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- All Subjects: Geochemistry
- All Subjects: Planetary Science
- Creators: School of Earth and Space Exploration
In this study, the influence of fluid mixing on temperature and geochemistry of hot spring fluids is investigated. Yellowstone National Park (YNP) is home to a diverse range of hot springs with varying temperature and chemistry. The mixing zone of interest in this paper, located in Geyser Creek, YNP, has been a point of interest since at least the 1960’s (Raymahashay, 1968). Two springs, one basic (~pH 7) and one acidic (~pH 3) mix together down an outflow channel. There are visual bands of different photosynthetic pigments which suggests the creation of temperature and chemical gradients due to the fluids mixing. In this study, to determine if fluid mixing is driving these changes of temperature and chemistry in the system, a model that factors in evaporation and cooling was developed and compared to measured temperature and chemical data collected downstream. Comparison of the modeled temperature and chemistry to the measured values at the downstream mixture shows that many of the ions, such as Cl⁻, F⁻, and Li⁺, behave conservatively with respect to mixing. This indicates that the influence of mixing accounts for a large proportion of variation in the chemical composition of the system. However, there are some chemical constituents like CH₄, H₂, and NO₃⁻, that were not conserved, and the concentrations were either depleted or increased in the downstream mixture. Some of these constituents are known to be used by microorganisms. The development of this mixing model can be used as a tool for predicting biological activity as well as building the framework for future geochemical and computational models that can be used to understand the energy availability and the microbial communities that are present.
Relatively small amounts of H2O frost (~ 10–100 μm) are also likely to form diurnally and seasonally. The global H2O frost point distribution follows water vapor column abundance closely, with a weak correlation with local surface pressure. There is a strong hemispherical dependence on the frost point temperature—with the northern hemisphere having a higher frost point (in general) than the southern hemisphere—likely due to elevation differences. Unlike the distribution of CO2 frost temperatures, there is little to no correlation with surface thermophysical properties (thermal inertia, albedo, etc.). Modeling suggests H2O frosts can briefly attain melting point temperatures for a few hours if present under thin layers of dust, and can perhaps play a role in present-day equatorial mass-wasting events (eg. McEwen et al., 2018).
Based on seasonal constraints on gully activity timing, preliminary field studies, frost presence from visible imagery, spectral data and thermal data (this work), it is likely that most present-day activity can be explained by frosts (primarily CO2, and possibly H2O). We predict that the conditions necessary for significant present-day activity include formation of sufficient amounts of frost (> ~20 cm/year) within loose, unconsolidated sediments (I < ~ 350) on available slopes. However, whether or not present-day gully activity is representative of gully formation as a whole is still open to debate, and the details on CO2 frost-induced gully formation mechanisms remain unresolved.
This method of using NGIMS data as a validation tool for MGITM simulations has been tested previously using dayside data from deep dip campaigns 2 and 8. In those cases, MGITM was able to accurately reproduce the measured density and temperature profiles; however, in the deep dip 5 and 6 campaigns, the results are not quite the same, due to the highly variable nature of the nightside thermosphere. MGITM was able to fairly accurately reproduce the density and temperature profiles for deep dip 5, but the deep dip 6 model output showed unexpected significant variation. The deep dip 6 results reveal possible changes to be made to MGITM to more accurately reflect the observed structure of the nighttime thermosphere. In particular, upgrading the model to incorporate a suitable gravity wave parameterization should better capture the role of global winds in maintaining the nighttime thermospheric structure.
This project reveals that there still exist many unknowns about the structure and dynamics of the night side of the Martian atmosphere, as well as significant diurnal variations in density. Further study is needed to uncover these unknowns and their role in atmospheric mass loss.
Lightning in the atmosphere of Venus is either ubiquitous, rare, or non-existent, depending on how one interprets diverse observations. Quantifying if, when, or where lightning occurs would provide novel information about Venus’s atmospheric dynamics and chemistry. Lightning is also a potential risk to future missions, which could float in the cloud layers (~50–70 km above the surface) for up to an Earth-year. For decades, spacecraft and ground-based telescopes have searched for lightning at Venus, using many instruments including magnetometers, radios, and optical cameras. Two surveys (from the Akatsuki orbiter and the 61-inch telescope on Mt. Bigelow, Arizona) observed several optical flashes that are often attributed to lightning. We expect that lightning at Venus is bright near 777 nm (the unresolved triplet emission lines of excited atomic oxygen) due to the high abundance of oxygen as carbon dioxide. However, meteor fireballs at Venus are probably bright at the same wavelength for the same reason. Here we derive power laws that quantify the rate and brightness of optical flashes from meteor fireballs at Venus. We calculated that meteor fireballs are statistically likely to cause bright optical flashes at rates that are consistent with published observations. Small meteors burn up at altitudes of ~100 km, roughly twice as high above the surface as the clouds. Therefore, we conclude that there is no concrete evidence that lightning strikes would be a hazard to missions that pass through or dwell within the clouds of Venus.
During the Dawn mission, bright spots were discovered on the surface of the dwarf planet Ceres, which were determined to be evaporite deposits of sodium carbonate, ammonium carbonate, and hydrohalite. These deposits are significant because they indicate the presence of subsurface water and potential geologic activity on Ceres. These evaporites form from the brine-water mixture in the deep Ceres reservoir, which likely possesses the conditions ideal for forming complex organics. Here, we report the results of a suite of laboratory techniques (CHN Elemental Analyzer, Secondary Ion Mass Spectrometry, Fourier-Transform Infrared Spectroscopy, Gas Chromatography, and Brunauer-Emmett-Teller Analysis) for quantifying the likelihood of primordial carbon survival and distribution in analog materials found on Ceres, particularly in salt evaporates. We are specifically looking at if the amino acid glycine can be preserved in sodium chloride crystals. Our results conclude that if the Ceres brine reservoir is saturated with organics, and with the lower limits that we have for our instrumentation thus far, these techniques should be more than sufficient to measure glycine content should we ever receive samples from Ceres.
