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- All Subjects: Aluminum silicates
- Creators: Chithiraputhiran, Sundara Raman
Description
The increased emphasis on the detrimental effects of the production of construction materials such as ordinary portland cement (OPC) have driven studies of the alkali activation of aluminosilicate materials as binder systems derived from industrial byproducts. They have been extensively studied due to the advantages they offer in terms of enhanced material properties, while increasing sustainability by the reuse of industrial waste and reducing the adverse impacts of OPC production. Ground granulated blast furnace slag is one of the commonly used materials for their content of calcium and silica species. Alkaline activators such as silicates, aluminates etc. are generally used. These materials undergo dissolution, polymerization with the alkali, condensation on particle surfaces and solidification under the influence of alkaline activators. Exhaustive studies exploring the effects of sodium silicate as an activator however there is a significant lack of work on exploring the effect of the cation and the effect of liquid and powder activators. The focus of this thesis is hence segmented into two topics: (i) influence of liquid Na and K silicate activators to explore the effect of silicate and hydroxide addition and (ii) influence of powder Na and K Silicate activators to explore the effect of cation, concentration and silicates. Isothermal calorimetric studies have been performed to evaluate the early hydration process, and to understand the reaction kinetics of the liquid and powder alkali activated systems. The reaction kinetics had an impact on the early age behavior of these binders which can be explained by the compressive strength results. It was noticed that the concentration and silica modulus of the activator had a greater influence than the cation over the compressive strength. Quantification of the hydration products resultant from these systems was performed via thermo gravimetric analysis (TGA). The difference in the reaction products formed with varying cation and silicate addition in these alkali activated systems is brought out. Fourier transform infrared (FTIR) spectroscopy was used to investigate the degree of polymerization achieved in these systems. This is indicative of silica and alumina bonds in the system. Differences in the behavior of the cation are attributable to size of the hydration sphere and polarizing effect of the cation which are summarized at the end of the study.
ContributorsDakhane, Akash (Author) / Neithalath, Narayanan (Thesis advisor) / Subramaniam, Dharmarajan (Committee member) / Mobashar, Barzin (Committee member) / Arizona State University (Publisher)
Created2013
Description
Alkali-activated aluminosilicates, commonly known as "geopolymers", are being increasingly studied as a potential replacement for Portland cement. These binders use an alkaline activator, typically alkali silicates, alkali hydroxides or a combination of both along with a silica-and-alumina rich material, such as fly ash or slag, to form a final product with properties comparable to or better than those of ordinary Portland cement. The kinetics of alkali activation is highly dependent on the chemical composition of the binder material and the activator concentration. The influence of binder composition (slag, fly ash or both), different levels of alkalinity, expressed using the ratios of Na2O-to-binders (n) and activator SiO2-to-Na2O ratios (Ms), on the early age behavior in sodium silicate solution (waterglass) activated fly ash-slag blended systems is discussed in this thesis. Optimal binder composition and the n values are selected based on the setting times. Higher activator alkalinity (n value) is required when the amount of slag in the fly ash-slag blended mixtures is reduced. Isothermal calorimetry is performed to evaluate the early age hydration process and to understand the reaction kinetics of the alkali activated systems. The differences in the calorimetric signatures between waterglass activated slag and fly ash-slag blends facilitate an understanding of the impact of the binder composition on the reaction rates. Kinetic modeling is used to quantify the differences in reaction kinetics using the Exponential as well as the Knudsen method. The influence of temperature on the reaction kinetics of activated slag and fly ash-slag blends based on the hydration parameters are discussed. Very high compressive strengths can be obtained both at early ages as well as later ages (more than 70 MPa) with waterglass activated slag mortars. Compressive strength decreases with the increase in the fly ash content. A qualitative evidence of leaching is presented through the electrical conductivity changes in the saturating solution. The impact of leaching and the strength loss is found to be generally higher for the mixtures made using a higher activator Ms and a higher n value. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) is used to obtain information about the reaction products.
ContributorsChithiraputhiran, Sundara Raman (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniyam D (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2012