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Description
The fluorescence enhancement by a single Noble metal sphere is separated into excitation/absorption enhancement and the emission quantum yield enhancement. Incorporating the classical model of molecular spontaneous emission into the excitation/absorption transition, the excitation enhancement is calculated rigorously by electrodynamics in the frequency domain. The final formula for the excitation

The fluorescence enhancement by a single Noble metal sphere is separated into excitation/absorption enhancement and the emission quantum yield enhancement. Incorporating the classical model of molecular spontaneous emission into the excitation/absorption transition, the excitation enhancement is calculated rigorously by electrodynamics in the frequency domain. The final formula for the excitation enhancement contains two parts: the primary field enhancement calculated from the Mie theory, and a derating factor due to the backscattering field from the molecule. When compared against a simplified model that only involves the primary Mie theory field calculation, this more rigorous model indicates that the excitation enhancement near the surface of the sphere is quenched severely due to the back-scattering field from the molecule. The degree of quenching depends in part on the bandwidth of the illumination because the presence of the sphere induces a red-shift in the absorption frequency of the molecule and at the same time broadens its spectrum. Monochromatic narrow band illumination at the molecule's original (unperturbed) resonant frequency yields large quenching. For the more realistic broadband illumination scenario, we calculate the final enhancement by integrating over the excitation/absorption spectrum. The numerical results indicate that the resonant illumination scenario overestimates the quenching and therefore would underestimate the total excitation enhancement if the illumination has a broader bandwidth than the molecule. Combining the excitation model with the exact Electrodynamical theory for emission, the complete realistic model demonstrates that there is a potential for significant fluorescence enhancement only for the case of a low quantum yield molecule close to the surface of the sphere. General expressions of the fluorescence enhancement for arbitrarily-shaped metal antennas are derived. The finite difference time domain method is utilized for analyzing these complicated antenna structures. We calculate the total excitation enhancement for the two-sphere dimer. Although the enhancement is greater in this case than for the single sphere, because of the derating effects the total enhancement can never reach the local field enhancement. In general, placing molecules very close to a plasmonic antenna surface yields poor enhancement because the local field is strongly affected by the molecular self-interaction with the metal antenna.
ContributorsZhang, Zhe (Author) / Diaz, Rodolfo E (Thesis advisor) / Lim, Derrick (Thesis advisor) / Pan, George (Committee member) / Yu, Hongyu (Committee member) / Arizona State University (Publisher)
Created2013
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Description
Asymptotic and Numerical methods are popular in applied electromagnetism. In this work, the two methods are applied for collimated antennas and calibration targets, respectively. As an asymptotic method, the diffracted Gaussian beam approach (DGBA) is developed for design and simulation of collimated multi-reflector antenna systems, based upon Huygens principle and

Asymptotic and Numerical methods are popular in applied electromagnetism. In this work, the two methods are applied for collimated antennas and calibration targets, respectively. As an asymptotic method, the diffracted Gaussian beam approach (DGBA) is developed for design and simulation of collimated multi-reflector antenna systems, based upon Huygens principle and independent Gaussian beam expansion, referred to as the frames. To simulate a reflector antenna in hundreds to thousands of wavelength, it requires 1E7 - 1E9 independent Gaussian beams. To this end, high performance parallel computing is implemented, based on Message Passing Interface (MPI). The second part of the dissertation includes the plane wave scattering from a target consisting of doubly periodic array of sharp conducting circular cones by the magnetic field integral equation (MFIE) via Coiflet based Galerkin's procedure in conjunction with the Floquet theorem. Owing to the orthogonally, compact support, continuity and smoothness of the Coiflets, well-conditioned impedance matrices are obtained. Majority of the matrix entries are obtained in the spectral domain by one-point quadrature with high precision. For the oscillatory entries, spatial domain computation is applied, bypassing the slow convergence of the spectral summation of the non-damping propagating modes. The simulation results are compared with the solutions from an RWG-MLFMA based commercial software, FEKO, and excellent agreement is observed.
ContributorsWang, Le, 1975- (Author) / Pan, George (Thesis advisor) / Yu, Hongyu (Committee member) / Aberle, James T., 1961- (Committee member) / Diaz, Rodolfo (Committee member) / Kitchen, Jennifer (Committee member) / Arizona State University (Publisher)
Created2012
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Description
This thesis is a study of Bandwidth limitation of basestation power amplifier and its Doherty application. Fundamentally, bandwidth of a power amplifier (PA) is limited by both its input and output prematch networks and its Doherty architecture, specifically the impedance inverter between the main and auxiliary amplifier. In this study,

This thesis is a study of Bandwidth limitation of basestation power amplifier and its Doherty application. Fundamentally, bandwidth of a power amplifier (PA) is limited by both its input and output prematch networks and its Doherty architecture, specifically the impedance inverter between the main and auxiliary amplifier. In this study, only the output prematch network and the Doherty architecture follows are being investigated. A new proposed impedance inverter in the Doherty architecture exhibits an extended bandwidth compared to traditional quarterwave line.

Base on the loadline analysis, output impedance of the power amplifier can be represented by a loadline resistor and an output shunt capacitor. Base on this simple model, the maximum allowed bandwidth of the output impedance of the power amplifier can be estimated using the Bode-Fano method. However, since power amplifier is in fact nonlinear, harmonic balance simulation is used to loadpull the device across a broad range of frequencies. Base on the simulated large signal impedance at maximum power, the prematch circuitry can be designed. On a system level, the prematch power amplifier is used in Doherty amplifier. Two different prematch circuitries, T- section and shunt L methods are investigated along with their comparison in the Doherty architecture at both back off power and peak power condition. The last section of the thesis will be incorporating the proposed impedance inverter structure between the main and auxiliary amplifiers.

The simulated results showed the shunt L prematch topology has the least impedance dispersion across frequency. Along with the new impedance inverter structure, the 65% efficiency bandwidth improves by 50% compared to the original impedance inverter structure at back off power level.
ContributorsYang, Nick (Author) / Pan, George (Committee member) / Aberle, James T (Committee member) / Yu, Hongyu (Committee member) / Arizona State University (Publisher)
Created2014