Matching Items (7)
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- All Subjects: Water resources management
- Genre: Academic theses
- Creators: Chester, Mikhail
- Creators: Green, Matthew
- Status: Published
Description
The large-scale anthropogenic emission of carbon dioxide into the atmosphere leads to many unintended consequences, from rising sea levels to ocean acidification. While a clean energy infrastructure is growing, mid-term strategies that are compatible with the current infrastructure should be developed. Carbon capture and storage in fossil-fuel power plants is one way to avoid our current gigaton-scale emission of carbon dioxide into the atmosphere. However, for this to be possible, separation techniques are necessary to remove the nitrogen from air before combustion or from the flue gas after combustion. Metal-organic frameworks (MOFs) are a relatively new class of porous material that show great promise for adsorptive separation processes. Here, potential mechanisms of O2/N2 separation and CO2/N2 separation are explored.
First, a logical categorization of potential adsorptive separation mechanisms in MOFs is outlined by comparing existing data with previously studied materials. Size-selective adsorptive separation is investigated for both gas systems using molecular simulations. A correlation between size-selective equilibrium adsorptive separation capabilities and pore diameter is established in materials with complex pore distributions. A method of generating mobile extra-framework cations which drastically increase adsorptive selectivity toward nitrogen over oxygen via electrostatic interactions is explored through experiments and simulations. Finally, deposition of redox-active ferrocene molecules into systematically generated defects is shown to be an effective method of increasing selectivity towards oxygen.
First, a logical categorization of potential adsorptive separation mechanisms in MOFs is outlined by comparing existing data with previously studied materials. Size-selective adsorptive separation is investigated for both gas systems using molecular simulations. A correlation between size-selective equilibrium adsorptive separation capabilities and pore diameter is established in materials with complex pore distributions. A method of generating mobile extra-framework cations which drastically increase adsorptive selectivity toward nitrogen over oxygen via electrostatic interactions is explored through experiments and simulations. Finally, deposition of redox-active ferrocene molecules into systematically generated defects is shown to be an effective method of increasing selectivity towards oxygen.
ContributorsMcIntyre, Sean (Author) / Mu, Bin (Thesis advisor) / Green, Matthew (Committee member) / Lind, Marylaura (Committee member) / Arizona State University (Publisher)
Created2019
Description
As urban populations rapidly increase in an era of climate change and multiple social and environmental uncertainties, scientists and governments are cultivating knowledge and solutions for the sustainable growth and maintenance of cities. Although substantial literature focuses on urban water resource management related to both human and ecological sustainability, few studies assess the unique role of waterway restorations to bridge anthropocentric and ecological concerns in urban environments. To address this gap, my study addressed if well-established sustainability principles are evoked during the nascent discourse of recently proposed urban waterway developments along over fifty miles of Arizona’s Salt River. In this study, a deductive content analysis is used to illuminate the emergence of sustainability principles, the framing of the redevelopment, and to illuminate macro-environmental discourses. Three sustainability principles dominated the discourse: civility and democratic governance; livelihood sufficiency and opportunity; and social-ecological system integrity. These three principles connected to three macro-discourses: economic rationalism; democratic pragmatism; and ecological modernity. These results hold implications for policy and theory and inform urban development processes for improvements to sustainability. As continued densification, in-fill and rapid urbanization continues in the 21st century, more cities are looking to reconstruct urban riverways. Therefore, the emergent sustainability discourse regarding potential revitalizations along Arizona’s Salt River is a manifestation of how waterways are perceived, valued, and essential to urban environments for anthropocentric and ecological needs.
ContributorsHorvath, Veronica (Author) / White, Dave D (Thesis advisor) / Mirumachi, Naho (Committee member) / Childers, Dan (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2019
Description
Water recovery from impaired sources, such as reclaimed wastewater, brackish groundwater, and ocean water, is imperative as freshwater resources are under great pressure. Complete reuse of urine wastewater is also necessary to sustain life on space exploration missions of greater than one year’s duration. Currently, the Water Recovery System (WRS) used on the National Aeronautics and Space Administration (NASA) shuttles recovers only 70% of generated wastewater.1 Current osmotic processes show high capability to increase water recovery from wastewater. However, commercial reverse osmosis (RO) membranes rapidly degrade when exposed to pretreated urine-containing wastewater. Also, non-ionic small molecules substances (i.e., urea) are very poorly rejected by commercial RO membranes.
In this study, an innovative composite membrane that integrates water-selective molecular sieve particles into a liquid-barrier chemically resistant polymer film is synthetized. This plan manipulates distinctive aspects of the two materials used to create the membranes: (1) the innate permeation and selectivity of the molecular sieves, and (2) the decay-resistant, versatile, and mechanical strength of the liquid-barrier polymer support matrix.
To synthesize the membrane, Linde Type A (LTA) zeolite particles are anchored to the porous substrate, producing a single layer of zeolite particles capable of transporting water through the membrane. Thereafter, coating the chemically resistant latex polymer filled the space between zeolites. Finally, excess polymer was etched from the surface to expose the zeolites to the feed solution. The completed membranes were tested in reverse osmosis mode with deionized water, sodium chloride, and rhodamine solutions to determine the suitability for water recovery.
The main distinguishing characteristics of the new membrane design compared with current composite membrane include: (1) the use of an impermeable polymer broadens the range of chemical resistant polymers that can be used as the polymer matrix; (2) the use of zeolite particles with specific pore size insures the high rejection of the neutral molecules since water is transported through the zeolite rather than the polymer; (3) the use of latex dispersions, environmentally friendly water based-solutions, as the polymer matrix shares the qualities of low volatile organic compound, low cost, and non- toxicity.
In this study, an innovative composite membrane that integrates water-selective molecular sieve particles into a liquid-barrier chemically resistant polymer film is synthetized. This plan manipulates distinctive aspects of the two materials used to create the membranes: (1) the innate permeation and selectivity of the molecular sieves, and (2) the decay-resistant, versatile, and mechanical strength of the liquid-barrier polymer support matrix.
To synthesize the membrane, Linde Type A (LTA) zeolite particles are anchored to the porous substrate, producing a single layer of zeolite particles capable of transporting water through the membrane. Thereafter, coating the chemically resistant latex polymer filled the space between zeolites. Finally, excess polymer was etched from the surface to expose the zeolites to the feed solution. The completed membranes were tested in reverse osmosis mode with deionized water, sodium chloride, and rhodamine solutions to determine the suitability for water recovery.
The main distinguishing characteristics of the new membrane design compared with current composite membrane include: (1) the use of an impermeable polymer broadens the range of chemical resistant polymers that can be used as the polymer matrix; (2) the use of zeolite particles with specific pore size insures the high rejection of the neutral molecules since water is transported through the zeolite rather than the polymer; (3) the use of latex dispersions, environmentally friendly water based-solutions, as the polymer matrix shares the qualities of low volatile organic compound, low cost, and non- toxicity.
ContributorsKhosravi, Afsaneh Khosravi (Author) / Lind, Mary Laura (Thesis advisor) / Dai, Lenore (Committee member) / Green, Matthew (Committee member) / Lin, Jerry (Committee member) / Seo, Don (Committee member) / Arizona State University (Publisher)
Created2016
Description
Cities are, at once, a habitat for humans, a center of economic production, a direct consumer of natural resources in the local environment, and an indirect consumer of natural resources at regional, national, and global scales. These processes do not take place in isolation: rather they are nested within complex coupled natural-human (CNH) systems that have nearby and distant teleconnections. Infrastructure systems—roads, electrical grids, pipelines, damns, and aqueducts, to name a few—have been built to convey and store these resources from their point of origin to their point of consumption. Traditional hard infrastructure systems are complemented by soft infrastructure, such as governance, legal, economic, and social systems, which rely upon the conveyance of information and currency rather than a physical commodity, creating teleconnections that link multiple CNH systems. The underlying structure of these systems allows for the creation of novel network methodologies to study the interdependencies, feedbacks, and timescales between direct and indirect resource consumers and producers; to identify potential vulnerabilities within the system; and to model the configuration of ideal system states. Direct and indirect water consumption provides an ideal indicator for such study because water risk is highly location-based in terms of geography, climate, economics, and cultural norms and is manifest at multiple geographic scales. Taken together, the CNH formed by economic trade and indirect water exchange networks create hydro-economic networks. Given the importance of hydro-economic networks for human well-being and economic production, this dissertation answers the overarching research question: What information do we gain from analyzing virtual water trade at the systems level rather than the component city level? Three studies are presented with case studies pertaining to the State of Arizona. The first derives a robust methodology to disaggregate indirect water flows to subcounty geographies. The second creates city-level metrics of hydro-economic vulnerability and functional diversity. The third analyzes the physical, legal, and economic allocation of a shared river basin to identify vulnerable nodes in river basin hydro-economic networks. This dissertation contributes to the literature through the creation of novel metrics to measure hydro-economic network properties and to generate insight into potential US hydro-economic shocks.
ContributorsRushforth, Richard Ray (Author) / Ruddell, Benajmin L (Thesis advisor) / Allenby, Braden (Committee member) / Chester, Mikhail (Committee member) / Seager, Thomas (Committee member) / Arizona State University (Publisher)
Created2016
Description
The Water-Energy Nexus (WEN) is a concept that recognizes the interdependence of water and energy systems. The Phoenix metropolitan region (PMA) in Arizona has significant and potentially vulnerable WEN interactions. Future projections indicate that the population will increase and, with it, energy needs, while changes in future water demand are more uncertain. Climate change will also likely cause a reduction in surface water supply sources. Under these constraints, the expansion of renewable energy technology has the potential to benefit both water and energy systems and increase environmental sustainability by meeting future energy demands while lowering water use and CO2 emissions. However, the WEN synergies generated by renewables have not yet been thoroughly quantified, nor have the related costs been studied and compared to alternative options.Quantifying WEN intercations using numerical models is key to assessing renewable energy synergy. Despite recent advances, WEN models are still in their infancy, and research is needed to improve their accuracy and identify their limitations. Here, I highlight three research needs. First, most modeling efforts have been conducted for large-scale domains (e.g., states), while smaller scales, like metropolitan regions, have received less attention. Second, impacts of adopting different temporal (e.g., monthly, annual) and spatial (network granularity) resolutions on simulation accuracy have not been quantified. Third, the importance of simulating feedbacks between water and energy components has not been analyzed.
This dissertation fills these major research gaps by focusing on long-term water allocations and energy dispatch in the metropolitan region of Phoenix. An energy model is developed using the Low Emissions Analysis Platform (LEAP) platform and is subsequently coupled with a water management model based on the Water Evaluation and Planning (WEAP) platform. Analyses are conducted to quantify (1) the value of adopting coupled models instead of single models that are externally coupled, and (2) the accuracy of simulations based on different temporal resolutions of supply and demand and spatial granularity of the water and energy networks. The WEAP-LEAP integrated model is then employed under future climate scenarios to quantify the potential of renewable energy technologies to develop synergies between the PMA's water and energy systems.
ContributorsMounir, Adil (Author) / Mascaro, Giuseppe (Thesis advisor) / White, Dave (Committee member) / Garcia, Margaret (Committee member) / Xu, Tianfang (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2022
Description
Cities are facing complex problems in urban water management due to unprecedented changes in climate, natural and built environment. The shift in urban hydrology from pre-development to post-development continues to accelerate the challenges of managing excess stormwater runoff, mitigating urban flood hazards and flood damages. Physically based hydrologic-hydraulic stormwater models are a useful tool for broad subset of urban flood management including risk and hazard assessment, flood forecasting, and infrastructure adaptation decision making and planning. The existing limitations in data availability, gaps in data, and uncertainty in data preclude reliable model construction, testing, deployment, knowledge generation, effective communication of flood risks, and adaptation decision making. These challenges that affect both the science and practice motivate three chapters of this dissertation. The first study conducts diagnostic analysis of the effects of stormwater infrastructure data completeness on model’s ability to simulate flood duration, flooding flow rate; and assesses the combined effects of data gaps and model resolution to simulate flood depth, extent and volume (chapter 2). The analysis showed the significance of complete stormwater infrastructure data and high model resolution to reduce error, bias and uncertainty; this study also presented an approach for filling infrastructure data gaps using available data and design standards. The second study addresses the lack of long-term hydrological observation in urban catchment by investigating the process and benefits of leveraging novel data sources in urban flood model construction and testing (chapter 3). A proof-of-concept demonstrated the application and benefits of leveraging novel data sources for urban flood monitoring and modeling. Furthermore, it highlights the need for developing and streamlining novel data collection infrastructure. The third study applies the hydrologic-hydraulic model as an adaptation planning tool and assess the effects of uncertainty in design precipitation estimates and land use change on the optimal configuration of green infrastructure (chapter 4). Several uncertainties affect infrastructure decision making as showed by variation in optimal green infrastructure configuration under precipitation estimates and land use change. Thus, the study further highlights the need of flexible planning process in infrastructure decision making.
ContributorsShrestha, Ashish (Author) / Garcia, Margaret (Thesis advisor) / Mascaro, Giuseppe (Committee member) / Chester, Mikhail (Committee member) / Fletcher, Sarah (Committee member) / Arizona State University (Publisher)
Created2022
Description
Per- and polyfluoroalkyl substances (PFAS) are anthropogenic chemicals used for a wide variety of products and industrial processes, including being an essential class of chemicals in the fabrication of semiconductors. Proven concerns related to bioaccumulation and toxicity across multiple species have resulted in health advisory and regulatory initiatives for PFAS in drinking and wastewaters. Among impacted users of PFAS, the semiconductor industry is in urgent need of technologies to remove PFAS from water. Specifically, they prefer technologies capable of mineralizing PFAS into inorganic fluoride (F-). The goal of this thesis is to compare the effectiveness of photo- versus electrocatalytic treatment in benchtop reactor systems PFAS in industrial wastewater before selecting one technology to investigate comprehensively. First, a model wastewater was developed based upon semiconductor samples to represent water matrices near where PFAS are used and the aggregate Fab effluent, which were then used in batch catalytic experiments. Second, batch experiments with homogenous photocatalysis (UV/SO32-) were found to be more energy-intensive than heterogeneous catalysis using boron-doped diamond (BDD) electrodes, and the latter approach was then studied in-depth.
During electrocatalysis, longer chain PFAS (C8; PFOA & PFOS) were observed to degrade faster than C6 and C4 PFAS. This study is the first to report near-complete defluorination of not only C8- and C6- PFAS, but also C4-PFAS, in model wastewaters using BDD electrocatalysis, and the first to report such degradation in real Fab wastewater effluents. Based upon differences in PFAS degradation rates observed in single-solute systems containing only C4 PFAS versus multi-solute systems including C4, C6, and C8 PFAS, it was concluded that the surfactant properties of the longer-chain PFAS created surface films on the BDD electrode surface which synergistically enhanced removal of shorter-chain PFAS. The results from batch experiments that serve as the basis of this thesis will be used to assess the chemical byproducts and their associated bioaccumulation and toxicity. This thesis was aimed at developing an efficient method for the degradation of perfluoroalkyl substances from industrial process waters at realistic concentrations.
ContributorsNienhauser, Alec Brockway (Author) / Westerhoff, Paul (Thesis advisor) / Garcia-Segura, Sergi (Committee member) / Thomas, Marylaura (Committee member) / Green, Matthew (Committee member) / Arizona State University (Publisher)
Created2021