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Description
Chemical and mineralogical data from Mars shows that the surface has been chemically weathered on local to regional scales. Chemical trends and the types of chemical weathering products present on the surface and their abundances can elucidate information about past aqueous processes. Thermal-infrared (TIR) data and their respective models are

Chemical and mineralogical data from Mars shows that the surface has been chemically weathered on local to regional scales. Chemical trends and the types of chemical weathering products present on the surface and their abundances can elucidate information about past aqueous processes. Thermal-infrared (TIR) data and their respective models are essential for interpreting Martian mineralogy and geologic history. However, previous studies have shown that chemical weathering and the precipitation of fine-grained secondary silicates can adversely affect the accuracy of TIR spectral models. Furthermore, spectral libraries used to identify minerals on the Martian surface lack some important weathering products, including poorly-crystalline aluminosilicates like allophane, thus eliminating their identification in TIR spectral models. It is essential to accurately interpret TIR spectral data from chemically weathered surfaces to understand the evolution of aqueous processes on Mars. Laboratory experiments were performed to improve interpretations of TIR data from weathered surfaces. To test the accuracy of deriving chemistry of weathered rocks from TIR spectroscopy, chemistry was derived from TIR models of weathered basalts from Baynton, Australia and compared to actual weathering rind chemistry. To determine how specific secondary silicates affect the TIR spectroscopy of weathered basalts, mixtures of basaltic minerals and small amounts of secondary silicates were modeled. Poorly-crystalline aluminosilicates were synthesized and their TIR spectra were added to spectral libraries. Regional Thermal Emission Spectrometer (TES) data were modeled using libraries containing these poorly-crystalline aluminosilicates to test for their presence on the Mars. Chemistry derived from models of weathered Baynton basalts is not accurate, but broad chemical weathering trends can be interpreted from the data. TIR models of mineral mixtures show that small amounts of crystalline and amorphous silicate weathering products (2.5-5 wt.%) can be detected in TIR models and can adversely affect modeled plagioclase abundances. Poorly-crystalline aluminosilicates are identified in Northern Acidalia, Solis Planum, and Meridiani. Previous studies have suggested that acid sulfate weathering was the dominant surface alteration process for the past 3.5 billion years; however, the identification of allophane indicates that alteration at near-neutral pH occurred on regional scales and that acid sulfate weathering is not the only weathering process on Mars.
ContributorsRampe, Elizabeth Barger (Author) / Sharp, Thomas G (Thesis advisor) / Christensen, Phillip (Committee member) / Hervig, Richard (Committee member) / Shock, Everett (Committee member) / Williams, Lynda (Committee member) / Arizona State University (Publisher)
Created2011
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Description
On Mars, sedimentary deposits reveal a complex history of water- and wind-related geologic processes. Central mounds – kilometer-scale stacks of sediment located within craters – occur across Mars, but the specific processes responsible for mound formation and subsequent modification are still uncertain. A survey of central mounds within large craters

On Mars, sedimentary deposits reveal a complex history of water- and wind-related geologic processes. Central mounds – kilometer-scale stacks of sediment located within craters – occur across Mars, but the specific processes responsible for mound formation and subsequent modification are still uncertain. A survey of central mounds within large craters was conducted. Mound locations, mound offsets within their host craters, and relative mound heights were used to address various mound formation hypotheses. The results suggest that mound sediments once filled their host craters and were later eroded into the features observed today. Mounds offsets from the center of their host crater imply that wind caused the erosion of central mounds. An in depth study of a single central mound (Mt. Sharp within Gale crater) was also conducted. Thermal Emission Imaging System Visible Imaging Subsystem (THEMIS-VIS) mosaics in grayscale and false color were used to characterize the morphology and color variations in and around Gale crater. One result of this study is that dunes within Gale crater vary in false color composites from blue to purple, and that these color differences may be due to changes in dust cover, grain size, and/or composition. To further investigate dune fields on Mars, albedo variations at eight dune fields were studied based on the hypothesis that a dune’s ripple migration rate is correlated to its albedo. This study concluded that a dune’s minimum albedo does not have a simple correlation with its ripple migration rate. Instead, dust devils remove dust on slow-moving and immobile dunes, whereas saltating sand caused by strong winds removes dust on faster-moving dunes.

On the Moon, explosive volcanic deposits within Oppenheimer crater that were emplaced ballistically were investigated. Lunar Reconnaissance Orbiter (LRO) Diviner Radiometer mid-infrared data, LRO Camera images, and Chandrayaan-1 orbiter Moon Mineralogy Mapper near-infrared spectra were used to test the hypothesis that the pyroclastic deposits in Oppenheimer crater were emplaced via Vulcanian activity by constraining their composition and mineralogy. The mineralogy and iron-content of the pyroclastic deposits vary significantly (including examples of potentially very high iron compositions), which indicates variability in eruption style. These results suggest that localized lunar pyroclastic deposits may have a more complex origin and mode of emplacement than previously thought.
ContributorsBennett, Kristen Alicia (Author) / Bell, James F. (Thesis advisor) / Christensen, Phillip (Committee member) / Clarke, Amanda (Committee member) / Robinson, Mark (Committee member) / Whipple, Kelin (Committee member) / Arizona State University (Publisher)
Created2016