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Description
Chemical and mineralogical data from Mars shows that the surface has been chemically weathered on local to regional scales. Chemical trends and the types of chemical weathering products present on the surface and their abundances can elucidate information about past aqueous processes. Thermal-infrared (TIR) data and their respective models are

Chemical and mineralogical data from Mars shows that the surface has been chemically weathered on local to regional scales. Chemical trends and the types of chemical weathering products present on the surface and their abundances can elucidate information about past aqueous processes. Thermal-infrared (TIR) data and their respective models are essential for interpreting Martian mineralogy and geologic history. However, previous studies have shown that chemical weathering and the precipitation of fine-grained secondary silicates can adversely affect the accuracy of TIR spectral models. Furthermore, spectral libraries used to identify minerals on the Martian surface lack some important weathering products, including poorly-crystalline aluminosilicates like allophane, thus eliminating their identification in TIR spectral models. It is essential to accurately interpret TIR spectral data from chemically weathered surfaces to understand the evolution of aqueous processes on Mars. Laboratory experiments were performed to improve interpretations of TIR data from weathered surfaces. To test the accuracy of deriving chemistry of weathered rocks from TIR spectroscopy, chemistry was derived from TIR models of weathered basalts from Baynton, Australia and compared to actual weathering rind chemistry. To determine how specific secondary silicates affect the TIR spectroscopy of weathered basalts, mixtures of basaltic minerals and small amounts of secondary silicates were modeled. Poorly-crystalline aluminosilicates were synthesized and their TIR spectra were added to spectral libraries. Regional Thermal Emission Spectrometer (TES) data were modeled using libraries containing these poorly-crystalline aluminosilicates to test for their presence on the Mars. Chemistry derived from models of weathered Baynton basalts is not accurate, but broad chemical weathering trends can be interpreted from the data. TIR models of mineral mixtures show that small amounts of crystalline and amorphous silicate weathering products (2.5-5 wt.%) can be detected in TIR models and can adversely affect modeled plagioclase abundances. Poorly-crystalline aluminosilicates are identified in Northern Acidalia, Solis Planum, and Meridiani. Previous studies have suggested that acid sulfate weathering was the dominant surface alteration process for the past 3.5 billion years; however, the identification of allophane indicates that alteration at near-neutral pH occurred on regional scales and that acid sulfate weathering is not the only weathering process on Mars.
ContributorsRampe, Elizabeth Barger (Author) / Sharp, Thomas G (Thesis advisor) / Christensen, Phillip (Committee member) / Hervig, Richard (Committee member) / Shock, Everett (Committee member) / Williams, Lynda (Committee member) / Arizona State University (Publisher)
Created2011
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Description

Papago Park in Tempe, Arizona (USA) is host to several buttes composed of landslide breccias. The focus of this thesis is a butte called “Contact Hill,” which is composed of metarhyolitic debris flows, granitic debris flows, and Barnes Butte Breccia. The Barnes Butte Breccia can be broken down into several

Papago Park in Tempe, Arizona (USA) is host to several buttes composed of landslide breccias. The focus of this thesis is a butte called “Contact Hill,” which is composed of metarhyolitic debris flows, granitic debris flows, and Barnes Butte Breccia. The Barnes Butte Breccia can be broken down into several different compositional categories that can be dated based on their relative ages. The depositional timeline of these rocks is explored through their mineral and physical properties. The rhyolitic debris flow is massively bedded and dips at 26° to the southeast. The granitic debris flow is not bedded and exhibits a mixture of granite clasts of different grain sizes. In thin section analysis, five mineral types were identified: opaque inclusions, white quartz, anhedral and subhedral biotite, yellow stained K-feldspar, and gray plagioclase. It is hypothesized that regional stretching and compression of the crust, accompanied with magmatism, helped bring the metarhyolite and granite to the surface. Domino-like fault blocks caused large brecciation, and collapse of a nearby quartzite and granite mountain helped create the Barnes Butte Breccia: a combination of quartzite, metarhyolite, and granite clasts. Evidence of Papago Park’s ancient terrestrial history is seen in metarhyolite clasts containing sand grains. These geologic events, in addition to erosion, are responsible for Papago Park’s unique appearance today.

ContributorsScheller, Jessica Rose (Author) / Reynolds, Stephen (Thesis director) / Johnson, Julia (Committee member) / School of Earth and Space Exploration (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Description
The temperature of a planet's surface depends on numerous physical factors, including thermal inertia, albedo and the degree of insolation. Mars is a good target for thermal measurements because the low atmospheric pressure combined with the extreme dryness results in a surface dominated by large differences in thermal inertia, minimizing

The temperature of a planet's surface depends on numerous physical factors, including thermal inertia, albedo and the degree of insolation. Mars is a good target for thermal measurements because the low atmospheric pressure combined with the extreme dryness results in a surface dominated by large differences in thermal inertia, minimizing the effect of other physical properties. Since heat is propagated into the surface during the day and re-radiated at night, surface temperatures are affected by sub-surface properties down to several thermal skin depths. Because of this, orbital surface temperature measurements combined with a computational thermal model can be used to determine sub-surface structure. This technique has previously been applied to estimate the thickness and thermal inertia of soil layers on Mars on a regional scale, but the Mars Odyssey Thermal Emission Imaging System "THEMIS" instrument allows much higher-resolution thermal imagery to be obtained. Using archived THEMIS data and the KRC thermal model, a process has been developed for creating high-resolution maps of Martian soil layer thickness and thermal inertia, allowing investigation of the distribution of dust and sand at a scale of 100 m/pixel.
ContributorsHeath, Simon (Author) / Christensen, Philip R. (Philip Russel) (Thesis advisor) / Bel, James (Thesis advisor) / Hervig, Richard (Committee member) / Arizona State University (Publisher)
Created2013
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Description
The present understanding of the formation and evolution of the earliest bodies in the Solar System is based in large part on geochemical and isotopic evidences contained within meteorites. The differentiated meteorites (meteorites originating from bodies that have experienced partial to complete melting) are particularly useful for deciphering magmatic processes

The present understanding of the formation and evolution of the earliest bodies in the Solar System is based in large part on geochemical and isotopic evidences contained within meteorites. The differentiated meteorites (meteorites originating from bodies that have experienced partial to complete melting) are particularly useful for deciphering magmatic processes occurring in the early Solar System. A rare group of differentiated meteorites, the angrites, are uniquely suited for such work. The angrites have ancient crystallization ages, lack secondary processing, and have been minimally affected by shock metamorphism, thus allowing them to retain their initial geochemical and isotopic characteristics at the time of formation. The scarcity of angrite samples made it difficult to conduct comprehensive investigations into the formation history of this unique meteorite group. However, a dramatic increase in the number of angrites recovered in recent years presents the opportunity to expand our understanding of their petrogenesis, as well as further refine our knowledge of the initial isotopic abundances in the early Solar System as recorded by their isotopic systematics. Using a combination of geochemical tools (radiogenic isotope chronometers and trace element chemistry), I have investigated the petrogenetic history of a group of four angrites that sample a range of formation conditions (cooling histories) and crystallization ages. Through isotope ratio measurements, I have examined a comprehensive set of long- and short-lived radiogenic isotope systems (26Al-26Mg, 87Rb-87Sr, 146Sm-142Nd, 147Sm-143Nd, and 176Lu-176Hf) within these four angrites. The results of these measurements provide information regarding crystallization ages, as well as revised estimates for the initial isotopic abundances of several key elements in the early Solar System. The determination of trace element concentrations in individual mineral phases, as well as bulk rock samples, provides important constraints on magmatic processes occurring on the angrite parent body. The measured trace element abundances are used to estimate the composition of the parent melts of individual angrites, examine crystallization conditions, and investigate possible geochemical affinities between various angrites. The new geochemical and isotopic measurements presented here significantly expand our understanding of the geochemical conditions found on the angrite parent body and the environment in which these meteorites formed.
ContributorsSanborn, Matthew E (Author) / Wadhwa, Meenakshi (Thesis advisor) / Hervig, Richard (Committee member) / Sharp, Thomas (Committee member) / Clarke, Amanda (Committee member) / Williams, Lynda (Committee member) / Carlson, Richard (Committee member) / Arizona State University (Publisher)
Created2012
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Description
The presence of a number of extinct radionuclides in the early Solar System (SS) is known from geochemical and isotopic studies of meteorites and their components. The half-lives of these isotopes are short relative to the age of the SS, such that they have now decayed to undetectable levels. They

The presence of a number of extinct radionuclides in the early Solar System (SS) is known from geochemical and isotopic studies of meteorites and their components. The half-lives of these isotopes are short relative to the age of the SS, such that they have now decayed to undetectable levels. They can be inferred to exist in the early SS from the presence of their daughter nuclides in meteoritic materials that formed while they were still extant. The extinct radionuclides are particularly useful as fine-scale chronometers for events in the early SS. They can also be used to help constrain the astrophysical setting of the formation of the SS because their short half-lives and unique formation environments yield information about the sources and timing of delivery of material to the protoplanetary disk. Some extinct radionuclides are considered evidence that the Sun interacted with a massive star (supernova) early in its history. The abundance of 60Fe in the early SS is particularly useful for constraining the astrophysical environment of the Sun's formation because, if present in sufficient abundance, its only likely source is injection from a nearby supernova. The initial SS abundance of 60Fe is poorly constrained at the present time, with estimates varying by 1-2 orders of magnitude. I have determined the 60Fe-60Ni isotope systematics of ancient, well-preserved meteorites using high-precision mass spectrometry to better constrain the initial SS abundance of 60Fe. I find identical estimates of the initial 60Fe abundance from both differentiated basaltic meteorites and from components of primitive chondrites formed in the Solar nebula, which suggest a lower 60Fe abundance than other recent estimates. With recent improved meteorite collection efforts there are more rare ungrouped meteorites being found that hold interesting clues to the origin and evolution of early SS objects. I use the 26Al-26Mg extinct radionuclide chronometer to constrain the ages of several recently recovered meteorites that sample previously unknown asteroid lithologies, including the only know felsic meteorite from an asteroid and two other ungrouped basaltic achondrites. These results help broaden our understanding of the timescales involved in igneous differentiation processes in the early SS.
ContributorsSpivak-Birndorf, Lev (Author) / Wadhwa, Meenakshi (Thesis advisor) / Hervig, Richard (Committee member) / Timmes, Francis (Committee member) / Williams, Lynda (Committee member) / Anbar, Ariel (Committee member) / Arizona State University (Publisher)
Created2012
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Description
The Kinsley Mountain gold deposit of northeastern Nevada, located ~70 km south of Wendover, Nevada, contains seven sediment-hosted, disseminated-gold deposits, in Cambrian limestones and shales. Mining ceased in 1999, with 138,000 ounces of gold mined at an average grade between 1.5-2.0 g/t. Resource estimates vary between 15,000 and 150,000 ounces

The Kinsley Mountain gold deposit of northeastern Nevada, located ~70 km south of Wendover, Nevada, contains seven sediment-hosted, disseminated-gold deposits, in Cambrian limestones and shales. Mining ceased in 1999, with 138,000 ounces of gold mined at an average grade between 1.5-2.0 g/t. Resource estimates vary between 15,000 and 150,000 ounces of gold remaining in several mineralized pods. Although exploration programs have been completed within the study area, the structural history and timing of precious-metal mineralization are still poorly understood. This study aims to better understand the relation between stratigraphy, structural setting, and style of gold mineralization. In order to accomplish these goals, geological mapping at a scale of 1:5,000 was conducted over the property as well as analysis of soil and rock chip samples for multi-element geochemistry. Using cross-cutting relationships, the structural history of Kinsley Mountain has been determined. The deformation can broadly be categorized as an early stage of compressional tectonics including folding, attenuation of the stratigraphy, and thrust faulting. This early stage was followed by a series of extensional deformation events, the youngest of which is an ongoing process. The structural history determined from this study fits well into a regional context and when viewed in conjunction with the mineralization event, can be used to bracket the timing of gold mineralization. The northwest oriented structure responsible for concentrating decalcification, silicification, and mineralization has two generations of cave fill breccias that both pre- and post-date the gold event. The statistical analysis of multi-element geochemistry for rock chip and soil samples has determined that Au is most strongly associated with Te, while weaker correlations exist between Au and Ag, As, Hg, Mo, Sb, Tl, and W. This suite of elements is associated with an intrusion driven system and is atypical of Carlin-type gold systems. From these elemental associations the gold mineralization event is thought to be controlled by the emplacement of a felsic intrusion. The responsible intrusion may be an exposed quartz monzonite to the south of the study area, as suggested by possible zonation of Cu, Pb, and Zn, which decrease in concentration with increasing distance from the outcropping stock. Alternatively, an unexposed intrusion at depth cannot be ruled out as the driver of the mineralizing system.
ContributorsMacFarlane, Bryan (Author) / Reynolds, Stephen (Thesis advisor) / Hervig, Richard (Committee member) / Burt, Donald (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Hydraulic fracturing, or fracking, has become a common practice in United States oil fields for enhancing their productivity. Among the concerns regarding fracking, however, is the possibility that it could trigger shallow earthquakes. The brine that results from fracking is injected into the subsurface for disposal. This brine causes a

Hydraulic fracturing, or fracking, has become a common practice in United States oil fields for enhancing their productivity. Among the concerns regarding fracking, however, is the possibility that it could trigger shallow earthquakes. The brine that results from fracking is injected into the subsurface for disposal. This brine causes a pore pressure gradient that is commonly believed to trigger failure along critically stressed subsurface faults. In Timpson, a small city in eastern Texas, earthquakes have become much more common since two injection wells were installed in 2007. 16 events of M_W > 2 have been detected since 2008 and are believed to be associated with failure along a subsurface fault. Applying interferometric synthetic aperture radar, we analyzed 3 sets of SAR images from the Advanced Land Observing Satellite (ALOS) from May 2007 to December 2010. Using these data sets, XX interferograms were generated. From these interferograms, it was possible to determine the spatial and temporal evolution of the crustal deformation in the line-of-sight of the satellite. The results show strong evidence of uplift in the region adjacent to the injection wells. While previous studies have established a strong connection between fluid injection and increased seismicity, this is to our knowledge the first observed case of crustal deformation that has been observed as a result of hydraulic fracturing fluid disposal.
Created2014-05
Description
Many radioactive decay schemes employed in geochronology prove imprecise when placing accurate age constraints on young basalt flows. The (U-Th)/He systematics of detrital zircon and apatite within baked zones is examined as an alternative. Parent-daughter radioisotope ratios within grains from baked zones can completely reset if subjected to temperatures high

Many radioactive decay schemes employed in geochronology prove imprecise when placing accurate age constraints on young basalt flows. The (U-Th)/He systematics of detrital zircon and apatite within baked zones is examined as an alternative. Parent-daughter radioisotope ratios within grains from baked zones can completely reset if subjected to temperatures high enough and long enough for bulk diffusive loss. Presented here is the reproducibility of initial attempts to date flows by examining the (U-Th)/He geochronology of grains within baked zones. We examine grains from two localities within the San Francisco Volcanic Field and the Mormon Volcanic Field in northern Arizona. Thirteen zircon and apatite grains yielded from locality 2 collected from the uppermost 10 cm beneath a 7m flow of a basalt yield an apparent age of 4.39 ± 0.28 Ma (2σ), which is within range of published Middle Pliocene ages. Twenty-nine grains from locality 1 collected from the uppermost 20 cm beneath a 2 to 5m flow yield dates ranging from 0.47 ± 0.02 Ma to 892.77 ± 27.02 Ma, indicating the grains were partially reset or not reset at all. The degree to which grains are reset depends on a variety of factors detailed in this study. With these factors accounted for however, our study confirms application of this indirect dating technique is a useful tool for dating basaltic flows.
ContributorsCronk, Stephanie Sarah (Author) / Hodges, Kip (Thesis director) / van Soest, Matthijs (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2014-05
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Description
Blue Mound State Park, located in the state of Wisconsin (USA), is host to a topographic anomaly known as Blue Mound. This mound is the western of the two mounds that make up the park, and it marks the highest elevation in southern Wisconsin. Unlike its eastern sibling, Blue Mound

Blue Mound State Park, located in the state of Wisconsin (USA), is host to a topographic anomaly known as Blue Mound. This mound is the western of the two mounds that make up the park, and it marks the highest elevation in southern Wisconsin. Unlike its eastern sibling, Blue Mound possesses an unusual chert cap that may have protected it from erosion, thus preserving its stratigraphic integrity. Although Blue Mound's unique chert armor was noted in 1927 by the Wisconsin Geological and Natural History Survey, no published work has satisfactorily explained its origin. As little was known about the formation of cherts until the mid-to-late 1900s, the Blue Mound cap was classified merely as a Silurian dolostone into which chert had somehow become integrated (Steidtmann). However, the published observations of the Blue Mound chert do not necessarily match with the classification granted by the Wisconsin Geological and Natural History Survey, nor were any convincing interpretations offered regarding the presence of the chert. Since 1927, significant progress in the field of sedimentology has been achieved. There now exists knowledge that may fill the gaps between observation and interpretation in the Blue Mound survey. The observations in the 1927 bulletin correspond with modern notions of a paleokarst chert breccia, which forms a chert rubble or residuum. A chert breccia is formed when existing clasts, or pieces, of chert become cemented together by further chert deposition (Kolodny, Chaussidon and Katz). This can form large boulders of chert rubble that resist erosion. Accumulation of chert rubble has been documented to form along old weathering surfaces as an insoluble residue in environments similar to Blue Mound (Kolodny, Chaussidon and Katz). The purpose of this investigation was to verify the observations within the 1927 survey of the Blue Mound chert, and determine through field observations and sample study if the Blue Mound chert fits the model of a paleokarst chert breccia.
ContributorsGalarowicz, Calley (Author) / Knauth, Paul (Thesis director) / Semken, Steven (Committee member) / Martin, Thomas (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2013-05
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Description
Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better

Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better understanding of their eruptions and associated hazards. I will approach this analysis by focusing on volcanic bombs and ballistics, which are large clots of lava that are launched from the volcanic vent, follow ballistic trajectories, and can travel meters to a few kilometers from their source (e.g. Fagents and Wilson 1993; Waitt et al. 1995).
Tecolote Volcano in the Pinacate Volcanic Field in Mexico contains multiple vents within a horseshoe-shaped crater that have all produced various ejecta (Zawacki et al. 2019). The objectives of this research are to map ballistic distribution to understand the relationship between the source vent or vents and the bombs and ballistics that litter the region around Tecolote, and interpret the eruption conditions that ejected those bombs by using their distributions, morphologies, and fine-scale textures.
The findings of this work are that these bombs are apparently from the last stages of the eruption, succeeding the final lava flows. The interiors and exteriors of the bombs display different cooling rates which can are indicated by the fabric found within. Using this, certain characteristics of the bombs during eruption were extrapolated. The ‘cow pie’ bombs were determined to be the least viscous or contained a higher gas content at the time of eruption. Whereas the ribbon/rope bombs were determined to be the most viscous or contained a lesser gas content. Looking at the Southern Bomb Field site, it is dominated by large bombs that were during flight were molded into aerodynamic shapes. The Eastern Rim site is dominated by smaller bombs that appeared to be more liquid during the eruption. This difference in the two sites is a probable indication of at least two different eruptive events of different degrees of explosivity. Overall, aerodynamic bombs are more common and extend to greater distances from the presumed vent (up to 800 m), while very fluidal bombs are uncommon beyond 500 meters. Fluidal bombs (‘cow pie’, ‘ribbon’, ‘rope/spindle’) show a clear trend in decreasing size with distance from vent, whereas the size-distance trend is less dramatic for the aerodynamic bombs.
ContributorsWest, Jacob Alexander (Co-author) / West, Jacob (Co-author) / Clarke, Amanda (Thesis director) / Arrowsmith, Ramon (Committee member) / Roggensack, Kurt (Committee member) / School of Earth and Space Exploration (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05