In this dissertation, predictive water allocation optimization models were developed which can be used to easily identify good alternatives for water management that can then be discussed, debated, adjusted, and simulated in greater detail. This study provides guidance for decision makers in Iraq for potential future conditions, where water supplies are reduced, and demonstrates how it is feasible to adopt an efficient water allocation strategy with flexibility in providing equitable water resource allocation considering alternative resource. Using reclaimed water will help in reducing the potential negative environmental impacts of treated or/and partially treated wastewater discharges while increasing the potential uses of reclaimed water for agriculture and other applications. Using reclaimed water for irrigation is logical and efficient to enhance the economy of farmers and the environment while providing a diversity of crops, especially since most of Iraq’s built or under construction wastewater treatment plants are located in or adjacent to agricultural lands. Adopting an optimization modelling approach can assist decision makers, ensuring their decisions will benefit the economy by incorporating global experiences to control water allocations in Iraq especially considering diminished water supplies.
Water heaters that are manufactured for swimming pools come in several forms, most of which require an electrical input for a source of power. Passive-circulation systems, however, require no electrical power input because fluid circulation occurs as a result of thermal gradients. In solar-based systems, thermal gradients are developed by energy collected from sunlight. The combination of solar collection and passive circulation yields a system in which fluids, particularly water, are heated and circulated without need of assistance from external mechanical or electrical sources. The design of such a system was adapted from that of forced-circulation solar collector systems, as were the equations describing its thermodynamic properties. The design was developed based on such constraints as material corrosion resistance, overall system cost, and location-controlled size limitations. The thermodynamic description of the designed system was adjusted on the basis of the designed system’s physical aspects, such as the configuration and material of each component within the solar collector. Numerical analysis performed with the altered thermodynamic equations projected a total energy gain of 7.39 W between 9:00 and 10:00 A.M. and a total energy gain of 13.12 W between 4:00 and 5:00 P.M. The temperature of heated water exiting the collector system was projected to be 17.62°C in the morning and 25.56°C in the afternoon. The morning projection utilized an initial fluid temperature of 12°C and an ambient air temperature of 13°C, while the afternoon projection utilized an initial fluid temperature of 17°C and an ambient air temperature of 22°C. Field testing of the designed passive thermosyphon solar collector system was performed over a period of about one month with one temperature measurement taken at the collector outlet in the morning and another taken in the afternoon. For an ambient air temperature of 13°C, the linear regression developed from the morning dataset yielded an outlet water temperature of 20°C and that for the afternoon dataset yielded an outlet water temperature of 39°C for an ambient air temperature of 17°C. The percentage error between the projected and measured results was 13.51% for the morning period and 52.58% for the afternoon period. Numerical simulation and field data demonstrated that while the collector system operated successfully, its effects were limited to the volume of water immediately surrounding the outlet of the system; the rate of circulation within the system was too low for there to be a meaningful increase in the temperature of the water body at large. The stated results demonstrate that while the particular configuration of passive circulation solar collection technology developed in this instance is capable of transferring solar thermal energy to water without additional energy sources, significant modifications are necessary in order to improve the effectiveness of the technology. Such changes may come from improvements in material availability or alterations to the configuration of components of the collector system.
Is there a mismatch between urban farmers’ perceptions of their farm’s environmental sustainability and its actual environmental impact? Focusing on the use of water and nutrients on each farm as described by the farmers through interviews, it is evident that there is some level of disconnect between ideals and practices. This project may aid in bridging the gap between the two in regard to the farmers’ sustainability goals. This project will move forward by continuing interviews with farmers as well as collecting soil and water from the farms in order to more accurately quantify the sustainability of the farms’ practices. This project demonstrates that there is some degree of misalignment between perception and reality. Two farms claimed they were sustainable when their practices did not reflect that, while 2 farms said they were not sure if they were sustainable when their practices indicated otherwise. Samples from two farms showed high concentrations of nutrients and salts, supporting the idea that there may be a mismatch between perceived and actual sustainability.
Enzyme-induced carbonate precipitation (EICP) is a biocementation technique that produces comparatively fewer carbon dioxide emissions than traditional cementation. However, the use of synthetic reagents for EICP is costly, and the process produces an ammonium byproduct which is a harmful pollutant. This study utilizes fresh urine as a source of urea and calcium-rich zeolites as an ammonium adsorbent and a source of calcium ions for the EICP cementation technique. Batch hydrolysis and adsorption experiments were conducted to determine the effects of zeolite type, zeolite form, and solution composition on ammonium adsorption and calcium release. Cementation experiments were then conducted to determine the effects of different hydrolysis and adsorption times on ammonium adsorption and calcium carbonate precipitation. The results showed that calcium-rich chabazite could be used as a source of calcium ions and as an effective adsorbent of ammonium for EICP. Additionally, synthetic, fresh urine and real, fresh urine had comparable ammonium adsorption and calcium release trends. Finally, inclusion of a pre-hydrolysis step reduced the ammonium adsorption and calcium release, but longer adsorption times lead to calcium carbonate precipitation outside of the sand column, which is an undesirable outcome for soil biocementation; even with this limitation, the calcium carbonate content of sand columns ranged from 0.48% to 0.92%, which signifies the potential of the proposed process for cementation, given a higher initial concentration of urea.