Matching Items (28)
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Description
Battery performance has been studied at different temperature, C rate. Different types of batteries have been used. Capacity and impedance are two factors, which are focused in the thesis. To evaluate battery performance and battery conditions, the SOC (state of charge) determination methods have been studied in the thesis. There

Battery performance has been studied at different temperature, C rate. Different types of batteries have been used. Capacity and impedance are two factors, which are focused in the thesis. To evaluate battery performance and battery conditions, the SOC (state of charge) determination methods have been studied in the thesis. There are two types of batteries divided in three groups: group I. Ni-Cd battery (2V, 8Ah); group II. Lead-acid battery (2V, 8Ah); and group III. Lead-acid battery (2V, 25Ah). The impedance testing is using electrochemical impedance spectroscopy methods. AC impedance method has been used to test different state of charge (100%, 80%, 60%, 40%, 20%). For the corrosion part, the corrosion rate of metal material in the heat transfer fluids has been tested at different temperature. Hastelloys C-276 in eutectic molten salts a mixture of NaCl, KCl and ZnCl2 using potentiodynamic method (swap from ± 30 mV in 0.2 mV.s-1). The lowest corrosion rate of Hastelloy C-276 is 5.51 µm per year at 250 °C. Particularly, the corrosion rate of Hastelloy C-276 jumps up to 53.33 µm per year at 400 °C.
ContributorsChu, Ximo (Author) / Madakannan, Arunachalanadar (Thesis advisor) / Peng, Xihong (Committee member) / Nam, Changho (Committee member) / Arizona State University (Publisher)
Created2013
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Description
In this work, we focused on the stability and reducibility of quasi-periodic systems. We examined the quasi-periodic linear Mathieu equation of the form x ̈+(ä+ϵ[cost+cosùt])x=0 The stability of solutions of Mathieu's equation as a function of parameter values (ä,ϵ) had been analyzed in this work. We used the Floquet type

In this work, we focused on the stability and reducibility of quasi-periodic systems. We examined the quasi-periodic linear Mathieu equation of the form x ̈+(ä+ϵ[cost+cosùt])x=0 The stability of solutions of Mathieu's equation as a function of parameter values (ä,ϵ) had been analyzed in this work. We used the Floquet type theory to generate stability diagrams which were used to determine the bounded regions of stability in the ä-ù plane for fixed ϵ. In the case of reducibility, we first applied the Lyapunov- Floquet (LF) transformation and modal transformation, which converted the linear part of the system into the Jordan form. Very importantly, quasi-periodic near-identity transformation was applied to reduce the system equations to a constant coefficient system by solving homological equations via harmonic balance. In this process we obtained the reducibility/resonance conditions that needed to be satisfied to convert a quasi-periodic system to a constant one.
ContributorsEzekiel, Evi (Author) / Redkar, Sangram (Thesis advisor) / Meitz, Robert (Committee member) / Nam, Changho (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Tire blowout often occurs during driving, which can suddenly disturb vehicle motions and seriously threaten road safety. Currently, there is still a lack of effective methods to mitigate tire blowout risks in everyday traffic, even for automated vehicles. To fundamentally study and systematically resolve the tire blowout issue for automated

Tire blowout often occurs during driving, which can suddenly disturb vehicle motions and seriously threaten road safety. Currently, there is still a lack of effective methods to mitigate tire blowout risks in everyday traffic, even for automated vehicles. To fundamentally study and systematically resolve the tire blowout issue for automated vehicles, a collaborative project between General Motors (GM) and Arizona State University (ASU) has been conducted since 2018. In this dissertation, three main contributions of this project will be presented. First, to explore vehicle dynamics with tire blowout impacts and establish an effective simulation platform for close-loop control performance evaluation, high-fidelity tire blowout models are thoroughly developed by explicitly considering important vehicle parameters and variables. Second, since human cooperation is required to control Level 2/3 partially automated vehicles (PAVs), novel shared steering control schemes are specifically proposed for tire blowout to ensure safe vehicle stabilization via cooperative driving. Third, for Level 4/5 highly automated vehicles (HAVs) without human control, the development of control-oriented vehicle models, controllability study, and automatic control designs are performed based on impulsive differential systems (IDS) theories. Co-simulations Matlab/Simulink® and CarSim® are conducted to validate performances of all models and control designs proposed in this dissertation. Moreover, a scaled test vehicle at ASU and a full-size test vehicle at GM are well instrumented for data collection and control implementation. Various tire blowout experiments for different scenarios are conducted for more rigorous validations. Consequently, the proposed high-fidelity tire blowout models can correctly and more accurately describe vehicle motions upon tire blowout. The developed shared steering control schemes for PAVs and automatic control designs for HAVs can effectively stabilize a vehicle to maintain path following performance in the driving lane after tire blowout. In addition to new research findings and developments in this dissertation, a pending patent for tire blowout detection is also generated in the tire blowout project. The obtained research results have attracted interest from automotive manufacturers and could have a significant impact on driving safety enhancement for automated vehicles upon tire blowout.
ContributorsLi, Ao (Author) / Chen, Yan (Thesis advisor) / Berman, Spring (Committee member) / Kannan, Arunachala Mada (Committee member) / Liu, Yongming (Committee member) / Lin, Wen-Chiao (Committee member) / Marvi, Hamidreza (Committee member) / Arizona State University (Publisher)
Created2023
Description
Soft robots currently rely on additional hardware such as pumps, high voltage supplies,light generation sources, and magnetic field generators for their operation. These components resist miniaturization; thus, embedding them into small-scale soft robots is challenging. This issue limits their applications, especially in hyper-redundant mobile robots. This dissertation aims at addressing some of the

Soft robots currently rely on additional hardware such as pumps, high voltage supplies,light generation sources, and magnetic field generators for their operation. These components resist miniaturization; thus, embedding them into small-scale soft robots is challenging. This issue limits their applications, especially in hyper-redundant mobile robots. This dissertation aims at addressing some of the challenges associated with creating miniature, untethered soft robots that can function without any attachment to external power supplies or receiving any control signals from outside sources. This goal is accomplished by introducing a soft active material and a manufacturing method that together, facilitate the miniaturization of soft robots and effectively supports their autonomous, mobile operation without any connection to outside equipment or human intervention. The soft active material presented here is a hydrogel based on a polymer called poly(Nisopropylacrylamide) (PNIPAAm). This hydrogel responds to changes in the temperature and responds by expanding or contracting. A major challenge regarding PNIPAAm-based hydrogels is their slow response. This challenge is addressed by introducing a mixedsolvent photo-polymerization technique that alters the pore structure of the hydrogel and facilitates the water transport and thus the rate of volume change. Using this technique, the re-swelling response time of hydrogels is reduced to 2:4min – over 25 times faster than hydrogels demonstrated previously. The material properties of hydrogels including their response rate and Young’s modulus are tuned simultaneously. The one-step photopolymerization using UV light is performed in under 15 sec, which is a significant improvement over thermo-polymerization, which takes anywhere between a few minutes to several hours. Photopolymerization is key towards simplifying recipes, improving access to these techniques, and making them tractable for iterative design processes. To address the manufacturing challenges, soft voxel actuators (SVAs) are presented. SVAs are actuated by electrical currents through Joule heating. SVAs weighing only 100 mg require small footprint microcontrollers for their operation which can be embedded in the robotic system. The advantages of hydrogel-based SVAs are demonstrated through different robotic platforms namely a hyper-redundant manipulator with 16 SVAs, an untethered miniature robot for mobile underwater applications using 8 SVAs, and a gripper using 32 SVAs.
ContributorsKhodambashi, Roozbeh (Author) / Aukes, Daniel (Thesis advisor) / Sugar, Thomas (Committee member) / Nam, Changho (Committee member) / Arizona State University (Publisher)
Created2021
Description

After the wind tunnels in the SIM building and Innovation Hub were donated or lost, Dr. Rajadas requested a new wind tunnel be designed, developed, and fabricated using facilities and resources available on ASU Polytech. Over 6 months, a single student was tasked with running the CAD modeling process, undergoing

After the wind tunnels in the SIM building and Innovation Hub were donated or lost, Dr. Rajadas requested a new wind tunnel be designed, developed, and fabricated using facilities and resources available on ASU Polytech. Over 6 months, a single student was tasked with running the CAD modeling process, undergoing the revision stages, and welding/fabricating the tunnel by the end of Fall 2021.

ContributorsAcevedo, Rodrigo (Author, Co-author) / Rajadas, John (Thesis director) / Nam, Changho (Committee member) / Barrett, The Honors College (Contributor) / Engineering Programs (Contributor)
Created2021-12
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Description
Hydrogen is considered one of the most potential fuels due to its highest gravimetric energy density with no pollutant emission during the energy cycle. Among several techniques for hydrogen generation, the promising photoelectrochemical water oxidation is considered a long-term solar pathway by splitting water. The system contains a photoanode and

Hydrogen is considered one of the most potential fuels due to its highest gravimetric energy density with no pollutant emission during the energy cycle. Among several techniques for hydrogen generation, the promising photoelectrochemical water oxidation is considered a long-term solar pathway by splitting water. The system contains a photoanode and a cathode immersed in an aqueous electrolyte where charge separation takes place in the bulk of the semiconducting material on light absorption, leading to water oxidation/reduction at the surface of the photoelectrodes/cathode. It is imperative to develop materials that demonstrate high light absorption in the wide spectrum along with photoelectrochemical stability. N-type Monoclinic scheelite bismuth vanadate (BiVO4) is selected due to its incredible light absorption capabilities, direct bandgap (Eg ∼ 2.4-2.5 eV) and relatively better photoelectrochemical stability. However, BiVO4 encounters huge electron-hole recombination due to smaller diffusion lengths and positive conduction bands that cause slow charge dynamics and sluggish water oxidation kinetics. In order to improve the illustrated drawbacks, four strategies were discussed. Chapter 1 describe the fundamental understanding of photoelectrochemical cell and BiVO4. Chapter 2 illustrates details of the experimental procedure and state-of-the-art material characterization. Chapter 3 provide the impact of alkali metal placement in the crystal structure of BiVO4 systematically that exhibited ~20 times more performance than intrinsic BiVO4, almost complete bulk charge separation and enhancement in the diffusion length. Detailed characterization determined that the alkali metal getting placed in the interstitial void of BiVO4 lattice and multiple interbands formation enhanced the charge dynamics. Chapter 4 contains stoichiometric doping of Y3+ or Er3+ or Yb3+ at the Bi3+ site, leading to an extended absorption region, whereas non-stoichiometric W6+ doping at the V5+ site minimizes defects and increased charge carriers. To further enhance the performance, type-II heterojunction with WO3 along p-n junction with Fe:NiO enhance light absorption and charge dynamics close to the theoretical performance. Chapter 5 provides a comprehensive study of a uniquely developed sulfur modified Bi2O3 interface layer to facilitate charge dynamics and carrier lifetime improvement by effectively passivating the WO3/BiVO4 heterojunction interface. Finally, chapter 6 summarized the major findings, conclusion and outlook in developing BiVO4 as an efficient photoanode material.
ContributorsPrasad, Umesh (Author) / Kannan, Arunachala Mada (Thesis advisor) / Azeredo, Bruno (Committee member) / Chan, Candace (Committee member) / Segura, Sergio Garcia (Committee member) / Arizona State University (Publisher)
Created2021
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Description
The silicon-based solar cell has been extensively deployed in photovoltaic industry and plays an important role in renewable energy industries. A more energy-efficient, environment-harmless and eco-friendly silicon production technique is required for price-competitive solar energy harvesting. Silicon electrorefining in molten salt is promising for the ultrapure solar-grade Si production. To

The silicon-based solar cell has been extensively deployed in photovoltaic industry and plays an important role in renewable energy industries. A more energy-efficient, environment-harmless and eco-friendly silicon production technique is required for price-competitive solar energy harvesting. Silicon electrorefining in molten salt is promising for the ultrapure solar-grade Si production. To avoid using highly corrosive fluoride salt, CaCl2-based salt is widely employed for silicon electroreduction. For Si electroreduction in CaCl2-based salt, CaO is usually added to enhance the solubility of SiO2. However, the existence of oxygen in molten salt could result in system corrosion, anode passivation and the co-deposition of secondary phases such as CaSiO3 and SiO2 at the cathode. This research focuses on the development of reusable oxygen-free CaCl2-based molten salt for solar-grade silicon electrorefining. A new multi-potential electropurification process has been proposed and proven to be more effective in impurities removal. The as-received salt and the salt after electrorefining have been electropurified. The inductively-coupled plasma mass spectrometry and cyclic voltammetry have been utilized to determine the impurities removal of electropurification. The salt after silicon electrorefining has been regenerated to its original purity level before by the multi-potential electropurification process, demonstrating the feasibility of a reusable salt by electropurification. In an oxygen-free CaCl2-based salt without silicon precursor, the silicon dissolved from the silicon anode can be successfully deposited at the cathode. The silicon anode has been operated for more than 50 hours without passivation in the oxygen-free system. Silicon ions start to be deposited after 0.17 g of silicon has been dissolved into the salt from the silicon anode. A 180 µm deposit with a silver-luster surface was obtained at the cathode. The main impurities in the silicon anode such as aluminum, iron and titanium were not found in the silicon deposits. No oxygen-containing secondary phases are detected in the silicon deposits. These results confirm the feasibility of silicon electrorefining in the oxygen-free CaCl2-based salt.
ContributorsTseng, Mao-Feng (Author) / Tao, Meng (Thesis advisor) / Kannan, Arunachala Mada (Committee member) / Mu, Linqin (Committee member) / Goryll, Michael (Committee member) / Arizona State University (Publisher)
Created2023
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Description

The current Solid-State Electrolyte (SSE) used in Li-ion batteries are limited by their current production methods (i.e., die-pressing; tape casting), planar geometries and random porosities. This constrains their use for mass production in manufacturing plants. 3D-printing of SSEs, however, is a new, highly-researched method that shows promise in expanding beyond

The current Solid-State Electrolyte (SSE) used in Li-ion batteries are limited by their current production methods (i.e., die-pressing; tape casting), planar geometries and random porosities. This constrains their use for mass production in manufacturing plants. 3D-printing of SSEs, however, is a new, highly-researched method that shows promise in expanding beyond the laboratory to more large-scale industrial production as rapid prototyping takes place. Indeed, laboratory studies to date suggest that SSE technology is safer than current production methods and provides a safe high energy solid-state battery. For SSE technology to become a reality though, it must be scalable and financially feasible. Therefore, this thesis aids to bridge the gap between laboratory studies and commercialization by examining the financial feasibility of adopting this technology for a hypothetical battery manufacturing plant. In doing this, I develop a model of the incremental net cash flows, and subsequently the Net Present Value (NPV), from such an enterprise. If the present value of future cash flows from the enterprise are anticipated to be greater than the investment costs, the NPV is positive and the investment in this new technology would be considered instantaneously value enhancing and thus financially feasible. However, future cash flows are highly uncertain, which brings into question financial feasibility in a risky environment. To address the riskiness of future cash flows, I model three risk factors: the cost of raw materials, the potential growth in battery sales, as well as the potential mark-up (profit margin) of the SSE enterprise. Using Monte Carlo simulation (MCS) I model the incremental cash flows considering these risk factors and derive probabilistic assessments of NPV. My analysis suggests that despite the uncertainty caused by the volatility of raw metal prices, assumptions on price mark-up, and uncertain market demand for Li-ion batteries, there is a high probability of an investment in SSE batteries being financially feasible. Future research should consider the value of real options (optionality embedded in tangible investments) as traditional NPV analysis may underestimate the potential value of an investment in the presence of uncertain cash flows, especially if management has the ability to respond to the uncertainty.

ContributorsFonseca, Nathan (Author) / Manfredo, Mark (Thesis director) / Kannan, Arunachala Mada (Committee member) / Barrett, The Honors College (Contributor) / Engineering Programs (Contributor)
Created2022-05
Description

Motorcycles must be designed for safety and long operation. Front suspension systems must in turn be safe and able to operate for long service lives. Challenges to achieving safe and long service lifetimes include designing components (rims, axles, forks, etc.) to withstand various loading conditions not just once but numerous

Motorcycles must be designed for safety and long operation. Front suspension systems must in turn be safe and able to operate for long service lives. Challenges to achieving safe and long service lifetimes include designing components (rims, axles, forks, etc.) to withstand various loading conditions not just once but numerous times as a matter of fatigue life. An already developed CAD model of a motorcycle suspension was taken and optimized for various loading conditions. These conditions included static loading, braking, cornering, and wheelie and front impact loads. In all cases, front impact load was the critical loading condition when FEA in SolidWorks Simulation was conducted for the components. All components were then optimized to handle the impact load by changing geometry until safety factors of 4.0 ± 0.25 were achieved. Components were then analyzed for fatigue life, with all steel and magnesium components having infinite predicted fatigue lives and all aluminum components having fatigue lives predicted with corrected S-N curves created for up to 500 million loading cycles. The design was optimized with all components becoming improved for stress compliance, with room for improvement existing in both defining loads for analysis and developing more accurate and rigorous fatigue life models.

ContributorsOrth, Trentten (Author) / Nam, Changho (Thesis director) / Chen, Yan (Committee member) / Barrett, The Honors College (Contributor) / Engineering Programs (Contributor)
Created2023-05
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Description
The fuel cell is a promising device that converts the chemical energy directly into the electrical energy without combustion process. However, the slow reaction rate of the oxygen reduction reaction (ORR) necessitates the development of cathode catalysts for low-temperature fuel cells. After a thorough literature review in Chapter 1, the

The fuel cell is a promising device that converts the chemical energy directly into the electrical energy without combustion process. However, the slow reaction rate of the oxygen reduction reaction (ORR) necessitates the development of cathode catalysts for low-temperature fuel cells. After a thorough literature review in Chapter 1, the thesis is divided into three parts as given below in Chapters 2-4.

Chapter 2 describes the study on the Pt and Pt-Me (Me: Co, Ni) alloy nanoparticles supported on the pyrolyzed zeolitic imidazolate framework (ZIF) towards ORR. The Co-ZIF and NiCo-ZIF were synthesized by the solvothermal method and then mixed with Pt precursor. After pyrolysis and acid leaching, the PtCo/NC and PtNiCo/NC were evaluated in proton exchange membrane fuel cells (PEMFC). The peak power density exhibited > 10% and 15% for PtCo/NC and PtNiCo/NC, respectively, compared to that with commercial Pt/C catalyst under identical test conditions.

Chapter 3 is the investigation of the oxygen vacancy (OV) effect in a-MnO2 as a cathode catalyst for alkaline membrane fuel cells (AMFC). The a-MnO2 nanorods were synthesized by hydrothermal method and heated at 300, 400 and 500 ℃ in the air to introduce the OV. The 400 ℃ treated material showed the best ORR performance among all other samples due to more OV in pure a-MnO2 phase. The optimized AMFC electrode showed ~ 45 mW.cm-2, which was slightly lower than that with commercial Pt/C (~60 mW.cm-2).

Chapter 4 is the density functional theory (DFT) study of the protonation effect and active sites towards ORR on a-MnO2 (211) plane. The theoretically optimized oxygen adsorption and hydroxyl ion desorption energies were ~ 1.55-1.95 eV and ~ 0.98-1.45 eV, respectively, by Nørskov et al.’s calculations. All the configurations showed oxygen adsorption and hydroxyl ion desorption energies were ranging from 0.27 to 1.76 eV and 1.59 to 15.0 eV, respectively. The site which was close to two Mn ions showed the best oxygen adsorption and hydroxyl ion desorption energies improvement with the surface protonation.

Based on the results given in Chapters 1-4, the major findings are summarized in Chapter 5.
ContributorsShi, Xuan, Ph.D (Author) / Kannan, Arunachalanadar Mada (Thesis advisor) / Liu, Jingyue (Committee member) / Nam, Changho (Committee member) / Peng, Xihong (Committee member) / Arizona State University (Publisher)
Created2019