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- Genre: Masters Thesis
Description
A new analytical method is proposed for measuring the deuterium to hydrogen ratio (D/H) of non-stoichiometric water in hydrous minerals via pyrolysis facilitated gas-chromatography - isotope ratio mass spectrometry (GC-IRMS). Previously published analytical methods have reported a poorly understood nonlinear dependence of D/H on sample size, for which any accurate correction is difficult. This sample size effect been variously attributed to kinetic isotope fractionation within the mass spectrometer and peripheral instruments, ion source linearity issues, and an unstable H_3^+-factor or incorrect H_3^+-factor calculations. The cause of the sample size effect is here identified by examinations of individual chromatograms as well as bulk data from chromatographic peaks. It is here determined that it is primarily an artifact of the calculations employed by the manufacturer's computer program, used to both monitor the functions of the mass spectrometer and to collect data. Ancillary causes of the sample size effect include a combination of persistent background interferences and chromatographic separation of the isotopologues of molecular hydrogen. Previously published methods are evaluated in light of these findings. A new method of H_3^+-factor and D/H calculation is proposed which makes portions of the Isodat software as well as other published calculation methods unnecessary. Using this new method, D/H is measured in non-stoichiometric water in chert from the Cretaceous Edwards Group, Texas, as well as the Precambrian Kromberg Formation, South Africa, to assess hydrological conditions as well as to estimate the maximum average surface temperature during precipitation of the chert. Data from Cretaceous chert are consistent with previously published data and interpretations, based upon conventional analyses of large samples. Data from Precambrian chert are consistent with maximum average surface temperatures approaching 65°C during the Archean, instead of the much lower temperatures derived from erroneous methods of sample preparation and analysis. D/H is likewise measured in non-stoichiometric water in silicified basalt from the Precambrian Hooggenoeg Complex, South Africa. Data are shown to be consistent with D/H of the Archean ocean similar to present day values.
ContributorsSheehan, Michael Robert (Author) / Knauth, Leroy P (Thesis advisor) / Anbar, Ariel (Committee member) / Farmer, Jack (Committee member) / Arizona State University (Publisher)
Created2011
Description
The spectacular geological panoramas of Grand Canyon National Park (GCNP) motivate the curiosity of visitors about geology. However, there is little research on how well these visitors understand the basic geologic principles on display in the Canyon walls. The new Trail of Time (ToT) interpretative exhibit along the South Rim uses Grand Canyon vistas to teach these principles. Now being visited by thousands daily, the ToT is a uniquely valuable setting for research on informal learning of geologic time and other basic geologic concepts. At the ToT, visitors are not only asked to comprehend a linear timeline, but to associate it with the strata exposed in the walls of the Canyon. The research addressed two primary questions: (1) how do visitors of the National Park use elements of the geologic landscape of the Grand Canyon to explain fundamental principles of relative geologic time? and (2) how do visitors reconcile the relationship between the horizontal ToT timeline and the vertical encoding of time in the strata exposed in the Canyon walls? Semi-structured interviews tracked participants' understanding of the ToT exhibit and of basic principles of geologic time. Administering the verbal analysis method of Chi (1997) to the interview transcripts, the researcher identified emergent themes related to how the respondents utilized the landscape to answer interview questions. Results indicate that a majority of respondents are able to understand principles of relative geologic time by utilizing both the observed and inferred landscape of Grand Canyon. Results also show that by applying the same integrated approach to the landscape, a majority of respondents are able to reconcile stratigraphic time with the horizontal ToT timeline. To gain deeper insight into the cognitive skills activated to correctly understand geologic principles the researcher used Dodick and Orion's application of Montangero's (1996) diachronic thinking model to code responses into three schemes: (1) transformation, (2) temporal organization, and (3) interstage linkage. Results show that correct responses required activation of the temporal organization scheme or the more advanced interstage linkage scheme. Appropriate application of these results can help inform the development of future outdoor interpretive geoscience exhibits.
ContributorsFrus, Rebecca (Author) / Semken, Steven (Thesis advisor) / Baker, Dale (Committee member) / Farmer, Jack (Committee member) / Arizona State University (Publisher)
Created2011
Description
For this study, the flora of the northern section of the Lower Verde River, within the Tonto National Forest in Yavapai and Gila Counties, Arizona was documented and analyzed. The study site, part of the northern leading edge of the Sonoran Desert, encompasses about 16,000 hectares and is located approximately 45 miles north-northeast of Phoenix. The area, extends roughly 28 river miles from the East Verde River in the north to Chalk Mountain in the south and is largely only accessible by foot, or by boat, and as a result was previously extremely under-collected. Over a three-year study period, from August, 2017 to May, 2020, 835 plant specimens were collected and identified, representing 360 species which, combined with earlier herbarium specimens collected by others, resulted in 427 plant species found in the study area. The plant diversity of this remote region reflects three distinct vegetation communities: upland Sonoran Desert, perennial riparian corridor, and semi-desert grasslands. Together, these communities act as an important transition zone between the Sonoran Desert and higher elevation habitats. Perennial streams are biodiversity hotspots within the study area. For example, the 400 hectares of Red Creek that falls within the study boundaries contain 28% of the total species. The study site contains several plants of conservation importance including 12 species endemic to Arizona, 22 vulnerable or imperiled species, five US Forest Service sensitive species, and one Federally Endangered species. In order to compare the diversity of the Lower Verde River Flora to nine other similar/related floras in Arizona, a species-area curve using five different models was generated. The resulting models showed the Lower Verde River flora to be very close to, although slightly below, the species-accumulation curve which may indicate that roughly 50-100 species may yet be added to the flora. This prediction seems realistic, as there were several locations that could not be collected due to remoteness and excessive heat.
ContributorsLarson-Whittaker, Cole (Author) / Pigg, Kathleen B (Thesis advisor) / Salywon, Andrew (Committee member) / Hodgson, Wendy (Committee member) / Arizona State University (Publisher)
Created2020
Description
Las Cienegas National Conservation Area (LCNCA), located in southeastern Arizona, is a place of ecological and historical value. It is host to rare native, threatened and endangered fauna and flora. as well as the site of the oldest operating ranch in the state. The first chapter of this thesis provides a preliminary flora of vascular plants at LCNCA assembled from field collections, photographs and herbarium specimens, and published through the online database SEINet. This preliminary flora of LCNCA identified 403 species in 76 families. Less than 6% of the flora is non-native, perennial forbs and grasses are the most abundant groups, and over a third of species in the checklist are associated with wetlands. LCNCA has been the target of adaptive management and conservation strategies to preserve its biotic diversity, and results from this study will help inform actions to preserve its rare habitats including cottonwood willow forests, mesquite bosques, sacaton grasslands, and cienegas. The second chapter investigates poorly understood aspects of the life history of the endangered Huachuca Water Umbel (Lilaeopsis schaffneriana subsp. recurva. Apiaceae) (hereafter HWU). This wetland species occurs in scattered cienegas and streams in southeastern Arizona and northern Sonora, Mexico. Three studies were conducted in a greenhouse to investigate seed bank establishment, seed longevity, and drought tolerance. A fourth study compared the reproductive phenology of populations transplanted at LCNCA to populations transplanted at urban sites like the Phoenix Zoo Conservation Center and the Desert Botanical Garden (DBG). Results from the greenhouse studies showed that HWU seeds were capable of germinating 15 years in a dormant state and that HWU seeds are present in the seed banks at sites where populations have been transplanted. Also, greenhouse experiments indicated that colonies of HWU can tolerate up to 3 weeks without flowing water, and up to 2 weeks in dry substrate. Transplanted populations at LCNCA monitored in the fourth study produced a higher abundance of flowers and fruit relative to urban sites (i.e. DBG) suggesting that in-situ conservation efforts may be more favorable for the recovery of HWU populations. Findings from these studies aim to inform gaps in knowledge highlighted in USFWS recovery plan for this species.
ContributorsSolves, Jean-Philippe Yvan (Author) / Pigg, Kathleen B (Thesis advisor) / Salywon, Andrew (Committee member) / Makings, Elizabeth (Committee member) / Arizona State University (Publisher)
Created2020
Description
The Phoenix Zoo, also known as the Arizona Center for Nature Conservation (PZ), is an Association of Zoos and Aquariums (AZA) accredited zoological institution and among largest-nonprofit, privately-owned zoos in the United States (Smith, 2020). Located within Papago Park in Phoenix (Maricopa County), Arizona, adjacent to the Desert Botanical Garden (DES), the two combine to bring environmental awareness to the Phoenix Metropolitan Region. While the DES specializes in botanical presentation, the ACNC focuses on zoological education. Whereas the flora of DES is well known, that of ACNC has yet to be completely documented. Given its role as a center for public engagement and education, documenting and mapping the floristic diversity of the Phoenix Zoo provides updated botanical information and occurrence records, an important component of understanding biodiversity for the Phoenix area. Between the fall of 2017 and the Spring of 2021, the grounds of the ACNC were walked within the 2-mile perimeter and surrounding exterior within Papago Park. Plant specimens and photographs were collected and archived for later identification using various botanical keys. Species names were verified through updated botanical databases such as Tropicos.org and worldfloraonline.org and compiled into a checklist. A total of 706 species have been identified, and of those 548 specimens have been collected as specimen vouchers. Of these, 120 are of taxa known to be native to the Phoenix Salt River Valley. While approximately 79 of those previously listed taxa native to Papago Park were either not found during this study or were extirpated from the grounds of the ACNC during urbanization of the region. There are 586 exotic taxa, some are common cultivars, while others are new to the region. Data for this survey is publicly available on SEINet, a regional network of North America herbaria (https://swbiodiversity.org/seinet/), as georeferenced voucher specimens, human observations, and photographs. Data is also partially duplicated through the iNaturalist platform (iNaturalist.com).
ContributorsBerry, Zachery R (Author) / Makings, Elizabeth (Thesis advisor) / Pigg, Kathleen B (Thesis advisor) / Wojciechowski, Martin F (Committee member) / Arizona State University (Publisher)
Created2021
Description
Baseline community composition data provides a snapshot in time that allows changes in composition to be monitored more effectively and can inform best practices. This study examines Arizona Upland plant community composition of the Sonoran Desert through three different lenses: floristic inventory, and fire and reseeding effects.
A floristic inventory was conducted at Cave Creek Regional Park (CCRP), Maricopa County, AZ. One hundred fifty-four taxa were documented within Park boundaries, including 148 species and six infraspecific taxa in 43 families. Asteraceae, Boraginaceae, and Fabaceae accounted for 40% of documented species and annuals accounted for 56% of documented diversity.
Fire effects were studied at three locations within McDowell Sonoran Preserve (MSP), Scottsdale, AZ. These fires occurred throughout the 1990s and recovered naturally. Fire and reseeding effects were studied at the site of a 2005 fire within CCRP that was reseeded immediately following the fire.
Two questions underlie the study regarding fire and reseeding effects: 1) How did fire and reseeding affect the cover and diversity of the plant communities? 2) Is there a difference in distribution of cover between treatments for individual species or growth habits? To address these questions, I compared burned and adjacent unburned treatments at each site, with an additional reseeded treatment added at CCRP.
MSP sites revealed overall diversity and cover was similar between treatments, but succulent cover was significantly reduced, and subshrub cover was significantly greater in the burn treatment. Seventeen species showed significant difference in distribution of cover between treatments.
The CCRP reseeded site revealed 11 of 28 species used in the seed mix persist 12 years post-fire. The reseeded treatment showed greater overall diversity than burned and unburned treatments. Succulent and shrub cover were significantly reduced by fire while subshrub cover was significantly greater in the reseeded treatment. Sixteen species showed significant difference in distribution of cover between treatments.
Fire appears to impact plant community composition across Arizona Upland sites. Choosing species to include in seed mixes for post-fire reseeding, based on knowledge of pre-fire species composition and individual species’ fire responses, may be a useful tool to promote post-fire plant community recovery.
A floristic inventory was conducted at Cave Creek Regional Park (CCRP), Maricopa County, AZ. One hundred fifty-four taxa were documented within Park boundaries, including 148 species and six infraspecific taxa in 43 families. Asteraceae, Boraginaceae, and Fabaceae accounted for 40% of documented species and annuals accounted for 56% of documented diversity.
Fire effects were studied at three locations within McDowell Sonoran Preserve (MSP), Scottsdale, AZ. These fires occurred throughout the 1990s and recovered naturally. Fire and reseeding effects were studied at the site of a 2005 fire within CCRP that was reseeded immediately following the fire.
Two questions underlie the study regarding fire and reseeding effects: 1) How did fire and reseeding affect the cover and diversity of the plant communities? 2) Is there a difference in distribution of cover between treatments for individual species or growth habits? To address these questions, I compared burned and adjacent unburned treatments at each site, with an additional reseeded treatment added at CCRP.
MSP sites revealed overall diversity and cover was similar between treatments, but succulent cover was significantly reduced, and subshrub cover was significantly greater in the burn treatment. Seventeen species showed significant difference in distribution of cover between treatments.
The CCRP reseeded site revealed 11 of 28 species used in the seed mix persist 12 years post-fire. The reseeded treatment showed greater overall diversity than burned and unburned treatments. Succulent and shrub cover were significantly reduced by fire while subshrub cover was significantly greater in the reseeded treatment. Sixteen species showed significant difference in distribution of cover between treatments.
Fire appears to impact plant community composition across Arizona Upland sites. Choosing species to include in seed mixes for post-fire reseeding, based on knowledge of pre-fire species composition and individual species’ fire responses, may be a useful tool to promote post-fire plant community recovery.
ContributorsBarron, Kara Lynn (Author) / Pigg, Kathleen B (Thesis advisor) / Stromberg, Juliet (Thesis advisor) / Makings, Elizabeth (Committee member) / McCue, Kimberlie (Committee member) / Arizona State University (Publisher)
Created2018