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Description
The purpose of this study was to determine the applicability of fluorescent microspheres as a surrogate to measure the removal of Cryptosporidium oocysts through the coagulation, flocculation, sedimentation, and filtration steps of conventional water treatment. In order to maintain accuracy and applicability, a local water treatment facility was chosen as

The purpose of this study was to determine the applicability of fluorescent microspheres as a surrogate to measure the removal of Cryptosporidium oocysts through the coagulation, flocculation, sedimentation, and filtration steps of conventional water treatment. In order to maintain accuracy and applicability, a local water treatment facility was chosen as the system to model. The city of Chandler Arizona utilizes conventional treatment methodologies to remove pathogens from municipal drinking water and thus the water, coagulant, polymer, and doses concentrations were sourced directly from the plant. Jar testing was performed on four combinations of coagulant, polymer, and fluorescent microsphere to determine if the log removal was similar to that of Cryptosporidium oocysts.

Complications with the material properties of the microspheres arose during testing that ultimately yielded unfavorable but conclusive results. Log removal of microspheres did not increase with added coagulant in the predicted manner, though the beads were seen aggregating, the low density of the particles made the sedimentation step inefficient. This result can be explained by the low density of the microspheres as well as the potential presence of residual coagulant present in the system. Given the unfavorable properties of the beads, they do not appear to be a suitable candidate for the surrogacy of Cryptosporidium oocysts in conventional drinking water treatment. The beads in their current state are not an adequate surrogate; however, future testing has been outlined to modify the experiment in such a way that the microspheres should behave like oocysts in terms of physical transportation.
ContributorsLinks, Alexander Glenn (Author) / Abbaszadegan, Morteza (Thesis advisor) / Alum, Absar (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Granular activated carbon (GAC) is effectively used to remove natural organic matter (NOM) and to assist in the removal of disinfection byproducts (DBPs) and their precursors. However, operation of GAC is cost- and labor-intensive due to frequent media replacement. Optimizing the use of GAC is necessary to ensure treatment efficiency

Granular activated carbon (GAC) is effectively used to remove natural organic matter (NOM) and to assist in the removal of disinfection byproducts (DBPs) and their precursors. However, operation of GAC is cost- and labor-intensive due to frequent media replacement. Optimizing the use of GAC is necessary to ensure treatment efficiency while reducing costs. This dissertation presents four strategies to reduce improve GAC usage while reducing formation of DBPs. The first part of this work adopts Rapid Small Scale Tests (RSSCTs) to evaluate removal of molecular weight fractions of NOM, characterized using size exclusion chromatography (SECDOC). Total trihalomethanes (TTHM), haloacetic acids (HAA5) and haloacetonitriles (HAN) formation were quantified after treatment with GAC. Low MW NOM was removed preferentially in the early bed volumes, up until exhaustion of available adsorption sites. DBP formation potential lowered with DOC removal. Chlorination prior to GAC is investigated in the second part of this work as a strategy to increase removal of NOM and DBP precursors. Results showed lower TTHM formation in the effluent of the GAC treatment when pre-chlorination was adopted, meaning this strategy could help optimize and extend the bed life if GAC filters. The third part of this work investigates in-situ GAC regeneration as an alternative to recover adsorption capacity of field-spent GAC that could potentially offer new modes of operation for water treatment facilities while savng costs with reactivation of spent GAC in an external facility. Field-spent GACs were treated with different oxidant solutions and recovery in adsorption capacity was evaluated for NOM and for two micro pollutants. Recovery of GAC adsorption capacity was not satisfactory for most of conditions evaluated. This indicates that in-situ GAC regeneration could be more effective when the adsorbates are present at high concentrations. Lastly, this work investigates the impact of low molecular weight polyDADMAC on N-nitrosodimethylamine (NDMA) formation. Water treatment facilities rely on polyDADMAC as a coagulant aid to comply with NOM removal and turbidity requirements. Since polymer-derived NDMA precursors are not removed by GAC, it is essential to optimize the use and synthesis of polyDADMAC to reduce NDMA precursors during water treatment.
ContributorsFischer, Natalia (Author) / Westerhoff, Paul (Thesis advisor) / Hristovski, Kiril (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2017
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Description
In the recent past, Iraq was considered relatively rich considering its water resources compared to its surroundings. Currently, the magnitude of water resource shortages in Iraq represents an important factor in the stability of the country and in protecting sustained economic development. The need for a practical, applicable, and sustainable

In the recent past, Iraq was considered relatively rich considering its water resources compared to its surroundings. Currently, the magnitude of water resource shortages in Iraq represents an important factor in the stability of the country and in protecting sustained economic development. The need for a practical, applicable, and sustainable river basin management for the Tigris and Euphrates Rivers in Iraq is essential. Applicable water resources allocation scenarios are important to minimize the potential future water crises in connection with water quality and quantity. The allocation of the available fresh water resources in addition to reclaimed water to different users in a sustainable manner is of the urgent necessities to maintain good water quantity and quality.

In this dissertation, predictive water allocation optimization models were developed which can be used to easily identify good alternatives for water management that can then be discussed, debated, adjusted, and simulated in greater detail. This study provides guidance for decision makers in Iraq for potential future conditions, where water supplies are reduced, and demonstrates how it is feasible to adopt an efficient water allocation strategy with flexibility in providing equitable water resource allocation considering alternative resource. Using reclaimed water will help in reducing the potential negative environmental impacts of treated or/and partially treated wastewater discharges while increasing the potential uses of reclaimed water for agriculture and other applications. Using reclaimed water for irrigation is logical and efficient to enhance the economy of farmers and the environment while providing a diversity of crops, especially since most of Iraq’s built or under construction wastewater treatment plants are located in or adjacent to agricultural lands. Adopting an optimization modelling approach can assist decision makers, ensuring their decisions will benefit the economy by incorporating global experiences to control water allocations in Iraq especially considering diminished water supplies.
ContributorsAhmed, Ahmed Abdulrazzaq (Author) / Mays, Larry W. (Thesis advisor) / Fox, Peter (Thesis advisor) / Mascaro, Giuseppe (Committee member) / Muenich, Rebecca (Committee member) / Arizona State University (Publisher)
Created2019
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Description
The phrase water-energy nexus is commonly used to describe the inherent and critical interdependencies between the electric power system and the water supply systems (WSS). The key interdependencies between the two systems are the power plant’s requirement of water for the cooling cycle and the water system’s need of electricity

The phrase water-energy nexus is commonly used to describe the inherent and critical interdependencies between the electric power system and the water supply systems (WSS). The key interdependencies between the two systems are the power plant’s requirement of water for the cooling cycle and the water system’s need of electricity for pumping for water supply. While previous work has considered the dependency of WSS on the electrical power, this work incorporates into an optimization-simulation framework, consideration of the impact of short and long-term limited availability of water and/or electrical energy.

This research focuses on the water supply system (WSS) facet of the multi-faceted optimization and control mechanism developed for an integrated water – energy nexus system under U.S. National Science Foundation (NSF) project 029013-0010 CRISP Type 2 – Resilient cyber-enabled electric energy and water infrastructures modeling and control under extreme mega drought scenarios. A water supply system (WSS) conveys water from sources (such as lakes, rivers, dams etc.) to the treatment plants and then to users via the water distribution systems (WDS) and/or water supply canal systems (WSCS). Optimization-simulation methodologies are developed for the real-time operation of water supply systems (WSS) under critical conditions of limited electrical energy and/or water availability due to emergencies such as extreme drought conditions, electric grid failure, and other severe conditions including natural and manmade disasters. The coupling between WSS and the power system was done through alternatively exchanging data between the power system and WSS simulations via a program control overlay developed in python.

A new methodology for WDS infrastructural-operational resilience (IOR) computation was developed as a part of this research to assess the real-time performance of the WDS under emergency conditions. The methodology combines operational resilience and component level infrastructural robustness to provide a comprehensive performance assessment tool.

The optimization-simulation and resilience computation methodologies developed were tested for both hypothetical and real example WDS and WSCS, with results depicting improved resilience for operations of the WSS under normal and emergency conditions.
ContributorsKhatavkar, Puneet (Author) / Mays, Larry W. (Thesis advisor) / Vittal, Vijay (Committee member) / Mascaro, Giuseppe (Committee member) / Fox, Peter (Committee member) / Zhang, Junshan (Committee member) / Arizona State University (Publisher)
Created2019
Description
The understanding of normal human physiology and disease pathogenesis shows great promise for progress with increasing ability to profile genomic loci and transcripts in single cells in situ. Using biorthogonal cleavable fluorescent oligonucleotides, a highly multiplexed single-cell in situ RNA and DNA analysis is reported. In this report, azide-based cleavable

The understanding of normal human physiology and disease pathogenesis shows great promise for progress with increasing ability to profile genomic loci and transcripts in single cells in situ. Using biorthogonal cleavable fluorescent oligonucleotides, a highly multiplexed single-cell in situ RNA and DNA analysis is reported. In this report, azide-based cleavable linker connects oligonucleotides to fluorophores to show nucleic acids through in situ hybridization. Post-imaging, the fluorophores are effectively cleaved off in half an hour without loss of RNA or DNA integrity. Through multiple cycles of hybridization, imaging, and cleavage this approach proves to quantify thousands of different RNA species or genomic loci because of single-molecule sensitivity in single cells in situ. Different nucleic acids can be imaged by shown by multi-color staining in each hybridization cycle, and that multiple hybridization cycles can be run on the same specimen. It is shown that in situ analysis of DNA, RNA and protein can be accomplished using both cleavable fluorescent antibodies and oligonucleotides. The highly multiplexed imaging platforms will have the potential for wide applications in both systems biology and biomedical research. Thus, proving to be cost effective and time effective.
ContributorsSamuel, Adam David (Author) / Guo, Jia (Thesis director) / Liu, Wei (Committee member) / Wang, Xu (Committee member) / School of Molecular Sciences (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
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Description
This study was designed to provide insight into microbial transport kinetics which might be applied to bioremediation technology development and prevention of groundwater susceptibility to pathogen contamination. Several pilot-scale experiments were conducted in a saturated, 2 dimensional, packed porous media tank to investigate the transport of Escherichia coli bacteria, P22

This study was designed to provide insight into microbial transport kinetics which might be applied to bioremediation technology development and prevention of groundwater susceptibility to pathogen contamination. Several pilot-scale experiments were conducted in a saturated, 2 dimensional, packed porous media tank to investigate the transport of Escherichia coli bacteria, P22 bacteriophage, and a visual tracer and draw comparisons and/or conclusions. A constructed tank was packed with an approximate 3,700 cubic inches (in3) of a fine grained, homogeneous, chemically inert sand which allowed for a controlled system. Sampling ports were located at 5, 15, 25, and 25 vertical inches from the base of the 39 inch saturated zone and were used to assess the transport of the selected microorganisms. Approximately 105 cells of E. coli or P22 were injected into the tank and allowed to move through the media at approximately 10.02 inches per day. Samples were collected intermittently after injection based off of an estimated sampling schedule established from the visual tracer.

The results suggest that bacteriophages pass through soil faster and with greater recovery than bacteria. P22 in the tank reservoir experienced approximately 1 log reduction after 36 hours. After 85 hours, P22 was still detected in the reservoir after experiencing a 2 log reduction from the start of the experiment. E. coli either did not reach the outlet or died before sampling, while P22 was able to be recovered. Bacterial breakthrough curves were produced for the microbial indicators and illustrate the peak concentrations found for each sampling port. For E. coli, concentrations at the 5 inch port peaked at a maximum of 5170 CFU/mL, and eventually at the 25 inch port at a maximum of 90 CFU/mL. It is presumed that E. coli might have experienced significant filtration, straining and attachment, while P22 might have experienced little adsorption and instead was transported rapidly in long distances and was able to survive for the duration of the experiment.
ContributorsAcosta, Jazlyn Cauren (Author) / Abbaszadegan, Morteza (Thesis advisor) / Dahlen, Paul (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2017
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Description
This dissertation investigates the mechanisms that lead to fouling, as well as how an understanding of how these mechanisms can be leveraged to mitigate fouling.

To limit fouling on feed spacers, various coatings were applied. The results showed silver-coated biocidal spacers outperformed other spacers by all measures. The control polypropylene

This dissertation investigates the mechanisms that lead to fouling, as well as how an understanding of how these mechanisms can be leveraged to mitigate fouling.

To limit fouling on feed spacers, various coatings were applied. The results showed silver-coated biocidal spacers outperformed other spacers by all measures. The control polypropylene spacers performed in-line with, or better than, the other coatings. Polypropylene’s relative anti-adhesiveness is due to its surface free energy (SFE; 30.0 +/- 2.8 mN/m), which, according to previously generated models, is near the ideal SFE for resisting adhesion of bacteria and organics (~25 mN/m).

Previous research has indicated that electrochemical surfaces can be used to remove biofilms. To better elucidate the conditions and kinetics of biofilm removal, optical coherence tomography microscopy was used to visualize the biofouling and subsequent cleaning of the surface. The 50.0 mA cm-2 and 87.5 mA cm-2 current densities proved most effective in removing the biofilm. The 50.0 mA cm-2 condition offers the best balance between performance and energy use for anodic operation.

To test the potential to incorporate electrochemical coatings into infrastructure, membranes were coated with carbon nanotubes (CNTs), rendering the membranes electrochemically active. These membranes were biofouled and subsequently cleaned via electrochemical reactions. P. aeruginosa was given 72h to develop a biofilm on the CNT-coated membranes in a synthetic medium simulating desalination brines. Cathodic reactions, which generate H2 gas, produce vigorous bubbling at a current density of 12.5 mA cm-2 and higher, leading to a rapid and complete displacement of the biofilm from the CNT-functionalized membrane surface. In comparison, anodic reactions were unable to disperse the biofilms from the surface at similar current densities.

The scaling behavior of a nanophotonics-enabled solar membrane distillation (NESMD) system was investigated. The results showed the NESMD system to be resistant to scaling. The system operated without any decline in flux up to concentrations 6x higher than the initial salt concentration (8,439 mg/L), whereas in traditional membrane distillation (MD), flux essentially stopped at a salt concentration factor of 2x. Microscope and analytical analyses showed more fouling on the membranes from the MD system.
ContributorsRice, Douglas, Ph.D (Author) / Perreault, Francois (Thesis advisor) / Abbaszadegan, Morteza (Committee member) / Fox, Peter (Committee member) / Lind-Thomas, Mary Laura (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Imagine you live in a place without any storm water or wastewater systems!

Wastewater and storm water systems are two of the most crucial systems for urban infrastructure. Water resources have become more limited and expensive in arid and semi-arid regions. According to the fourth World Water Development Report, over

Imagine you live in a place without any storm water or wastewater systems!

Wastewater and storm water systems are two of the most crucial systems for urban infrastructure. Water resources have become more limited and expensive in arid and semi-arid regions. According to the fourth World Water Development Report, over 80% of global wastewater is released into the environment without adequate treatment. Wastewater collection and treatment systems in the Kingdom of Saudi Arabia (KSA) covers about 49% of urban areas; about 25% of treated wastewater is used for landscape and crop irrigation (Ministry of Environment Water and Agriculture [MEWA], 2017). According to Guizani (2016), during each event of flooding, there are fatalities. In 2009, the most deadly flood occurred in Jeddah, KSA within more than 160 lives lost. As a consequence, KSA has set a goal to provide 100% sewage collection and treatment services to every city with a population above 5000 by 2025, where all treated wastewater will be used.

This research explores several optimization models of planning and designing collection systems, such as regional wastewater and stormwater systems, in order to understand and overcome major performance-related disadvantages and high capital costs. The first model (M-1) was developed for planning regional wastewater system, considering minimum costs of location, type, and size sewer network and wastewater treatment plants (WWTPs). The second model (M-2) was developed for designing a regional wastewater system, considering minimum hydraulic design costs, such as pump stations, commercial diameters, excavation costs, and WWTPs. Both models were applied to the Jizan region, KSA.

The third model (M-3) was developed to solve layout and pipe design for storm water systems simultaneously. This model was applied to four different case scenarios, using two approaches for commercial diameters. The fourth model (M-4) was developed to solve the optimum pipe design of a storm sewer system for given layouts. However, M-4 was applied to a storm sewer network published in the literature.

M-1, M-2, and M-3 were developed in the general algebraic modeling system (GAMS) program, which was formulated as a mixed integer nonlinear programming (MINLP) solver, while M-4 was formulated as a nonlinear programming (NLP) procedure.
ContributorsAlfaisal, Faisal M (Author) / Mays, Larry W. (Thesis advisor) / Mascaro, Giuseppe (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Water reuse and nutrient recovery are long-standing strategies employed in agricultural systems. This is especially true in dry climates where water is scarce, and soils do not commonly contain the nutrients or organic matter to sustain natural crop growth. Agriculture accounts for approximately 70% of all freshwater withdrawals globally. This

Water reuse and nutrient recovery are long-standing strategies employed in agricultural systems. This is especially true in dry climates where water is scarce, and soils do not commonly contain the nutrients or organic matter to sustain natural crop growth. Agriculture accounts for approximately 70% of all freshwater withdrawals globally. This essential sector of society therefore plays an important role in ensuring water sources are maintained and that the food system can remain resilient to dwindling water resources. The purpose of this research is to quantify the benefits of organic residuals and reclaimed water use in agriculture in arid environments through the development of a systematic review and case study. Data from the systematic review was extracted to be applied to a case study identifying the viability and benefits of organic residuals on arid agriculture. Results show that the organic residuals investigated do have quantitative benefits to agriculture such as improving soil health, reducing the need for conventional fertilizers, and reducing irrigation needs from freshwater sources. Some studies found reclaimed water sources to be of better quality than local freshwater sources due to environmental factors. Biosolids and manure are the most concentrated of the organic residuals, providing nutrient inputs and enhancing long-term soil health. A conceptual model is presented to demonstrate the quantitative benefits of using a reclaimed water source in Pinal County, Arizona on a hypothetical crop of cotton. A goal of the model is to take implied nutrient inputs from reclaimed water sources and quantify them against standard practice of using irrigated groundwater and conventional fertilizers on agricultural operations. Pinal County is an important case study area where farmers are facing cuts to their water resources amid a prolonged drought in the Colorado River Basin. The model shows that a reclaimed water source would be able to offset all freshwater and conventional fertilizer use, but salinity in reclaimed water sources would force a need for additional irrigation in the form of a large leaching fraction. This review combined with the case study demonstrate the potential for nutrient and water reuse, while highlighting potential barriers to address.
ContributorsKrukowski, William Lee (Author) / Muenich, Rebecca (Thesis advisor) / Williams, Clinton (Committee member) / Hamilton, Kerry (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Nitrogen removal and energy reduction in wastewater treatment are shared goals. Approaches to achieve those goals include the techniques of shortcut nitrogen removal utilizing nitrite shunt, biocatalyst, nitritation, deammonification, and simultaneous nitrification-denitrification. The practice of those techniques is newer in the industry of wastewater treatment but continues to develop, along

Nitrogen removal and energy reduction in wastewater treatment are shared goals. Approaches to achieve those goals include the techniques of shortcut nitrogen removal utilizing nitrite shunt, biocatalyst, nitritation, deammonification, and simultaneous nitrification-denitrification. The practice of those techniques is newer in the industry of wastewater treatment but continues to develop, along with the understanding of the biological and chemical activities that drive those processes. The kinetics and stoichiometry of traditional and shortcut nitrogen removal reactions are generally well understood to date. However, the thermodynamics of those processes are complex and deserve additional research to better understand the dominant factors that drive cell synthesis. Additionally, the implementation of nitrogen shortcut techniques can reduce the footprint of wastewater treatment processes that implement nitrogen removal by approximately 5 percent and can reduce operating costs by between 12 and 26 percent annually. Combined, nitrogen shortcut techniques can contribute to significant reduction in the long-term cost to operate, due to lower energy and consumable requirements, fast reaction times resulting in shorter solids retention times, and improvement efficiency in nitrogen removal from wastewater. This dissertation explores and defines the dominant factors that contribute to the success of efficiencies in traditional and shortcut nitrogen removal techniques, focusing on the natural microbiological processes. The culmination of these efforts was used to develop decision matrices to promote consideration of nitrogen shortcut techniques by practitioners during conceptual planning and design of wastewater treatment facilities.
ContributorsTack, Frederick Henry (Author) / Fox, Peter (Thesis advisor) / Krajmalnik-Brown, Rosa (Committee member) / Abbaszadegan, Morteza (Committee member) / Alum, Absar (Committee member) / Arizona State University (Publisher)
Created2021