This dissertation is focused on highlighting the importance of end of life on the life-cycle of biopolymers, identifying how compostable biopolymer products are entering waste streams, improving collection and waste processing, and quantifying the impacts that result from the disposal of biopolymers. Biopolymers, while somewhat available to residential consumers, are primarily being used by various food service organizations trying to achieve a variety of goals such as zero waste, green advertising, and providing more consumer options. While compostable biopolymers may be able to help reduce wastes to landfill they do result in environmental tradeoffs associated with agriculture during the production phase. Biopolymers may improve the management for compostable waste streams by enabling streamlined services and reducing non-compostable fossil-based plastic contamination. The concerns about incomplete degradation of biopolymers in composting facilities may be ameliorated using alkaline amendments sourced from waste streams of other industries. While recycling still yields major benefits for traditional resins, bio-based equivalents may provide addition benefits and compostable biopolymers offer benefits with regards to global warming and fossil fuel depletion. The research presented here represents two published studies, two studies which have been accepted for publication, and a life-cycle assessment that will be submitted for publication.
Two main strategies have emerged for integrating sustainability grand challenges. In the stand-alone course method, engineering programs establish one or two distinct courses that address sustainability grand challenges in depth. In the module method, engineering programs integrate sustainability grand challenges throughout existing courses. Neither method has been assessed in the literature.
This thesis aimed to develop sustainability modules, to create methods for evaluating the modules’ effectiveness on student cognitive and affective outcomes, to create methods for evaluating students’ cumulative sustainability knowledge, and to evaluate the stand-alone course method to integrate sustainability grand challenges into engineering curricula via active and experiential learning.
The Sustainable Metrics Module for teaching sustainability concepts and engaging and motivating diverse sets of students revealed that the activity portion of the module had the greatest impact on learning outcome retention.
The Game Design Module addressed methods for assessing student mastery of course content with student-developed games indicated that using board game design improved student performance and increased student satisfaction.
Evaluation of senior design capstone projects via novel comprehensive rubric to assess sustainability learned over students’ curriculum revealed that students’ performance is primarily driven by their instructor’s expectations. The rubric provided a universal tool for assessing students’ sustainability knowledge and could also be applied to sustainability-focused projects.
With this in mind, engineering educators should pursue modules that connect sustainability grand challenges to engineering concepts, because student performance improves and students report higher satisfaction. Instructors should utilize pedagogies that engage diverse students and impact concept retention, such as active and experiential learning. When evaluating the impact of sustainability in the curriculum, innovative assessment methods should be employed to understand student mastery and application of course concepts and the impacts that topics and experiences have on student satisfaction.
In this dissertation, I have synthesized the present state of knowledge and application of uncertainty and variability in ‘attributional’ LCA, and contribute to its quantitative assessment.
Firstly, the present state of addressment of uncertainty and variability in LCA is consolidated and reviewed. It is evident that sources of uncertainty and variability exist in the following areas: ISO standards, supplementary guides, software tools, life cycle inventory (LCI) databases, all four methodological phases of LCA, and use of LCA information. One source of uncertainty and variability, each, is identified, selected, quantified, and its implications discussed.
The use of surrogate LCI data in lieu of missing dataset(s) or data-gaps is a source of uncertainty. Despite the widespread use of surrogate data, there has been no effort to (1) establish any form of guidance for the appropriate selection of surrogate data and, (2) estimate the uncertainty associated with the choice and use of surrogate data. A formal expert elicitation-based methodology to select the most appropriate surrogates and to quantify the associated uncertainty was proposed and implemented.
Product-evolution in a non-uniform manner is a source of temporal variability that is presently not considered in LCA modeling. The resulting use of outdated LCA information will lead to misguided decisions affecting the issue at concern and eventually the environment. In order to demonstrate product-evolution within the scope of ISO 14044, and given that variability cannot be reduced, the sources of product-evolution were identified, generalized, analyzed and their implications (individual and coupled) on LCA results are quantified.
Finally, recommendations were provided for the advancement of robustness of 'attributional' LCA, with respect to uncertainty and variability.
Public transportation systems are often part of strategies to reduce urban environmental impacts from passenger transportation, yet comprehensive energy and environmental life-cycle measures, including upfront infrastructure effects and indirect and supply chain processes, are rarely considered. Using the new bus rapid transit and light rail lines in Los Angeles, near-term and long-term life-cycle impact assessments are developed, including consideration of reduced automobile travel. Energy consumption and emissions of greenhouse gases and criteria pollutants are assessed, as well the potential for smog and respiratory impacts.
Results show that life-cycle infrastructure, vehicle, and energy production components significantly increase the footprint of each mode (by 48–100% for energy and greenhouse gases, and up to 6200% for environmental impacts), and emerging technologies and renewable electricity standards will significantly reduce impacts. Life-cycle results are identified as either local (in Los Angeles) or remote, and show how the decision to build and operate a transit system in a city produces environmental impacts far outside of geopolitical boundaries. Ensuring shifts of between 20–30% of transit riders from automobiles will result in passenger transportation greenhouse gas reductions for the city, and the larger the shift, the quicker the payback, which should be considered for time-specific environmental goals.
Public transit systems are often accepted as energy and environmental improvements to automobile travel, however, few life cycle assessments exist to understand the effects of implementation of transit policy decisions. To better inform decision-makers, this project evaluates the decision to construct and operate public transportation systems and the expected energy and environmental benefits over continued automobile use. The public transit systems are selected based on screening criteria. Initial screening included advanced implementation (5 to 10 years so change in ridership could be observed), similar geographic regions to ensure consistency of analysis parameters, common transit agencies or authorities to ensure a consistent management culture, and modes reflecting large infrastructure investments to provide an opportunity for robust life cycle assessment of large impact components. An in-depth screening process including consideration of data availability, project age, energy consumption, infrastructure information, access and egress information, and socio-demographic characteristics was used as the second filter. The results of this selection process led to Los Angeles Metro’s Orange and Gold lines.
In this study, the life cycle assessment framework is used to evaluate energy inputs and emissions of greenhouse gases, particulate matter (10 and 2.5 microns), sulfur dioxide, nitrogen oxides, volatile organic compounds, and carbon monoxide. For the Orange line, Gold line, and competing automobile trip, an analysis system boundary that includes vehicle, infrastructure, and energy production components is specified. Life cycle energy use and emissions inventories are developed for each mode considering direct (vehicle operation), ancillary (non-vehicle operation including vehicle maintenance, infrastructure construction, infrastructure operation, etc.), and supply chain processes and services. In addition to greenhouse gas emissions, the inventories are linked to their potential for respiratory impacts and smog formation, and the time it takes to payback in the lifetime of each transit system.
Results show that for energy use and greenhouse gas emissions, the inclusion of life cycle components increases the footprint between 42% and 91% from vehicle propulsion exclusively. Conventional air emissions show much more dramatic increases highlighting the effectiveness of “tailpipe” environmental policy. Within the life cycle, vehicle operation is often small compared to other components. Particulate matter emissions increase between 270% and 5400%. Sulfur dioxide emissions increase by several orders of magnitude for the on road modes due to electricity use throughout the life cycle. NOx emissions increase between 31% and 760% due to supply chain truck and rail transport. VOC emissions increase due to infrastructure material production and placement by 420% and 1500%. CO emissions increase by between 20% and 320%. The dominating contributions from life cycle components show that the decision to build an infrastructure and operate a transportation mode in Los Angeles has impacts far outside of the city and region. Life cycle results are initially compared at each system’s average occupancy and a breakeven analysis is performed to compare the range at which modes are energy and environmentally competitive.
The results show that including a broad suite of energy and environmental indicators produces potential tradeoffs that are critical to decision makers. While the Orange and Gold line require less energy and produce fewer greenhouse gas emissions per passenger mile traveled than the automobile, this ordering is not necessarily the case for the conventional air emissions. It is possible that a policy that focuses on one pollutant may increase another, highlighting the need for a broad set of indicators and life cycle thinking when making transportation infrastructure decisions.
The goal of this working paper is to provide the methodological background for several upcoming reports and peer-reviewed journal publications. This manuscript only provides background methodology and does not show or interpret any of the results that are being generated by the research team. The methodology is consistent with the transportation LCA approach developed by the author in previous research. The discussion in this working paper provides the detailed background data and steps used by the research team for their assessment of Los Angeles Metro transit lines and a competing automobile trip.