Theses and Dissertations
This collection includes both ASU Theses and Dissertations, submitted by graduate students, and the Barrett, Honors College theses submitted by undergraduate students.
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- Genre: Doctoral Dissertation
Description
An array of north-striking, left-stepping, active normal faults is situated along the southwestern margin of the Gulf of California. This normal fault system is the marginal fault system of the oblique-divergent plate boundary within the Gulf of California. To better understand the role of upper-crustal processes during development of an obliquely rifted plate margin, gravity surveys were conducted across the normal-fault-bounded basins within the gulf-margin array and, along with optically stimulated luminescence dating of offset surfaces, fault-slip rates were estimated and fault patterns across basins were assessed, providing insight into sedimentary basin evolution. Additionally, detailed geologic and geomorphic maps were constructed along two faults within the system, leading to a more complete understanding of the role of individual normal faults within a larger array. These faults slip at a low rate (0.1-1 mm/yr) and have relatively shallow hanging wall basins (~500-3000 m). Overall, the gulf-margin faults accommodate protracted, distributed deformation at a low rate and provide a minor contribution to overall rifting. Integrating figures with text can lead to greater science learning than when either medium is presented alone. Textbooks, composed of text and graphics, are a primary source of content in most geology classes. It is essential to understand how students approach learning from text and figures in textbook-style learning materials and how the arrangement of the text and figures influences their learning approach. Introductory geology students were eye tracked while learning from textbook-style materials composed of text and graphics. Eye fixation data showed that students spent less time examining the figure than the text, but the students who more frequently examined the figure tended to improve more from the pretest to the posttest. In general, students tended to examine the figure at natural breaks in the reading. Textbook-style materials should, therefore, be formatted to include a number of natural breaks so that learners can pause to inspect the figure without the risk of losing their place in the reading and to provide a chance to process the material in small chunks. Multimedia instructional materials should be designed to support the cognitive processes of the learner.
ContributorsBusch, Melanie M. D (Author) / Arrowsmith, Ramon (Thesis advisor) / Reynolds, Stephen (Thesis advisor) / Chi, Michelene (Committee member) / Semken, Steven (Committee member) / Tyburczy, James (Committee member) / Arizona State University (Publisher)
Created2011
Description
Chemical and mineralogical data from Mars shows that the surface has been chemically weathered on local to regional scales. Chemical trends and the types of chemical weathering products present on the surface and their abundances can elucidate information about past aqueous processes. Thermal-infrared (TIR) data and their respective models are essential for interpreting Martian mineralogy and geologic history. However, previous studies have shown that chemical weathering and the precipitation of fine-grained secondary silicates can adversely affect the accuracy of TIR spectral models. Furthermore, spectral libraries used to identify minerals on the Martian surface lack some important weathering products, including poorly-crystalline aluminosilicates like allophane, thus eliminating their identification in TIR spectral models. It is essential to accurately interpret TIR spectral data from chemically weathered surfaces to understand the evolution of aqueous processes on Mars. Laboratory experiments were performed to improve interpretations of TIR data from weathered surfaces. To test the accuracy of deriving chemistry of weathered rocks from TIR spectroscopy, chemistry was derived from TIR models of weathered basalts from Baynton, Australia and compared to actual weathering rind chemistry. To determine how specific secondary silicates affect the TIR spectroscopy of weathered basalts, mixtures of basaltic minerals and small amounts of secondary silicates were modeled. Poorly-crystalline aluminosilicates were synthesized and their TIR spectra were added to spectral libraries. Regional Thermal Emission Spectrometer (TES) data were modeled using libraries containing these poorly-crystalline aluminosilicates to test for their presence on the Mars. Chemistry derived from models of weathered Baynton basalts is not accurate, but broad chemical weathering trends can be interpreted from the data. TIR models of mineral mixtures show that small amounts of crystalline and amorphous silicate weathering products (2.5-5 wt.%) can be detected in TIR models and can adversely affect modeled plagioclase abundances. Poorly-crystalline aluminosilicates are identified in Northern Acidalia, Solis Planum, and Meridiani. Previous studies have suggested that acid sulfate weathering was the dominant surface alteration process for the past 3.5 billion years; however, the identification of allophane indicates that alteration at near-neutral pH occurred on regional scales and that acid sulfate weathering is not the only weathering process on Mars.
ContributorsRampe, Elizabeth Barger (Author) / Sharp, Thomas G (Thesis advisor) / Christensen, Phillip (Committee member) / Hervig, Richard (Committee member) / Shock, Everett (Committee member) / Williams, Lynda (Committee member) / Arizona State University (Publisher)
Created2011
Description
As the use of engineered nanomaterials (ENMs) in consumer products becomes more common, the amount of ENMs entering wastewater treatment plants (WWTPs) increases. Investigating the fate of ENMs in WWTPs is critical for risk assessment and pollution control. The objectives of this dissertation were to (1) quantify and characterize titanium (Ti) in full-scale wastewater treatment plants, (2) quantify sorption of different ENMs to wastewater biomass in laboratory-scale batch reactors, (3) evaluate the use of a standard, soluble-pollutant sorption test method for quantifying ENM interaction with wastewater biomass, and (4) develop a mechanistic model of a biological wastewater treatment reactor to serve as the basis for modeling nanomaterial fate in WWTPs. Using titanium (Ti) as a model material for the fate of ENMs in WWTPs, Ti concentrations were measured in 10 municipal WWTPs. Ti concentrations in pant influent ranged from 181 to 3000 µg/L, and more than 96% of Ti was removed, with effluent Ti concentrations being less than 25 µg/L. Ti removed from wastewater accumulated in solids at concentrations ranging from 1 to 6 µg Ti/mg solids. Using transmission electron microscopy, spherical titanium oxide nanoparticles with diameters ranging from 4 to 30 nm were found in WWTP effluents, evidence that some nanoscale particles will pass through WWTPs and enter aquatic systems. Batch experiments were conducted to quantify sorption of different ENM types to activated sludge. Percentages of sorption to 400 mg TSS/L biomass ranged from about 10 to 90%, depending on the ENM material and functionalization. Natural organic matter, surfactants, and proteins had a stabilizing effect on most of the ENMs tested. The United States Environmental Protection Agency's standard sorption testing method (OPPTS 835.1110) used for soluble compounds was found to be inapplicable to ENMs, as freeze-dried activated sludge transforms ENMs into stable particles in suspension. In conjunction with experiments, we created a mechanistic model of the microbiological processes in membrane bioreactors to predict MBR, extended and modified this model to predict the fate of soluble micropollutants, and then discussed how the micropollutant fate model could be used to predict the fate of nanomaterials in wastewater treatment plants.
ContributorsKiser, Mehlika Ayla (Author) / Westerhoff, Paul K (Thesis advisor) / Rittmann, Bruce E. (Committee member) / Hristovski, Kiril D (Committee member) / Arizona State University (Publisher)
Created2011
Description
It is estimated that wind induced soil transports more than 500 x 106 metric tons of fugitive dust annually. Soil erosion has negative effects on human health, the productivity of farms, and the quality of surface waters. A variety of different polymer stabilizers are available on the market for fugitive dust control. Most of these polymer stabilizers are expensive synthetic polymer products. Their adverse effects and expense usually limits their use. Biopolymers provide a potential alternative to synthetic polymers. They can provide dust abatement by encapsulating soil particles and creating a binding network throughout the treated area. This research into the effectiveness of biopolymers for fugitive dust control involved three phases. Phase I included proof of concept tests. Phase II included carrying out the tests in a wind tunnel. Phase III consisted of conducting the experiments in the field. Proof of concept tests showed that biopolymers have the potential to reduce soil erosion and fugitive dust transport. Wind tunnel tests on two candidate biopolymers, xanthan and chitosan, showed that there is a proportional relationship between biopolymer application rates and threshold wind velocities. The wind tunnel tests also showed that xanthan gum is more successful in the field than chitosan. The field tests showed that xanthan gum was effective at controlling soil erosion. However, the chitosan field data was inconsistent with the xanthan data and field data on bare soil.
ContributorsAlsanad, Abdullah (Author) / Kavazanjian, Edward (Thesis advisor) / Edwards, David (Committee member) / Zapata, Claudia (Committee member) / Arizona State University (Publisher)
Created2011
Description
The San Andreas Fault (SAF) is the primary structure within a system of faults accommodating motion between the North American and Pacific plates. Physical models of faulting and characterizations of seismic hazard are informed by investigations of paleoseismology, slip distribution, and slip rate. The impact of earthquakes on people is due in large part to social vulnerability. This dissertation contributes an analysis about the relationships between earthquake hazard and social vulnerability in Los Angeles, CA and investigations of paleoseismology and fault scarp array complexity on the central SAF. Analysis of fault scarp array geometry and morphology using 0.5 m digital elevation models along 122 km of the central SAF reveals significant variation in the complexity of SAF structure. Scarp trace complexity is measured by scarp separation, changes in strike, fault trace gaps, and scarp length per SAF kilometer. Geometrical complexity in fault scarp arrays indicates that the central SAF can be grouped into seven segments. Segment boundaries are controlled by interactions with subsidiary faults. Investigation of an offset channel at Parkfield, CA yields a late Holocene slip rate of 26.2 +6.4/- 4.3 mm/yr. This rate is lower than geologic measurements on the Carrizo section of the SAF and rates implied by far-field geodesy. However, it is consistent with historical observations of slip at Parkfield. Paleoseismology at Parkfield indicates that large earthquakes are absent from the stratigraphic record for at least a millennia. Together these observations imply that the amount of plate boundary slip accommodated by the main SAF varies along strike. Contrary to most environmental justice analyses showing that vulnerable populations are spatially-tied to environmental hazards, geospatial analyses relating social vulnerability and earthquake hazard in southern California show that these groups are not disproportionately exposed to the areas of greatest hazard. Instead, park and green space is linked to earthquake hazard through fault zone regulation. In Los Angeles, a parks poor city, the distribution of social vulnerability is strongly tied to a lack of park space. Thus, people with access to financial and political resources strive to live in neighborhoods with parks, even in the face of forewarned risk.
ContributorsToké, Nathan A (Author) / Arrowsmith, J R (Thesis advisor) / Boone, Christopher G (Committee member) / Heimsath, Arjun M (Committee member) / Shock, Everett L (Committee member) / Whipple, Kelin X (Committee member) / Arizona State University (Publisher)
Created2011
Description
Lipids and free fatty acids (FFA) from cyanobacterium Synechocystis can be used for biofuel (e.g. biodiesel or renewable diesel) production. In order to utilize and scale up this technique, downstream processes including culturing and harvest, cell disruption, and extraction were studied. Several solvents/solvent systems were screened for lipid extraction from Synechocystis. Chloroform + methanol-based Folch and Bligh & Dyer methods were proved to be "gold standard" for small-scale analysis due to their highest lipid recoveries that were confirmed by their penetration of the cell membranes, higher polarity, and stronger interaction with hydrogen bonds. Less toxic solvents, such as methanol and MTBE, or direct transesterification of biomass (without pre-extraction step) gave only slightly lower lipid-extraction yields and can be considered for large-scale application. Sustained exposure to high and low temperature extremes severely lowered the biomass and lipid productivity. Temperature stress also triggered changes of lipid quality such as the degree of unsaturation; thus, it affected the productivities and quality of Synechocystis-derived biofuel. Pulsed electric field (PEF) was evaluated for cell disruption prior to lipid extraction. A treatment intensity > 35 kWh/m3 caused significant damage to the plasma membrane, cell wall, and thylakoid membrane, and it even led to complete disruption of some cells into fragments. Treatment by PEF enhanced the potential for the low-toxicity solvent isopropanol to access lipid molecules during subsequent solvent extraction, leading to lower usage of isopropanol for the same extraction efficiency. Other cell-disruption methods also were tested. Distinct disruption effects to the cell envelope, plasma membrane, and thylakoid membranes were observed that were related to extraction efficiency. Microwave and ultrasound had significant enhancement of lipid extraction. Autoclaving, ultrasound, and French press caused significant release of lipid into the medium, which may increase solvent usage and make medium recycling difficult. Production of excreted FFA by mutant Synechocystis has the potential of reducing the complexity of downstream processing. Major problems, such as FFA precipitation and biodegradation by scavengers, account for FFA loss in operation. Even a low concentration of FFA scavengers could consume FFA at a high rate that outpaced FFA production rate. Potential strategies to overcome FFA loss include high pH, adsorptive resin, and sterilization techniques.
ContributorsSheng, Chieh (Author) / Rittmann, Bruce E. (Thesis advisor) / Westerhoff, Paul (Committee member) / Vermaas, Willem (Committee member) / Arizona State University (Publisher)
Created2011
Description
Geoscience educators commonly teach geology by projecting a photograph in front of the class. Geologic photographs often contain animals, people, and inanimate objects that help convey the scale of features in the photograph. Although scale items seem innocuous to instructors and other experts, the presence of such items is distracting and has a profound effect on student learning behavior. To evaluate how students visually interact with distracting scale items in photographs and to determine if cueing or signaling is an effective means to direct students to pertinent information, students were eye tracked while looking at geologically-rich photographs. Eye-tracking data revealed that learners primarily looked at the center of an image, focused on faces of both humans and animals if they were present, and repeatedly returned to looking at the scale item (distractor) for the duration an image was displayed. The presence of a distractor caused learners to look at less of an image than when a distractor was not present. Learners who received signaling tended to look at the distractor less, look at the geology more, and surveyed more of the photograph than learners who did not receive signaling. The San Antonio area in the southern part of the Baja California Peninsula is host to hydrothermal gold deposits. A field study, including drill-core analysis and detailed geologic mapping, was conducted to determine the types of mineralization present, the types of structures present, and the relationship between the two. This investigation revealed that two phases of mineralization have occurred in the area; the first is hydrothermal deposition of gold associated with sulfide deposits and the second is oxidation of sulfides to hematite, goethite, and jarosite. Mineralization varies as a function of depth, whereas sulfides occurring at depth, while minerals indicative of oxidation are limited to shallow depths. A structural analysis revealed that the oldest structures in the study area include low-grade to medium-grade metamorphic foliation and ductile mylonitic shear zones overprinted by brittle-ductile mylonitic fabrics, which were later overprinted by brittle deformation. Both primary and secondary mineralization in the area is restricted to the later brittle features. Alteration-bearing structures have an average NNW strike consistent with northeast-southwest-directed extension, whereas unaltered structures have an average NNE strike consistent with more recent northwest-southeast-directed extension.
ContributorsCoyan, Joshua (Author) / Reynolds, Stephen (Thesis advisor) / Arrowsmith, Ramon (Committee member) / Chi, Michelene (Committee member) / Piburn, Michael (Committee member) / Semken, Steven (Committee member) / Arizona State University (Publisher)
Created2011
Description
Sedimentary basins in the Afar Depression, Ethiopia archive the progression of continental breakup, record regional changes in east African climate and volcanism, and host what are arguably the most important fossiliferous strata for studying early human evolution and innovation. Significant changes in rift tectonics, climate, and faunal assemblages occur between 3-2.5 million years ago (Ma), but sediments spanning this time period are sparse. In this dissertation, I present the results of a geologic investigation targeting sediments between 3-2.5 Ma in the central and eastern Ledi Geraru (CLG and ELG) field areas in the lower Awash Valley, using a combination of geologic mapping, stratigraphy, and tephra chemistry and dating. At Gulfaytu in CLG, I mapped the northern-most outcrops of the hominin-bearing Hadar Formation (3.8-2.9 Ma), a 20 m-thick section of flat-lying lacustrine sediments containing 8 new tephras that directly overlie the widespread BKT-2 marker beds (2.95 Ma). Paleolake Hadar persisted after 2.95 Ma, and the presence and characteristics of the Busidima Formation (2.7-0.016 Ma) indicates Gulfaytu was affected by a reversal in depositional basin polarity. Combined with regional and geophysical data, I show the Hadar Formation underlying CLG is >300 m thick, supporting the hypothesis that it was the lower Awash Pliocene depocenter. At ELG, I mapped >300 m of sediments spanning 3.0-2.45 Ma. These sediments coarsen upward and show a progression from fluctuating lake conditions to fluvial landscapes and widespread soil development. This is consistent with the temporal change in depositional environments observed elsewhere in the lower Awash Valley, and suggests that these strata are correlative with the Hadar Formation. Furthermore, the strata and basalts at ELG are highly faulted, and overprinted by shifting extension directions attributed to the northern migration of the Afar triple junction. The presence of fossiliferous beds and stone tools makes ELG a high-priority target for anthropological and archaeological research. This study provides a new temporally-calibrated and high-resolution record of deposition, volcanism, and faulting patterns during a period of significant change in the Afar.
ContributorsDiMaggio, Erin Nicole (Author) / Arrowsmith, J Ramon (Thesis advisor) / Whipple, Kelin X (Committee member) / Heimsath, Arjun M (Committee member) / Clarke, Amanda B (Committee member) / Reed, Kaye E (Committee member) / Arizona State University (Publisher)
Created2013
Description
Lunar Reconnaissance Orbiter (LRO) and MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft missions provide new data for investigating the youngest impact craters on Mercury and the Moon, along with lunar volcanic end-members: ancient silicic and young basaltic volcanism. The LRO Wide Angle Camera (WAC) and Narrow Angle Camera (NAC) in-flight absolute radiometric calibration used ground-based Robotic Lunar Observatory and Hubble Space Telescope data as standards. In-flight radiometric calibration is a small aspect of the entire calibration process but an important improvement upon the pre-flight measurements. Calibrated reflectance data are essential for comparing images from LRO to missions like MESSENGER, thus enabling science through engineering. Relative regolith optical maturation rates on Mercury and the Moon are estimated by comparing young impact crater densities and impact ejecta reflectance, thus empirically testing previous models of faster rates for Mercury relative to the Moon. Regolith maturation due to micrometeorite impacts and solar wind sputtering modies UV-VIS-NIR surface spectra, therefore understanding maturation rates is critical for interpreting remote sensing data from airless bodies. Results determined the regolith optical maturation rate on Mercury is 2 to 4 times faster than on the Moon. The Gruithuisen Domes, three lunar silicic volcanoes, represent relatively rare lunar lithologies possibly similar to rock fragments found in the Apollo sample collection. Lunar nonmare silicic volcanism has implications for lunar magmatic evolution. I estimated a rhyolitic composition using morphologic comparisons of the Gruithuisen Domes, measured from NAC 2-meter-per-pixel digital topographic models (DTMs), with terrestrial silicic dome morphologies and laboratory models of viscoplastic dome growth. Small, morphologically sharp irregular mare patches (IMPs) provide evidence for recent lunar volcanism widely distributed across the nearside lunar maria, which has implications for long-lived nearside magmatism. I identified 75 IMPs (100-5000 meters in dimension) in NAC images and DTMs, and determined stratigraphic relationships between units common to all IMPs. Crater counts give model ages from 18-58 Ma, and morphologic comparisons with young lunar features provided an additional age constraint of <100 Ma. The IMPs formed as low-volume basaltic eruptions significantly later than previous evidence of lunar mare basalt volcanism's end (1-1.2 Ga).
ContributorsBraden, Sarah E (Author) / Robinson, Mark S (Thesis advisor) / Bell, James F. (Committee member) / Christensen, Philip R. (Committee member) / Clarke, Amanda B (Committee member) / Lawrence, Samuel J (Committee member) / Arizona State University (Publisher)
Created2013
Description
Impact craters are ubiquitous throughout the Solar System, formed by one of the principal processes responsible for surface modification of terrestrial planets and solid bodies (i.e., asteroids, icy moons). The impact cratering process is well studied, particularly on the Moon and Mercury, where the results remain uncomplicated by atmospheric effects, plate tectonics, or interactions with water and ices. Crater measurements, used to determine relative and absolute ages for geologic units by relating the cumulative crater frequency per unit area to radiometrically-determined ages from returned samples, are sensitive to the solar incidence angle of images used for counts. Earlier work is quantitatively improved by investigating this important effect and showing that absolute model ages are most accurately determined using images with incidence angles between 65° and 80°, and equilibrium crater diameter estimates are most accurate at ~80° incidence angle. A statistical method is developed using crater size-frequencies to distinguish lunar mare age units in the absence of spectral differences. Applied to the Moon, the resulting areal crater densities confidently identify expansive units with >300–500 my age differences, distinguish non-obvious secondaries, and determine that an area >1×104 km2 provides statistically robust crater measurements. This areal crater density method is also applied to the spectrally-homogeneous volcanic northern smooth plains (NSP) on Mercury. Although crater counts and observations of embayed craters indicate that the NSP experienced at least two resurfacing episodes, no observable age units are observed using areal crater density measurements, so smooth plains emplacement occurred over a relatively short timescale (<500 my). For the first time, the distribution of impact melt on Mercury and the Moon are compared at high resolution. Mercurian craters with diameters ≥30 km have a greater areal extent of interior melt deposits than similarly sized lunar craters, a result consistent with melt-generation model predictions. The effects of shaking on compositional sorting within a granular regolith are experimentally tested, demonstrating the possibility of mechanical segregation of particles in the lunar regolith. These results provide at least one explanation toward understanding the inconsistencies between lunar remote sensing datasets and are important for future spacecraft sample return missions.
ContributorsOstrach, Lillian Rose (Author) / Robinson, Mark S (Thesis advisor) / Bell Iii, James F (Committee member) / Christensen, Philip R. (Committee member) / Clarke, Amanda B (Committee member) / Garnero, Edward J (Committee member) / Arizona State University (Publisher)
Created2013