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The origin of the solar system and formation of planets such as Earth are among the most fascinating, outstanding scientific problems. From theoretical models to natural observations, it is possible to infer a general way of how the solar system evolved from the gravitational collapse of the molecular cloud to

The origin of the solar system and formation of planets such as Earth are among the most fascinating, outstanding scientific problems. From theoretical models to natural observations, it is possible to infer a general way of how the solar system evolved from the gravitational collapse of the molecular cloud to accretion and differentiation of planetary-sized bodies. This dissertation attempts to place additional constraints on the source, distribution, and evolution of chemical variability in the early solar system, Mars, and Earth.

A new method was developed for the measurement of titanium isotopes in calcium-aluminum-rich inclusions (CAIs) by laser ablation multi-collector inductively coupled plasma mass spectrometry. The isotopic compositions of 17 Allende CAIs define a narrow range with clearly resolved excesses in 46Ti and 50Ti and suggests that "normal" CAIs formed from a relatively uniform reservoir. Petrologic and isotopic analysis of a new FUN (Fractionated and Unknown Nuclear effects) CAI suggests that normal and FUN CAIs condensed in similar environments, but subsequently evolved under vastly different conditions.

Volatiles may have influenced the formation and evolution of basaltic magmas on Mars. Light lithophile element (LLE) and fluorine (F) concentrations and isotopic compositions of pyroxene determined in situ in several Martian meteorites suggests that the primary magmatic signature of LLE and F zonation in Shergottite pyroxene has been disturbed by post-crystallization diffusive equilibration. Using relevant crystal-melt partition coefficients the F contents for Martian meteorite parental melts are ~910 and ~220 ppm. Estimates of the F content in the Shergottite and Nakhlite source regions are similar to that of mid-ocean ridge basalts (MORB) and ocean island basalts (OIB), respectively, here on Earth.

Noble gas systematics of OIBs relative to MORBs, suggests OIBs preferentially sample a primordial reservoir located within Earth's mantle. Geodynamic calculations were performed to investigate the time-dependent rate of material entrained into plumes from these primordial reservoirs. These models predict melts rising to the surface will contain variable proportions of primordial material. The results demonstrate that although high 3He/4He ratios may mandate a mantle plume that samples a primordial reservoir, more MORB-like 3He/4He ratios in OIBs do not preclude a deep plume source.
ContributorsWilliams, Curtis Davis (Author) / Wadhwa, Meenakshi (Thesis advisor) / McNamara, Allen K (Committee member) / Bell, David R. (Committee member) / Garnero, Edward J (Committee member) / Young, Patrick (Committee member) / Arizona State University (Publisher)
Created2014
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I combine, compare, and contrast the results from two different numerical techniques (grid vs. particle methods) studying multi-scale processes in galaxy and structure formation. I produce a method for recreating identical initial conditions for one method from those of the other, and explore methodologies necessary for making these two methods

I combine, compare, and contrast the results from two different numerical techniques (grid vs. particle methods) studying multi-scale processes in galaxy and structure formation. I produce a method for recreating identical initial conditions for one method from those of the other, and explore methodologies necessary for making these two methods as consistent as possible. With this, I first study the impact of streaming velocities of baryons with respect to dark matter, present at the epoch of reionization, on the ability for small halos to accrete gas at high redshift. With the inclusion of this stream velocity, I find the central density profile of halos is reduced, overall gas condensation is delayed, and infer a delay in the inevitable creation of stars.

I then combine the two numerical methods to study starburst outflows as they interact with satellite halos. This process leads to shocks catalyzing the formation of molecular coolants that lead to bursts in star formation, a process that is better captured in grid methods. The resultant clumps of stars are removed from their initial dark matter halo, resemble precursors to modern-day globular clusters, and their formation may be observable with upcoming telescopes.

Finally, I perform two simulation suites, comparing each numerical method's ability to model the impact of energetic feedback from accreting black holes at the core of giant clusters. With these comparisons I show that black hole feedback can maintain a hot diffuse medium while limiting the amount of gas that can condense into the interstellar medium, reducing the central star formation by up to an order of magnitude.
ContributorsRichardson, Mark Lawrence Albert (Author) / Scannapieco, Evan (Thesis advisor) / Rhoads, James (Committee member) / Scowen, Paul (Committee member) / Timmes, Frank (Committee member) / Young, Patrick (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Historically, uranium has received intense study of its chemical and isotopic properties for use in the nuclear industry, but has been largely ignored by geoscientists despite properties that make it an intriguing target for geochemists and cosmochemists alike. Uranium was long thought to have an invariant 238U/235U ratio in natural

Historically, uranium has received intense study of its chemical and isotopic properties for use in the nuclear industry, but has been largely ignored by geoscientists despite properties that make it an intriguing target for geochemists and cosmochemists alike. Uranium was long thought to have an invariant 238U/235U ratio in natural samples, making it uninteresting for isotopic work. However, recent advances in mass spectrometry have made it possible to detect slight differences in the 238U/235U ratio, creating many exciting new opportunities for U isotopic research. Using uranium ore samples from diverse depositional settings from around the world, it is shown that the low-temperature redox transition of uranium (U6+ to U4+) causes measurable fractionation of the 238U/235U ratio. Moreover, it is shown experimentally that a coordination change of U can also cause measurable fractionation in the 238U/235U ratio. This improved understanding of the fractionation mechanisms of U allows for the use of the 238U/235U ratio as a paleoredox proxy. The 238U/235U ratios of carbonates deposited spanning the end-Permian extinction horizon provide evidence of pronounced and persistent widespread ocean anoxia at, or immediately preceding, the extinction boundary. Variable 238U/235U ratios correlated with proxies for initial Cm/U in the Solar System's earliest objects demonstrates the existence of 247Cm in the early Solar System. Proof of variable 238U/235U ratios in meteoritic material forces a substantive change in the previously established procedures of Pb-Pb dating, which assumed an invariant 238U/235U ratio. This advancement improves the accuracy of not only the Pb-Pb chronometer that directly utilizes the 238U/235U ratio, but also for short-lived radiometric dating techniques that indirectly use the 238U/235U ratio to calculate ages of Solar System material.
ContributorsBrennecka, Gregory A (Author) / Anbar, Ariel D (Thesis advisor) / Wadhwa, Meenakshi (Thesis advisor) / Herrmann, Achim D (Committee member) / Hervig, Richard (Committee member) / Young, Patrick (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Most stars form in groups, and these clusters are themselves nestled within larger associations and stellar complexes. It is not yet clear, however, whether stars cluster on preferred size scales within galaxies, or if stellar groupings have a continuous size distribution. I have developed two methods to select stellar groupings

Most stars form in groups, and these clusters are themselves nestled within larger associations and stellar complexes. It is not yet clear, however, whether stars cluster on preferred size scales within galaxies, or if stellar groupings have a continuous size distribution. I have developed two methods to select stellar groupings across a wide range of size-scales in order to assess trends in the size distribution and other basic properties of stellar groupings. The first method uses visual inspection of color-magnitude and color-color diagrams of clustered stars to assess whether the compact sources within the potential association are coeval, and thus likely to be born from the same parentmolecular cloud. This method was developed using the stellar associations in the M51/NGC 5195 interacting galaxy system. This process is highly effective at selecting single-aged stellar associations, but in order to assess properties of stellar clustering in a larger sample of nearby galaxies, an automated method for selecting stellar groupings is needed. I have developed an automated stellar grouping selection method that is sensitive to stellar clustering on all size scales. Using the Source Extractor software package on Gaussian-blurred images of NGC 4214, and the annular surface brightness to determine the characteristic size of each cluster/association, I eliminate much of the size and density biases intrinsic to other methods. This automated method was tested in the nearby dwarf irregular galaxy NGC 4214, and can detect stellar groupings with sizes ranging from compact clusters to stellar complexes. In future work, the automatic selection method developed in this dissertation will be used to identify stellar groupings in a set of nearby galaxies to determine if the size scales for stellar clustering are uniform in the nearby universe or if it is dependent on local galactic environment. Once the stellar clusters and associations have been identified and age-dated, this information can be used to deduce disruption times from the age distribution as a function of the position of the stellar grouping within the galaxy, the size of the cluster or association, and the morphological type of the galaxy. The implications of these results for galaxy formation and evolution are discussed.
ContributorsKaleida, Catherine (Author) / Scowen, Paul A. (Thesis advisor) / Windhorst, Rogier A. (Thesis advisor) / Jansen, Rolf A. (Committee member) / Timmes, Francis X. (Committee member) / Scannapieco, Evan (Committee member) / Arizona State University (Publisher)
Created2011
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Description
The isotopic compositions of meteorites provide valuable insights into the earliest history of the Solar System and, in some cases, provide constraints on presolar components that contributed to the solar nebula. In the past decade or so, mass-independent isotope anomalies in titanium have become particularly important geochemical tracers to study

The isotopic compositions of meteorites provide valuable insights into the earliest history of the Solar System and, in some cases, provide constraints on presolar components that contributed to the solar nebula. In the past decade or so, mass-independent isotope anomalies in titanium have become particularly important geochemical tracers to study the distinct isotopic reservoirs in the early Solar System. In particular, mass-independent anomalies in the most neutron-rich isotope of titanium (50Ti) have been used to distinguish between carbonaceous chondritic (CC) and non-carbonaceous chondritic (NC) materials. These two groupings likely represent distinct isotopic reservoirs in the inner (NC) and outer (CC) Solar System. However, while the titanium isotope compositions of CC and NC materials are distinct, each group's full range of compositional variability is poorly characterized. For example, only one CK carbonaceous chondrite group member has been analyzed thus far for its bulk Ti isotope composition. This work aims to characterize better the range of mass-independent Ti isotope compositions within and among the carbonaceous chondrites, which has implications for the degree and potential sources of Ti isotope heterogeneity in the early Solar System. Methods utilized in this study include column chromatography to purify Ti and high-precision multi-collector inductively coupled plasma mass spectrometry for measuring Ti isotope compositions. The Ti isotope compositions of bulk samples of nine carbonaceous chondrites are reported here. In addition, the bulk fractions of the meteorites used in this study were taken from homogenized powders of relatively large (~200 mg each) samples. This was done to assess whether variability in mass-independent Ti isotope compositions previously reported within some meteorites could be a sampling artifact. Results from this work show that the various CM2 chondrites and ungrouped carbonaceous chondrites have ε50Ti values that are similar, suggesting that the Ti in these samples was likely sourced from a common isotopic reservoir. On the other hand, the ε50Ti values reported for CI1 and CH/CBb bulk samples suggest that the parent bodies of these carbonaceous chondrite groups were formed in isotopic reservoir(s) distinct from that of the other CC groups in the early Solar System.
ContributorsPhelan, Nicole Danielle (Author) / Wadhwa, Meenakshi (Thesis advisor) / Young, Patrick (Committee member) / Nittler, Larry R. (Committee member) / Arizona State University (Publisher)
Created2023