Matching Items (5)
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- All Subjects: Planetary Science
- Creators: Hervig, Richard
- Creators: Li, Mingming
Description
Historically, uranium has received intense study of its chemical and isotopic properties for use in the nuclear industry, but has been largely ignored by geoscientists despite properties that make it an intriguing target for geochemists and cosmochemists alike. Uranium was long thought to have an invariant 238U/235U ratio in natural samples, making it uninteresting for isotopic work. However, recent advances in mass spectrometry have made it possible to detect slight differences in the 238U/235U ratio, creating many exciting new opportunities for U isotopic research. Using uranium ore samples from diverse depositional settings from around the world, it is shown that the low-temperature redox transition of uranium (U6+ to U4+) causes measurable fractionation of the 238U/235U ratio. Moreover, it is shown experimentally that a coordination change of U can also cause measurable fractionation in the 238U/235U ratio. This improved understanding of the fractionation mechanisms of U allows for the use of the 238U/235U ratio as a paleoredox proxy. The 238U/235U ratios of carbonates deposited spanning the end-Permian extinction horizon provide evidence of pronounced and persistent widespread ocean anoxia at, or immediately preceding, the extinction boundary. Variable 238U/235U ratios correlated with proxies for initial Cm/U in the Solar System's earliest objects demonstrates the existence of 247Cm in the early Solar System. Proof of variable 238U/235U ratios in meteoritic material forces a substantive change in the previously established procedures of Pb-Pb dating, which assumed an invariant 238U/235U ratio. This advancement improves the accuracy of not only the Pb-Pb chronometer that directly utilizes the 238U/235U ratio, but also for short-lived radiometric dating techniques that indirectly use the 238U/235U ratio to calculate ages of Solar System material.
ContributorsBrennecka, Gregory A (Author) / Anbar, Ariel D (Thesis advisor) / Wadhwa, Meenakshi (Thesis advisor) / Herrmann, Achim D (Committee member) / Hervig, Richard (Committee member) / Young, Patrick (Committee member) / Arizona State University (Publisher)
Created2011
Description
The present understanding of the formation and evolution of the earliest bodies in the Solar System is based in large part on geochemical and isotopic evidences contained within meteorites. The differentiated meteorites (meteorites originating from bodies that have experienced partial to complete melting) are particularly useful for deciphering magmatic processes occurring in the early Solar System. A rare group of differentiated meteorites, the angrites, are uniquely suited for such work. The angrites have ancient crystallization ages, lack secondary processing, and have been minimally affected by shock metamorphism, thus allowing them to retain their initial geochemical and isotopic characteristics at the time of formation. The scarcity of angrite samples made it difficult to conduct comprehensive investigations into the formation history of this unique meteorite group. However, a dramatic increase in the number of angrites recovered in recent years presents the opportunity to expand our understanding of their petrogenesis, as well as further refine our knowledge of the initial isotopic abundances in the early Solar System as recorded by their isotopic systematics. Using a combination of geochemical tools (radiogenic isotope chronometers and trace element chemistry), I have investigated the petrogenetic history of a group of four angrites that sample a range of formation conditions (cooling histories) and crystallization ages. Through isotope ratio measurements, I have examined a comprehensive set of long- and short-lived radiogenic isotope systems (26Al-26Mg, 87Rb-87Sr, 146Sm-142Nd, 147Sm-143Nd, and 176Lu-176Hf) within these four angrites. The results of these measurements provide information regarding crystallization ages, as well as revised estimates for the initial isotopic abundances of several key elements in the early Solar System. The determination of trace element concentrations in individual mineral phases, as well as bulk rock samples, provides important constraints on magmatic processes occurring on the angrite parent body. The measured trace element abundances are used to estimate the composition of the parent melts of individual angrites, examine crystallization conditions, and investigate possible geochemical affinities between various angrites. The new geochemical and isotopic measurements presented here significantly expand our understanding of the geochemical conditions found on the angrite parent body and the environment in which these meteorites formed.
ContributorsSanborn, Matthew E (Author) / Wadhwa, Meenakshi (Thesis advisor) / Hervig, Richard (Committee member) / Sharp, Thomas (Committee member) / Clarke, Amanda (Committee member) / Williams, Lynda (Committee member) / Carlson, Richard (Committee member) / Arizona State University (Publisher)
Created2012
Description
This project focuses on using Neutral Gas and Ion Mass Spectrometer (NGIMS) density data for carbon dioxide, oxygen, carbon monoxide, and nitrogen during deep dip campaigns 5, 6, and 8. Density profiles obtained from NGIMS were plotted against simulated density profiles from the Mars Global Ionosphere-Thermosphere Model (MGITM). Averaged temperature profiles were also plotted for the three deep dip campaigns, using NGIMS data and MGITM output. MGITM was also used as a tool to uncover potential heat balance terms needed to reproduce the mean density and temperature profiles measured by NGIMS.
This method of using NGIMS data as a validation tool for MGITM simulations has been tested previously using dayside data from deep dip campaigns 2 and 8. In those cases, MGITM was able to accurately reproduce the measured density and temperature profiles; however, in the deep dip 5 and 6 campaigns, the results are not quite the same, due to the highly variable nature of the nightside thermosphere. MGITM was able to fairly accurately reproduce the density and temperature profiles for deep dip 5, but the deep dip 6 model output showed unexpected significant variation. The deep dip 6 results reveal possible changes to be made to MGITM to more accurately reflect the observed structure of the nighttime thermosphere. In particular, upgrading the model to incorporate a suitable gravity wave parameterization should better capture the role of global winds in maintaining the nighttime thermospheric structure.
This project reveals that there still exist many unknowns about the structure and dynamics of the night side of the Martian atmosphere, as well as significant diurnal variations in density. Further study is needed to uncover these unknowns and their role in atmospheric mass loss.
This method of using NGIMS data as a validation tool for MGITM simulations has been tested previously using dayside data from deep dip campaigns 2 and 8. In those cases, MGITM was able to accurately reproduce the measured density and temperature profiles; however, in the deep dip 5 and 6 campaigns, the results are not quite the same, due to the highly variable nature of the nightside thermosphere. MGITM was able to fairly accurately reproduce the density and temperature profiles for deep dip 5, but the deep dip 6 model output showed unexpected significant variation. The deep dip 6 results reveal possible changes to be made to MGITM to more accurately reflect the observed structure of the nighttime thermosphere. In particular, upgrading the model to incorporate a suitable gravity wave parameterization should better capture the role of global winds in maintaining the nighttime thermospheric structure.
This project reveals that there still exist many unknowns about the structure and dynamics of the night side of the Martian atmosphere, as well as significant diurnal variations in density. Further study is needed to uncover these unknowns and their role in atmospheric mass loss.
ContributorsRobinson, Jenna (Author) / Desch, Steven (Thesis director) / Hervig, Richard (Committee member) / School of Earth and Space Exploration (Contributor) / School for the Future of Innovation in Society (Contributor) / School of International Letters and Cultures (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
Hydrogen is the main constituent of stars, and thus dominates the protoplanetary disc from which planets are born. Many planets may at some point in their growth have a high-pressure interface between refractory planetary materials and ahydrogen-dominated atmosphere. However, little experimental data for these materials at the relevant pressure-temperature conditions exists. I have experimentally explored the interactions between planetary materials and hydrogen at high P-T conditions utilizing the pulsed laser-heated diamond-anvil cell. First, I found that ferric/ferrous iron (as Fe2O3 hematite and (Mg,Fe)O ferropericlase) are reduced to metal by hydrogen: Fe2O3 + 4H2 → 2FeO + H2O + 3H2 → 2FeH + 3H2O and (Mg1−xFex) O + 3/2 xH2 → xFeH + (1 − x) MgO + xH2O respectively. This reduction of iron by hydrogen is important because it produces iron metal and water from iron oxide. This can partition H into the core (as FeH) or mantle (as H2O/OH−) of a growing planet.
Next, I expanded my starting materials to silicates. I conducted experiments on San Carlos Olivine at pressures of 5-42 GPa. In the presence hydrogen, I observed the breakdown of molten magnesium silicate and the reduction of both iron and silicon to metal, forming alloys of both Fe-H and Fe-Si: Mg2SiO4 + 2H2 + 3Fe →
2MgO + FeSi + 2FeH + 2H2O.
Similar experiments using natural fayalite (Fe2SiO4) as a starting material at pressures of 5-21 GPa yielded similar results. Hydrogen reduced iron to metal as it did in experiments with iron oxides. Unlike with San Carlos olivine, above 10 GPa silicon remained oxidized, implying the following reaction: Fe2SiO4 + 3H2 → 2FeH+2H2O +SiO2. However, below 7 GPa, silicon reduces and alloys with iron. The formation of Fe-Si alloys from silicates facilitated by hydrogen could have important effects for core composition in growing planets. I also observed at low pressures (<10 GPa), quenched iron melt can trap more hydrogen than previously thought (H/Fe nearly 2 instead of 1). This may have important effects for the chemical sequestration of a hydrogen atmosphere at shallow depths in an early magma ocean.
All of the experimental work presented herein show that the composition, chemical partitioning, and phase stability of the condensed portion of growing planets can be modified via interaction with overlaying or ingassed volatile species.
ContributorsAllen-Sutter, Harrison (Author) / Shim, Sang-Heon Dan (Thesis advisor) / Li, Mingming (Committee member) / Leinenweber, Kurt D (Committee member) / Tyburczy, James A (Committee member) / Gabriel, Travis S.J. (Committee member) / Arizona State University (Publisher)
Created2022
Description
The pace of exoplanet discoveries has rapidly accelerated in the past few decades and the number of planets with measured mass and radius is expected to pick up in the coming years. Many more planets with a size similar to earth are expected to be found. Currently, software for characterizing rocky planet interiors is lacking. There is no doubt that a planet’s interior plays a key role in determining surface conditions including atmosphere composition and land area. Comparing data with diagrams of mass vs. radius for terrestrial planets provides only a first-order estimate of the internal structure and composition of planets [e.g. Seager et al 2007]. This thesis will present a new Python library, ExoPlex, which has routines to create a forward model of rocky exoplanets between 0.1 and 5 Earth masses. The ExoPlex code offers users the ability to model planets of arbitrary composition of Fe-Si-Mg-Al-Ca-O in addition to a water layer. This is achieved by modeling rocky planets after the earth and other known terrestrial planets. The three distinct layers which make up the Earth's internal structure are: core, mantle, and water. Terrestrial planet cores will be dominated by iron however, like earth, there may be some quantity of light element inclusion which can serve to enhance expected core volumes. In ExoPlex, these light element inclusions are S-Si-O and are included as iron-alloys. Mantles will have a more diverse mineralogy than planet cores. Unlike most other rocky planet models, ExoPlex remains unbiased in its treatment of the mantle in terms of composition. Si-Mg-Al-Ca oxide components are combined by predicting the mantle mineralogy using a Gibbs free energy minimization software package called Perple\_X [Connolly 2009]. By allowing an arbitrary composition, ExoPlex can uniquely model planets using their host star’s composition as an indicator of planet composition. This is a proven technique [Dorn et al 2015] which has not yet been widely utilized, possibly due to the lack of availability of easy to use software. I present a model sensitivity analysis to indicate the most important parameters to constrain in future observing missions. ExoPlex is currently available on PyPI so it may be installed using pip or conda on Mac OS or Linux based operating systems. It requires a specific scripting environment which is explained in the documentation currently stored on the ExoPlex GitHub page.
ContributorsLorenzo, Alejandro M., Jr (Author) / Desch, Steven (Thesis advisor) / Shim, Dan S.-H. (Committee member) / Line, Michael (Committee member) / Li, Mingming (Committee member) / Arizona State University (Publisher)
Created2018