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Description
Microsolvation studies have begun to shed the light on the impact that single water molecules have on the structure of a molecule. The difference in behavior that molecules show when exposed to an increasing number of water molecules has been considered important but remains elusive. The cluster distributions of formic acid were studied for its known importance as an intermediate in the water gas shift reaction. Implementations of the water gas shift reaction range from a wide range of applications. Studies have proposed implementations such as variety such as making water on the manned mission to mars and as an industrial energy source. The reaction pathway of formic acid favors decarboxylation in solvated conditions but control over the pathway is an important field of study. Formic acid was introduced into a high vacuum system in the form of a cluster beam via supersonic expansion and was ionized with the second harmonic (400nm) of a pump-probe laser. Mass spectra showed a ‘magic’ 5,1 (formic acid, water) peak which showed higher intensity than was usually observed in clusters with 1 water molecule. Peak integration showed a higher relative abundance for the 5,1 cluster as well and showed the increased binding favorability of this conformation. As a result, there is an enhanced probability of molecules sticking together in this arrangement and this is due to the stable, cage-like structure that the formic acid forms when surrounding the water molecule.
ContributorsQuiroz, Lenin Mejia (Author) / Sayres, Scott G. (Thesis director) / Mills, Jeremy (Committee member) / Biegasiewicz, Kyle (Committee member) / School of Molecular Sciences (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
As a demonstration study of low-resolution spectrophotometry, the photometric redshift estimation with narrow-band optical photometry of nine galaxy clusters is presented in this thesis. A complete data reduction process of the photometryusing up to 16 10nm wide narrow-band optical filters from 490nm − 660nm are provided. Narrow-band photometry data are combined with broad-band photometry (SDSS/Pan-STARRS) for photometric redshift fitting. With available spectroscopic
redshift data from eight of the fields, I evaluated the fitted photometric redshift results and showed that combining broad-band photometric data with narrow-band data result in improvements of factor 2-3, compared to redshift estimations from
broad-band photometry alone. With 15 or 16 narrow-band data combined with SDSS (Sloan Digital Sky Survey) or Pan-STARRS1 (The Panoramic Survey Telescope and Rapid Response System) data, a Normalized Median Absolute Deviation of σNMAD ∼ 0.01−0.016 can be achieved.
The multiband images of galaxy cluster ABELL 611 have been used to further study intracluster light around its brightest cluster galaxy (BCG). It can be shown here that fitting of BCG+ICL stellar properties using the averaged 1-dimensional
radial profile is possible up to ∼ 100kpc within this cluster. The decreasing in age of the stellar population as a function of radius from the BCG+ICL profile, though not entirely conclusive, demonstrates possible future application of low-resolution
spectrophotometry on the ICL studies.
Finally, Spectro-Photometer for the History of the Universe, Epoch of Reionization, and Ices Explorer (SPHEREx) mission planning study are covered, and a methodology of visualization tool for target availability is described.
ContributorsWang, Pao-Yu (Author) / Mauskopf, Philip (Thesis advisor) / Butler, Nathaniel (Committee member) / Jansen, Rolf (Committee member) / Vachaspati, Tanmay (Committee member) / Arizona State University (Publisher)
Created2022