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There are many outstanding questions regarding the petrologic processes that give rise to andesitic and basaltic magmas in subduction zones, including the specifics that govern their geographical distribution in a given arc segment. Here I investigate the genesis of calc-alkaline and tholeiitic basalts from the Lassen Volcanic Center in order

There are many outstanding questions regarding the petrologic processes that give rise to andesitic and basaltic magmas in subduction zones, including the specifics that govern their geographical distribution in a given arc segment. Here I investigate the genesis of calc-alkaline and tholeiitic basalts from the Lassen Volcanic Center in order to determine the pressure, temperature, source composition, and method of melting that lead to the production of melt in the mantle below Lassen. To this aim, a suite of primitive basalts (i.e. SiO2<52 and Mg#>65) are corrected for fractional crystallization by adding minerals back to the bulk rock composition with the goal of returning them to a primary composition in equilibrium with the mantle. Thermobarometry of the primary melt compositions is conducted to determine temperature and pressure of melting, in addition to a forward mantle modeling technique to simulate mantle melting at varying pressures to constrain source composition and method of melting (batch vs. fractional). The results from the two techniques agree on an average depth of melt extraction of 36 km and a source composition similar to that of depleted mantle melted by batch melting. Although attempted for both calc-alkaline and tholeiitic basalts, the fractional crystallization correction and thus the pressure-temperature calculations were only successful for tholeiitic basalts due to the hydrous nature of the calc-alkaline samples. This leaves an opportunity to repeat this study with parameters appropriate for hydrous basalts, allowing for the comparison of calc-alkaline and tholeiitic melting conditions.
ContributorsSheppard, Katherine Davis (Author) / Till, Christy (Thesis director) / Hervig, Richard (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2015-05
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Description
Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better

Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better understanding of their eruptions and associated hazards. I will approach this analysis by focusing on volcanic bombs and ballistics, which are large clots of lava that are launched from the volcanic vent, follow ballistic trajectories, and can travel meters to a few kilometers from their source (e.g. Fagents and Wilson 1993; Waitt et al. 1995).
Tecolote Volcano in the Pinacate Volcanic Field in Mexico contains multiple vents within a horseshoe-shaped crater that have all produced various ejecta (Zawacki et al. 2019). The objectives of this research are to map ballistic distribution to understand the relationship between the source vent or vents and the bombs and ballistics that litter the region around Tecolote, and interpret the eruption conditions that ejected those bombs by using their distributions, morphologies, and fine-scale textures.
The findings of this work are that these bombs are apparently from the last stages of the eruption, succeeding the final lava flows. The interiors and exteriors of the bombs display different cooling rates which can are indicated by the fabric found within. Using this, certain characteristics of the bombs during eruption were extrapolated. The ‘cow pie’ bombs were determined to be the least viscous or contained a higher gas content at the time of eruption. Whereas the ribbon/rope bombs were determined to be the most viscous or contained a lesser gas content. Looking at the Southern Bomb Field site, it is dominated by large bombs that were during flight were molded into aerodynamic shapes. The Eastern Rim site is dominated by smaller bombs that appeared to be more liquid during the eruption. This difference in the two sites is a probable indication of at least two different eruptive events of different degrees of explosivity. Overall, aerodynamic bombs are more common and extend to greater distances from the presumed vent (up to 800 m), while very fluidal bombs are uncommon beyond 500 meters. Fluidal bombs (‘cow pie’, ‘ribbon’, ‘rope/spindle’) show a clear trend in decreasing size with distance from vent, whereas the size-distance trend is less dramatic for the aerodynamic bombs.
ContributorsWest, Jacob Alexander (Co-author) / West, Jacob (Co-author) / Clarke, Amanda (Thesis director) / Arrowsmith, Ramon (Committee member) / Roggensack, Kurt (Committee member) / School of Earth and Space Exploration (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
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Description
This project focuses on using Neutral Gas and Ion Mass Spectrometer (NGIMS) density data for carbon dioxide, oxygen, carbon monoxide, and nitrogen during deep dip campaigns 5, 6, and 8. Density profiles obtained from NGIMS were plotted against simulated density profiles from the Mars Global Ionosphere-Thermosphere Model (MGITM). Averaged temperature

This project focuses on using Neutral Gas and Ion Mass Spectrometer (NGIMS) density data for carbon dioxide, oxygen, carbon monoxide, and nitrogen during deep dip campaigns 5, 6, and 8. Density profiles obtained from NGIMS were plotted against simulated density profiles from the Mars Global Ionosphere-Thermosphere Model (MGITM). Averaged temperature profiles were also plotted for the three deep dip campaigns, using NGIMS data and MGITM output. MGITM was also used as a tool to uncover potential heat balance terms needed to reproduce the mean density and temperature profiles measured by NGIMS.

This method of using NGIMS data as a validation tool for MGITM simulations has been tested previously using dayside data from deep dip campaigns 2 and 8. In those cases, MGITM was able to accurately reproduce the measured density and temperature profiles; however, in the deep dip 5 and 6 campaigns, the results are not quite the same, due to the highly variable nature of the nightside thermosphere. MGITM was able to fairly accurately reproduce the density and temperature profiles for deep dip 5, but the deep dip 6 model output showed unexpected significant variation. The deep dip 6 results reveal possible changes to be made to MGITM to more accurately reflect the observed structure of the nighttime thermosphere. In particular, upgrading the model to incorporate a suitable gravity wave parameterization should better capture the role of global winds in maintaining the nighttime thermospheric structure.

This project reveals that there still exist many unknowns about the structure and dynamics of the night side of the Martian atmosphere, as well as significant diurnal variations in density. Further study is needed to uncover these unknowns and their role in atmospheric mass loss.
ContributorsRobinson, Jenna (Author) / Desch, Steven (Thesis director) / Hervig, Richard (Committee member) / School of Earth and Space Exploration (Contributor) / School for the Future of Innovation in Society (Contributor) / School of International Letters and Cultures (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
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Description
Volcanic eruptions can be serious geologic hazards, and have the potential to effect human life, infrastructure, and climate. Therefore, an understanding of the evolution and conditions of the magmas stored beneath volcanoes prior to their eruption is crucial for the ability to monitor such systems and develop effective hazard mitigation

Volcanic eruptions can be serious geologic hazards, and have the potential to effect human life, infrastructure, and climate. Therefore, an understanding of the evolution and conditions of the magmas stored beneath volcanoes prior to their eruption is crucial for the ability to monitor such systems and develop effective hazard mitigation plans. This dissertation combines classic petrologic tools such as mineral chemistry and thermometry with novel techniques such as diffusion chronometry and statistical modeling in order to better understand the processes and timing associated with volcanic eruptions. By examining zoned crystals from the fallout ash of Yellowstone’s most recent supereruption, my work shows that the rejuvenation of magma has the ability to trigger a catastrophic supereruption at Yellowstone caldera in the years (decades at most) prior to eruption. This provides one of the first studies to thoroughly identify a specific eruption trigger of a past eruption using the crystal record. Additionally, through experimental investigation, I created a novel diffusion chronometer with application to determine magmatic timescales in silicic volcanic systems (i.e., rhyolite/dacite). My results show that Mg-in-sanidine diffusion operates simultaneously by both a fast and slow diffusion path suggesting that experimentally-derived diffusion chronometers may be more complex than previously thought. When applying Mg-in-sanidine chronometry to zoned sanidine from the same supereruption at Yellowstone, the timing between rejuvenation and eruption is further resolved to as short as five months, providing a greater understanding of the timing of supereruption triggers. Additionally, I developed a new statistical model to examine the controls on a single volcano’s distribution of eruptions through time, therefore the controls on the timing between successive eruptions, or repose time. When examining six Cascade volcanoes with variable distribution patterns through time, my model shows these distributions are not result of sampling bias, rather may represent geologic processes. There is a robust negative correlation between average repose time and average magma composition (i.e., SiO2), suggesting this may be a controlling factor of long-term repose time at Cascade volcanoes. Together, my work provides a better vision for forecasting models to mitigate potential destruction.
ContributorsShamloo, Hannah (Author) / Till, Christy (Thesis advisor) / Hervig, Richard (Committee member) / Barboni, Melanie (Committee member) / Shock, Everett (Committee member) / Shim, Sang-Heon (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Primitive arc magmas provide a critical glimpse into the geochemical evolution of subduction zone magmas, as they represent the most unadulterated mantle-derived magmas observed in nature in these tectonic environments and are the precursors of the more abundant andesites and dacites typical in arcs. To date, the study of primitive

Primitive arc magmas provide a critical glimpse into the geochemical evolution of subduction zone magmas, as they represent the most unadulterated mantle-derived magmas observed in nature in these tectonic environments and are the precursors of the more abundant andesites and dacites typical in arcs. To date, the study of primitive arc magmas has largely focused on their origins at depth, while significantly less is known about pre-eruptive crustal storage and ascent history. This study examines the crustal storage and ascent history of the Mt. Shasta primitive magnesian andesite (PMA), the demonstrated dominant parent magma for the abundant mixed andesites erupted at Mt. Shasta. Petrographic and geochemical observations of the PMA identify a mid-crustal magma mixing event with a less evolved relative of the PMA recorded in multiple populations of reversely zoned clinopyroxene and orthopyroxene phenocrysts. Prior phase equilibrium experiments and thermobarometric calculations as part of this study suggest the PMA experienced storage, mixing with a less evolved version of itself, and subsequent crystallization at 5kbar and 975°C. Modeling of Fe-Mg interdiffusion between the rims and cores of the reversely-zoned clinopyroxene and orthopyroxenes suggest this mixing, crystallization and subsequent ascent occurred within 10 years, or ~2.9 (+6.5 / -2.5) years, prior to eruption. Ascent from 5kbar or ~15 km, with no meaningful shallower storage, suggests minimum crustal transit rates of ~5 km/year. This rate is comparable to only a couple of other similar types of crustal transit rates (and slower than the much faster, syn-eruptive ascent rates measured through methods like olivine-hosted melt embayment volatile gradients and U-series isotope measurements on other arc magmas). The results of this study help to constrain the pre-eruptive history and ascent rates of hydrous primitive arc magmas, illuminating their magmatic processes during ascent. When combined with geophysical signals of magma movement, mixing to eruption timescales such as this have the power to inform volcanic hazard models for monogenetic, cinder cone eruptions in the Southern Cascades.
ContributorsPhillips, Mitchell (Author) / Till, Christy B. (Thesis advisor) / Hervig, Richard (Committee member) / Barboni, Melanie (Committee member) / Arizona State University (Publisher)
Created2019
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Description
My dissertation research broadly focuses on the geochemical and physical exchange of materials between the Earth’s crust and mantle at convergent margins, and how this drives the compositional diversity observed on the Earth’s surface. I combine traditional petrologic and geochemical studies of natural and experimental high-pressure mafic rocks, with thermodynamic

My dissertation research broadly focuses on the geochemical and physical exchange of materials between the Earth’s crust and mantle at convergent margins, and how this drives the compositional diversity observed on the Earth’s surface. I combine traditional petrologic and geochemical studies of natural and experimental high-pressure mafic rocks, with thermodynamic modeling of high-pressure aqueous fluids and mafic-ultramafic lithologies allowing for more complete understanding of fluid-melt-rock interactions. The results of the research that follows has important implications for: the role of lower crustal foundering in the geochemical origin and evolution of the modern continental crust (Chapter 2; Guild et al., under review), metasomatic processes involving aqueous metal-carbon complexes in high pressure-temperature subduction zone fluids (Chapter 3; Guild & Shock, 2020), natural hydrous mineral stability at the slab-mantle interface (Chapter 4; Guild, et al., in preparation) and water-undersaturated melting in the sub-arc (Chapter 5; Guild & Till, in preparation).
ContributorsGuild, Meghan Rose (Author) / Till, Christy B. (Thesis advisor) / Shock, Everett L (Committee member) / Hervig, Richard L (Committee member) / Hartnett, Hilairy (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2020