Theses and Dissertations
This collection includes both ASU Theses and Dissertations, submitted by graduate students, and the Barrett, Honors College theses submitted by undergraduate students.
Displaying 1 - 3 of 3
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- All Subjects: Environmental engineering
- Creators: Vivoni, Enrique
Description
The National Research Council 2011 report lists quantifying the extent of de facto (or unplanned) potable reuse in the U.S. as the top research need associated with assessing the potential for expanding the nations water supply through reuse of municipal wastewater. Efforts to identify the significance and potential health impacts of de facto water reuse are impeded by out dated information regarding the contribution of municipal wastewater effluent to potable water supplies. This project aims to answer this research need. The overall goal of the this project is to quantify the extent of de facto reuse by developing a model that estimates the amount of wastewater effluent that is present within drinking water treatment plants; and to use the model in conjunction with a survey to help assess public perceptions. The four-step approach to accomplish this goal includes: (1) creating a GIS-based model coupled with Python programming; (2) validating the model with field studies by analyzing sucralose as a wastewater tracer; (3) estimating the percentage of wastewater in raw drinking water sources under varying streamflow conditions; (4) and assessing through a social survey the perceptions of the general public relating to acceptance and occurrence of de facto reuse. The resulting De Facto Reuse in our Nations Consumable Supply (DRINCS) Model, estimates that treated municipal wastewater is present at nearly 50% of drinking water treatment plant intake sites serving greater than 10,000 people (N=2,056). Contrary to the high frequency of occurrence, the magnitude of occurrence is relatively low with 50% of impacted intakes yielding less than 1% de facto reuse under average streamflow conditions. Model estimates increase under low flow conditions (modeled by Q95), in several cases treated wastewater makes up 100% of the water supply. De facto reuse occurs at levels that surpass what is publically perceived in the three cities of Atlanta, GA, Philadelphia, PA, and Phoenix, AZ. Respondents with knowledge of de facto reuse occurrence are 10 times more likely to have a high acceptance (greater than 75%) of treated wastewater at their home tap.
ContributorsRice, Jacelyn (Author) / Westerhoff, Paul (Thesis advisor) / Abbaszadegan, Morteza (Committee member) / Vivoni, Enrique (Committee member) / Wutich, Amber (Committee member) / Arizona State University (Publisher)
Created2014
Description
Nitrate, a widespread contaminant in surface water, can cause eutrophication and toxicity to aquatic organisms. To augment the nitrate-removal capacity of constructed wetlands, I applied the H2-based Membrane Biofilm Reactor (MBfR) in a novel configuration called the in situ MBfR (isMBfR). The goal of my thesis is to evaluate and model the nitrate removal performance for a bench-scale isMBfR system.
I operated the bench-scale isMBfR system in 7 different conditions to evaluate its nitrate-removal performance. When I supplied H2 with the isMBfR (stages 1 - 6), I observed at least 70% nitrate removal, and almost all of the denitrification occurred in the "MBfR zone." When I stopped the H2 supply in stage 7, the nitrate-removal percentage immediately dropped from 92% (stage 6) to 11% (stage 7). Denitrification raised the pH of the bulk liquid to ~ 9.0 for the first 6 stages, but the high pH did not impair the performance of the denitrifiers. Microbial community analyses indicated that DB were the dominant bacteria in the "MBfR zone," while photosynthetic Cyanobacteria were dominant in the "photo-zone".
I derived stoichiometric relationships among COD, alkalinity, H2, Dissolved Oxygen (DO), and nitrate to model the nitrate removal capacity of the "MBfR zone." The stoichiometric relationships corresponded well to the nitrate-removal capacity for all stages expect stage 3, which was limited by the abundance of Denitrifying Bacteria (DB) so that the H2 supply capacity could not be completely used.
Finally, I analyzed two case studies for the real-world application of the isMBfR to constructed wetlands. Based on the characteristics for the wetlands and the stoichiometric relationships, I designed a feasible operation condition (membrane area and H2 pressure) for each wetland. In both cases, the amount of isMBfR surface area was modest, from 0.022 to 1.2 m2/m3 of wetland volume.
I operated the bench-scale isMBfR system in 7 different conditions to evaluate its nitrate-removal performance. When I supplied H2 with the isMBfR (stages 1 - 6), I observed at least 70% nitrate removal, and almost all of the denitrification occurred in the "MBfR zone." When I stopped the H2 supply in stage 7, the nitrate-removal percentage immediately dropped from 92% (stage 6) to 11% (stage 7). Denitrification raised the pH of the bulk liquid to ~ 9.0 for the first 6 stages, but the high pH did not impair the performance of the denitrifiers. Microbial community analyses indicated that DB were the dominant bacteria in the "MBfR zone," while photosynthetic Cyanobacteria were dominant in the "photo-zone".
I derived stoichiometric relationships among COD, alkalinity, H2, Dissolved Oxygen (DO), and nitrate to model the nitrate removal capacity of the "MBfR zone." The stoichiometric relationships corresponded well to the nitrate-removal capacity for all stages expect stage 3, which was limited by the abundance of Denitrifying Bacteria (DB) so that the H2 supply capacity could not be completely used.
Finally, I analyzed two case studies for the real-world application of the isMBfR to constructed wetlands. Based on the characteristics for the wetlands and the stoichiometric relationships, I designed a feasible operation condition (membrane area and H2 pressure) for each wetland. In both cases, the amount of isMBfR surface area was modest, from 0.022 to 1.2 m2/m3 of wetland volume.
ContributorsLi, Yizhou (Author) / Rittmann, Bruce (Thesis advisor) / Vivoni, Enrique (Committee member) / Krajmalnik-Brown, Rosa (Committee member) / Arizona State University (Publisher)
Created2014
Description
The increasingly recurrent extraordinary flood events in the metropolitan area of Monterrey, Mexico have led to significant stakeholder interest in understanding the hydrologic response of the Santa Catarina watershed to extreme events. This study analyzes a flood mitigation strategy proposed by stakeholders through a participatory workshop and are assessed using two hydrological models: The Hydrological Modeling System (HEC-HMS) and the Triangulated Irregular Network (TIN)-based Real-time Integrated Basin Simulator (tRIBS).
The stakeholder-derived flood mitigation strategy consists of placing new hydraulic infrastructure in addition to the current flood controls in the basin. This is done by simulating three scenarios: (1) evaluate the impact of the current structure, (2) implementing a large dam similar to the Rompepicos dam and (3) the inclusion of three small detention dams. These mitigation strategies are assessed in the context of a major flood event caused by the landfall of Hurricane Alex in July 2010 through a consistent application of the two modeling tools. To do so, spatial information on topography, soil, land cover and meteorological forcing were assembled, quality-controlled and input into each model. Calibration was performed for each model based on streamflow observations and maximum observed reservoir levels from the National Water Commission in Mexico.
Simulation analyses focuses on the differential capability of the two models in capturing the spatial variability in rainfall, topographic conditions, soil hydraulic properties and its effect on the flood response in the presence of the different flood mitigation structures. The implementation of new hydraulic infrastructure is shown to have a positive impact on mitigating the flood peak with a more favorable reduction in the peak at the outlet from the larger dam (16.5% in tRIBS and 23% in HEC-HMS) than the collective effect from the small structures (12% in tRIBS and 10% in HEC-HMS). Furthermore, flood peak mitigation depends strongly on the number and locations of the new dam sites in relation to the spatial distribution of rainfall and flood generation. Comparison of the two modeling approaches complements the analysis of available observations for the flood event and provides a framework within which to derive a multi-model approach for stakeholder-driven solutions.
The stakeholder-derived flood mitigation strategy consists of placing new hydraulic infrastructure in addition to the current flood controls in the basin. This is done by simulating three scenarios: (1) evaluate the impact of the current structure, (2) implementing a large dam similar to the Rompepicos dam and (3) the inclusion of three small detention dams. These mitigation strategies are assessed in the context of a major flood event caused by the landfall of Hurricane Alex in July 2010 through a consistent application of the two modeling tools. To do so, spatial information on topography, soil, land cover and meteorological forcing were assembled, quality-controlled and input into each model. Calibration was performed for each model based on streamflow observations and maximum observed reservoir levels from the National Water Commission in Mexico.
Simulation analyses focuses on the differential capability of the two models in capturing the spatial variability in rainfall, topographic conditions, soil hydraulic properties and its effect on the flood response in the presence of the different flood mitigation structures. The implementation of new hydraulic infrastructure is shown to have a positive impact on mitigating the flood peak with a more favorable reduction in the peak at the outlet from the larger dam (16.5% in tRIBS and 23% in HEC-HMS) than the collective effect from the small structures (12% in tRIBS and 10% in HEC-HMS). Furthermore, flood peak mitigation depends strongly on the number and locations of the new dam sites in relation to the spatial distribution of rainfall and flood generation. Comparison of the two modeling approaches complements the analysis of available observations for the flood event and provides a framework within which to derive a multi-model approach for stakeholder-driven solutions.
ContributorsCázares Rodríguez, Jorge E (Author) / Vivoni, Enrique (Thesis advisor) / Wang, Zhihua (Committee member) / Mays, Larry W. (Committee member) / Arizona State University (Publisher)
Created2016