Matching Items (3)
Description
In this thesis, an issue is post at the beginning, that there is limited experience in connecting a battery analytical model with a battery circuit model. Then it describes the process of creating a new battery circuit model which is referred to as the kinetic battery model. During this process, a new general equation is derived. The original equation in the kinetic battery model is only valid at a constant current rate, while the new equation can be used for not only constant current but also linear or nonlinear current. Following the new equation, a circuit representation is built based on the kinetic battery model. Then, by matching the two sets of differential equations of the two models together, the ability to connect the analytical model with the battery circuit model is found. To verify the new battery circuit model is built correctly, the new circuit model is implemented into PSpice simulation software to test the charging performance with constant current, and Matlab/Simulink is also employed to simulate a realistic battery charging process with two-stage charging method. The results have shown the new circuit model is available to be used in realistic scenarios. And because the kinetic battery model can describe different types of rechargeable batteries, the new circuit model is also capable to be used for various battery types.
ContributorsKong, Dexinghui (Author) / Holbert, Keith E. (Thesis advisor) / Karady, George G. (Committee member) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2012
Description
Due to the increasing trend of electricity price for the future and the price reduction of solar electronics price led by the policy stimulus and the technological improvement, the residential distribution solar photovoltaic (PV) system’s market is prosperous. Excess energy can be sold back to the grid, however peak demand of a residential customer typically occurs in late afternoon/early evening when PV systems are not a productive. The solar PV system can provide residential customers sufficient energy during the daytime, even the exceeding energy can be sold back to the grid especially during the day with good sunlight, however, the peak demand of a regular family always appears during late afternoon and early evening which are not productive time for PV system. In this case, the PV customers only need the grid energy when other customers also need it the most. Because of the lower contribution of PV systems during times of peak demand, utilities are beginning to adjust rate structures to better align the bills paid by PV customers with the cost to the utility to serve those customers. Different rate structures include higher fixed charges, higher on-peak electricity prices, on-peak demand charges, or prices based on avoided costs. The demand charge and the on-peak energy charge significantly reduced the savings brought by the PV system. This will result in a longer the customer’s payback period. Eventually PV customers are not saving a lot in their electricity bill compare to those customers who do not own a PV system.
A battery system is a promising technology that can improve monthly bill savings since a battery can store the solar energy and the off-peak grid energy and release it later during the on-peak hours. Sponsored by Salt River Project (SRP), a smart home model consists 1.35 kW PV panels, a 7.76 kWh lithium-ion battery and an adjustable resistive load bank was built on the roof of Engineering Research Center (ERC) building. For analysis, data was scaled up by 6/1.35 times to simulate a real residential PV setup. The testing data had been continuously recorded for more than one year (Aug.2014 - Oct.2015) and a battery charging strategy was developed based on those data. The work of this thesis deals with the idea of this charging strategy and the economic benefits this charging strategy can bring to the PV customers. Part of this research work has been wrote into a conference paper which is accepted by IEEE PES General Meeting 2016. A new and larger system has been installed on the roof with 6 kW PV modules and 6 kW output integrated electronics. This project will go on and the method come up by this thesis will be tested.
A battery system is a promising technology that can improve monthly bill savings since a battery can store the solar energy and the off-peak grid energy and release it later during the on-peak hours. Sponsored by Salt River Project (SRP), a smart home model consists 1.35 kW PV panels, a 7.76 kWh lithium-ion battery and an adjustable resistive load bank was built on the roof of Engineering Research Center (ERC) building. For analysis, data was scaled up by 6/1.35 times to simulate a real residential PV setup. The testing data had been continuously recorded for more than one year (Aug.2014 - Oct.2015) and a battery charging strategy was developed based on those data. The work of this thesis deals with the idea of this charging strategy and the economic benefits this charging strategy can bring to the PV customers. Part of this research work has been wrote into a conference paper which is accepted by IEEE PES General Meeting 2016. A new and larger system has been installed on the roof with 6 kW PV modules and 6 kW output integrated electronics. This project will go on and the method come up by this thesis will be tested.
ContributorsWang, Xin'an (Author) / Karady, George G. (Thesis advisor) / Smedley, Grant (Committee member) / Qin, Jiangchao (Committee member) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2016
Description
A lack of adequate energy storage technologies is arguably the greatest hindrance to a modern sustainable energy infrastructure. Chemical energy storage, in the form of batteries, is an obvious solution to the problem. Unfortunately, today’s state of the art battery technologies fail to meet the desired metrics for full scale electric grid and/or electric vehicle role out. Considerable effort from scientists and engineers has gone into the pursuit of battery chemistries theoretically capable of far outperforming leading technologies like Li-ion cells. For instance, an anode of the relatively abundant and cheap metal, magnesium, would boost the specific energy by over 4.6 times that of the current Li-ion anode (LiC6).
The work presented here explores the compatibility of magnesium electrolytes in TFSI–-based ionic liquids with a Mg anode (TFSI = bis(trifluoromethylsulfonyl)imide). Correlations are made between the Mg2+ speciation conditions in bulk solutions (as determined via Raman spectroscopy) and the corresponding electrochemical behavior of the electrolytes. It was found that by creating specific chelating conditions, with an appropriate Mg salt, the desired electrochemical behavior could be obtained, i.e. reversible electrodeposition and dissolution. Removal of TFSI– contact ion pairs from the Mg2+ solvation shell was found to be essential for reversible electrodeposition. Ionic liquids with polyethylene glycol chains pendent from a parent pyrrolidinium cation were synthesized and used to create the necessary complexes with Mg2+, from Mg(BH4)2, so that reversible electrodeposition from a purely ionic liquid medium was achieved.
The following document discusses findings from several electrochemical experiments on magnesium electrolytes in ionic liquids. Explanations for the failure of many of these systems to produce reversible Mg electrodeposition are provided. The key characteristics of ionic liquid systems that are capable of achieving reversible Mg electrodeposition are also given.
The work presented here explores the compatibility of magnesium electrolytes in TFSI–-based ionic liquids with a Mg anode (TFSI = bis(trifluoromethylsulfonyl)imide). Correlations are made between the Mg2+ speciation conditions in bulk solutions (as determined via Raman spectroscopy) and the corresponding electrochemical behavior of the electrolytes. It was found that by creating specific chelating conditions, with an appropriate Mg salt, the desired electrochemical behavior could be obtained, i.e. reversible electrodeposition and dissolution. Removal of TFSI– contact ion pairs from the Mg2+ solvation shell was found to be essential for reversible electrodeposition. Ionic liquids with polyethylene glycol chains pendent from a parent pyrrolidinium cation were synthesized and used to create the necessary complexes with Mg2+, from Mg(BH4)2, so that reversible electrodeposition from a purely ionic liquid medium was achieved.
The following document discusses findings from several electrochemical experiments on magnesium electrolytes in ionic liquids. Explanations for the failure of many of these systems to produce reversible Mg electrodeposition are provided. The key characteristics of ionic liquid systems that are capable of achieving reversible Mg electrodeposition are also given.
ContributorsWatkins, Tylan Strike (Author) / Buttry, Daniel A (Thesis advisor) / Wolf, George (Committee member) / Williams, Peter (Committee member) / Arizona State University (Publisher)
Created2016