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Family adaptation to child developmental disability is a dynamic transactional process that has yet to be tested in a longitudinal, rigorous fashion. In addition, although children with developmental delays frequently have behavior problems, not enough research has examined possible underlying mechanisms in the relation between child developmental delay, adaptation and behavior problems. In the current study, factor analysis examined how best to conceptualize the construct of family adaptation to developmental delay. Also, longitudinal growth curve modeling tested models in which child behavior problems mediated the relation between developmental risk and indices of family adaptation. Participants included 130 typically developing children and their families (Mental Development Index [MDI] > 85) and 104 children with developmental delays and their families (MDI < 85). Data were collected yearly between the ages of three and eight as part of a multi-site, longitudinal investigation examining the interrelations among children's developmental status, family processes, and the emergence of child psychopathology. Results of the current study indicated that adaptation is best conceptualized as a multi-index construct. Different aspects of adaptation changed in unique ways over time, with some facets of adaptation remaining stable while others fluctuated. Child internalizing and externalizing behavior problems were found to decrease over time for both children with developmental delays and typically developing children. Child behavior problems were also found to mediate the relation between developmental risk and family adaptation for over half of the mediation pathways. Significant mediation results indicated that children with developmental delays showed higher early levels of behavior problems, which in turn was associated with more maladaptive adaptation. These findings provide further evidence that families of children with developmental delays experience both positive and more challenging changes in their families over time. This study implies important next steps for research and clinical practice in the area of developmental disability.
ContributorsPedersen y Arbona, Anita (Author) / Crnic, Keith A (Thesis advisor) / Sandler, Irwin (Committee member) / Lemery, Kathryn (Committee member) / Enders, Craig (Committee member) / Arizona State University (Publisher)
Created2011
Description
Traditional methods of environmental regulation and enforcement have been questioned over the last decade. Due to the number of environmental regulations, and subsequent cost of enforcement, governments have begun to incentivize the adoption of environmental management systems (EMSs). These management systems encourage companies to better manage their environmental performance voluntarily. It is the purpose of this study to list the types of government incentives that have been used and categorize them into three groups based off of their characteristics. Ten incentive types were identified and put into three categories; (a) reducing the barriers to EMS adoption; (b) enhancing benefits derived from EMS adoption, and (c) rewarding EMS implementers with reduced enforcement. The research shows that each category of incentives encourages different manufacturing facilities to adopt EMSs. Using data from previously conducted case studies and surveys to determine what type of manufacturing facilities are affected, this study finds that government incentives have been shown to have a measurable impact on the decision makers of manufacturing facilities to adopt an EMS. The study concludes that a combination of traditional environmental regulation used with targeted incentives provide the most efficient use of resources by governments.
ContributorsBlanton, Arnold (Author) / Olson, Larry (Thesis advisor) / Peterson, Danny (Committee member) / Hild, Nicholas (Committee member) / Arizona State University (Publisher)
Created2011
Description
Emission of CO2 into the atmosphere has become an increasingly concerning issue as we progress into the 21st century Flue gas from coal-burning power plants accounts for 40% of all carbon dioxide emissions. The key to successful separation and sequestration is to separate CO2 directly from flue gas (10-15% CO2, 70% N2), which can range from a few hundred to as high as 1000°C. Conventional microporous membranes (carbons/silicas/zeolites) are capable of separating CO2 from N2 at low temperatures, but cannot achieve separation above 200°C. To overcome the limitations of microporous membranes, a novel ceramic-carbonate dual-phase membrane for high temperature CO2 separation was proposed. The membrane was synthesized from porous La0.6Sr0.4Co0.8Fe0.2O3-d (LSCF) supports and infiltrated with molten carbonate (Li2CO3/Na2CO3/K2CO3). The CO2 permeation mechanism involves a reaction between CO2 (gas phase) and O= (solid phase) to form CO3=, which is then transported through the molten carbonate (liquid phase) to achieve separation. The effects of membrane thickness, temperature and CO2 partial pressure were studied. Decreasing thickness from 3.0 to 0.375 mm led to higher fluxes at 900°C, ranging from 0.186 to 0.322 mL.min-1.cm-2 respectively. CO2 flux increased with temperature from 700 to 900°C. Activation energy for permeation was similar to that for oxygen ion conduction in LSCF. For partial pressures above 0.05 atm, the membrane exhibited a nearly constant flux. From these observations, it was determined that oxygen ion conductivity limits CO2 permeation and that the equilibrium oxygen vacancy concentration in LSCF is dependent on the partial pressure of CO2 in the gas phase. Finally, the dual-phase membrane was used as a membrane reactor. Separation at high temperatures can produce warm, highly concentrated streams of CO2 that could be used as a chemical feedstock for the synthesis of syngas (H2 + CO). Towards this, three different membrane reactor configurations were examined: 1) blank system, 2) LSCF catalyst and 3) 10% Ni/y-alumina catalyst. Performance increased in the order of blank system < LSCF catalyst < Ni/y-alumina catalyst. Favorable conditions for syngas production were high temperature (850°C), low sweep gas flow rate (10 mL.min-1) and high methane concentration (50%) using the Ni/y-alumina catalyst.
ContributorsAnderson, Matthew Brandon (Author) / Lin, Jerry (Thesis advisor) / Alford, Terry (Committee member) / Rege, Kaushal (Committee member) / Anderson, James (Committee member) / Rivera, Daniel (Committee member) / Arizona State University (Publisher)
Created2011
Description
Semiconductor manufacturing facilities are very complex and capital intensive in nature. During the lifecycle of these facilities various disciplines come together, generate and use a tremendous amount of building and process information to support various decisions that enable them to successfully design, build and sustain these advanced facilities. However, a majority of the information generated and processes taking place are neither integrated nor interoperable and result in a high degree of redundancy. The objective of this thesis is to build an interoperable Building Information Model (BIM) for the Base-Build and Tool Installation in a semiconductor manufacturing facility. It examines existing processes and data exchange standards available to facilitate the implementation of BIM and provides a framework for the development of processes and standards that can help in building an intelligent information model for a semiconductor manufacturing facility. To understand the nature of the flow of information between the various stakeholders the flow of information between the facility designer, process tool manufacturer and tool layout designer is examined. An information model for the base build and process tool is built and the industry standards SEMI E6 and SEMI E51 are used as a basis to model the information. It is found that applications used to create information models support interoperable industry standard formats such as the Industry Foundation Classes (IFC) and ISO 15926 in a limited manner. A gap analysis has revealed that interoperability standards applicable to the semiconductor manufacturing industry such as the IFC and ISO15926 need to be expanded to support information transfers unique to the industry. Information modeling for a semiconductor manufacturing facility is unique in that it is a process model (Process Tool Information Model) within a building model (Building Information Model), each of them supported more robustly by different interoperability standards. Applications support interoperability data standards specific to the domain or industry they serve but information transfers need to occur between the various domains. To facilitate flow of information between the different domains it is recommended that a mapping of the industry standards be undertaken and translators between them be developed for business use.
ContributorsPindukuri, Shruthi (Author) / Chasey, Allan D (Thesis advisor) / Wiezel, Avi (Committee member) / Mamlouk, Michael (Committee member) / Arizona State University (Publisher)
Created2011
Description
The price based marketplace has dominated the construction industry. The majority of owners use price based practices of management (expectation and decision making, control, direction, and inspection.) The price based/management and control paradigm has not worked. Clients have now been moving toward the best value environment (hire contractors who know what they are doing, who preplan, and manage and minimize risk and deviation.) Owners are trying to move from client direction and control to hiring an expert and allowing them to do the quality control/risk management. The movement of environments changes the paradigm for the contractors from a reactive to a proactive, from a bureaucratic
on-accountable to an accountable position, from a relationship based
on-measuring to a measuring entity, and to a contractor who manages and minimizes the risk that they do not control. Years of price based practices have caused poor quality and low performance in the construction industry. This research identifies what is a best value contractor or vendor, what factors make up a best value vendor, and the methodology to transform a vendor to a best value vendor. It will use deductive logic, a case study to confirm the logic and the proposed methodology.
on-accountable to an accountable position, from a relationship based
on-measuring to a measuring entity, and to a contractor who manages and minimizes the risk that they do not control. Years of price based practices have caused poor quality and low performance in the construction industry. This research identifies what is a best value contractor or vendor, what factors make up a best value vendor, and the methodology to transform a vendor to a best value vendor. It will use deductive logic, a case study to confirm the logic and the proposed methodology.
ContributorsPauli, Michele (Author) / Kashiwagi, Dean (Thesis advisor) / Sullivan, Kenneth (Committee member) / Badger, William (Committee member) / Arizona State University (Publisher)
Created2011
Description
Fuel cells, particularly solid oxide fuel cells (SOFC), are important for the future of greener and more efficient energy sources. Although SOFCs have been in existence for over fifty years, they have not been deployed extensively because they need to be operated at a high temperature (∼1000 °C), are expensive, and have slow response to changes in energy demands. One important need for commercialization of SOFCs is a lowering of their operating temperature, which requires an electrolyte that can operate at lower temperatures. Doped ceria is one such candidate. For this dissertation work I have studied different types of doped ceria to understand the mechanism of oxygen vacancy diffusion through the bulk. Doped ceria is important because they have high ionic conductivities thus making them attractive candidates for the electrolytes of solid oxide fuel cells. In particular, I have studied how the ionic conductivities are improved in these doped materials by studying the oxygen-vacancy formations and migrations. In this dissertation I describe the application of density functional theory (DFT) and Kinetic Lattice Monte Carlo (KLMC) simulations to calculate the vacancy diffusion and ionic conductivities in doped ceria. The dopants used are praseodymium (Pr), gadolinium (Gd), and neodymium (Nd), all belonging to the lanthanide series. The activation energies for vacancy migration between different nearest neighbor (relative to the dopant) positions were calculated using the commercial DFT code VASP (Vienna Ab-initio Simulation Package). These activation energies were then used as inputs to the KLMC code that I co-developed. The KLMC code was run for different temperatures (673 K to 1073 K) and for different dopant concentrations (0 to 40%). These simulations have resulted in the prediction of dopant concentrations for maximum ionic conductivity at a given temperature.
ContributorsAnwar, Shahriar (Author) / Adams, James B (Thesis advisor) / Crozier, Peter (Committee member) / Krause, Stephen (Committee member) / Arizona State University (Publisher)
Created2011
Description
An array of north-striking, left-stepping, active normal faults is situated along the southwestern margin of the Gulf of California. This normal fault system is the marginal fault system of the oblique-divergent plate boundary within the Gulf of California. To better understand the role of upper-crustal processes during development of an obliquely rifted plate margin, gravity surveys were conducted across the normal-fault-bounded basins within the gulf-margin array and, along with optically stimulated luminescence dating of offset surfaces, fault-slip rates were estimated and fault patterns across basins were assessed, providing insight into sedimentary basin evolution. Additionally, detailed geologic and geomorphic maps were constructed along two faults within the system, leading to a more complete understanding of the role of individual normal faults within a larger array. These faults slip at a low rate (0.1-1 mm/yr) and have relatively shallow hanging wall basins (~500-3000 m). Overall, the gulf-margin faults accommodate protracted, distributed deformation at a low rate and provide a minor contribution to overall rifting. Integrating figures with text can lead to greater science learning than when either medium is presented alone. Textbooks, composed of text and graphics, are a primary source of content in most geology classes. It is essential to understand how students approach learning from text and figures in textbook-style learning materials and how the arrangement of the text and figures influences their learning approach. Introductory geology students were eye tracked while learning from textbook-style materials composed of text and graphics. Eye fixation data showed that students spent less time examining the figure than the text, but the students who more frequently examined the figure tended to improve more from the pretest to the posttest. In general, students tended to examine the figure at natural breaks in the reading. Textbook-style materials should, therefore, be formatted to include a number of natural breaks so that learners can pause to inspect the figure without the risk of losing their place in the reading and to provide a chance to process the material in small chunks. Multimedia instructional materials should be designed to support the cognitive processes of the learner.
ContributorsBusch, Melanie M. D (Author) / Arrowsmith, Ramon (Thesis advisor) / Reynolds, Stephen (Thesis advisor) / Chi, Michelene (Committee member) / Semken, Steven (Committee member) / Tyburczy, James (Committee member) / Arizona State University (Publisher)
Created2011
Description
Type Ia supernovae are important, but mysterious cosmological tools. Their standard brightnesses have enabled cosmologists to measure extreme distances and to discover dark energy. However, the nature of their progenitor mechanisms remains elusive, with many competing models offering only partial clues to their origins. Here, type Ia supernova delay times are explored using analytical models. Combined with a new observation technique, this model places new constraints on the characteristic time delay between the formation of stars and the first type Ia supernovae. This derived delay time (500 million years) implies low-mass companions for single degenerate progenitor scenarios. In the latter portions of this dissertation, two progenitor mechanisms are simulated in detail; white dwarf collisions and mergers. From the first of these simulations, it is evident that white dwarf collisions offer a viable and unique pathway to producing type Ia supernovae. Many of the combinations of masses simulated produce sufficient quantities of 56Ni (up to 0.51 solar masses) to masquerade as normal type Ia supernovae. Other combinations of masses produce 56Ni yields that span the entire range of supernova brightnesses, from the very dim and underluminous, with 0.14 solar masses, to the over-bright and superluminous, with up to 1.71 solar masses. The 56Ni yield in the collision simulations depends non-linearly on total system mass, mass ratio, and impact parameter. Using the same numerical tools as in the collisions examination, white dwarf mergers are studied in detail. Nearly all of the simulations produce merger remnants consisting of a cold, degenerate core surrounded by a hot accretion disk. The properties of these disks have strong implications for various viscosity treatments that have attempted to pin down the accretion times. Some mass combinations produce super-Chandrasekhar cores on shorter time scales than viscosity driven accretion. A handful of simulations also exhibit helium detonations on the surface of the primary that bear a resemblance to helium novae. Finally, some of the preliminary groundwork that has been laid for constructing a new numerical tool is discussed. This new tool advances the merger simulations further than any research group has done before, and has the potential to answer some of the lingering questions that the merger study has uncovered. The results of thermal diffusion tests using this tool have a remarkable correspondence to analytical predictions.
ContributorsRaskin, Cody (Author) / Scannapieco, Evan (Thesis advisor) / Rhoads, James (Committee member) / Young, Patrick (Committee member) / Mcnamara, Allen (Committee member) / Timmes, Francis (Committee member) / Arizona State University (Publisher)
Created2011
Description
La frontera entre México y Estados Unidos es un territorio que se ha conceptualizado y construido por el centralismo mexicano y por el discurso chicano dominante: el de Borderlands. Estos dos focos equidistantes establecen sus perspectivas a partir del contacto que la región fronteriza tiene con los Estados Unidos en términos de intercambios económicos y culturales. La tradición de definir la zona fronteriza se inicia a partir de 1848 con el Tratado de Guadalupe Hidalgo. Más tarde, dicha región estaría en indiferencia por su distancia geográfica con el centro mexicano, excepto durante la Revolución mexicana. Sin embargo, la región fronteriza empieza a recibir gran atención hacia finales del Siglo XX, cuando nuevas formas de intercambio económico entre México y Estados Unidos se empiezan a desarrollar. La frontera, entonces experimenta un crecimiento económico que se refleja, a su vez, en el resurgimiento y crecimiento de la cultura fronteriza. El antropólogo cultural, Nestor García Canclini intentó definir la cultura fronteriza al analizar el uso del idioma inglés en Tijuana. En sus estudios, tanto Tijuana: la casa de toda la gente (1989) como Culturas híbridas: Cómo entrar y salir de la modernidad (1992), García Canclini sostiene que la frontera es un espacio de hibridación cultural. Por otro lado, las teorías dominantes dentro del campo chicano definen la frontera en términos metafísicos. Para Gloria Anzaldúa, el espacio fronterizo es el Borderlands: un área geográfica en donde los paradigmas de la psicología del individuo están en constante conflicto. Considerando estos antecedentes como punto de partida, esta investigación se enfoca en el estudio de la cultura fronteriza como múltiples universos de signos que entran en contacto unos con otros. Tal como lo establece Iury Lotman en su estudio teórico La semiosfera (1996), una semiosfera es un espacio delimitado por una frontera que, a su vez, tiene la función de traducir información de otras semiosferas. De manera que dicho concepto se muestra adecuado para analizar El gran preténder (1992) de Luis Humberto Crosthwaite y Berlín 77 (y otros relatos) (2003) de Carlos Adolfo Gutiérrez Vidal. En última instancia, al establecer los espacios fronterizos como universos culturales (semiosferas) se devela el nivel de contacto entre éstas, especialmente entre las semiosferas mexicana/americana y la fronteriza.
ContributorsEncinas, Diana (Author) / Volek, Emil (Committee member) / Hernández-G., Manuel De Jesús (Committee member) / Acereda, Alberto (Committee member) / Arizona State University (Publisher)
Created2011
Description
Parents die during the lives of their children. If the child is an adolescent, that death will impact the student's education immediately or in subsequent years. Findings show the death of a mother does impact the daughter's education. It is imperative educators are willing to work with the student at the time the death occurs as well as in the ensuing months. Seidman's (2006) three-interview format was used as a template for the interviews of 11 women, ranging in age from 19 to 78 and whose mothers died when the women were adolescents. The interviews were primarily conducted in one sitting, transcribed, and then analyzed for common themes that connected to the research on the topic. Those themes include grieving, the role of caring in education, the role of teacher as the second mother, mother-daughter relationships, and the impact of parent death on schooling. These themes from the data cross cut with thematic strands within the study's theoretical framework: the nurturing and empathetic role of the mother, a desire of the daughter not to be different, and the ethics of caring. Findings in this study reveal that the negative impacts of mother loss are felt in diffuse ways, such as a lack of academic or emotional encouragement. Many women discussed the need and availability of support groups including groups at colleges. One practical implication of these findings is schools need to become caring communities in which caring is the norm for all students and teachers, thereby providing all students with needed support in times of crisis. The implications for further research include the impact of the mother death on the education of daughters, how volunteering with an organization related to the cause of the mother's death assists the daughter and types of programs most important to a student's success in post-secondary education. Adolescents are in a time of great change in their lives, and for a daughter, the loss of a mother has an everlasting, life-changing impact.
ContributorsRatti, Theresa Helen McLuskey (Author) / Mccarty, Teresa L (Thesis advisor) / Fischman, Gustavo E. (Committee member) / Powers, Jeanne M. (Committee member) / Arizona State University (Publisher)
Created2011