Matching Items (67)
Filtering by
- Genre: Masters Thesis
- Creators: Phelan, Patrick
Description
Solar photovoltaic (PV) industry is tipped to be one of the front-runners in the renewable industry. Typically, PV module manufacturers provide a linear or step warranty of 80% of original power over 25 years. This power loss during the field exposure is primarily attributed to the development of performance affecting defects in the PV modules. As many as 86 different defects can occur in a PV module. One of the major defects that can cause significant power loss is the interconnect metallization system (IMS) degradation which is the focus of this thesis. The IMS is composed of cell-interconnect (cell-ribbon interconnect) and string-interconnect (ribbon-ribbon interconnect). The cell interconnect is in turn composed of silver metallization (fingers and busbars) and solder bonds between silver busbar and copper ribbon. Weak solder bonding between copper ribbon and busbar of a cell results in increase of series resistance that in turn affects the fill factor causing a power drop. In this thesis work, the results obtained from various non-destructive and destructive experiments performed on modules exposed in three different climates (Arizona - Hot and Dry, Mexico - Warm and Humid, and California - Temperate) are presented. These experiments include light I-V measurements, dark I-V measurements, infrared imaging, extraction of test samples from the modules, peel strength measurements and four-point resistance measurements. The extraction of test samples was performed using a mechanical method and a chemical method. The merits and demerits of these two methods are presented. A drop of 10.33% in fill factor was observed for a 0.05Ω increase in the series resistance of the modules investigated in this work. Different combinations in a cell that can cause series resistance increase were considered and their effect on fill factor were observed using four-point probe experiments. Peel test experiments were conducted to correlate the effect of series resistance on the ribbon peel strength. Finally, climate specific thermal modelling was performed for 4 different sites over 20 years in order to calculate the accumulated thermal fatigue and also to evaluate its correlation, if any, with the increase of series resistance.
ContributorsTummala, Abhishiktha (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
Description
Soiling is one of the major environmental factors causing the negative performance of photovoltaic (PV) modules. Dust particles, air pollution particles, pollen, bird droppings and other industrial airborne particles are some natural sources that cause soiling. The thickness of soiling layer has a direct impact on the performance of PV modules. This phenomenon occurs over a period of time with many unpredictable environmental variables indicated above. This situation makes it difficult to calculate or predict the soiling effect on performance. The dust particles vary from one location to the other in terms of particle size, color and chemical composition. These properties influence the extent of performance (current) loss, spectral loss and adhesion of soil particles on the surface of the PV modules. To address this uncontrolled environmental issues, research institutes around the world have started designing indoor artificial soiling stations to deposit soil layers in various controlled environments using reference soil samples and/or soil samples collected from the surface of PV modules installed in the locations of interest. This thesis is part of a twin thesis. The first thesis (this thesis) authored by Shanmukha Mantha is related to the development of soiling stations and the second thesis authored by Darshan Choudhary is associated with the characterization of the soiled samples (glass coupons, one-cell PV coupons and multi-cell PV coupons). This thesis is associated with the development of three types of indoor artificial soiling deposition techniques replicating the outside environmental conditions to achieve required soil density, uniformity and other required properties. The three types of techniques are: gravity deposition method, dew deposition method, and humid deposition method. All the three techniques were applied on glass coupons, single-cell PV laminates containing monocrystalline silicon cells and multi-cell PV laminates containing polycrystalline silicon cells. The density and uniformity for each technique on all targets are determined. In this investigation, both reference soil sample (Arizona road dust, ISO 12103-1) and the soil samples collected from the surface of installed PV modules were used. All the three techniques are compared with each other to determine the best method for uniform deposition at varying thickness levels. The advantages, limitations and improvements made in each technique are discussed.
ContributorsMantha, Shanmukha (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
Description
The majority of the natural issues the world is confronting today is because of our dependence on fossil fuels and the increase in CO2 emissions. The alternative solution for this problem is the use of renewable energy for the energy production, but these are uncertain energy sources. So, the combination of reducing carbon dioxide with the use of renewable energy sources is the finest way to mitigate this problem. Electrochemical reduction of carbon dioxide (ERC) is a reasonable approach as it eliminates as well as utilizes the carbon dioxide as a source for generating valuable products.
In this study, development of electrochemical reactor, characterization of membrane electrode assembly (MEA) and analysis of electrochemical reduction of carbon dioxide (ERC) is discussed. Electrodes using various catalyst materials in solid polymer based electrolyte (SPE) along with gas diffusion layer (GDL) are developed. The prepared membrane electrodes are characterized under ex-situ conditions using scanning electron microscopy (SEM). The membranes are later placed in the electrochemical reactor for the in-situ characterization to assess the performance of the membrane electrode assembly.
The electrodes are processed by airbrushing the metal particles on the nafion membrane and then are electrochemically characterized by linear sweep voltammetry. The anode was kept constant with platinum whereas the cathode was examined with compositions of different metal catalysts. The products formed subsequently are analyzed using gas chromatography (GC) and Residual gas analysis (RGA). Hydrogen (H2) and carbon monoxide (CO) are detected using GC while the hydrocarbons are detected by performing quantitative analysis using RGA. The preliminary experiments gave very encouraging results. However, more work needs to be done to achieve new heights.
In this study, development of electrochemical reactor, characterization of membrane electrode assembly (MEA) and analysis of electrochemical reduction of carbon dioxide (ERC) is discussed. Electrodes using various catalyst materials in solid polymer based electrolyte (SPE) along with gas diffusion layer (GDL) are developed. The prepared membrane electrodes are characterized under ex-situ conditions using scanning electron microscopy (SEM). The membranes are later placed in the electrochemical reactor for the in-situ characterization to assess the performance of the membrane electrode assembly.
The electrodes are processed by airbrushing the metal particles on the nafion membrane and then are electrochemically characterized by linear sweep voltammetry. The anode was kept constant with platinum whereas the cathode was examined with compositions of different metal catalysts. The products formed subsequently are analyzed using gas chromatography (GC) and Residual gas analysis (RGA). Hydrogen (H2) and carbon monoxide (CO) are detected using GC while the hydrocarbons are detected by performing quantitative analysis using RGA. The preliminary experiments gave very encouraging results. However, more work needs to be done to achieve new heights.
ContributorsVenka, Rishika (Author) / Kannan, Arunachala Mada (Thesis advisor) / Huang, Huei-Ping (Thesis advisor) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2016
Description
This work aimed to characterize and optimize the variables that influence the Gas Diffusion Layer (GDL) preparation using design of experiment (DOE) approach. In the process of GDL preparation, the quantity of carbon support and Teflon were found to have significant influence on the Proton Exchange Membrane Fuel Cell (PEMFC). Characterization methods like surface roughness, wetting characteristics, microstructure surface morphology, pore size distribution, thermal conductivity of GDLs were examined using laser interferometer, Goniometer, SEM, porosimetry and thermal conductivity analyzer respectively. The GDLs were evaluated in single cell PEMFC under various operating conditions of temperature and relative humidity (RH) using air as oxidant. Electrodes were prepared with different PUREBLACK® and poly-tetrafluoroethylene (PTFE) content in the diffusion layer and maintaining catalytic layer with a Pt-loading (0.4 mg cm-2). In the study, a 73.16 wt.% level of PB and 34 wt.% level of PTFE was the optimal compositions for GDL at 70 °C for 70% RH under air atmosphere.
For most electrochemical processes the oxygen reduction is very vita reaction. Pt loading in the electrocatalyst contributes towards the total cost of electrochemical devices. Reducing the Pt loading in electrocatalysts with high efficiency is important for the development of fuel cell technologies. To this end, this thesis work reports the approach to lower down the Pt loading in electrocatalyst based on N-doped carbon nanotubes derived from Zeolitic Imidazolate Frameworks (ZIF-67) for oxygen reduction. This electrocatalyst perform with higher electrocatalytic activity and stability for oxygen reduction in fuel cell testing. The electrochemical properties are mainly due to the synergistic effect from N-doped carbon nanotubes derived from ZIF and Pt loading. The strategy with low Pt loading forecasts in emerging highly active and less expensive electrocatalysts in electrochemical energy devices.
This thesis focuses on: (i) methods to obtain greater power density by optimizing content of wet-proofing agent (PTFE) and fine-grained, hydrophobic, microporous layer (MPL); (ii) modeling full factorial analysis of PEMFC for evaluation with experimental results and predicting further improvements in performance; (iii) methods to obtain high levels of performance with low Pt loading electrodes based on N-doped carbon nanotubes derived from ZIF-67 and Pt.
For most electrochemical processes the oxygen reduction is very vita reaction. Pt loading in the electrocatalyst contributes towards the total cost of electrochemical devices. Reducing the Pt loading in electrocatalysts with high efficiency is important for the development of fuel cell technologies. To this end, this thesis work reports the approach to lower down the Pt loading in electrocatalyst based on N-doped carbon nanotubes derived from Zeolitic Imidazolate Frameworks (ZIF-67) for oxygen reduction. This electrocatalyst perform with higher electrocatalytic activity and stability for oxygen reduction in fuel cell testing. The electrochemical properties are mainly due to the synergistic effect from N-doped carbon nanotubes derived from ZIF and Pt loading. The strategy with low Pt loading forecasts in emerging highly active and less expensive electrocatalysts in electrochemical energy devices.
This thesis focuses on: (i) methods to obtain greater power density by optimizing content of wet-proofing agent (PTFE) and fine-grained, hydrophobic, microporous layer (MPL); (ii) modeling full factorial analysis of PEMFC for evaluation with experimental results and predicting further improvements in performance; (iii) methods to obtain high levels of performance with low Pt loading electrodes based on N-doped carbon nanotubes derived from ZIF-67 and Pt.
ContributorsKasat, Harshal Anil (Author) / Kannan, Arunachalana (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Arizona State University (Publisher)
Created2016
Description
One the major problems of this modern industrialized world is its dependence on fossil fuels for its energy needs. Burning of fossils fuels generates green-house gases which have adverse effects on global climate contributing to global warming. According to Environmental Protection Agency (EPA), carbon dioxide makes up 80 percent of green-house gases emitted in USA. Electrochemical reduction of carbon dioxide is an approach which uses CO2 emissions to produce other useful hydrocarbons which can be used in many ways.
In this study, primary focus was on optimizing the operating conditions, determining the better catalyst material, and analyzing the reaction products for the process of electrochemical reduction of carbon dioxide (ERC). Membrane electrode assemblies (MEA’s) are developed by air bushing the metal particles with a spray gun on to Nafion-212 which is a solid polymer based electrolyte (SPE), to support the electrodes in the electrochemical reactor gas diffusion layers (GDL) are developed using porous carbon paper. Anode was always made using the same material which is platinum but cathode material was changed as it is the working electrode.
The membrane electrode assembly (MEA) is then placed into the electrochemical reactor along with gas diffusion layer (GDL) to assess the performance of the catalyst material by techniques like linear sweep voltammetry and chronoamperometry. Performance of MEA was analyzed at 4 different potentials, 2 different temperatures and for 2 different cathode catalyst materials. The reaction products of the process are analyzed using gas chromatography (GC) which has thermal conductivity detector (TCD) used for detecting hydrogen (H2), carbon monoxide (CO) and flame ionization detector (FID) used for detecting hydrocarbons. The experiments performed at 40o C gave the better results when compared with the experiments performed at ambient temperature. Also results suggested that copper oxide cathode catalyst has better durability than platinum-carbon. Maximum faradaic efficiency for methane was 5.3% it was obtained at 2.25V using copper oxide catalyst. Furthermore, experiments must be carried out to make the electrochemical reactor more robust to withstand all the operating conditions like higher potentials and to make it a solar powered reactor.
In this study, primary focus was on optimizing the operating conditions, determining the better catalyst material, and analyzing the reaction products for the process of electrochemical reduction of carbon dioxide (ERC). Membrane electrode assemblies (MEA’s) are developed by air bushing the metal particles with a spray gun on to Nafion-212 which is a solid polymer based electrolyte (SPE), to support the electrodes in the electrochemical reactor gas diffusion layers (GDL) are developed using porous carbon paper. Anode was always made using the same material which is platinum but cathode material was changed as it is the working electrode.
The membrane electrode assembly (MEA) is then placed into the electrochemical reactor along with gas diffusion layer (GDL) to assess the performance of the catalyst material by techniques like linear sweep voltammetry and chronoamperometry. Performance of MEA was analyzed at 4 different potentials, 2 different temperatures and for 2 different cathode catalyst materials. The reaction products of the process are analyzed using gas chromatography (GC) which has thermal conductivity detector (TCD) used for detecting hydrogen (H2), carbon monoxide (CO) and flame ionization detector (FID) used for detecting hydrocarbons. The experiments performed at 40o C gave the better results when compared with the experiments performed at ambient temperature. Also results suggested that copper oxide cathode catalyst has better durability than platinum-carbon. Maximum faradaic efficiency for methane was 5.3% it was obtained at 2.25V using copper oxide catalyst. Furthermore, experiments must be carried out to make the electrochemical reactor more robust to withstand all the operating conditions like higher potentials and to make it a solar powered reactor.
ContributorsMudunur, Santosh shekar (Author) / Kannan, Arunachala (Thesis advisor) / Phelan, Patrick (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2017
Description
Photovoltaic modules degrade in the field. This thesis aims to answer two questions: 1. Do photovoltaic modules degrade linearly or not? 2. Do soiled modules operate at lower temperatures than clean modules? Answers to these questions are provided in part 1 and part 2 of this thesis respectively.
Part 1: Linearity determination in degradation: The electricity output from PV power plants degrades every year. Generally, a system’s life is considered to last for 20-25 years and rate of degradation is commonly assumed as 1% per year. PV degradation can be found out using Performance Ratio (PR), Performance Index (PI) and raw kWh output. The rate of degradation is considered linear for simplicity of calculations. In this thesis, statistical methods are used to check whether systems in Arizona are degrading linearly or not. Time series modeling such as Winters’ method and ARIMA are used to model the data. Winters’ method and Seasonal ARIMA consider the seasonality component and perform well for small data sets of about 10 years. Rate of degradation is found out as linear for all the evaluated systems.
Part 2: Temperature analysis of clean and soiled modules: Soiling and temperature are important parameters in performance of PV modules. In this paper, an analysis is carried out on a soiling station located in Mesa, Arizona. The soiling station consists of 10 different c-Si coupons with tilt angles varying from 0° to 45° with the difference of 5°. These coupons are cut in half, one is cleaned periodically and the other is remained soiled naturally. The analysis involves data worth for 19 months. 6 dry spells in all four seasons within 19 months were analyzed. The temperature difference between a clean module and a soiled module (ΔT) is compared with the soiling loss factor (SLF). The analysis concludes stating in which season a soiled module is hotter or cooler than a clean module.
Part 1: Linearity determination in degradation: The electricity output from PV power plants degrades every year. Generally, a system’s life is considered to last for 20-25 years and rate of degradation is commonly assumed as 1% per year. PV degradation can be found out using Performance Ratio (PR), Performance Index (PI) and raw kWh output. The rate of degradation is considered linear for simplicity of calculations. In this thesis, statistical methods are used to check whether systems in Arizona are degrading linearly or not. Time series modeling such as Winters’ method and ARIMA are used to model the data. Winters’ method and Seasonal ARIMA consider the seasonality component and perform well for small data sets of about 10 years. Rate of degradation is found out as linear for all the evaluated systems.
Part 2: Temperature analysis of clean and soiled modules: Soiling and temperature are important parameters in performance of PV modules. In this paper, an analysis is carried out on a soiling station located in Mesa, Arizona. The soiling station consists of 10 different c-Si coupons with tilt angles varying from 0° to 45° with the difference of 5°. These coupons are cut in half, one is cleaned periodically and the other is remained soiled naturally. The analysis involves data worth for 19 months. 6 dry spells in all four seasons within 19 months were analyzed. The temperature difference between a clean module and a soiled module (ΔT) is compared with the soiling loss factor (SLF). The analysis concludes stating in which season a soiled module is hotter or cooler than a clean module.
ContributorsPatankar, Adit (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2017
Description
Efficient performance of gas turbines depends, among several parameters, on the mainstream gas entry temperature. At the same time, transport of this high temperature gas into the rotor-stator cavities of turbine stages affects the durability of rotor disks. This transport is usually countered by installing seals on the rotor and stator disk rims and by pressurizing the cavities by injecting air (purge gas) bled from the compressor discharge. The configuration of the rim seals influences the magnitude of main gas ingestion as well as the interaction of the purge gas with the main gas. The latter has aerodynamic and hub endwall heat transfer implications in the main gas path. In the present work, experiments were performed on model single-stage and 1.5-stage axial-flow turbines. The turbines featured vanes, blades, and rim seals on both the rotor and stator disks. Three different rim seal geometries, viz., axially overlapping radial clearance rim seals for the single-stage turbine cavity and the 1.5-stage turbine aft cavity, and a rim seal with angular clearance for the single-stage turbine cavity were studied. In the single-stage turbine, an inner seal radially inboard in the cavity was also provided; this effectively divided the disk cavity into a rim cavity and an inner cavity. For the aft rotor-stator cavity of the 1.5-stage turbine, a labyrinth seal was provided radially inboard, again creating a rim cavity and an inner cavity. Measurement results of time-average main gas ingestion into the cavities using tracer gas (CO2), and ensemble-averaged trajectories of the purge gas flowing out through the rim seal gap into the main gas path using particle image velocimetry are presented. For both turbines, significant ingestion occurred only in the rim cavity. The inner cavity was almost completely sealed by the inner seal, at all purge gas flow rates for the single-stage turbine and at the higher purge gas flow rates for 1.5-stage turbine. Purge gas egress trajectory was found to depend on main gas and purge gas flow rates, the rim seal configuration, and the azimuthal location of the trajectory mapping plane with respect to the vanes.
ContributorsBalasubramanian, Jagdish Harihara (Author) / Roy, Ramendra P (Thesis advisor) / Lee, Taewoo (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2010
Description
Phase Change Material (PCM) plays an important role as a thermal energy storage device by utilizing its high storage density and latent heat property. One of the potential applications for PCM is in buildings by incorporating them in the envelope for energy conservation. During the summer season, the benefits are a decrease in overall energy consumption by the air conditioning unit and a time shift in peak load during the day. Experimental work was carried out by Arizona Public Service (APS) in collaboration with Phase Change Energy Solutions (PCES) Inc. with a new class of organic-based PCM. This "BioPCM" has non-flammable properties and can be safely used in buildings. The experimental setup showed maximum energy savings of about 30%, a maximum peak load shift of ~ 60 min, and maximum cost savings of about 30%. Simulation was performed to validate the experimental results. EnergyPlus was chosen as it has the capability to simulate phase change material in the building envelope. The building material properties were chosen from the ASHRAE Handbook - Fundamentals and the HVAC system used was a window-mounted heat pump. The weather file used in the simulation was customized for the year 2008 from the National Renewable Energy Laboratory (NREL) website. All EnergyPlus inputs were ensured to match closely with the experimental parameters. The simulation results yielded comparable trends with the experimental energy consumption values, however time shifts were not observed. Several other parametric studies like varying PCM thermal conductivity, temperature range, location, insulation R-value and combination of different PCMs were analyzed and results are presented. It was found that a PCM with a melting point from 23 to 27 °C led to maximum energy savings and greater peak load time shift duration, and is more suitable than other PCM temperature ranges for light weight building construction in Phoenix.
ContributorsMuruganantham, Karthik (Author) / Phelan, Patrick (Thesis advisor) / Reddy, Agami (Committee member) / Lee, Taewoo (Committee member) / Arizona State University (Publisher)
Created2010
Description
This study analyzes the thermoelectric phenomena of nanoparticle suspensions, which are composed of liquid and solid nanoparticles that show a relatively stable Seebeck coefficient as bulk solids near room temperature. The approach is to explore the thermoelectric character of the nanoparticle suspensions, predict the outcome of the experiment and compare the experimental data with anticipated results. In the experiment, the nanoparticle suspension is contained in a 15cm*2.5cm*2.5cm glass container, the temperature gradient ranges from 20 °C to 60 °C, and room temperature fluctuates from 20 °C to 23°C. The measured nanoparticles include multiwall carbon nanotubes, aluminum dioxide and bismuth telluride. A temperature gradient from 20 °C to 60 °C is imposed along the length of the container, and the resulting voltage (if any) is measured. Both heating and cooling processes are measured. With three different nanoparticle suspensions (carbon nano tubes, Al2O3 nanoparticles and Bi2Te3 nanoparticles), the correlation between temperature gradient and voltage is correspondingly 8%, 38% and 96%. A comparison of results calculated from the bulk Seebeck coefficients with our measured results indicate that the Seebeck coefficient measured for each suspension is much more than anticipated, which indicates that the thermophoresis effect could have enhanced the voltage. Further research with a closed-loop system might be able to affirm the results of this study.
ContributorsZhu, Moxuan (Author) / Phelan, Patrick (Thesis advisor) / Trimble, Steve (Committee member) / Prasher, Ravi (Committee member) / Arizona State University (Publisher)
Created2010
Description
Rooftop photovoltaic (PV) systems are becoming increasingly common as the efficiency of solar panels increase, the cost decreases, and worries about climate change increase and become increasingly prevalent. An under explored aspect of rooftop solar systems is the thermal effects that the systems have on the local area. These effects are investigated in this paper to determine the overall impact that solar systems have on the heating and cooling demands of a building as well as on the efficiency losses of the solar panels due to the increased temperature on the panels themselves. The specific building studied in this paper is the Goldwater Center for Science and Engineering located in the Tempe campus of Arizona State University. The ambient conditions were modeled from a typical July day in Tempe. A numerical model of a simple flat roof was also created to find the average rooftop temperature throughout the day. Through this study it was determined that solar panels cause a decrease in the maximum temperature of the rooftop during the day, while reducing the ability of the roof to be cooled during the night. The solar panels also saw a high temperature during the day during the most productive time of day for solar panels, which saw a decrease in total energy production for the panels.
ContributorsNaber, Nicholas (Author) / Huang, Huei-Ping (Thesis advisor) / Phelan, Patrick (Committee member) / Bocanegra, Luis (Committee member) / Arizona State University (Publisher)
Created2022