtering by
- All Subjects: solar
- Creators: Phelan, Patrick
This dissertation first discusses the use of gold nanowires as narrow-band selective metamaterial absorbers. An investigation into plasmonic localized heating indicated that film-coupled gold nanoparticles exhibit tunable selective absorption based on the size of the nanoparticles. By using anodized aluminum oxide templates, aluminum nanodisc narrow-band absorbers were fabricated. A metrology instrument to measure the reflectance and transmittance of micro-scale samples was also developed and used to measure the reflectance of the aluminum nanodisc absorbers (220 µm diameter area). Tuning of the resonance wavelengths of these absorbers can be achieved through changing their geometry. Broadband absorption can be achieved by using a combination of geometries for these metamaterials which would facilitate their use as solar absorbers.
Recently, solar energy harvesting has become a topic of considerable research investigation due to it being an environmentally conscious alternative to fossil fuels. The next section discusses the steady-state temperature measurement of a lab-scale multilayer solar absorber, named metafilm. A lab-scale experimental setup is developed to characterize the solar thermal performance of selective solar absorbers. Under a concentration factor of 20.3 suns, a steady-state temperature of ~500 degrees Celsius was achieved for the metafilm compared to 375 degrees Celsius for a commercial black absorber under the same conditions. Thermal durability testing showed that the metafilm could withstand up to 700 degrees Celsius in vacuum conditions and up to 400 degrees Celsius in atmospheric conditions with little degradation of its optical and radiative properties. Moreover, cost analysis of the metafilm found it to cost significantly less ($2.22 per square meter) than commercial solar coatings ($5.41-100 per square meter).
Finally, this dissertation concludes with recommendations for further studies like using these selective metamaterials and metafilms as absorbers and emitters and using the aluminum nanodiscs on glass as selective filters for photovoltaic cells to enhance solar thermophotovoltaic energy conversion.
Water heaters that are manufactured for swimming pools come in several forms, most of which require an electrical input for a source of power. Passive-circulation systems, however, require no electrical power input because fluid circulation occurs as a result of thermal gradients. In solar-based systems, thermal gradients are developed by energy collected from sunlight. The combination of solar collection and passive circulation yields a system in which fluids, particularly water, are heated and circulated without need of assistance from external mechanical or electrical sources. The design of such a system was adapted from that of forced-circulation solar collector systems, as were the equations describing its thermodynamic properties. The design was developed based on such constraints as material corrosion resistance, overall system cost, and location-controlled size limitations. The thermodynamic description of the designed system was adjusted on the basis of the designed system’s physical aspects, such as the configuration and material of each component within the solar collector. Numerical analysis performed with the altered thermodynamic equations projected a total energy gain of 7.39 W between 9:00 and 10:00 A.M. and a total energy gain of 13.12 W between 4:00 and 5:00 P.M. The temperature of heated water exiting the collector system was projected to be 17.62°C in the morning and 25.56°C in the afternoon. The morning projection utilized an initial fluid temperature of 12°C and an ambient air temperature of 13°C, while the afternoon projection utilized an initial fluid temperature of 17°C and an ambient air temperature of 22°C. Field testing of the designed passive thermosyphon solar collector system was performed over a period of about one month with one temperature measurement taken at the collector outlet in the morning and another taken in the afternoon. For an ambient air temperature of 13°C, the linear regression developed from the morning dataset yielded an outlet water temperature of 20°C and that for the afternoon dataset yielded an outlet water temperature of 39°C for an ambient air temperature of 17°C. The percentage error between the projected and measured results was 13.51% for the morning period and 52.58% for the afternoon period. Numerical simulation and field data demonstrated that while the collector system operated successfully, its effects were limited to the volume of water immediately surrounding the outlet of the system; the rate of circulation within the system was too low for there to be a meaningful increase in the temperature of the water body at large. The stated results demonstrate that while the particular configuration of passive circulation solar collection technology developed in this instance is capable of transferring solar thermal energy to water without additional energy sources, significant modifications are necessary in order to improve the effectiveness of the technology. Such changes may come from improvements in material availability or alterations to the configuration of components of the collector system.