ASU Scholarship Showcase

Urea is an added value chemical with wide applications in the industry and agriculture. The release of urea waste to the environment affects ecosystem health despite its low toxicity. Online monitoring of urea for industrial applications and environmental health is an unaddressed challenge. Electroanalytical techniques can be a smart integrated solution for online monitoring if sensors can overcome the major barrier associated with long-term stability. Mixed metal oxides have shown excellent stability in environmental conditions with long lasting operational lives. However, these materials have been barely explored for sensing applications. This work presents a proof of concept that demonstrates the applicability of an indirect electroanalytical quantification method of urea. The use of Ti/RuO2-TiO2-SnO2 dimensional stable anode (DSA®) can provide accurate and sensitive quantification of urea in aqueous samples exploiting the excellent catalytic properties of DSA® on the electrogeneration of active chlorine species. The cathodic reduction of accumulated HClO/ClO− from anodic electrogeneration presented a direct relationship with urea concentration. This novel method can allow urea quantification with a competitive LOD of 1.83 × 10−6 mol L−1 within a linear range of 6.66 × 10−6 to 3.33 × 10−4 mol L−1 of urea concentration.

Does school participatory budgeting (SPB) increase students’ political efficacy? SPB, which is implemented in thousands of schools around the world, is a democratic process of deliberation and decision-making in which students determine how to spend a portion of the school’s budget. We examined the impact of SPB on political efficacy in one middle school in Arizona. Our participants’ (n = 28) responses on survey items designed to measure self-perceived growth in political efficacy indicated a large effect size (Cohen’s d = 1.46), suggesting that SPB is an effective approach to civic pedagogy, with promising prospects for developing students’ political efficacy.

The current study examined heterogeneity in emerging adult children's routine and self-disclosure to parents using mixture modeling and explored predictors and outcomes associated with the patterns of disclosure. Participants consisted of 449 emerging adults (49% male, 68% European American, 65% college students, 33% single-parent families) who completed questionnaires every year across three waves (Mage at Time 1 = 18.4 years). Latent profile analyses suggested that large groups of emerging adults reported moderate levels of routine disclosure and low levels of self-disclosure to both mothers (79%) and fathers (36%), while other groups (20%) reported high levels of routine and self-disclosure to both parents. Profile membership was associated with predictors (parental autonomy granting, self-disclosure to friend, gender, family structure, college attendance) at Time 1 and outcomes (delinquency, depression, and prosocial behavior) at Time 3. Implications regarding the continued parent-child relationship and disclosure to parents in the third decade of life are discussed.