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Hydrogen is the main constituent of stars, and thus dominates the protoplanetary disc from which planets are born. Many planets may at some point in their growth have a high-pressure interface between refractory planetary materials and ahydrogen-dominated atmosphere. However, little experimental data for these materials at the relevant pressure-temperature conditions

Hydrogen is the main constituent of stars, and thus dominates the protoplanetary disc from which planets are born. Many planets may at some point in their growth have a high-pressure interface between refractory planetary materials and ahydrogen-dominated atmosphere. However, little experimental data for these materials at the relevant pressure-temperature conditions exists. I have experimentally explored the interactions between planetary materials and hydrogen at high P-T conditions utilizing the pulsed laser-heated diamond-anvil cell. First, I found that ferric/ferrous iron (as Fe2O3 hematite and (Mg,Fe)O ferropericlase) are reduced to metal by hydrogen: Fe2O3 + 4H2 → 2FeO + H2O + 3H2 → 2FeH + 3H2O and (Mg1−xFex) O + 3/2 xH2 → xFeH + (1 − x) MgO + xH2O respectively. This reduction of iron by hydrogen is important because it produces iron metal and water from iron oxide. This can partition H into the core (as FeH) or mantle (as H2O/OH−) of a growing planet. Next, I expanded my starting materials to silicates. I conducted experiments on San Carlos Olivine at pressures of 5-42 GPa. In the presence hydrogen, I observed the breakdown of molten magnesium silicate and the reduction of both iron and silicon to metal, forming alloys of both Fe-H and Fe-Si: Mg2SiO4 + 2H2 + 3Fe → 2MgO + FeSi + 2FeH + 2H2O. Similar experiments using natural fayalite (Fe2SiO4) as a starting material at pressures of 5-21 GPa yielded similar results. Hydrogen reduced iron to metal as it did in experiments with iron oxides. Unlike with San Carlos olivine, above 10 GPa silicon remained oxidized, implying the following reaction: Fe2SiO4 + 3H2 → 2FeH+2H2O +SiO2. However, below 7 GPa, silicon reduces and alloys with iron. The formation of Fe-Si alloys from silicates facilitated by hydrogen could have important effects for core composition in growing planets. I also observed at low pressures (<10 GPa), quenched iron melt can trap more hydrogen than previously thought (H/Fe nearly 2 instead of 1). This may have important effects for the chemical sequestration of a hydrogen atmosphere at shallow depths in an early magma ocean. All of the experimental work presented herein show that the composition, chemical partitioning, and phase stability of the condensed portion of growing planets can be modified via interaction with overlaying or ingassed volatile species.
ContributorsAllen-Sutter, Harrison (Author) / Shim, Sang-Heon Dan (Thesis advisor) / Li, Mingming (Committee member) / Leinenweber, Kurt D (Committee member) / Tyburczy, James A (Committee member) / Gabriel, Travis S.J. (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Many planetary science missions study thermophysical properties of surfaces using infrared spectrometers and infrared cameras. Thermal inertia is a frequently derived thermophysical property that quantifies the ability for heat to exchange through planetary surfaces.

To conceptualize thermal inertia, the diffusion equation analogies are extended using a general effusivity term: the square

Many planetary science missions study thermophysical properties of surfaces using infrared spectrometers and infrared cameras. Thermal inertia is a frequently derived thermophysical property that quantifies the ability for heat to exchange through planetary surfaces.

To conceptualize thermal inertia, the diffusion equation analogies are extended using a general effusivity term: the square root of a product of conductivity and capacity terms. A hypothetical thermal inductance was investigated for diurnal planetary heating. The hyperbolic heat diffusion equation was solved to derive an augmented thermal inertia. The hypothetical thermal inductance was modeled with negligible effect on Mars.

Extending spectral performance of infrared cameras was desired for colder bodies in the outer solar system where peak infrared emission is at longer wavelengths. The far-infrared response of an infrared microbolometer array with a retrofitted diamond window was determined using an OSIRIS-REx—OTES interferometer. An instrument response function of the diamond interferometer-microbolometer system shows extended peak performance from 15 µm out to 20 µm and 40% performance to at least 30 µm. The results are folded into E-THEMIS for the NASA flagship mission: Europa Clipper.

Infrared camera systems are desired for the expanding smallsat community that can inherit risk and relax performance requirements. The Thermal-camera for Exploration, Science, and Imaging Spacecraft (THESIS) was developed for the Prox-1 microsat mission. THESIS, incorporating 2001 Mars Odyssey—THEMIS experience, consists of an infrared camera, a visible camera, and an instrument computer. THESIS was planned to provide images for demonstrating autonomous proximity operations between two spacecraft, verifying deployment of the Planetary Society’s LightSail-B, and conducting remote sensing of Earth. Prox-1—THESIS was selected as the finalist for the competed University Nanosatellite Program-7 and was awarded a launch on the maiden commercial SpaceX Falcon Heavy. THESIS captures 8-12 µm IR images with 100 mm optics and RGB color images with 25 mm optics. The instrument computer was capable of instrument commanding, automatic data processing, image storage, and telemetry recording. The completed THESIS has a mass of 2.04 kg, a combined volume of 3U, and uses 7W of power. THESIS was designed, fabricated, integrated, and tested in ASU’s 100K clean lab.
ContributorsVeto, Michael (Author) / Christensen, Philip C (Thesis advisor) / Bell III, Jim (Committee member) / Clarke, Amanda B (Committee member) / Asphaug, Erik (Committee member) / Sariapli, Srikanth (Committee member) / Ruff, Steven (Committee member) / Arizona State University (Publisher)
Created2018
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Description
The pace of exoplanet discoveries has rapidly accelerated in the past few decades and the number of planets with measured mass and radius is expected to pick up in the coming years. Many more planets with a size similar to earth are expected to be found. Currently, software for characterizing

The pace of exoplanet discoveries has rapidly accelerated in the past few decades and the number of planets with measured mass and radius is expected to pick up in the coming years. Many more planets with a size similar to earth are expected to be found. Currently, software for characterizing rocky planet interiors is lacking. There is no doubt that a planet’s interior plays a key role in determining surface conditions including atmosphere composition and land area. Comparing data with diagrams of mass vs. radius for terrestrial planets provides only a first-order estimate of the internal structure and composition of planets [e.g. Seager et al 2007]. This thesis will present a new Python library, ExoPlex, which has routines to create a forward model of rocky exoplanets between 0.1 and 5 Earth masses. The ExoPlex code offers users the ability to model planets of arbitrary composition of Fe-Si-Mg-Al-Ca-O in addition to a water layer. This is achieved by modeling rocky planets after the earth and other known terrestrial planets. The three distinct layers which make up the Earth's internal structure are: core, mantle, and water. Terrestrial planet cores will be dominated by iron however, like earth, there may be some quantity of light element inclusion which can serve to enhance expected core volumes. In ExoPlex, these light element inclusions are S-Si-O and are included as iron-alloys. Mantles will have a more diverse mineralogy than planet cores. Unlike most other rocky planet models, ExoPlex remains unbiased in its treatment of the mantle in terms of composition. Si-Mg-Al-Ca oxide components are combined by predicting the mantle mineralogy using a Gibbs free energy minimization software package called Perple\_X [Connolly 2009]. By allowing an arbitrary composition, ExoPlex can uniquely model planets using their host star’s composition as an indicator of planet composition. This is a proven technique [Dorn et al 2015] which has not yet been widely utilized, possibly due to the lack of availability of easy to use software. I present a model sensitivity analysis to indicate the most important parameters to constrain in future observing missions. ExoPlex is currently available on PyPI so it may be installed using pip or conda on Mac OS or Linux based operating systems. It requires a specific scripting environment which is explained in the documentation currently stored on the ExoPlex GitHub page.
ContributorsLorenzo, Alejandro M., Jr (Author) / Desch, Steven (Thesis advisor) / Shim, Dan S.-H. (Committee member) / Line, Michael (Committee member) / Li, Mingming (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Seismic observations have revealed two large low shear velocity provinces (LLSVPs) in the lowermost mantle beneath Pacific and Africa. One hypothesis for the origin of LLSVPs is that they are caused by accumulation of subducted oceanic crust on the core-mantle boundary (CMB). Here, I perform high resolution geodynamical calculations to

Seismic observations have revealed two large low shear velocity provinces (LLSVPs) in the lowermost mantle beneath Pacific and Africa. One hypothesis for the origin of LLSVPs is that they are caused by accumulation of subducted oceanic crust on the core-mantle boundary (CMB). Here, I perform high resolution geodynamical calculations to test this hypothesis. The result shows that it is difficult for a thin (~ 6 km) subducted oceanic crust to accumulate on the CMB, and the major part of it is viscously stirred into the surrounding mantle. Another hypothesis for the origin of LLSVPs is that they are caused by thermochemical piles of more-primitive material which is remnant of Earth's early differentiation. In such case, a significant part of the subducted oceanic crust would enter the more-primitive reservoir, while other parts are either directly entrained into mantle plumes forming on top of the more-primitive reservoir or stirred into the background mantle. As a result, mantle plumes entrain a variable combination of compositional components including more-primitive material, old oceanic crust which first enters the more-primitive reservoir and is later entrained into mantle plumes with the more-primitive material, young oceanic crust which is directly entrained into mantle plumes without contacting the more-primitive reservoir, and depleted background mantle material. The result reconciles geochemical observation of multiple compositional components and varying ages of oceanic crust in the source of ocean-island basalts. Seismic studies have detected ultra-low velocity zones (ULVZs) in some localized regions on the CMB. Here, I present 3D thermochemical calculations to show that the distribution of ULVZs provides important information about their origin. ULVZs with a distinct composition tend to be located at the edges of LLSVPs, while ULVZs solely caused by partial melting tend to be located inboard from the edges of LLSVPs. This indicates that ULVZs at the edges of LLSVPs are best explained by distinct compositional heterogeneity, while ULVZs located insider of LLSVPs are better explained by partial melting. The results provide additional constraints for the origin of ULVZs.
ContributorsLi, Mingming (Author) / McNamara, Allen K (Thesis advisor) / Garnero, Edward J (Committee member) / Shim, Sang-Heon (Committee member) / Tyburczy, James (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2015