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- Creators: Poulenc, Francis, 1899-1963
Description
Emission of CO2 into the atmosphere has become an increasingly concerning issue as we progress into the 21st century Flue gas from coal-burning power plants accounts for 40% of all carbon dioxide emissions. The key to successful separation and sequestration is to separate CO2 directly from flue gas (10-15% CO2, 70% N2), which can range from a few hundred to as high as 1000°C. Conventional microporous membranes (carbons/silicas/zeolites) are capable of separating CO2 from N2 at low temperatures, but cannot achieve separation above 200°C. To overcome the limitations of microporous membranes, a novel ceramic-carbonate dual-phase membrane for high temperature CO2 separation was proposed. The membrane was synthesized from porous La0.6Sr0.4Co0.8Fe0.2O3-d (LSCF) supports and infiltrated with molten carbonate (Li2CO3/Na2CO3/K2CO3). The CO2 permeation mechanism involves a reaction between CO2 (gas phase) and O= (solid phase) to form CO3=, which is then transported through the molten carbonate (liquid phase) to achieve separation. The effects of membrane thickness, temperature and CO2 partial pressure were studied. Decreasing thickness from 3.0 to 0.375 mm led to higher fluxes at 900°C, ranging from 0.186 to 0.322 mL.min-1.cm-2 respectively. CO2 flux increased with temperature from 700 to 900°C. Activation energy for permeation was similar to that for oxygen ion conduction in LSCF. For partial pressures above 0.05 atm, the membrane exhibited a nearly constant flux. From these observations, it was determined that oxygen ion conductivity limits CO2 permeation and that the equilibrium oxygen vacancy concentration in LSCF is dependent on the partial pressure of CO2 in the gas phase. Finally, the dual-phase membrane was used as a membrane reactor. Separation at high temperatures can produce warm, highly concentrated streams of CO2 that could be used as a chemical feedstock for the synthesis of syngas (H2 + CO). Towards this, three different membrane reactor configurations were examined: 1) blank system, 2) LSCF catalyst and 3) 10% Ni/y-alumina catalyst. Performance increased in the order of blank system < LSCF catalyst < Ni/y-alumina catalyst. Favorable conditions for syngas production were high temperature (850°C), low sweep gas flow rate (10 mL.min-1) and high methane concentration (50%) using the Ni/y-alumina catalyst.
ContributorsAnderson, Matthew Brandon (Author) / Lin, Jerry (Thesis advisor) / Alford, Terry (Committee member) / Rege, Kaushal (Committee member) / Anderson, James (Committee member) / Rivera, Daniel (Committee member) / Arizona State University (Publisher)
Created2011
ContributorsPoulenc, Francis, 1899-1963 (Composer)
ContributorsPoulenc, Francis, 1899-1963 (Composer)
ContributorsPoulenc, Francis, 1899-1963 (Composer)
ContributorsPoulenc, Francis, 1899-1963 (Composer)
Description
In this thesis, different H∞ observers for time-delay systems are implemented and
their performances are compared. Equations that can be used to calculate observer gains are mentioned. Different methods that can be used to implement observers for time-delay systems are illustrated. Various stable and unstable systems are used and H∞ bounds are calculated using these observer designing methods. Delays are assumed to be known constants for all systems. H∞ gains are calculated numerically using disturbance signals and performances of observers are compared.
The primary goal of this thesis is to implement the observer for Time Delay Systems designed using SOS and compare its performance with existing H∞ optimal observers. These observers are more general than other observers for time-delay systems as they make corrections to the delayed state as well along with the present state. The observer dynamics can be represented by an ODE coupled with a PDE. Results shown in this thesis show that this type of observers performs better than other H∞ observers. Sub-optimal observer-based state feedback system is also generated and simulated using the SOS observer. The simulation results show that the closed loop system converges very quickly, and the observer can be used to design full state-feedback closed loop system.
their performances are compared. Equations that can be used to calculate observer gains are mentioned. Different methods that can be used to implement observers for time-delay systems are illustrated. Various stable and unstable systems are used and H∞ bounds are calculated using these observer designing methods. Delays are assumed to be known constants for all systems. H∞ gains are calculated numerically using disturbance signals and performances of observers are compared.
The primary goal of this thesis is to implement the observer for Time Delay Systems designed using SOS and compare its performance with existing H∞ optimal observers. These observers are more general than other observers for time-delay systems as they make corrections to the delayed state as well along with the present state. The observer dynamics can be represented by an ODE coupled with a PDE. Results shown in this thesis show that this type of observers performs better than other H∞ observers. Sub-optimal observer-based state feedback system is also generated and simulated using the SOS observer. The simulation results show that the closed loop system converges very quickly, and the observer can be used to design full state-feedback closed loop system.
ContributorsTalati, Rushabh Vikram (Author) / Peet, Matthew (Thesis advisor) / Berman, Spring (Committee member) / Rivera, Daniel (Committee member) / Arizona State University (Publisher)
Created2018
Description
Vertical taking off and landing (VTOL) drones started to emerge at the beginning of this century, and finds applications in the vast areas of mapping, rescuing, logistics, etc. Usually a VTOL drone control system design starts from a first principles model. Most of the VTOL drones are in the shape of a quad-rotor which is convenient for dynamic analysis.
In this project, a VTOL drone with shape similar to a Convair XFY-1 is studied and the primary focus is developing and examining an alternative method to identify a system model from the input and output data, with which it is possible to estimate system parameters and compute model uncertainties on discontinuous data sets. We verify the models by designing controllers that stabilize the yaw, pitch, and roll angles for the VTOL drone in the hovering state.
This project comprises of three stages: an open-loop identification to identify the yaw and pitch dynamics, an intermediate closed-loop identification to identify the roll action dynamic and a closed-loop identification to refine the identification of yaw and pitch action. In open and closed loop identifications, the reference signals sent to the servos were recorded as inputs to the system and the angles and angular velocities in yaw and pitch directions read by inertial measurement unit were recorded as outputs of the system. In the intermediate closed loop identification, the difference between the reference signals sent to the motors on the contra-rotators was recorded as input and the roll angular velocity is recorded as output. Next, regressors were formed by using a coprime factor structure and then parameters of the system were estimated using the least square method. Multiplicative and divisive uncertainties were calculated from the data set and were used to guide PID loop-shaping controller design.
In this project, a VTOL drone with shape similar to a Convair XFY-1 is studied and the primary focus is developing and examining an alternative method to identify a system model from the input and output data, with which it is possible to estimate system parameters and compute model uncertainties on discontinuous data sets. We verify the models by designing controllers that stabilize the yaw, pitch, and roll angles for the VTOL drone in the hovering state.
This project comprises of three stages: an open-loop identification to identify the yaw and pitch dynamics, an intermediate closed-loop identification to identify the roll action dynamic and a closed-loop identification to refine the identification of yaw and pitch action. In open and closed loop identifications, the reference signals sent to the servos were recorded as inputs to the system and the angles and angular velocities in yaw and pitch directions read by inertial measurement unit were recorded as outputs of the system. In the intermediate closed loop identification, the difference between the reference signals sent to the motors on the contra-rotators was recorded as input and the roll angular velocity is recorded as output. Next, regressors were formed by using a coprime factor structure and then parameters of the system were estimated using the least square method. Multiplicative and divisive uncertainties were calculated from the data set and were used to guide PID loop-shaping controller design.
ContributorsLiu, Yiqiu (Author) / Tsakalis, Konstantinos (Thesis advisor) / Rodriguez, Armando (Thesis advisor) / Rivera, Daniel (Committee member) / Arizona State University (Publisher)
Created2015
Description
A computational framework based on convex optimization is presented for stability analysis of systems described by Partial Differential Equations (PDEs). Specifically, two forms of linear PDEs with spatially distributed polynomial coefficients are considered.
The first class includes linear coupled PDEs with one spatial variable. Parabolic, elliptic or hyperbolic PDEs with Dirichlet, Neumann, Robin or mixed boundary conditions can be reformulated in order to be used by the framework. As an example, the reformulation is presented for systems governed by Schr¨odinger equation, parabolic type, relativistic heat conduction PDE and acoustic wave equation, hyperbolic types. The second form of PDEs of interest are scalar-valued with two spatial variables. An extra spatial variable allows consideration of problems such as local stability of fluid flows in channels and dynamics of population over two dimensional domains.
The approach does not involve discretization and is based on using Sum-of-Squares (SOS) polynomials and positive semi-definite matrices to parameterize operators which are positive on function spaces. Applying the parameterization to construct Lyapunov functionals with negative derivatives allows to express stability conditions as a set of LinearMatrix Inequalities (LMIs). The MATLAB package SOSTOOLS was used to construct the LMIs. The resultant LMIs then can be solved using existent Semi-Definite Programming (SDP) solvers such as SeDuMi or MOSEK. Moreover, the proposed approach allows to calculate bounds on the rate of decay of the solution norm.
The methodology is tested using several numerical examples and compared with the results obtained from simulation using standard methods of numerical discretization and analytic solutions.
The first class includes linear coupled PDEs with one spatial variable. Parabolic, elliptic or hyperbolic PDEs with Dirichlet, Neumann, Robin or mixed boundary conditions can be reformulated in order to be used by the framework. As an example, the reformulation is presented for systems governed by Schr¨odinger equation, parabolic type, relativistic heat conduction PDE and acoustic wave equation, hyperbolic types. The second form of PDEs of interest are scalar-valued with two spatial variables. An extra spatial variable allows consideration of problems such as local stability of fluid flows in channels and dynamics of population over two dimensional domains.
The approach does not involve discretization and is based on using Sum-of-Squares (SOS) polynomials and positive semi-definite matrices to parameterize operators which are positive on function spaces. Applying the parameterization to construct Lyapunov functionals with negative derivatives allows to express stability conditions as a set of LinearMatrix Inequalities (LMIs). The MATLAB package SOSTOOLS was used to construct the LMIs. The resultant LMIs then can be solved using existent Semi-Definite Programming (SDP) solvers such as SeDuMi or MOSEK. Moreover, the proposed approach allows to calculate bounds on the rate of decay of the solution norm.
The methodology is tested using several numerical examples and compared with the results obtained from simulation using standard methods of numerical discretization and analytic solutions.
ContributorsMeyer, Evgeny (Author) / Peet, Matthew (Thesis advisor) / Berman, Spring (Committee member) / Rivera, Daniel (Committee member) / Arizona State University (Publisher)
Created2016
ContributorsPoulenc, Francis, 1899-1963 (Composer)
ContributorsPoulenc, Francis, 1899-1963 (Composer)