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- Genre: Doctoral Dissertation
Description
Programmable Metallization Cell (PMC) is a technology platform which utilizes mass transport in solid or liquid electrolyte coupled with electrochemical (redox) reactions to form or remove nanoscale metallic electrodeposits on or in the electrolyte. The ability to redistribute metal mass and form metallic nanostructure in or on a structure in situ, via the application of a bias on laterally placed electrodes, creates a large number of promising applications. A novel PMC-based lateral microwave switch was fabricated and characterized for use in microwave systems. It has demonstrated low insertion loss, high isolation, low voltage operation, low power and low energy consumption, and excellent linearity. Due to its non-volatile nature the switch operates with fewer biases and its simple planar geometry makes possible innovative device structures which can be potentially integrated into microwave power distribution circuits. PMC technology is also used to develop lateral dendritic metal electrodes. A lateral metallic dendritic network can be grown in a solid electrolyte (GeSe) or electrodeposited on SiO2 or Si using a water-mediated method. These dendritic electrodes grown in a solid electrolyte (GeSe) can be used to lower resistances for applications like self-healing interconnects despite its relatively low light transparency; while the dendritic electrodes grown using water-mediated method can be potentially integrated into solar cell applications, like replacing conventional Ag screen-printed top electrodes as they not only reduce resistances but also are highly transparent. This research effort also laid a solid foundation for developing dendritic plasmonic structures. A PMC-based lateral dendritic plasmonic structure is a device that has metallic dendritic networks grown electrochemically on SiO2 with a thin layer of surface metal nanoparticles in liquid electrolyte. These structures increase the distribution of particle sizes by connecting pre-deposited Ag nanoparticles into fractal structures and result in three significant effects, resonance red-shift, resonance broadening and resonance enhancement, on surface plasmon resonance for light trapping simultaneously, which can potentially enhance thin film solar cells' performance at longer wavelengths.
ContributorsRen, Minghan (Author) / Kozicki, Michael (Thesis advisor) / Schroder, Dieter (Committee member) / Roedel, Ronald (Committee member) / Barnaby, Hugh (Committee member) / Arizona State University (Publisher)
Created2011
Description
Programmable Metallization Cell (PMC) technology has been shown to possess the necessary qualities for it to be considered as a leading contender for the next generation memory. These qualities include high speed and endurance, extreme scalability, ease of fabrication, ultra low power operation, and perhaps most importantly ease of integration with the CMOS back end of line (BEOL) process flow. One area where detailed study is lacking is the reliability of PMC devices. In previous reliability work, the low and high resistance states were monitored for periods of hours to days without any applied voltage and the results were extrapolated to several years (>10) but little has been done to analyze the low resistance state under stress. With or without stress, the low resistance state appears to be highly stable but a gradual increase in resistance with time, less than one order of magnitude after ten years when extrapolated, has been observed. It is important to understand the physics behind this resistance rise mechanism to comprehend the reliability issues associated with the low resistance state. This is also related to the erase process in PMC cells where the transition from the ON to OFF state occurs under a negative voltage. Hence it is important to investigate this erase process in PMC cells under different conditions and to model it. Analyzing the programming and the erase operations separately is important for any memory technology but its ability to cycle efficiently (reliably) at low voltages and for more than 1E4 cycles (without affecting the cells performance) is more critical. Future memory technologies must operate with the low power supply voltages (<1V) required for small geometry nodes. Low voltage programming of PMC memory devices has previously been demonstrated using slow voltage sweeps and small numbers of fast pulses. In this work PMC memory cells were cycled at low voltages using symmetric pulses with different load resistances and the distribution of the ON and OFF resistances was analyzed. The effect of the program current used during the program-erase cycling on the resulting resistance distributions is also investigated. Finally the variation found in the behavior of similar resistance ON states in PMC cells was analyzed more in detail and measures to reduce this variation were looked into. It was found that slow low current programming helped reducing the variation in erase times of similar resistance ON states in PMC cells. This scheme was also used as a pre-conditioning technique and the improvements in subsequent cycling behavior were compared.
ContributorsKamalanathan, Deepak (Author) / Kozicki, Dr. Michael (Thesis advisor) / Schroder, Dr. Dieter (Committee member) / Goryll, Dr. Michael (Committee member) / Alford, Dr. Terry (Committee member) / Arizona State University (Publisher)
Created2011