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- Creators: Kavazanjian, Edward
- Creators: Cadillo – Quiroz, Hinsby
- Creators: Olson, Larry
- Resource Type: Text
Description
In geotechnical engineering, measuring the unsaturated hydraulic conductivity of fine grained soils can be time consuming and tedious. The various applications that require knowledge of the unsaturated hydraulic conductivity function are great, and in geotechnical engineering, they range from modeling seepage through landfill covers to determining infiltration of water under a building slab. The unsaturated hydraulic conductivity function can be measured using various direct and indirect techniques. The instantaneous profile method has been found to be the most promising unsteady state method for measuring the unsaturated hydraulic conductivity function for fine grained soils over a wide range of suction values. The instantaneous profile method can be modified by using different techniques to measure suction and water content and also through the way water is introduced or removed from the soil profile. In this study, the instantaneous profile method was modified by creating duplicate soil samples compacted into cylindrical tubes at two different water contents. The techniques used in the duplicate method to measure the water content and matric suction included volumetric moisture probes, manual water content measurements, and filter paper tests. The experimental testing conducted in this study provided insight into determining the unsaturated hydraulic conductivity using the instantaneous profile method for a sandy clay soil and recommendations are provided for further evaluation. Overall, this study has demonstrated that the presence of cracks has no significant impact on the hydraulic behavior of soil in high suction ranges. The results of this study do not examine the behavior of cracked soil unsaturated hydraulic conductivity at low suction and at moisture contents near saturation.
ContributorsJacquemin, Sean Christopher (Author) / Zapata, Claudia (Thesis advisor) / Houston, Sandra (Committee member) / Kavazanjian, Edward (Committee member) / Arizona State University (Publisher)
Created2011
Description
As a prelude to a study on the post-liquefaction properties and structure of soil, an investigation of ground freezing as an undisturbed sampling technique was conducted to investigate the ability of this sampling technique to preserve soil structure and properties. Freezing the ground is widely regarded as an appropriate technique to recover undisturbed samples of saturated cohesionless soil for laboratory testing, despite the fact that water increases in volume when frozen. The explanation generally given for the preservation of soil structure using the freezing technique was that, as long as the freezing front advanced uni-directionally, the expanding pore water is expelled ahead of the freezing front as the front advances. However, a literature review on the transition of water to ice shows that the volume of ice expands approximately nine percent after freezing, bringing into question the hypothesized mechanism and the ability of a frozen and then thawed specimen to retain the properties and structure of the soil in situ. Bench-top models were created by pluviation of sand. The soil in the model was then saturated and subsequently frozen. Freezing was accomplished using a pan filled with alcohol and dry ice placed on the surface of the sand layer to induce a unidirectional freezing front in the sample container. Coring was used to recover frozen samples from model containers. Recovered cores were then placed in a triaxial cell, thawed, and subjected to consolidated undrained loading. The stress-strain-strength behavior of the thawed cores was compared to the behavior of specimens created in a split mold by pluviation and then saturated and sheared without freezing and thawing. The laboratory testing provide insight to the impact of freezing and thawing on the properties of cohesionless soil.
ContributorsKatapa, Kanyembo (Author) / Kavazanjian, Edward (Thesis advisor) / Houston, Sandra (Committee member) / Zapata, Claudia (Committee member) / Arizona State University (Publisher)
Created2011
Description
The influence of temperature on soil engineering properties is a major concern in the design of engineering systems such as radioactive waste disposal barriers, ground source heat pump systems and pavement structures. In particular, moisture redistribution under pavement systems might lead to changes in unbound material stiffness that will affect pavement performance. Accurate measurement of thermal effects on unsaturated soil hydraulic properties may lead to reduction in design and construction costs. This thesis presents preliminary results of an experimental study aimed at determining the effect of temperature on the soil water characteristic curve (SWCC) and the unsaturated hydraulic conductivity function (kunsat). Pressure plate devices with volume change control were used to determine the SWCC and the instantaneous profile method was used to obtain the kunsat function. These properties were measured on two fine-grained materials subjected to controlled temperatures of 5oC, 25oC and 40oC. The results were used to perform a sensitivity analysis of the effect of temperature changes on the prediction of moisture movement under a covered area. In addition, two more simulations were performed where changes in hydraulic properties were done in a stepwise fashion. The findings were compared to field measured water content data obtained on the subgrade material of the FAA William Hughes test facility located in Atlantic City. Results indicated that temperature affects the unsaturated hydraulic properties of the two soils used in the study. For the DuPont soil, a soil with high plasticity, it was found that the water retention was higher at low temperatures for suction levels lower than about 10,000 kPa; while the kunsat functions at the three temperatures were not significantly different. For the County soil, a material with medium plasticity, it was found that it holds around 10% more degree of saturation at 5°C than that at 40°C for suction levels higher than about 1,000 kPa; while the hydraulic conductivity at 40°C was at least one order of magnitude higher than that at 5°C, for suction levels higher than 1,000 kPa. These properties were used to perform two types of numerical analyses: a sensitivity analysis and stepwise analysis. Absolute differences between predicted and field measured data were considered to be acceptable, ranging from 4.5% to 9% for all simulations. Overall results show an improvement in predictions when non-isothermal conditions were used over the predictions obtained with isothermal conditions.
ContributorsLu, Yutong (Author) / Zapata, Claudia E (Thesis advisor) / Kavazanjian, Edward (Committee member) / Houston, Sandra L. (Committee member) / Arizona State University (Publisher)
Created2015
Description
Currently conventional Subtitle D landfills are the primary means of disposing of our waste in the United States. While this method of waste disposal aims at protecting the environment, it does so through the use of liners and caps that effectively freeze the breakdown of waste. Because this method can keep landfills active, and thus a potential groundwater threat for over a hundred years, I take an in depth look at the ability of bioreactor landfills to quickly stabilize waste. In the thesis I detail the current state of bioreactor landfill technologies, assessing the pros and cons of anaerobic and aerobic bioreactor technologies. Finally, with an industrial perspective, I conclude that moving on to bioreactor landfills as an alternative isn't as simple as it may first appear, and that it is a contextually specific solution that must be further refined before replacing current landfills.
ContributorsWhitten, George Avery (Author) / Kavazanjian, Edward (Thesis director) / Allenby, Braden (Committee member) / Houston, Sandra (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2013-05
Characterization and Manipulation of Microbiomes From Arid Landfills for Improved Methane Production
Description
Environmentally harmful byproducts from solid waste’s decomposition, including methane (CH4) emissions, are managed through standardized landfill engineering and gas-capture mechanisms. Yet only a limited number of studies have analyzed the development and composition of Bacteria and Archaea involved in CH4 production from landfills. The objectives of this research were to compare microbiomes and bioactivity from CH4-producing communities in contrasting spatial areas of arid landfills and to tests a new technology to biostimulate CH4 production (methanogenesis) from solid waste under dynamic environmental conditions controlled in the laboratory. My hypothesis was that the diversity and abundance of methanogenic Archaea in municipal solid waste (MSW), or its leachate, play an important role on CH4 production partially attributed to the group’s wide hydrogen (H2) consumption capabilities. I tested this hypothesis by conducting complementary field observations and laboratory experiments. I describe niches of methanogenic Archaea in MSW leachate across defined areas within a single landfill, while demonstrating functional H2-dependent activity. To alleviate limited H2 bioavailability encountered in-situ, I present biostimulant feasibility and proof-of-concepts studies through the amendment of zero valent metals (ZVMs). My results demonstrate that older-aged MSW was minimally biostimulated for greater CH4 production relative to a control when exposed to iron (Fe0) or manganese (Mn0), due to highly discernable traits of soluble carbon, nitrogen, and unidentified fluorophores found in water extracts between young and old aged, starting MSW. Acetate and inhibitory H2 partial pressures accumulated in microcosms containing old-aged MSW. In a final experiment, repeated amendments of ZVMs to MSW in a 600 day mesocosm experiment mediated significantly higher CH4 concentrations and yields during the first of three ZVM injections. Fe0 and Mn0 experimental treatments at mesocosm-scale also highlighted accelerated development of seemingly important, but elusive Archaea including Methanobacteriaceae, a methane-producing family that is found in diverse environments. Also, prokaryotic classes including Candidatus Bathyarchaeota, an uncultured group commonly found in carbon-rich ecosystems, and Clostridia; All three taxa I identified as highly predictive in the time-dependent progression of MSW decomposition. Altogether, my experiments demonstrate the importance of H2 bioavailability on CH4 production and the consistent development of Methanobacteriaceae in productive MSW microbiomes.
ContributorsReynolds, Mark Christian (Author) / Cadillo-Quiroz, Hinsby (Thesis advisor) / Krajmalnik-Brown, Rosa (Thesis advisor) / Wang, Xuan (Committee member) / Kavazanjian, Edward (Committee member) / Arizona State University (Publisher)
Created2022
Description
Zero-Valent Metals (ZVM) are highly reactive materials and have been proved to be effective in contaminant reduction in soils and groundwater remediation. In fact, zero-Valent Iron (ZVI) has proven to be very effective in removing, particularly chlorinated organics, heavy metals, and odorous sulfides. Addition of ZVI has also been proved in enhancing the methane gas generation in anaerobic digestion of activated sludge. However, no studies have been conducted regarding the effect of ZVM stimulation to Municipal Solid Waste (MSW) degradation. Therefore, a collaborative study was developed to manipulate microbial activity in the landfill bioreactors to favor methane production by adding ZVMs. This study focuses on evaluating the effects of added ZVM on the leachate generated from replicated lab scale landfill bioreactors. The specific objective was to investigate the effects of ZVMs addition on the organic and inorganic pollutants in leachate. The hypothesis here evaluated was that adding ZVM including ZVI and Zero Valent Manganese (ZVMn) will enhance the removal rates of the organic pollutants present in the leachate, likely by a putative higher rate of microbial metabolism. Test with six (4.23 gallons) bioreactors assembled with MSW collected from the Salt River Landfill and Southwest Regional Landfill showed that under 5 grams /liter of ZVI and 0.625 grams/liter of ZVMn additions, no significant difference was observed in the pH and temperature data of the leachate generated from these reactors. The conductivity data suggested the steady rise across all reactors over the period of time. The removal efficiency of sCOD was highest (27.112 mg/lit/day) for the reactors added with ZVMn at the end of 150 days for bottom layer, however the removal rate was highest (16.955 mg/lit/day) for ZVI after the end of 150 days of the middle layer. Similar trends in the results was observed in TC analysis. HPLC study indicated the dominance of the concentration of heptanoate and isovalerate were leachate generated from the bottom layer across all reactors. Heptanoate continued to dominate in the ZVMn added leachate even after middle layer injection. IC analysis concluded the chloride was dominant in the leachate generated from all the reactors and there was a steady increase in the chloride content over the period of time. Along with chloride, fluoride, bromide, nitrate, nitrite, phosphate and sulfate were also detected in considerable concentrations. In the summary, the addition of the zero valent metals has proved to be efficient in removal of the organics present in the leachate.
ContributorsPandit, Gandhar Abhay (Author) / Cadillo – Quiroz, Hinsby (Thesis advisor) / Olson, Larry (Thesis advisor) / Boyer, Treavor (Committee member) / Arizona State University (Publisher)
Created2019