New sol-gel routes based on peroxo complexes of early transition metals in a highly acidic medium were developed, to prepare metal oxide phosphates that feature structural protons. A sol-gel synthetic route was chosen because it allows atomic level mixing of precursors and lower heating temperatures, which are preferable in exploring metastable phases. Titanium and molybdenum sol-gel chemistries were the focus of the initial studies and the synthesis of Ti1-xMoxP2O7 (x = 0 – 0.5) and Mo1-yTiyP2O8-y (y = 0 – 0.4) type metal oxide phosphates were explored.
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- Partial requirement for: M.S., Arizona State University, 2018Note typethesis
- Includes bibliographical references (pages 87-94)Note typebibliography
- Field of study: Chemistry