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CubeSats are a newly emerging, low-cost, rapid development platform for space exploration research. They are small spacecraft with a mass and volume of up to 12 kg and 12,000 cm3, respectively. To date, CubeSats have only been flown in Low Earth Orbit (LEO), though a large number are currently being

CubeSats are a newly emerging, low-cost, rapid development platform for space exploration research. They are small spacecraft with a mass and volume of up to 12 kg and 12,000 cm3, respectively. To date, CubeSats have only been flown in Low Earth Orbit (LEO), though a large number are currently being designed to be dropped off by a mother ship on Earth escape trajectories intended for Lunar and Martian flyby missions. Advancements in propulsion technologies now enable these spacecraft to achieve capture orbits around the moon and Mars, providing a wealth of scientific data at low-cost. However, the mass, volume and launch constraints of CubeSats severely limit viable propulsion options.

We present an innovative propulsion solution using energy generated by onboard photovoltaic panels to electrolyze water, thus producing combustible hydrogen and oxygen for low-thrust applications. Water has a high storage density allowing for sufficient fuel within volume constraints. Its high enthalpy of formation provides more fuel that translates into increased ∆V and vastly reduced risk for the launch vehicle. This innovative technology poses significant challenges including the design and operation of electrolyzers at ultra-cold temperatures, the efficient separation of the resultant hydrogen and oxygen gases from liquid water in a microgravity environment, as well as the effective utilization of thrust to produce desired trajectories.

Analysis of the gas combustion and flow through the nozzle using both theoretical equations and finite-volume CFD modeling suggests an expected specific impulse of 360 s. Preliminary results from AGI's Satellite Toolkit (STK) indicate that the ΔV produced by the system for an 8kg CubeSat with 6kg of propellant in a LEO orbit (370 km altitude) is sufficient for an earth escape trajectory, lunar capture orbit or even a Mars capture orbit. These results suggest a promising pathway for an in-depth study supported by laboratory experiments to characterize the strengths and weaknesses of the proposed concept.
ContributorsPothamsetti, Ramana Kumar (Author) / Thangavelautham, Jekanthan (Thesis advisor) / Dahm, Werner J.A (Committee member) / Solanki, Kiran N (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Commercially pure (CP) and extra low interstitial (ELI) grade Ti-alloys present excellent corrosion resistance, lightweight, and formability making them attractive materials for expanded use in transportation and medical applications. However, the strength and toughness of CP titanium are affected by relatively small variations in their impurity/solute content (IC), e.g., O,

Commercially pure (CP) and extra low interstitial (ELI) grade Ti-alloys present excellent corrosion resistance, lightweight, and formability making them attractive materials for expanded use in transportation and medical applications. However, the strength and toughness of CP titanium are affected by relatively small variations in their impurity/solute content (IC), e.g., O, Al, and V. This increase in strength is due to the fact that the solute either increases the critical stress required for the prismatic slip systems ({10-10}<1-210>) or activates another slip system ((0001)<11-20>, {10-11}<11-20>). In particular, solute additions such as O can effectively strengthen the alloy but with an attendant loss in ductility by changing the behavior from wavy (cross slip) to planar nature. In order to understand the underlying behavior of strengthening by solutes, it is important to understand the atomic scale mechanism. This dissertation aims to address this knowledge gap through a synergistic combination of density functional theory (DFT) and molecular dynamics. Further, due to the long-range strain fields of the dislocations and the periodicity of the DFT simulation cells, it is difficult to apply ab initio simulations to study the dislocation core structure. To alleviate this issue we developed a multiscale quantum mechanics/molecular mechanics approach (QM/MM) to study the dislocation core. We use the developed QM/MM method to study the pipe diffusion along a prismatic edge dislocation core. Complementary to the atomistic simulations, the Semi-discrete Variational Peierls-Nabarro model (SVPN) was also used to analyze the dislocation core structure and mobility. The chemical interaction between the solute/impurity and the dislocation core is captured by the so-called generalized stacking fault energy (GSFE) surface which was determined from DFT-VASP calculations. By taking the chemical interaction into consideration the SVPN model can predict the dislocation core structure and mobility in the presence and absence of the solute/impurity and thus reveal the effect of impurity/solute on the softening/hardening behavior in alpha-Ti. Finally, to study the interaction of the dislocation core with other planar defects such as grain boundaries (GB), we develop an automated method to theoretically generate GBs in HCP type materials.
ContributorsBhatia, Mehul Anoopkumar (Author) / Solanki, Kiran N (Thesis advisor) / Peralta, Pedro (Committee member) / Jiang, Hanqing (Committee member) / Neithalath, Narayanan (Committee member) / Rajagopalan, Jagannathan (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Dissimilar metal joints such as aluminum-steel joints are extensively used in automobile, naval and aerospace applications and these are subjected to corrosive environmental and mechanical loading resulting in eventual failure of the structural joints. In the case of aluminum alloys under aggressive environment, the damage accumulation is predominantly due to

Dissimilar metal joints such as aluminum-steel joints are extensively used in automobile, naval and aerospace applications and these are subjected to corrosive environmental and mechanical loading resulting in eventual failure of the structural joints. In the case of aluminum alloys under aggressive environment, the damage accumulation is predominantly due to corrosion and is accelerated in presence of other metals. During recent years several approaches have been employed to develop models to assess the metal removal rate in the case of galvanic corrosion. Some of these models are based on empirical methods such as regression analysis while others are based on quantification of the ongoing electrochemical processes. Here, a numerical model for solving the Nernst- Planck equation, which captures the electrochemical process, is implemented to predict the galvanic current distribution and, hence, the corrosion rate of a galvanic couple. An experimentally validated numerical model for an AE44 (Magnesium alloy) and mild steel galvanic couple, available in the literature, is extended to simulate the mechano- electrochemical process in order to study the effect of mechanical loading on the galvanic current density distribution and corrosion rate in AE44-mild steel galvanic couple through a multiphysics field coupling technique in COMSOL Multiphysics®. The model is capable of tracking moving boundariesy of the corroding constituent of the couple by employing Arbitrary Langrangian Eulerian (ALE) method.Results show that, when an anode is under a purely elastic deformation, there is no apparent effect of mechanical loading on the electrochemical galvanic process. However, when the applied tensile load is sufficient to cause a plastic deformation, the local galvanic corrosion activity at the vicinity of the interface is increased remarkably. The effect of other factors, such as electrode area ratios, electrical conductivity of the electrolyte and depth of the electrolyte, are studied. It is observed that the conductivity of the electrolyte significantly influences the surface profile of the anode, especially near the junction. Although variations in electrolyte depth for a given galvanic couple noticeably affect the overall corrosion, the change in the localized corrosion rate at the interface is minimal. Finally, we use the model to predict the current density distribution, rate of corrosion and depth profile of aluminum alloy 7075-stainless steel 316 galvanic joints, which are extensively used in maritime structures.
ContributorsMuthegowda, Nitin Chandra (Author) / Solanki, Kiran N (Thesis advisor) / Rykaczewski, Konrad (Committee member) / Jiao, Yang (Committee member) / Arizona State University (Publisher)
Created2015