Barrett

Barrett, The Honors College at Arizona State University proudly showcases the work of undergraduate honors students by sharing this collection exclusively with the ASU community.

Barrett accepts high performing, academically engaged undergraduate students and works with them in collaboration with all of the other academic units at Arizona State University. All Barrett students complete a thesis or creative project which is an opportunity to explore an intellectual interest and produce an original piece of scholarly research. The thesis or creative project is supervised and defended in front of a faculty committee. Students are able to engage with professors who are nationally recognized in their fields and committed to working with honors students. Completing a Barrett thesis or creative project is an opportunity for undergraduate honors students to contribute to the ASU academic community in a meaningful way.

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Nanostructured Faujasite Zeolites for Carbon Dioxide Adsorption: Adsorption Equilibrium and Dynamics Modeling

Description
Carbon capture is an essential way to reduce greenhouse gas emissions. One way to decrease the emissions is through the use of adsorbents such as zeolites. Dr. Dong-Kyun Seo’s group (School of Molecular Sciences, Arizona State University) synthesized the nanostructured faujasite (NaX). The zeolite was characterized using Scanning Electron Microscopy…

Carbon capture is an essential way to reduce greenhouse gas emissions. One way to decrease the emissions is through the use of adsorbents such as zeolites. Dr. Dong-Kyun Seo’s group (School of Molecular Sciences, Arizona State University) synthesized the nanostructured faujasite (NaX). The zeolite was characterized using Scanning Electron Microscopy (SEM) and the physisorption properties were determined using ASAP 2020. ASAP 2020 tests of the nano-zeolite pellets at 77K in a liquid N2 bath determined the BET surface area of 547.1 m2/mol, T-plot micropore volume of 0.2257 cm3/g, and an adsorption average pore width of 5.9 Å. The adsorption isotherm (equilibrium) of CH4, N2, and CO2 were measured at 25ºC. Adsorption isotherm experiments concluded that the linear isotherm was the best fit for N2, and CH4 and the Sips isotherm was a better fit than the Langmuir and Freundlich isotherm for CO2. At 25ºC and 1 atm the zeolite capacity for CO2 is 4.3339 mmol/g, 0.1948 mmol/g for CH4, and 0.3534 mmol/g for N2. The zeolite has a higher CO2 capacity than the conventional NaX zeolite. Breakthrough experiments were performed in a fixed bed 22in, 0.5 in packing height and width at 1 atm and 298 K with nano-zeolite pellets. The gas chromatographer tested and recorded the data every two minutes with a flow rate of 10 cm3/min for N2 and 10 cm3/min CO2. Breakthrough simulations of the zeolite in a fixed bed adsorber column were conducted on MATLAB utilizing varying pressures, flow rates, and fed ratios of various CO2, N2 and CH4. Simulations using ideal adsorbed solution theory (IAST) calculations determined that the selectivity of CO2 in flue gas (15% CO2 + 85% N2) is 571.79 at 1 MPa, significantly higher than commercial zeolites and literature. The nanostructured faujasite zeolite appears to be a very promising adsorbent for CO2/N2 capture from flue gas and the separation of CO2/N2.
ContributorsClark, Krysta D. (Author) / Deng, Shuguang (Thesis director) / Green, Matthew (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
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A Study of Zeolite Membrane Material Balance and Commercialization Potential

Description
The United States and most of the world is pushing to significantly reduce carbon emissions, with many countries intent on fostering carbon negative energy processes to offset ozone depletion and climate changes. 30% of the U.S. greenhouse gas emissions are generated from the combustion of fossil fuels to generate electricity1.…

The United States and most of the world is pushing to significantly reduce carbon emissions, with many countries intent on fostering carbon negative energy processes to offset ozone depletion and climate changes. 30% of the U.S. greenhouse gas emissions are generated from the combustion of fossil fuels to generate electricity1. Current commercial IGCC carbon capture processes employ a capital and operating cost intensive water-gas shift reaction facilitated by a high temperature reactor followed by a low temperature reactor and an amine absorber to separate the hydrogen and carbon dioxide streams to capture the carbon. Dr. Jerry Y.S. and his laboratory at Arizona State have developed a hydrogen permselective MFI type ZSM-5 zeolite membrane reactor that effectively facilities the water gas shift reaction with high conversion and separates the CO2 and H2 streams during reaction to generate ultrapure retentate and permeate streams. The membrane, formed by secondary free growth, is synthesized on an ultrapure a-alumina membrane support currently purchased from an outside vendor. The purpose of this study was to design an α-alumina support processing plant with capability to supply one full-scale commercial reactor annually with membranes. The design yielded a DCFRoR of 71% for a 20-year project life. A zeolite membrane processing material balance was conducted using alumina support as the raw material. The study showed very low material costs and consumption rates for all materials except a gas used to refine the membrane after processing. The results of both studies were favorable enough to suggest further study.
ContributorsNorman, Taylor Cristine (Author) / Lin, Jerry Y.S. (Thesis director) / Meng, Lie (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
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Adsorptive CO2 Capture from Ambient Air by Zeolite

Description

Carbon capture has been a highly sought-after technology for decades because of its<br/>capabilities to restore atmospheric damage done by greenhouse gasses. Thanks to evolving<br/>separation techniques, carbon capture is becoming more efficient with every new discovery in<br/>the field. Currently the biggest problems that carbon capture are facing is the cost of<br/>manufacturing…

Carbon capture has been a highly sought-after technology for decades because of its<br/>capabilities to restore atmospheric damage done by greenhouse gasses. Thanks to evolving<br/>separation techniques, carbon capture is becoming more efficient with every new discovery in<br/>the field. Currently the biggest problems that carbon capture are facing is the cost of<br/>manufacturing material to aid the process and obtaining ideal conditions for removal of carbon<br/>from air and devising solutions for removal of CO2 in ambient and flue gas conditions.<br/>This Honors Thesis is a continuation of Dr. Shuguang Deng and Dr. Mai Xu’s research<br/>initiative to manufacture and test various zeolitic CO2 removal efficiencies. The goals of this<br/>Honors Thesis are to investigate the adsorption/desorption kinetics and isothermal equilibrium<br/>CO2 capacity of a NaX nanozeolite under ambient air conditions.<br/>What was determined from the following testing was that the zeolite of interest had a<br/>higher adsorption capacity of CO2 at lower temperatures, had a maximum equilibrium quantity<br/>adsorbed of 0.203 mmol/g for CO2 and 0.367 mmol/g of N2, had a maximum breakthrough CO2<br/>capacity of 0.101 mmol of CO2 per gram of zeolite at dry conditions and 298.15K and this<br/>linearly decreased to 0.040 mmol/g at 25% relative humidity.
ContributorsBonelli, Xavier Berlage (Author) / Deng, Shuguang (Thesis director) / Xu, Mai (Committee member) / Chemical Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2021-05