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Unsaturated soil mechanics is becoming a part of geotechnical engineering practice, particularly in applications to moisture sensitive soils such as expansive and collapsible soils and in geoenvironmental applications. The soil water characteristic curve, which describes the amount of water in a soil versus soil suction, is perhaps the most important

Unsaturated soil mechanics is becoming a part of geotechnical engineering practice, particularly in applications to moisture sensitive soils such as expansive and collapsible soils and in geoenvironmental applications. The soil water characteristic curve, which describes the amount of water in a soil versus soil suction, is perhaps the most important soil property function for application of unsaturated soil mechanics. The soil water characteristic curve has been used extensively for estimating unsaturated soil properties, and a number of fitting equations for development of soil water characteristic curves from laboratory data have been proposed by researchers. Although not always mentioned, the underlying assumption of soil water characteristic curve fitting equations is that the soil is sufficiently stiff so that there is no change in total volume of the soil while measuring the soil water characteristic curve in the laboratory, and researchers rarely take volume change of soils into account when generating or using the soil water characteristic curve. Further, there has been little attention to the applied net normal stress during laboratory soil water characteristic curve measurement, and often zero to only token net normal stress is applied. The applied net normal stress also affects the volume change of the specimen during soil suction change. When a soil changes volume in response to suction change, failure to consider the volume change of the soil leads to errors in the estimated air-entry value and the slope of the soil water characteristic curve between the air-entry value and the residual moisture state. Inaccuracies in the soil water characteristic curve may lead to inaccuracies in estimated soil property functions such as unsaturated hydraulic conductivity. A number of researchers have recently recognized the importance of considering soil volume change in soil water characteristic curves. The study of correct methods of soil water characteristic curve measurement and determination considering soil volume change, and impacts on the unsaturated hydraulic conductivity function was of the primary focus of this study. Emphasis was placed upon study of the effect of volume change consideration on soil water characteristic curves, for expansive clays and other high volume change soils. The research involved extensive literature review and laboratory soil water characteristic curve testing on expansive soils. The effect of the initial state of the specimen (i.e. slurry versus compacted) on soil water characteristic curves, with regard to volume change effects, and effect of net normal stress on volume change for determination of these curves, was studied for expansive clays. Hysteresis effects were included in laboratory measurements of soil water characteristic curves as both wetting and drying paths were used. Impacts of soil water characteristic curve volume change considerations on fluid flow computations and associated suction-change induced soil deformations were studied through numerical simulations. The study includes both coupled and uncoupled flow and stress-deformation analyses, demonstrating that the impact of volume change consideration on the soil water characteristic curve and the estimated unsaturated hydraulic conductivity function can be quite substantial for high volume change soils.
ContributorsBani Hashem, Elham (Author) / Houston, Sandra L. (Thesis advisor) / Kavazanjian, Edward (Committee member) / Zapata, Claudia (Committee member) / Arizona State University (Publisher)
Created2013
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Description
The importance of unsaturated soil behavior stems from the fact that a vast majority of infrastructures are founded on unsaturated soils. Research has recently been concentrated on unsaturated soil properties. In the evaluation of unsaturated soils, researchers agree that soil water retention characterized by the soil water characteristic curve (SWCC)

The importance of unsaturated soil behavior stems from the fact that a vast majority of infrastructures are founded on unsaturated soils. Research has recently been concentrated on unsaturated soil properties. In the evaluation of unsaturated soils, researchers agree that soil water retention characterized by the soil water characteristic curve (SWCC) is among the most important factors when assessing fluid flow, volume change and shear strength for these soils. The temperature influence on soil moisture flow is a major concern in the design of important engineering systems such as barriers in underground repositories for radioactive waste disposal, ground-source heat pump (GSHP) systems, evapotranspirative (ET) covers and pavement systems.. Accurate modeling of the temperature effect on the SWCC may lead to reduction in design costs, simpler constructability, and hence, more sustainable structures. . The study made use of two possible approaches to assess the temperature effect on the SWCC. In the first approach, soils were sorted from a large soil database into families of similar properties but located on sites with different MAAT. The SWCCs were plotted for each family of soils. Most families of soils showed a clear trend indicating the influence of temperature on the soil water retention curve at low degrees of saturation.. The second approach made use of statistical analysis. It was demonstrated that the suction increases as the MAAT decreases. The statistical analysis showed that even though the plasticity index proved to have the greatest influence on suction, the mean annual air temperature effect proved not to be negligible. In both approaches, a strong relationship between temperature, suction and soil properties was observed. Finally, a comparison of the model based on the mean annual air temperature environmental factor was compared to another model that makes use of the Thornthwaite Moisture Index (TMI) to estimate the environmental effects on the suction of unsaturated soils. Results showed that the MAAT can be a better indicator when compared to the TMI found but the results were inconclusive due to the lack of TMI data available.
ContributorsElkeshky, Maie Mohamed (Author) / Zapata, Claudia E (Thesis advisor) / Houston, Sandra (Committee member) / Kavazanjian, Edward (Committee member) / Arizona State University (Publisher)
Created2011
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Description
In geotechnical engineering, measuring the unsaturated hydraulic conductivity of fine grained soils can be time consuming and tedious. The various applications that require knowledge of the unsaturated hydraulic conductivity function are great, and in geotechnical engineering, they range from modeling seepage through landfill covers to determining infiltration of water

In geotechnical engineering, measuring the unsaturated hydraulic conductivity of fine grained soils can be time consuming and tedious. The various applications that require knowledge of the unsaturated hydraulic conductivity function are great, and in geotechnical engineering, they range from modeling seepage through landfill covers to determining infiltration of water under a building slab. The unsaturated hydraulic conductivity function can be measured using various direct and indirect techniques. The instantaneous profile method has been found to be the most promising unsteady state method for measuring the unsaturated hydraulic conductivity function for fine grained soils over a wide range of suction values. The instantaneous profile method can be modified by using different techniques to measure suction and water content and also through the way water is introduced or removed from the soil profile. In this study, the instantaneous profile method was modified by creating duplicate soil samples compacted into cylindrical tubes at two different water contents. The techniques used in the duplicate method to measure the water content and matric suction included volumetric moisture probes, manual water content measurements, and filter paper tests. The experimental testing conducted in this study provided insight into determining the unsaturated hydraulic conductivity using the instantaneous profile method for a sandy clay soil and recommendations are provided for further evaluation. Overall, this study has demonstrated that the presence of cracks has no significant impact on the hydraulic behavior of soil in high suction ranges. The results of this study do not examine the behavior of cracked soil unsaturated hydraulic conductivity at low suction and at moisture contents near saturation.
ContributorsJacquemin, Sean Christopher (Author) / Zapata, Claudia (Thesis advisor) / Houston, Sandra (Committee member) / Kavazanjian, Edward (Committee member) / Arizona State University (Publisher)
Created2011
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Description
The influence of temperature on soil engineering properties is a major concern in the design of engineering systems such as radioactive waste disposal barriers, ground source heat pump systems and pavement structures. In particular, moisture redistribution under pavement systems might lead to changes in unbound material stiffness that will affect

The influence of temperature on soil engineering properties is a major concern in the design of engineering systems such as radioactive waste disposal barriers, ground source heat pump systems and pavement structures. In particular, moisture redistribution under pavement systems might lead to changes in unbound material stiffness that will affect pavement performance. Accurate measurement of thermal effects on unsaturated soil hydraulic properties may lead to reduction in design and construction costs. This thesis presents preliminary results of an experimental study aimed at determining the effect of temperature on the soil water characteristic curve (SWCC) and the unsaturated hydraulic conductivity function (kunsat). Pressure plate devices with volume change control were used to determine the SWCC and the instantaneous profile method was used to obtain the kunsat function. These properties were measured on two fine-grained materials subjected to controlled temperatures of 5oC, 25oC and 40oC. The results were used to perform a sensitivity analysis of the effect of temperature changes on the prediction of moisture movement under a covered area. In addition, two more simulations were performed where changes in hydraulic properties were done in a stepwise fashion. The findings were compared to field measured water content data obtained on the subgrade material of the FAA William Hughes test facility located in Atlantic City. Results indicated that temperature affects the unsaturated hydraulic properties of the two soils used in the study. For the DuPont soil, a soil with high plasticity, it was found that the water retention was higher at low temperatures for suction levels lower than about 10,000 kPa; while the kunsat functions at the three temperatures were not significantly different. For the County soil, a material with medium plasticity, it was found that it holds around 10% more degree of saturation at 5°C than that at 40°C for suction levels higher than about 1,000 kPa; while the hydraulic conductivity at 40°C was at least one order of magnitude higher than that at 5°C, for suction levels higher than 1,000 kPa. These properties were used to perform two types of numerical analyses: a sensitivity analysis and stepwise analysis. Absolute differences between predicted and field measured data were considered to be acceptable, ranging from 4.5% to 9% for all simulations. Overall results show an improvement in predictions when non-isothermal conditions were used over the predictions obtained with isothermal conditions.
ContributorsLu, Yutong (Author) / Zapata, Claudia E (Thesis advisor) / Kavazanjian, Edward (Committee member) / Houston, Sandra L. (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Currently conventional Subtitle D landfills are the primary means of disposing of our waste in the United States. While this method of waste disposal aims at protecting the environment, it does so through the use of liners and caps that effectively freeze the breakdown of waste. Because this method can

Currently conventional Subtitle D landfills are the primary means of disposing of our waste in the United States. While this method of waste disposal aims at protecting the environment, it does so through the use of liners and caps that effectively freeze the breakdown of waste. Because this method can keep landfills active, and thus a potential groundwater threat for over a hundred years, I take an in depth look at the ability of bioreactor landfills to quickly stabilize waste. In the thesis I detail the current state of bioreactor landfill technologies, assessing the pros and cons of anaerobic and aerobic bioreactor technologies. Finally, with an industrial perspective, I conclude that moving on to bioreactor landfills as an alternative isn't as simple as it may first appear, and that it is a contextually specific solution that must be further refined before replacing current landfills.
ContributorsWhitten, George Avery (Author) / Kavazanjian, Edward (Thesis director) / Allenby, Braden (Committee member) / Houston, Sandra (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2013-05
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Description
Zero-Valent Metals (ZVM) are highly reactive materials and have been proved to be effective in contaminant reduction in soils and groundwater remediation. In fact, zero-Valent Iron (ZVI) has proven to be very effective in removing, particularly chlorinated organics, heavy metals, and odorous sulfides. Addition of ZVI has also been proved

Zero-Valent Metals (ZVM) are highly reactive materials and have been proved to be effective in contaminant reduction in soils and groundwater remediation. In fact, zero-Valent Iron (ZVI) has proven to be very effective in removing, particularly chlorinated organics, heavy metals, and odorous sulfides. Addition of ZVI has also been proved in enhancing the methane gas generation in anaerobic digestion of activated sludge. However, no studies have been conducted regarding the effect of ZVM stimulation to Municipal Solid Waste (MSW) degradation. Therefore, a collaborative study was developed to manipulate microbial activity in the landfill bioreactors to favor methane production by adding ZVMs. This study focuses on evaluating the effects of added ZVM on the leachate generated from replicated lab scale landfill bioreactors. The specific objective was to investigate the effects of ZVMs addition on the organic and inorganic pollutants in leachate. The hypothesis here evaluated was that adding ZVM including ZVI and Zero Valent Manganese (ZVMn) will enhance the removal rates of the organic pollutants present in the leachate, likely by a putative higher rate of microbial metabolism. Test with six (4.23 gallons) bioreactors assembled with MSW collected from the Salt River Landfill and Southwest Regional Landfill showed that under 5 grams /liter of ZVI and 0.625 grams/liter of ZVMn additions, no significant difference was observed in the pH and temperature data of the leachate generated from these reactors. The conductivity data suggested the steady rise across all reactors over the period of time. The removal efficiency of sCOD was highest (27.112 mg/lit/day) for the reactors added with ZVMn at the end of 150 days for bottom layer, however the removal rate was highest (16.955 mg/lit/day) for ZVI after the end of 150 days of the middle layer. Similar trends in the results was observed in TC analysis. HPLC study indicated the dominance of the concentration of heptanoate and isovalerate were leachate generated from the bottom layer across all reactors. Heptanoate continued to dominate in the ZVMn added leachate even after middle layer injection. IC analysis concluded the chloride was dominant in the leachate generated from all the reactors and there was a steady increase in the chloride content over the period of time. Along with chloride, fluoride, bromide, nitrate, nitrite, phosphate and sulfate were also detected in considerable concentrations. In the summary, the addition of the zero valent metals has proved to be efficient in removal of the organics present in the leachate.
ContributorsPandit, Gandhar Abhay (Author) / Cadillo – Quiroz, Hinsby (Thesis advisor) / Olson, Larry (Thesis advisor) / Boyer, Treavor (Committee member) / Arizona State University (Publisher)
Created2019