Matching Items (26)
Description
Proton and fluorine diffusivity and ionic conductivity of 2-fluoropyridinium triflate (2-FPTf) and proton and fluorine diffusivity, ionic conductivity, and viscosity of trifluoromethanesulfonic acid (TFMSA) monohydrate have been measured over a wide range of temperatures. Diffusivities were measured using the pulsed-gradient spin-echo (PGSE) technique on a 300 MHz NMR spectrometer. Conductivities were measured using electrochemical impedance spectroscopy (EIS) on standard equipment and viscosities were determined using a Cannon-Ubbelohde viscometer. For 2-FPTF, the diffusivity of mobile protons increased from 1.84+/-0.06 x 10(-11) m2/s at 55 degC to 1.64+/-0.05 x 10(-10) m2/s at 115 degC while the diffusivity of 2-fluoropyridine fluorines increased from 2.22+/-0.07 x 10(-11) m2/s at 70 degC to 9.40+/-0.28 x 10(-11) m2/s at 115 degC. For TFMSA monohydrate, the diffusivity of protons increased from 7.67+/-0.23 x 10(-11) m2/s at 40 degC to 3.92+/-0.12 x 10(-10) m2/s at 110 degC while the diffusivity of fluorines increased from 4.63+/-0.14 x 10(-11) m2/s at 40 degC to 2.79+/-0.08 x 10(-10) m2/s at 110 degC, protons diffusing approximately 1.5 times faster than fluorines over the entire temperature range. NMR spectra indicate that proton diffusion occurs via direct hopping from TFMSA molecule to molecule. The conductivity of 2-FPTf varied from 0.85+/-0.03 mS/cm to 35.9+/-1.08 mS/cm between 25 and 110 degC. The conductivity of TFMSA monohydrate varied from 6.60+/-0.2 mS/cm to 84.6+/-2.5 mS/cm between 23 and 139 degC and its viscosity varied from 27.5+/-1.4 mPa.s to 4.38+/-0.22 mPa.s between 49 and 121.5 degC, in good agreement with literature values. Temperature dependences of the measured properties showed Arrhenius behavior with activation energies for proton diffusion, fluorine diffusion and ionic conduction for 2-FPTf above the melting point of 16.9+/-0.8 kJ/mol, 48.0+/-2.4 kJ/mol and 27.8+/-1.4 kJ/mol respectively. Activation energies for proton diffusion, fluorine diffusion, ionic conduction and viscosity for TFMSA monohydrate were 23.4+/-1.2 kJ/mol, 26.0+/-1.3 kJ/mol, 22.1+/-1.1 kJ/mol, and 26.9+/-1.3 kJ/mol respectively. The degree of dissociation of the charged species, calculated using the Nernst-Einstein relation, varied from 13 to 24% for 2-FPTf and from 25 to 29% for TFMSA monohydrate over the temperature range.
ContributorsAbdullah, Mohammed Wahed (Author) / Marzke, Robert F (Thesis advisor) / Gervasio, Dominic (Committee member) / Chamberlin, Ralph (Committee member) / Alarcon, Ricardo (Committee member) / Arizona State University (Publisher)
Created2015
Description
Precision measurements of kinematic correlation parameters of free neutron decayserve as a powerful probe of the Standard Model of particle physics. A wide array
of Beyond the Standard Model physics theories can be probed by precision neutron
physics. The Nab experiment will measure a, the electron-neutrino correlation coefficient, and b, the Fierz interference term. a is amongst the most sensitive decay
parameters to λ = gA/gV , the ratio of the axial-vector and vector coupling constants
in the weak force. Two important systematic considerations for the Nab experiment
are average detector timing bias, which must be held to ≤ 0.3 ns, and energy calibration and linearity, which must be held to 1 part in 104
. Both systematics require an
in depth understanding of charge collection in Nab’s Si detectors. Simulation of Si
charge collection using numerical methods and the Shockley-Ramo Theorem has been
completed. A variety of detector tests, including detector and amplification electronics acceptance testing have also been completed. Also included in this dissertation is
my work with the Nab ultra-high vacuum and cryogenic system.
ContributorsRandall, Glenn (Author) / Alarcon, Ricardo (Thesis advisor) / Chamberlin, Ralph (Committee member) / Dugger, Michael (Committee member) / Lebed, Richard (Committee member) / Arizona State University (Publisher)
Created2021
Description
The GlueX experiment housed in Hall D of the Thomas Jefferson National Laboratory was created to map the light meson spectrum in order to contribute to the Standard Model of particle physics by strengthening our understanding of the strong interaction. GlueX is a medium-energy photoproduction experiment that utilizes a linearly polarized photon beam to create hadronic forms of matter. By mapping the light meson spectrum, the GlueX collaboration hopes to identify meson states forbidden by the Constituent Quark Model. As a main research objective, the GlueX collaboration is searching for hybrid $q\bar{q}g$ meson states that exhibit exotic quantum numbers. One hybrid meson candidate is the $\eta'_1$, which is predicted to decay to $K^\ast\bar{K}$ and have a mass near $2.3~\mathrm{GeV}$ (\citeauthor{qn_exotic_status}, \citeyear{qn_exotic_status}; \citeauthor{hybrid_mesons}, \citeyear{hybrid_mesons}). At this time, very few meson states have been identified in the $2.0~\mathrm{GeV}$ mass region. This dearth of evidence for existing states requires any tool developed to search for meson states above $2.0~\mathrm{GeV}$ must be verified by looking at known meson states. In order to search for the $\eta'_1$ hybrid meson candidate in $\gamma p \rightarrow pK^+K^-\gamma\gamma$ events, meson states decaying $K^\ast\bar{K}$ that contribute to the low mass region must be identified, defined in this document as particles having masses between $1400$ and $1600~\mathrm{MeV}$. Identifying what meson states exist in the low mass region is also critical to mapping the light meson spectrum and determining the quark-gluonic content of those meson states. The results of a partial wave analysis (PWA) of $\gamma p \rightarrow pX$ where $X\rightarrow K^\ast\bar{K}$ from $\gamma p \rightarrow pK^+K^-\gamma\gamma$ events in GlueX are presented. In the $J=0$ invariant mass distribution, the $\eta(1405)$ and $\eta(1475)$ are identified, adding to the debate as to whether two pseudoscalar mesons exist in the low mass region. For the $J=1$ distribution, the $f_1(1420)$ and $f_1(1510)$ axial vector mesons are seen, where the former helps further elaborate on the $E\iota$ puzzle of the twentieth century \citep{E_iota_puzzle}. With respect to the controversy of meson states in the low mass region, evidence for the existence of the $f_2(1430)$ meson is strengthened in the $J=2$ distribution, and the $f'_2(1525)$ state is seen. This work lays a foundation for the ASU Meson Physics Group to continue a wider search for hybrid mesons in the $\gamma p \rightarrow pK^+K^-\gamma\gamma$ reaction topology.
ContributorsCole, Sebastian Miles (Author) / Dugger, Michael (Thesis advisor) / Ritchie, Barry (Committee member) / Alarcon, Ricardo (Committee member) / Shovkovy, Igor (Committee member) / Arizona State University (Publisher)
Created2021
Description
This research evaluates the capabilities of typical radiological measures and dual-energy systems to differentiate common kidney stones materials: uric acid, oxalates, phosphates, struvite, and cystine. Two different X-ray spectra (80 kV and 120 kV) were applied and the dual-energy ratio of individual kidney stones was used to figure out the discriminability of different materials. A CT cross-section with a prospective kidney stone was analyzed to see the capabilities of such a technique. Typical radiological measures suggested that phosphates and oxalate stones can be distinguished from uric acid stones while dual-energy seemed to prove similar effectiveness.
ContributorsDelafuente, Nicholas William (Author) / Rez, Peter (Thesis director) / Alarcon, Ricardo (Committee member) / Department of Physics (Contributor) / Economics Program in CLAS (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
Professor Alarcon’s lab is producing proton beam detectors, and this project is focused on informing the decision as to which layout of detector is more effective at producing an accurate backprojection for an equal number of data channels. The comparison is between “square pad” detectors and “wire pad” detectors. The square pad detector consists of a grid of square pads all of identical size, that each collect their own data. The wire pad detector consists of large rectangular pads that span the entire detector in one direction, with 2 additional layers of identical pads each rotated by 60° from the previous. In order to test each design Python was used to simulate Gaussian beams of varying amplitudes, position and size and integrate them in each of the two methods. They were then backprojected and fit to a Gaussian function and the error between the backprojected parameters and the original parameters of the beam were measured.
ContributorsFoley, Brendan (Author) / Alarcon, Ricardo (Thesis director) / Galyaev, Eugene (Committee member) / Department of Physics (Contributor) / School of Mathematical and Statistical Sciences (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
Cubic boron nitride (c-BN), hexagonal boron nitride (h-BN), and semiconducting diamond all have physical properties that make them ideal materials for applications in high power and high frequency electronics, as well as radiation detectors. However, there is limited research on the unique properties and growth of c-BN or h-BN thin films. This dissertation addresses the deposition of c-BN via plasma enhanced chemical vapor deposition (PECVD) on boron doped diamond substrates. In-Situ X-ray photoelectron spectroscopy (XPS) is used to characterize the thickness and hexagonal to cubic ratio of boron nitride thin films. The effects of hydrogen concentration during the deposition of boron nitride are investigated. The boron nitride deposition rate is found to be dependent on the hydrogen gas flow. The sp2 to sp3 bonding is also found to be dependent on the hydrogen gas flow. Preferential growth of h-BN is observed when an excess of hydrogen is supplied to the reaction, while h-BN growth is suppressed when hydrogen flow is reduced to be the limiting reactant. Reduced hydrogen flow is also observed to promote preferential growth of c-BN.
The hydrogen limited reaction is used to deposit c-BN on single crystal (100) boron-doped diamond substrates. In-situ ultra-violet photoelectron spectroscopy (UPS) and XPS are used to deduce the valence band offset of the diamond/c-BN interface. A valence band offset of -0.3 eV is measured with the diamond VBM above the VBM of c-BN. This value is then discussed in context of previous experimental results and theoretical calculations.
Finally, UPS and XPS are used to characterize the surface states of phosphorus-doped diamond. Variations within the processing parameters for surface preparation and the effects on the electronic surface states are presented and discussed.
ContributorsBrown, Jesse (Author) / Nemanich, Robert J (Thesis advisor) / Alarcon, Ricardo (Committee member) / Lindsay, Stuart (Committee member) / Zaniewski, Anna (Committee member) / Arizona State University (Publisher)
Created2021