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Cavitation bubbles in the human body, when subjected to rapid mechanical load, are being increasingly considered as a possible brain injury mechanism during contact sports and military operations. Due to this great importance, it is essential to fundamentally understand the cavitation bubble dynamics in varying biological systems. In this dissertation,

Cavitation bubbles in the human body, when subjected to rapid mechanical load, are being increasingly considered as a possible brain injury mechanism during contact sports and military operations. Due to this great importance, it is essential to fundamentally understand the cavitation bubble dynamics in varying biological systems. In this dissertation, experimental and theoretical characterization of cavitation dynamics in soft matters from tissue simulant soft gels (e.g., agar, agarose, and gelatin) to actual live cells are performed.First, cavitation nucleation and bubble growth in different types of tissue simulants are studied under translation impact. The critical acceleration that corresponds to onset of cavitation bubble burst is measured in the soft gels and individual gel types indicate significantly different trends in the critical acceleration and bubble shape (e.g., A gel-specific sphere-to-saucer transition) with increasing gel stiffness. Possible underlying mechanisms of the experimental observations are provided in the concepts of a damaged zone and crack propagation. This study sheds light on potential links between traumatic brain injuries and cavitation bubbles induced by translational acceleration, the overlooked mechanism in the literature. Second, a drop-tower-based repetitive impact tester is newly designed to mimic biological systems under a wide range of impact conditions including high strain rate as well as repeated loadings. Theoretical approach based on a two-degree-of-freedom mass-spring-damper model simulates the transient dynamic response of the system with experimental validations. As one of main implications, a novel noncontact detecting method is developed to capture initial cavitation nucleation during successive drop events. This study also observes impact characteristics dependent cavitation bubble responses, which have not been characterized by other methods (e.g., laser or ultrasound induced cavitation rheology). Finally, although significant efforts have been made in the dynamic response of tissue simulants, there is a huge knowledge gap between the soft gels and actual live cells due to the lack of the experimental capability and of knowledge for complicated cell responses. Newly designed in vitro experimental setup and systematic characterization of specific cell types, i.e., Hs27 fibroblasts, enable a testing of spatio-temporal responses of cells under mechanical impact by controlling their static and dynamic behaviors.
ContributorsKim, Chunghwan (Author) / Kang, Wonmo WK (Thesis advisor) / Acharya, Abhinav AA (Committee member) / Rajagopalan, Jagannathan JR (Committee member) / Oswald, Jay JO (Committee member) / Kim, Jeonglae JK (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Failures in the cold chain, the system of refrigerated storage and transport that provides fresh produce or other essentials to be maintained at desired temperatures and environmental conditions, lead to food and energy waste. The mini container (MC) concept is introduced as an alternative to conventional refrigerated trucks (“reefers”), particularly

Failures in the cold chain, the system of refrigerated storage and transport that provides fresh produce or other essentials to be maintained at desired temperatures and environmental conditions, lead to food and energy waste. The mini container (MC) concept is introduced as an alternative to conventional refrigerated trucks (“reefers”), particularly for small growers. The energy consumption and corresponding GHG emissions for transporting tomatoes in two cities representing contrasting climates is analyzed for conventional reefers and the proposed mini containers. The results show that, for partial reefer loads, using the MCs reduces energy consumption and GHG emissions. The transient behavior of the vapor compression refrigeration cycle is analyzed by considering each component as a “lumped” system, and the resulting sub-models are solved using the Runge Kutta 4th-order method in a MATLAB code at hot and cold ambient temperatures. The time needed to reach steady state temperatures and the temperature values are determined. The maximum required compressor work in the transient phase and at steady state are computed, and as expected, as the ambient temperature increases, both values increase. Finally, the average coefficient of performance (COP) is determined for varying heat transfer coefficient values for the condenser and for the evaporator. The results show that the average COP increases as heat transfer coefficient values for the condenser and the evaporator increase. Starting the system from rest has an adverse effect on the COP due to the higher compressor load needed to change the temperature of the condenser and the evaporator. Finally, the impact on COP is analyzed by redirecting a fraction of the cold exhaust air to provide supplemental cooling of the condenser. It is noted that cooling the condenser improves the system's performance better than cooling the fresh air at 0% of returned air to the system.To sum up, the dissertation shows that the comparison between the conventional reefer and the MC illustrates the promising advantages of the MC, then a transient analysis is developed for deeply understanding the behaviors of the system component parameters, which leads finally to improvements in the system to enhance its performance.
ContributorsSyam, Mahmmoud Muhammed (Author) / Phelan, Patrick (Thesis advisor) / Villalobos, Rene (Thesis advisor) / Huang, Huei-Ping (Committee member) / Bocanegra, Luis (Committee member) / Al Omari, Salah (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Formula 1 car front wings have evolved significantly over the last fifty years. Looking back at the past decade shows significant changes made due to rules and regulations by the Federation Internationale de l'Automobile and an increased understanding of aerodynamic concepts. There seems to be a trend where aerodynamic design

Formula 1 car front wings have evolved significantly over the last fifty years. Looking back at the past decade shows significant changes made due to rules and regulations by the Federation Internationale de l'Automobile and an increased understanding of aerodynamic concepts. There seems to be a trend where aerodynamic design concepts, previously seen in aviation, are being applied to Formula 1 front wings; this helps race teams increase downforce and reduce drag. This thesis analyzes these changes made over the past years and relates the material back to material that was learned by the aviation industry and attempts to synthesize conceptual Formula 1 front Wing designs using VORLAX, a vortex lattice panel method, used in the aviation industry. This insight would be beneficial for Formula 1 teams as there are budget and time restrictions applied to Computational Fluid Dynamic and wind tunnel testing, but panel methods are run in a matter of seconds as opposed to hours or days. So, if verified, preliminary designs can be rapidly tested to optimize the workflow and reduce the time required for Computational Fluid Dynamic and wind tunnel testing.
ContributorsRatnayake, Sajana Sathsara (Author) / Takahashi, Timothy T (Thesis advisor) / Perez, Ruben E (Committee member) / Kim, Jeonglae (Committee member) / Arizona State University (Publisher)
Created2023
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Description
As the explorations beyond the Earth's boundaries continue to evolve, researchers and engineers strive to develop versatile technologies capable of adapting to unknown space conditions. For instance, the utilization of Screw-Propelled Vehicles (SPVs) and robotics that utilize helical screws propulsion to transverse planetary bodies is a growing area of interest.

As the explorations beyond the Earth's boundaries continue to evolve, researchers and engineers strive to develop versatile technologies capable of adapting to unknown space conditions. For instance, the utilization of Screw-Propelled Vehicles (SPVs) and robotics that utilize helical screws propulsion to transverse planetary bodies is a growing area of interest. An example of such technology is the Extant Exobiology Life Surveyor (EELS), a snake-like robot currently developed by the NASA Jet Propulsion Laboratory (JPL) to explore the surface of Saturn’s moon, Enceladus. However, the utilization of such a mechanism requires a deep and thorough understanding of screw mobility in uncertain conditions. The main approach to exploring screw dynamics and optimal design involves the utilization of Discrete Element Method (DEM) simulations to assess interactions and behavior of screws when interacting with granular terrains. In this investigation, the Simplified Johnson-Kendall-Roberts (SJKR) model is implemented into the utilized simulation environment to account for cohesion effects similar to what is experienced on celestial bodies like Enceladus. The model is verified and validated through experimental and theoretical testing. Subsequently, the performance characteristics of screws are explored under varying parameters, such as thread depth, number of screw starts, and the material’s cohesion level. The study has examined significant relationships between the parameters under investigation and their influence on the screw performance.
ContributorsAbdelrahim, Mohammad (Author) / Marvi, Hamid (Thesis advisor) / Berman, Spring (Committee member) / Lee, Hyunglae (Committee member) / Arizona State University (Publisher)
Created2023
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Energy storage technologies are essential to overcome the temporal variability in renewable energy. The primary aim of this thesis is to develop reactor solutions to better analyze the potential of thermochemical energy storage (TCES) using non-stoichiometric metal oxides, for the multi-day energy storage application. A TCES system consists of a

Energy storage technologies are essential to overcome the temporal variability in renewable energy. The primary aim of this thesis is to develop reactor solutions to better analyze the potential of thermochemical energy storage (TCES) using non-stoichiometric metal oxides, for the multi-day energy storage application. A TCES system consists of a reduction reactor and an insulated MOx storage bin. The reduction reactor heats (to ~ 1100 °C) and partially reduces the MOx, thereby adding sensible and chemical energy (i.e., charging it) under reduced pO2 environments (~10 Pa). Inert gas removes the oxygen generated during reduction. The storage bin holds the hot and partially reduced MOx (typically particles) until it is used in an energy recovery device (i.e., discharge). Irrespective of the reactor heat source (here electrical), or the particle-inert gas flows (here countercurrent), the thermal reduction temperature and inert gas (here N2) flow minimize when the process approaches reversibility, i.e., operates near equilibrium. This study specifically focuses on developing a reduction reactor based on the theoretical considerations for approaching reversibility along the reaction path. The proposed Zigzag flow reactor (ZFR) is capable of thermally reducing CAM28 particles at temperatures ~ 1000 °C under an O2 partial pressure ~ 10 Pa. The associated analytical and numerical models analyze the reaction equilibrium under a real (discrete) reaction path and the mass transfer kinetic conditions necessary to approach equilibrium. The discrete equilibrium model minimizes the exergy destroyed in a practical reactor and identifies methods of maximizing the energy storage density () and the exergetic efficiency. The mass transfer model analyzes the O2 N2 concentration boundary layers to recommend sizing considerations to maximize the reactor power density. Two functional ZFR prototypes, the -ZFR and the -ZFR, establish the proof of concept and achieved a reduction extent, Δδ = 0.071 with CAM28 at T~950 °C and pO2 = 10 Pa, 7x higher than a previous attempt in the literature. The -ZFR consistently achieved  > 100 Wh/kg during >10 h. runtime and the -ZFR displayed an improved  = 130 Wh/kg during >5 h. operation with CAM28. A techno-economic model of a grid-scale ZFR with an associated storage bin analyzes the cost of scaling the ZFR for grid energy storage requirements. The scaled ZFR capital costs contribute < 1% to the levelized cost of thermochemical energy storage, which ranges from 5-20 ¢/kWh depending on the storage temperature and storage duration.
ContributorsGhotkar, Rhushikesh (Author) / Milcarek, Ryan (Thesis advisor) / Ermanoski, Ivan (Committee member) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Animals have always been a source of inspiration for real-life problems. The octopus is one such animal that has a lot of untapped potential. The octopus’s arm is without solid joints or bone structure and despite this it can achieve many complicated movements with virtually infinite degrees of freedom. This

Animals have always been a source of inspiration for real-life problems. The octopus is one such animal that has a lot of untapped potential. The octopus’s arm is without solid joints or bone structure and despite this it can achieve many complicated movements with virtually infinite degrees of freedom. This ability is made possible through the unique morphology of the arm. The octopus’s arm is divided into transverse, longitudinal, oblique, and circular muscle groups and each one has a unique muscle fiber orientation. The octopus’s arm is classified as a hydrostat because it maintains a constant volume while contracting with the help of its different muscle groups. These muscle groups allow elongation, shortening, bending, and twisting of the arm when they work in combination with each other. To confirm the role of transverse and longitudinal muscle groups, an electromyography (EMG) recording of these muscle groups was performed while an amputated arm of an Octopus bimaculoides was stimulated with an electrical signal to induce movement. Statistical analysis was performed on these results to confirm the roles of each muscle group quantitatively. Octopus arm morphology was previously assumed to be uniform along the arm. Through a magnetic resonance imaging (MRI) study at the proximal, middle, and distal sections of the arm this notion was disproven, and a new pattern was discovered. Drawing inspiration from this finding and previous octopus arm prototypes, 4 bio-inspired designs were conceived and tested in finite element analysis (FEA) simulations. Four tests in elongation, shortening, bending, and transverse-assisted bending movements were performed on all designs to compare each design’s performance. The findings in this study have applications in engineering and soft robotics fields for use cases such as, handling fragile objects, minimally invasive surgeries, difficult-to-access areas that require squeezing through small holes, and other novel cases.
ContributorsAhmadi, Salaheddin (Author) / Marvi, Hamidreza (Thesis advisor) / Fisher, Rebecca (Committee member) / Xu, Zhe (Committee member) / Arizona State University (Publisher)
Created2023
Description
Heusler alloys were discovered in 1903, and materials with half-metallic characteristics have drawn more attention from researchers since the advances in semiconductor industry [1]. Heusler alloys have found application as spin-filters, tunnel junctions or giant magnetoresistance (GMR) devices in technological applications [1]. In this work, the electronic structures, phonon

Heusler alloys were discovered in 1903, and materials with half-metallic characteristics have drawn more attention from researchers since the advances in semiconductor industry [1]. Heusler alloys have found application as spin-filters, tunnel junctions or giant magnetoresistance (GMR) devices in technological applications [1]. In this work, the electronic structures, phonon dispersion, thermal properties, and electrical conductivities of PdMnSn and six novel alloys (AuCrSn, AuMnGe, Au2MnSn, Cu2NiGe, Pd2NiGe and Pt2CoSn) along with their magnetic moments are studied using ab initio calculations to understand the roots of half-metallicity in these alloys of Heusler family. From the phonon dispersion, the thermodynamic stability of the alloys in their respective phases is assessed. Phonon modes were also used to further understand the electrical transport in the crystals of these seven alloys. This study evaluates the relationship between materials' electrical conductivity and minority-spin bandgap in the band structure, and it provides suggestions for selecting constituent elements when designing new half-metallic Heusler alloys of C1b and L21 structures.
ContributorsPatel, Deep (Author) / Zhuang, Houlong (Thesis advisor) / Solanki, Kiran (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Air conditioning is a significant energy consumer in buildings, especially in humid regions where a substantial portion of energy is used to remove moisture rather than cool the air. Traditional dehumidification methods, which cool air to its dew point to condense water vapor, are energy intensive. This process unnecessarily overcools

Air conditioning is a significant energy consumer in buildings, especially in humid regions where a substantial portion of energy is used to remove moisture rather than cool the air. Traditional dehumidification methods, which cool air to its dew point to condense water vapor, are energy intensive. This process unnecessarily overcools the air, only to reheat it to the desired temperature.This research introduces thermoresponsive materials as efficient desiccants to reduce energy demand for dehumidification. A system using lower critical solution temperature (LCST) type ionic liquids (ILs) as dehumidifiers is presented. Through the Flory-Huggins theory of mixtures, interactions between ionic liquids and water are analyzed. LCST ionic liquids demonstrate superior performance, with a coefficient of performance (COP) four times higher than non-thermoresponsive desiccants under similar conditions. The efficacy of ionic liquids as dehumidifiers is assessed based on properties like LCST temperature and enthalpic interaction parameter. The research also delves into thermoresponsive solid desiccants, particularly polymers, using the Vrentas-Vrentas model. This model offers a more accurate depiction of their behaviors compared to the Flory-Huggins theory by considering elastic energy stored in the polymers. Moisture absorption in thin film polymers is studied under diverse conditions, producing absorption isotherms for various temperatures and humidities. Using temperature-dependent interaction parameters, the behavior of the widely-used thermoresponsive polymer (TRP) PNIPAAm and hypothetical TRPs is investigated. The parameters from the model are used as input to do a finite element analysis of a thermoresponsive dehumidifier. This model demonstrates the complete absorption-desorption cycle under varied conditions such as polymer absorption temperature, relative humidity, and air speed. Results indicate that a TRP with enhanced absorption capacity and an LCST of 50℃ achieves a peak moisture removal efficiency (MRE) of 0.9 at 75% relative humidity which is comparable to other existing thermoresponsive dehumidification systems. But other TRPs with even greater absorption capacity can produce MRE as high as 3.6. This system also uniquely recovers water in liquid form.
ContributorsRana, Ashish (Author) / Wang, Robert RW (Thesis advisor) / Green, Matthew MG (Committee member) / Milcarek, Ryan RM (Committee member) / Wang, Liping LW (Committee member) / Phelan, Patrick PP (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Advancements in three-dimensional (3D) additive manufacturing techniques have opened up new possibilities for healthcare systems and the medical industry, allowing for the realization of concepts that were once confined to theoretical discussions. Among these groundbreaking research endeavors is the development of intricate magnetic structures that can be actuated through non-invasive

Advancements in three-dimensional (3D) additive manufacturing techniques have opened up new possibilities for healthcare systems and the medical industry, allowing for the realization of concepts that were once confined to theoretical discussions. Among these groundbreaking research endeavors is the development of intricate magnetic structures that can be actuated through non-invasive methods, including electromagnetic and magnetic actuation. Magnetic actuation, in particular, offers the advantage of untethered operation. In this study, a photopolymerizable resin infused with Fe3O4 oxide nanoparticles is employed in the printing process using the micro-continuous liquid interface production technique. The objective is to optimize the manufacturing process to produce microstructures featuring smooth surfaces and reduced surface porosity, and enhanced flexibility and magnetic actuation. Various intricate structures are fabricated to validate the printing process's capabilities. Furthermore, the assessment of the flexibilty of these 3D-printed structures is conducted in the presence of an external magnetic field using a homemade bending test setup, allowing for a comprehensive characterization of these components. This research serves as a foundation for the future design and development of micro-robots using micro-continuous liquid interface production technique.
ContributorsJha, Ujjawal (Author) / Chen, Xiangfan (Thesis advisor) / Li, Xiangjia (Committee member) / Jin, Kailong (Committee member) / Nian, Qiong (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Ethylene is one of the most widely used organic compounds worldwide with ever increasing demand. Almost all the industries currently producing ethylene globally use the method of steam cracking, which, though highly selective and cost effective, is energy intensive along with having a high carbon footprint. This study aims to

Ethylene is one of the most widely used organic compounds worldwide with ever increasing demand. Almost all the industries currently producing ethylene globally use the method of steam cracking, which, though highly selective and cost effective, is energy intensive along with having a high carbon footprint. This study aims to analyze micro-scale partial oxidation of propane as a novel approach towards ethylene generation which is simpler, less energy consuming, operates at lower temperatures and causes minimum CO2 emission. The experimental study endeavors to maximize the ethylene production by investigating the effect of variables such as temperature, flow rate, equivalence ratio and reactor diameter. The micro-scale partial oxidation of propane is studied inside quartz tube reactors of 1 mm and 3 mm diameter at a temperature range of 800 to 900 oC, at varying flow rates of 10 to 100 sccm and equivalence ratios of 1 to 6. The study reveals ethylene yield has a strong dependence on all the above factors. However, the factors are not completely independent of each other. Adjusting certain factors and levels results in greater ethylene yields as high as 10%, but propane to ethylene conversion efficiency is approximately constant for most conditions. Low CO2 concentrations are also recorded for most of the factor and level combinations, indicating the potential to achieve lower CO2 yields compared to conventional approaches. The investigation indicates promise for application in the field of ethylene generation.
ContributorsMAHALKAR, PAWAN MUKUND (Author) / Milcarek, Ryan (Thesis advisor) / Kwon, Beomjin (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2023