Matching Items (100)
Description
This is a two-part thesis:
Part 1 characterizes soiling losses using various techniques to understand the effect of soiling on photovoltaic modules. The higher the angle of incidence (AOI), the lower will be the photovoltaic (PV) module performance. Our research group has already reported the AOI investigation for cleaned modules of five different technologies with air/glass interface. However, the modules that are installed in the field would invariably develop a soil layer with varying thickness depending on the site condition, rainfall and tilt angle. The soiled module will have the air/soil/glass interface rather than air/glass interface. This study investigates the AOI variations on soiled modules of five different PV technologies. It is demonstrated that AOI effect is inversely proportional to the soil density. In other words, the power or current loss between clean and soiled modules would be much higher at a higher AOI than at a lower AOI leading to excessive energy production loss of soiled modules on cloudy days, early morning hours and late afternoon hours. Similarly, the spectral influence of soil on the performance of the module was investigated through reflectance and transmittance measurements. It was observed that the reflectance and transmittances losses vary linearly with soil density variation and the 600-700 nm band was identified as an ideal band for soil density measurements.
Part 2 of this thesis performs statistical risk analysis for a power plant through FMECA (Failure Mode, Effect, and Criticality Analysis) based on non-destructive field techniques and count data of the failure modes. Risk Priority Number is used for the grading guideline for criticality analysis. The analysis was done on a 19-year-old power plant in cold-dry climate to identify the most dominant failure and degradation modes. In addition, a comparison study was done on the current power plant (framed) along with another 18-year-old (frameless) from the same climate zone to understand the failure modes for cold-dry climatic condition.
Part 1 characterizes soiling losses using various techniques to understand the effect of soiling on photovoltaic modules. The higher the angle of incidence (AOI), the lower will be the photovoltaic (PV) module performance. Our research group has already reported the AOI investigation for cleaned modules of five different technologies with air/glass interface. However, the modules that are installed in the field would invariably develop a soil layer with varying thickness depending on the site condition, rainfall and tilt angle. The soiled module will have the air/soil/glass interface rather than air/glass interface. This study investigates the AOI variations on soiled modules of five different PV technologies. It is demonstrated that AOI effect is inversely proportional to the soil density. In other words, the power or current loss between clean and soiled modules would be much higher at a higher AOI than at a lower AOI leading to excessive energy production loss of soiled modules on cloudy days, early morning hours and late afternoon hours. Similarly, the spectral influence of soil on the performance of the module was investigated through reflectance and transmittance measurements. It was observed that the reflectance and transmittances losses vary linearly with soil density variation and the 600-700 nm band was identified as an ideal band for soil density measurements.
Part 2 of this thesis performs statistical risk analysis for a power plant through FMECA (Failure Mode, Effect, and Criticality Analysis) based on non-destructive field techniques and count data of the failure modes. Risk Priority Number is used for the grading guideline for criticality analysis. The analysis was done on a 19-year-old power plant in cold-dry climate to identify the most dominant failure and degradation modes. In addition, a comparison study was done on the current power plant (framed) along with another 18-year-old (frameless) from the same climate zone to understand the failure modes for cold-dry climatic condition.
ContributorsBoppana, Sravanthi (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2015
Description
This dissertation develops advanced controls for distributed energy systems and evaluates performance on technical and economic benefits. Microgrids and thermal systems are of primary focus with applications shown for residential, commercial, and military applications that have differing equipment, rate structures, and objectives. Controls development for residential energy heating and cooling systems implement adaptive precooling strategies and thermal energy storage, with comparisons made of each approach separately and then together with precooling and thermal energy storage. Case studies show on-peak demand and annual energy related expenses can be reduced by up to 75.6% and 23.5%, respectively, for a Building America B10 Benchmark home in Phoenix Arizona, Los Angeles California, and Kona Hawaii. Microgrids for commercial applications follow after with increased complexity. Three control methods are developed and compared including a baseline logic-based control, model predictive control, and model predictive control with ancillary service control algorithms. Case studies show that a microgrid consisting of 326 kW solar PV, 634 kW/ 634 kWh battery, and a 350 kW diesel generator can reduce on-peak demand and annual energy related expenses by 82.2% and 44.1%, respectively. Findings also show that employing a model predictive control algorithm with ancillary services can reduce operating expenses by 23.5% when compared to a logic-based algorithm. Microgrid evaluation continues with an investigation of off-grid operation and resilience for military applications. A statistical model is developed to evaluate the survivability (i.e. probability to meet critical load during an islanding event) to serve critical load out to 7 days of grid outage. Case studies compare the resilience of a generator-only microgrid consisting of 5,250 kW in generators and hybrid microgrid consisting of 2,250 kW generators, 3,450 kW / 13,800 kWh storage, and 16,479 kW solar photovoltaics. Findings show that the hybrid microgrid improves survivability by 10.0% and decreases fuel consumption by 47.8% over a 168-hour islanding event when compared to a generator-only microgrid under nominal conditions. Findings in this dissertation can increase the adoption of reliable, low cost, and low carbon distributed energy systems by improving the operational capabilities and economic benefits to a variety of customers and utilities.
ContributorsNelson, James Robert (Author) / Johnson, Nathan (Thesis advisor) / Stadler, Michael (Committee member) / Zhang, Wenlong (Committee member) / Arizona State University (Publisher)
Created2019
Description
An airborne, tethered, multi-rotor wind turbine, effectively a rotorcraft kite, provides one platform for accessing the energy in high altitude winds. The craft is maintained at altitude by its rotors operating in autorotation, and its equilibrium attitude and dynamic performance are affected by the aerodynamic rotor forces, which in turn are affected by the orientation and motion of the craft. The aerodynamic performance of such rotors can vary significantly depending on orientation, influencing the efficiency of the system. This thesis analyzes the aerodynamic performance of an autorotating rotor through a range of angles of attack covering those experienced by a typical autogyro through that of a horizontal-axis wind turbine. To study the behavior of such rotors, an analytical model using the blade element theory coupled with momentum theory was developed. The model uses a rigid-rotor assumption and is nominally limited to cases of small induced inflow angle and constant induced velocity. The model allows for linear twist. In order to validate the model, several rotors -- off-the-shelf model-aircraft propellers -- were tested in a low speed wind tunnel. Custom built mounts allowed rotor angles of attack from 0 to 90 degrees in the test section, providing data for lift, drag, thrust, horizontal force, and angular velocity. Experimental results showed increasing thrust and angular velocity with rising pitch angles, whereas the in-plane horizontal force peaked and dropped after a certain value. The analytical results revealed a disagreement with the experimental trends, especially at high pitch angles. The discrepancy was attributed to the rotor operating in turbulent wake and vortex ring states at high pitch angles, where momentum theory has proven to be invalid. Also, aerodynamic design constants, which are not precisely known for the test propellers, have an underlying effect on the analytical model. The developments of the thesis suggest that a different analytical model may be needed for high rotor angles of attack. However, adding a term for resisting torque to the model gives analytical results that are similar to the experimental values.
ContributorsHota, Piyush (Author) / Wells, Valana L. (Thesis advisor) / Calhoun, Ronald (Committee member) / Garrett, Frederick (Committee member) / Arizona State University (Publisher)
Created2019
Description
An ongoing effort in the photovoltaic (PV) industry is to reduce the major manufacturing cost components of solar cells, the great majority of which are based on crystalline silicon (c-Si). This includes the substitution of screenprinted silver (Ag) cell contacts with alternative copper (Cu)-based contacts, usually applied with plating. Plated Cu contact schemes have been under study for many years with only minor traction in industrial production. One of the more commonly-cited barriers to the adoption of Cu-based contacts for photovoltaics is long-term reliability, as Cu is a significant contaminant in c-Si, forming precipitates that degrade performance via degradation of diode character and reduction of minority carrier lifetime. Cu contamination from contacts might cause degradation during field deployment if Cu is able to ingress into c-Si. Furthermore, Cu contamination is also known to cause a form of light-induced degradation (LID) which further degrades carrier lifetime when cells are exposed to light.
Prior literature on Cu-contact reliability tended to focus on accelerated testing at the cell and wafer level that may not be entirely replicative of real-world environmental stresses in PV modules. This thesis is aimed at advancing the understanding of Cu-contact reliability from the perspective of quasi-commercial modules under more realistic stresses. In this thesis, c-Si solar cells with Cu-plated contacts are fabricated, made into PV modules, and subjected to environmental stress in an attempt to induce hypothesized failure modes and understand any new vulnerabilities that Cu contacts might introduce. In particular, damp heat stress is applied to conventional, p-type c-Si modules and high efficiency, n-type c-Si heterojunction modules. I present evidence of Cu-induced diode degradation that also depends on PV module materials, as well as degradation unrelated to Cu, and in either case suggest engineering solutions to the observed degradation. In a forensic search for degradation mechanisms, I present novel evidence of Cu outdiffusion from contact layers and encapsulant-driven contact corrosion as potential key factors. Finally, outdoor exposures to light uncover peculiarities in Cu-plated samples, but do not point to especially serious vulnerabilities.
Prior literature on Cu-contact reliability tended to focus on accelerated testing at the cell and wafer level that may not be entirely replicative of real-world environmental stresses in PV modules. This thesis is aimed at advancing the understanding of Cu-contact reliability from the perspective of quasi-commercial modules under more realistic stresses. In this thesis, c-Si solar cells with Cu-plated contacts are fabricated, made into PV modules, and subjected to environmental stress in an attempt to induce hypothesized failure modes and understand any new vulnerabilities that Cu contacts might introduce. In particular, damp heat stress is applied to conventional, p-type c-Si modules and high efficiency, n-type c-Si heterojunction modules. I present evidence of Cu-induced diode degradation that also depends on PV module materials, as well as degradation unrelated to Cu, and in either case suggest engineering solutions to the observed degradation. In a forensic search for degradation mechanisms, I present novel evidence of Cu outdiffusion from contact layers and encapsulant-driven contact corrosion as potential key factors. Finally, outdoor exposures to light uncover peculiarities in Cu-plated samples, but do not point to especially serious vulnerabilities.
ContributorsKaras, Joseph (Author) / Bowden, Stuart (Thesis advisor) / Alford, Terry (Thesis advisor) / Tamizhmani, Govindasamy (Committee member) / Michaelson, Lynne (Committee member) / Arizona State University (Publisher)
Created2020
Description
Energy projects have the potential to provide critical services for human well-being and help eradicate poverty. However, too many projects fail because their approach oversimplifies the problem to energy poverty: viewing it as a narrow problem of access to energy services and technologies. This thesis presents an alternative paradigm for energy project development, grounded in theories of socio-energy systems, recognizing that energy and poverty coexist as a social, economic, and technological problem.
First, it shows that social, economic, and energy insecurity creates a complex energy-poverty nexus, undermining equitable, fair, and sustainable energy futures in marginalized communities. Indirect and access-based measures of energy poverty are a mismatch for the complexity of the energy-poverty nexus. The thesis, using the concept of social value of energy, develops a methodology for systematically mapping benefits, burdens and externalities of the energy system, illustrated using empirical investigations in communities in Nepal, India, Brazil, and Philippines. The thesis argues that key determinants of the energy-poverty nexus are the functional and economic capabilities of users, stressors and resulting thresholds of capabilities characterizing the energy and poverty relationship. It proposes ‘energy thriving’ as an alternative standard for evaluating project outcomes, requiring energy systems to not only remedy human well-being deficits but create enabling conditions for discovering higher forms of well-being.
Second, a novel, experimental approach to sustainability interventions is developed, to improve the outcomes of energy projects. The thesis presents results from a test bed for community sustainability interventions established in the village of Rio Claro in Brazil, to test innovative project design strategies and develop a primer for co-producing sustainable solutions. The Sustainable Rio Claro 2020 initiative served as a longitudinal experiment in participatory collective action for sustainable futures.
Finally, results are discussed from a collaborative project with grassroots practitioners to understand the energy-poverty nexus, map the social value of energy and develop energy thriving solutions. Partnering with local private and non-profit organizations in Uganda, Bolivia, Nepal and Philippines, the project evaluated and refined methods for designing and implementing innovative energy projects using the theoretical ideas developed in the thesis, subsequently developing a practitioner toolkit for the purpose.
First, it shows that social, economic, and energy insecurity creates a complex energy-poverty nexus, undermining equitable, fair, and sustainable energy futures in marginalized communities. Indirect and access-based measures of energy poverty are a mismatch for the complexity of the energy-poverty nexus. The thesis, using the concept of social value of energy, develops a methodology for systematically mapping benefits, burdens and externalities of the energy system, illustrated using empirical investigations in communities in Nepal, India, Brazil, and Philippines. The thesis argues that key determinants of the energy-poverty nexus are the functional and economic capabilities of users, stressors and resulting thresholds of capabilities characterizing the energy and poverty relationship. It proposes ‘energy thriving’ as an alternative standard for evaluating project outcomes, requiring energy systems to not only remedy human well-being deficits but create enabling conditions for discovering higher forms of well-being.
Second, a novel, experimental approach to sustainability interventions is developed, to improve the outcomes of energy projects. The thesis presents results from a test bed for community sustainability interventions established in the village of Rio Claro in Brazil, to test innovative project design strategies and develop a primer for co-producing sustainable solutions. The Sustainable Rio Claro 2020 initiative served as a longitudinal experiment in participatory collective action for sustainable futures.
Finally, results are discussed from a collaborative project with grassroots practitioners to understand the energy-poverty nexus, map the social value of energy and develop energy thriving solutions. Partnering with local private and non-profit organizations in Uganda, Bolivia, Nepal and Philippines, the project evaluated and refined methods for designing and implementing innovative energy projects using the theoretical ideas developed in the thesis, subsequently developing a practitioner toolkit for the purpose.
ContributorsBiswas, Saurabh (Author) / Miller, Clark A. (Thesis advisor) / Wiek, Arnim (Committee member) / Janssen, Marcus A (Committee member) / Arizona State University (Publisher)
Created2020
Description
Photocatalytic water splitting over suspended nanoparticles represents a potential solution for achieving CO2-neutral energy generation and storage. To design efficient photocatalysts, a fundamental understanding of the material’s structure, electronic properties, defects, and how these are controlled via synthesis is essential. Both bulk and nanoscale materials characterization, in addition to various performance metrics, can be combined to elucidate functionality at multiple length scales. In this work, two promising visible light harvesting systems are studied in detail: Pt-functionalized graphitic carbon nitrides (g-CNxHys) and TiO2-supported CeO2-x composites.
Electron energy-loss spectroscopy (EELS) is used to sense variations in the local concentration of amine moieties (defects believed to facilitate interfacial charge transfer) at the surface of a g-CNxHy flake. Using an aloof-beam configuration, spatial resolution is maximized while minimizing damage thus providing nanoscale vibrational fingerprints similar to infrared absorption spectra. Structural disorder in g-CNxHys is further studied using transmission electron microscopy at low electron fluence rates. In-plane structural fluctuations revealed variations in the local azimuthal orientation of the heptazine building blocks, allowing planar domain sizes to be related to the average polymer chain length. Furthermore, competing factors regulating photocatalytic performance in a series of Pt/g-CNxHys is elucidated. Increased polymer condensation in the g-CNxHy support enhances the rate of charge transfer to reactants owing to higher electronic mobility. However, active site densities are over 3x lower on the most condensed g-CNxHy which ultimately limits its H2 evolution rate (HER). Based on these findings, strategies to improve the cocatalyst configuration on intrinsically active supports are given.
In TiO2/CeO2-x photocatalysts, the effect of the support particle size on the bulk
anoscale properties and photocatalytic performance is investigated. Small anatase supports facilitate highly dispersed CeO2-x species, leading to increased visible light absorption and HERs resulting from a higher density of mixed metal oxide (MMO) interfaces with Ce3+ species. Using monochromated EELS, bandgap states associated with MMO interfaces are detected, revealing electronic transitions from 0.5 eV up to the bulk bandgap onset of anatase. Overall, the electron microscopy/spectroscopy techniques developed and applied herein sheds light onto the relevant defects and limiting processes operating within these photocatalyst systems thus suggesting rational design strategies.
Electron energy-loss spectroscopy (EELS) is used to sense variations in the local concentration of amine moieties (defects believed to facilitate interfacial charge transfer) at the surface of a g-CNxHy flake. Using an aloof-beam configuration, spatial resolution is maximized while minimizing damage thus providing nanoscale vibrational fingerprints similar to infrared absorption spectra. Structural disorder in g-CNxHys is further studied using transmission electron microscopy at low electron fluence rates. In-plane structural fluctuations revealed variations in the local azimuthal orientation of the heptazine building blocks, allowing planar domain sizes to be related to the average polymer chain length. Furthermore, competing factors regulating photocatalytic performance in a series of Pt/g-CNxHys is elucidated. Increased polymer condensation in the g-CNxHy support enhances the rate of charge transfer to reactants owing to higher electronic mobility. However, active site densities are over 3x lower on the most condensed g-CNxHy which ultimately limits its H2 evolution rate (HER). Based on these findings, strategies to improve the cocatalyst configuration on intrinsically active supports are given.
In TiO2/CeO2-x photocatalysts, the effect of the support particle size on the bulk
anoscale properties and photocatalytic performance is investigated. Small anatase supports facilitate highly dispersed CeO2-x species, leading to increased visible light absorption and HERs resulting from a higher density of mixed metal oxide (MMO) interfaces with Ce3+ species. Using monochromated EELS, bandgap states associated with MMO interfaces are detected, revealing electronic transitions from 0.5 eV up to the bulk bandgap onset of anatase. Overall, the electron microscopy/spectroscopy techniques developed and applied herein sheds light onto the relevant defects and limiting processes operating within these photocatalyst systems thus suggesting rational design strategies.
ContributorsHaiber, Diane Michelle (Author) / Crozier, Peter (Thesis advisor) / Chan, Candace (Committee member) / Liu, Jingyue (Committee member) / Treacy, Michael (Committee member) / Arizona State University (Publisher)
Created2019
Description
The increasing concentrations of greenhouse gases into the atmosphere call for urgent measures to use non-fossil feedstock for fuels and chemicals. Synthesis gas (or syngas) is a mixture of three gases: hydrogen (H2), carbon monoxide (CO), and carbon dioxide (CO2). Syngas already is widely used as a non-fossil fuel and a building block for a variety of chemicals using the Fischer-Tropsch process. Recently, syngas fermentation has attracted attention as a more sustainable way for the conversion of syngas to chemicals, since its biocatalysts are self-generating, are resilient, and can utilize a wide range of syngas compositions. However, syngas fermentation has technical and economic limitations. This dissertation, by contributing to the understanding of syngas fermentation, helps to overcome the limitations. A bibliometric analysis showed the topic’s landscape and identified that mass transfer is the biggest challenge for the process. One means to improve syngas mass transfer is to use the membrane biofilm reactor, or MBfR, to deliver syngas to the microorganisms. MBfR experiments delivering pure H2 demonstrated that the H2:IC ratio (IC is inorganic carbon) controlled the overall production rate of organic compounds and their carbon-chain length. Organic chemicals up to eight carbons could be produced with a high H2:IC ratio. A novel asymmetric membrane dramatically improved mass transfer rates for all syngas components, and its low selectivity among them made it ideal for high-rate syngas fermentation. MBfR experiments using syngas and the asymmetric membrane, as well as a conventional symmetric membrane, confirmed that the key parameter for generating long-chain products was a high H2:IC ratio. The fast mass transfer rate of the asymmetric membrane allowed a very high areal production rate of acetate: 253 g.m-2.d-1, the highest reported to date. Since the membrane delivered H2 and C from the syngas feed, the relatively low selectivity of the asymmetric membrane favored acetogenesis over microbial chain elongation. A techno-economic analysis of the MBfR showed that the cost to produce acetate was less than its market price. All results presented in this dissertation support the potential of syngas fermentation using the MBfR as a means to produce commodity chemicals and biofuels from syngas.
ContributorsCalvo Martinez, Diana Carolina (Author) / Rittmann, Bruce E (Thesis advisor) / Torres, César I (Thesis advisor) / Kralmajnik-Brown, Rosa (Committee member) / Arizona State University (Publisher)
Created2021
Description
This is a two part thesis:
Part 1 of this thesis determines the most dominant failure modes of field aged photovoltaic (PV) modules using experimental data and statistical analysis, FMECA (Failure Mode, Effect, and Criticality Analysis). The failure and degradation modes of about 5900 crystalline-Si glass/polymer modules fielded for 6 to 16 years in three different photovoltaic (PV) power plants with different mounting systems under the hot-dry desert climate of Arizona are evaluated. A statistical reliability tool, FMECA that uses Risk Priority Number (RPN) is performed for each PV power plant to determine the dominant failure modes in the modules by means of ranking and prioritizing the modes. This study on PV power plants considers all the failure and degradation modes from both safety and performance perspectives, and thus, comes to the conclusion that solder bond fatigue/failure with/without gridline/metallization contact fatigue/failure is the most dominant failure mode for these module types in the hot-dry desert climate of Arizona.
Part 2 of this thesis determines the best method to compute degradation rates of PV modules. Three different PV systems were evaluated to compute degradation rates using four methods and they are: I-V measurement, metered kWh, performance ratio (PR) and performance index (PI). I-V method, being an ideal method for degradation rate computation, were compared to the results from other three methods. The median degradation rates computed from kWh method were within ±0.15% from I-V measured degradation rates (0.9-1.37 %/year of three models). Degradation rates from the PI method were within ±0.05% from the I-V measured rates for two systems but the calculated degradation rate was remarkably different (±1%) from the I-V method for the third system. The degradation rate from the PR method was within ±0.16% from the I-V measured rate for only one system but were remarkably different (±1%) from the I-V measured rate for the other two systems. Thus, it was concluded that metered raw kWh method is the best practical method, after I-V method and PI method (if ground mounted POA insolation and other weather data are available) for degradation computation as this method was found to be fairly accurate, easy, inexpensive, fast and convenient.
Part 1 of this thesis determines the most dominant failure modes of field aged photovoltaic (PV) modules using experimental data and statistical analysis, FMECA (Failure Mode, Effect, and Criticality Analysis). The failure and degradation modes of about 5900 crystalline-Si glass/polymer modules fielded for 6 to 16 years in three different photovoltaic (PV) power plants with different mounting systems under the hot-dry desert climate of Arizona are evaluated. A statistical reliability tool, FMECA that uses Risk Priority Number (RPN) is performed for each PV power plant to determine the dominant failure modes in the modules by means of ranking and prioritizing the modes. This study on PV power plants considers all the failure and degradation modes from both safety and performance perspectives, and thus, comes to the conclusion that solder bond fatigue/failure with/without gridline/metallization contact fatigue/failure is the most dominant failure mode for these module types in the hot-dry desert climate of Arizona.
Part 2 of this thesis determines the best method to compute degradation rates of PV modules. Three different PV systems were evaluated to compute degradation rates using four methods and they are: I-V measurement, metered kWh, performance ratio (PR) and performance index (PI). I-V method, being an ideal method for degradation rate computation, were compared to the results from other three methods. The median degradation rates computed from kWh method were within ±0.15% from I-V measured degradation rates (0.9-1.37 %/year of three models). Degradation rates from the PI method were within ±0.05% from the I-V measured rates for two systems but the calculated degradation rate was remarkably different (±1%) from the I-V method for the third system. The degradation rate from the PR method was within ±0.16% from the I-V measured rate for only one system but were remarkably different (±1%) from the I-V measured rate for the other two systems. Thus, it was concluded that metered raw kWh method is the best practical method, after I-V method and PI method (if ground mounted POA insolation and other weather data are available) for degradation computation as this method was found to be fairly accurate, easy, inexpensive, fast and convenient.
ContributorsShrestha, Sanjay (Author) / Tamizhmani, Govindsamy (Thesis advisor) / Srinivasan, Devrajan (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2014
Description
Energy storage technologies are essential to overcome the temporal variability in renewable energy. The primary aim of this thesis is to develop reactor solutions to better analyze the potential of thermochemical energy storage (TCES) using non-stoichiometric metal oxides, for the multi-day energy storage application. A TCES system consists of a reduction reactor and an insulated MOx storage bin. The reduction reactor heats (to ~ 1100 °C) and partially reduces the MOx, thereby adding sensible and chemical energy (i.e., charging it) under reduced pO2 environments (~10 Pa). Inert gas removes the oxygen generated during reduction. The storage bin holds the hot and partially reduced MOx (typically particles) until it is used in an energy recovery device (i.e., discharge). Irrespective of the reactor heat source (here electrical), or the particle-inert gas flows (here countercurrent), the thermal reduction temperature and inert gas (here N2) flow minimize when the process approaches reversibility, i.e., operates near equilibrium. This study specifically focuses on developing a reduction reactor based on the theoretical considerations for approaching reversibility along the reaction path. The proposed Zigzag flow reactor (ZFR) is capable of thermally reducing CAM28 particles at temperatures ~ 1000 °C under an O2 partial pressure ~ 10 Pa. The associated analytical and numerical models analyze the reaction equilibrium under a real (discrete) reaction path and the mass transfer kinetic conditions necessary to approach equilibrium. The discrete equilibrium model minimizes the exergy destroyed in a practical reactor and identifies methods of maximizing the energy storage density () and the exergetic efficiency. The mass transfer model analyzes the O2 N2 concentration boundary layers to recommend sizing considerations to maximize the reactor power density. Two functional ZFR prototypes, the -ZFR and the -ZFR, establish the proof of concept and achieved a reduction extent, Δδ = 0.071 with CAM28 at T~950 °C and pO2 = 10 Pa, 7x higher than a previous attempt in the literature. The -ZFR consistently achieved > 100 Wh/kg during >10 h. runtime and the -ZFR displayed an improved = 130 Wh/kg during >5 h. operation with CAM28. A techno-economic model of a grid-scale ZFR with an associated storage bin analyzes the cost of scaling the ZFR for grid energy storage requirements. The scaled ZFR capital costs contribute < 1% to the levelized cost of thermochemical energy storage, which ranges from 5-20 ¢/kWh depending on the storage temperature and storage duration.
ContributorsGhotkar, Rhushikesh (Author) / Milcarek, Ryan (Thesis advisor) / Ermanoski, Ivan (Committee member) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2023
Description
This study focuses on the implications of a high reverse bias breakdown in silicon heterojunction cells (SHJ). In relevant literature, there is a lack of explicit investigation which
compares high breakdown voltage cells (commonly SHJ) to low breakdown voltage cells
(commonly silicon homojunctions) in an installation setting. In addition, their relationship with
shading and how they react with bypass diodes are also not very prevalent. Therefore, my project
dives into how shading impacts a string of high breakdown voltage cells and a string of low
breakdown voltage cells, as well as how those cells interact with a bypass diode.
In order to conduct this investigation, I used the simulation software LTSpice XVII to
create an accurate simulation model of a SHJ cell with a 21 V reverse breakdown voltage. With
this cell model, I strung 10 cells together, and varied the shading on a single cell while measuring
the string’s output current, voltage, and power. Next, I attached a bypass diode to the shaded
cell, and continued to increase the number of cells attached to the bypass diode while continuing
to examine the string’s output. Once I gathered this data, I modified the original cell model to
have a lower reverse breakdown voltage of 5 V. From here, I strung 10 cells together again, and
repeated the same measurements from the 21 V string.
Upon completing these measurements, I found that the SHJ cells were in fact harder to
force into reverse bias than the cells with the lower reverse breakdown voltage, suggesting that
solar installation owners should consider transitioning to SHJ-based modules. When bypass
diodes are being considered, my results demonstrated that heavy shading (about 65% and
higher) was required for the bypass diodes to have an observable impact on the string’s power
output. Therefore, owners should consider how severe the shading their installation may receive
before investing in bypass diodes. If owners do find the need for the bypass diodes, my findings
also show that the diodes should be used sparingly and in a compromise with output power and
cost.
ContributorsAvalos, Christian (Author) / Honsberg, Christiana (Thesis advisor) / Bowden, Stuart (Committee member) / Goodnick, Stephen (Committee member) / Arizona State University (Publisher)
Created2023