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Description
A method of determining nanoparticle temperature through fluorescence intensity levels is described. Intracellular processes are often tracked through the use of fluorescence tagging, and ideal temperatures for many of these processes are unknown. Through the use of fluorescence-based thermometry, cellular processes such as intracellular enzyme movement can be studied and

A method of determining nanoparticle temperature through fluorescence intensity levels is described. Intracellular processes are often tracked through the use of fluorescence tagging, and ideal temperatures for many of these processes are unknown. Through the use of fluorescence-based thermometry, cellular processes such as intracellular enzyme movement can be studied and their respective temperatures established simultaneously. Polystyrene and silica nanoparticles are synthesized with a variety of temperature-sensitive dyes such as BODIPY, rose Bengal, Rhodamine dyes 6G, 700, and 800, and Nile Blue A and Nile Red. Photographs are taken with a QImaging QM1 Questar EXi Retiga camera while particles are heated from 25 to 70 C and excited at 532 nm with a Coherent DPSS-532 laser. Photographs are converted to intensity images in MATLAB and analyzed for fluorescence intensity, and plots are generated in MATLAB to describe each dye's intensity vs temperature. Regression curves are created to describe change in fluorescence intensity over temperature. Dyes are compared as nanoparticle core material is varied. Large particles are also created to match the camera's optical resolution capabilities, and it is established that intensity values increase proportionally with nanoparticle size. Nile Red yielded the closest-fit model, with R2 values greater than 0.99 for a second-order polynomial fit. By contrast, Rhodamine 6G only yielded an R2 value of 0.88 for a third-order polynomial fit, making it the least reliable dye for temperature measurements using the polynomial model. Of particular interest in this work is Nile Blue A, whose fluorescence-temperature curve yielded a much different shape from the other dyes. It is recommended that future work describe a broader range of dyes and nanoparticle sizes, and use multiple excitation wavelengths to better quantify each dye's quantum efficiency. Further research into the effects of nanoparticle size on fluorescence intensity levels should be considered as the particles used here greatly exceed 2 ìm. In addition, Nile Blue A should be further investigated as to why its fluorescence-temperature curve did not take on a characteristic shape for a temperature-sensitive dye in these experiments.
ContributorsTomforde, Christine (Author) / Phelan, Patrick (Thesis advisor) / Dai, Lenore (Committee member) / Adrian, Ronald (Committee member) / Arizona State University (Publisher)
Created2011
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Description
In these times of increasing industrialization, there arises a need for effective and energy efficient heat transfer/heat exchange devices. The focus nowadays is on identifying various methods and techniques which can aid the process of developing energy efficient devices. One of the most common heat transfer devices is a heat

In these times of increasing industrialization, there arises a need for effective and energy efficient heat transfer/heat exchange devices. The focus nowadays is on identifying various methods and techniques which can aid the process of developing energy efficient devices. One of the most common heat transfer devices is a heat exchanger. Heat exchangers are an essential commodity to any industry and their efficiency can play an important role in making industries energy efficient and reduce the energy losses in the devices, in turn decreasing energy inputs to run the industry.

One of the ways in which we can improve the efficiency of heat exchangers is by applying ultrasonic energy to a heat exchanger. This research explores the possibility of introducing the external input of ultrasonic energy to increase the efficiency of the heat exchanger. This increase in efficiency can be estimated by calculating the parameters important for the characterization of a heat exchanger, which are effectiveness (ε) and overall heat transfer coefficient (U). These parameters are calculated for both the non-ultrasound and ultrasound conditions in the heat exchanger.

This a preliminary study of ultrasound and its effect on a conventional shell-and-coil heat exchanger. From the data obtained it can be inferred that the increase in effectiveness and overall heat transfer coefficient upon the application of ultrasound is 1% and 6.22% respectively.
ContributorsAnnam, Roshan Sameer (Author) / Phelan, Patrick (Thesis advisor) / Rykaczewski, Konrad (Committee member) / Milcarek, Ryan (Committee member) / Arizona State University (Publisher)
Created2019
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Description
The proposed research mainly focuses on employing tunable materials to achieve dynamic control of radiative heat transfer in both far and near fields for thermal management. Vanadium dioxide (VO2), which undergoes a phase transition from insulator to metal at the temperature of 341 K, is one tunable material being applied.

The proposed research mainly focuses on employing tunable materials to achieve dynamic control of radiative heat transfer in both far and near fields for thermal management. Vanadium dioxide (VO2), which undergoes a phase transition from insulator to metal at the temperature of 341 K, is one tunable material being applied. The other one is graphene, whose optical properties can be tuned by chemical potential through external bias or chemical doping.

In the far field, a VO2-based metamaterial thermal emitter with switchable emittance in the mid-infrared has been theoretically studied. When VO2 is in the insulating phase, high emittance is observed at the resonance frequency of magnetic polaritons (MPs), while the structure becomes highly reflective when VO2 turns metallic. A VO2-based thermal emitter with tunable emittance is also demonstrated due to the excitation of MP at different resonance frequencies when VO2 changes phase. Moreover, an infrared thermal emitter made of graphene-covered SiC grating could achieve frequency-tunable emittance peak via the change of the graphene chemical potential.

In the near field, a radiation-based thermal rectifier is constructed by investigating radiative transfer between VO2 and SiO2 separated by nanometer vacuum gap distances. Compared to the case where VO2 is set as the emitter at 400 K as a metal, when VO2 is considered as the receiver at 300 K as an insulator, the energy transfer is greatly enhanced due to the strong surface phonon polariton (SPhP) coupling between insulating VO2 and SiO2. A radiation-based thermal switch is also explored by setting VO2 as both the emitter and the receiver. When both VO2 emitter and receiver are at the insulating phase, the switch is at the “on” mode with a much enhanced heat flux due to strong SPhP coupling, while the near-field radiative transfer is greatly suppressed when the emitting VO2 becomes metallic at temperatures higher than 341K during the “off” mode. In addition, an electrically-gated thermal modulator made of graphene covered SiC plates is theoretically studied with modulated radiative transport by varying graphene chemical potential. Moreover, the MP effect on near-field radiative transport has been investigated by spectrally enhancing radiative heat transfer between two metal gratings.
ContributorsYang, Yue (Author) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Tongay, Sefaattin (Committee member) / Rykaczewski, Konrad (Committee member) / Arizona State University (Publisher)
Created2016
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Description
The space industry is rapidly expanding, and components are getting increasinglysmaller leading to the prominence of cubesats. Cubesats are satellites from about coffee mug size to cereal box size. The challenges of shortened timeline and smaller budgets for smaller spacecraft are also their biggest advantages. This benefits educational missions and industry missions a

The space industry is rapidly expanding, and components are getting increasinglysmaller leading to the prominence of cubesats. Cubesats are satellites from about coffee mug size to cereal box size. The challenges of shortened timeline and smaller budgets for smaller spacecraft are also their biggest advantages. This benefits educational missions and industry missions a like but can burden teams to be smaller or have less experience. Thermal analysis of cubesats is no exception to these burdens which is why this thesis has been written to provide a guide for conducting the thermal analysis of a cubesat using the Deployable Optical Receiver Aperture (DORA) mission as an example. Background on cubesats and their role in the space industry will be examined. The theoretical side of heat transfer necessary for conducting a thermal analysis will be explored. The DORA thermal analysis will then be conducted by constructing a thermal model in Thermal Desktop software from the ground up. Insight to assumptions for model construction to move accurately yet quickly will be detailed. Lastly, this fast and quick method will be compared to a standard finite element mesh model to show quality results can be achieved in significantly less time.
ContributorsAdkins, Matthew Thomas (Author) / Phelan, Patrick (Thesis advisor) / Jacobs, Danny (Thesis advisor) / Wang, Liping (Committee member) / Bowman, Judd (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Additive manufacturing, also known as 3-dimensional (3-d) printing, is now a rapidly growing manufacturing technique. Innovative and complex designs in various aspects of engineering have called for more efficient manufacturing techniques and 3-d printing has been a perfect choice in that direction. This research investigates the use of additive manufacturing

Additive manufacturing, also known as 3-dimensional (3-d) printing, is now a rapidly growing manufacturing technique. Innovative and complex designs in various aspects of engineering have called for more efficient manufacturing techniques and 3-d printing has been a perfect choice in that direction. This research investigates the use of additive manufacturing in fabricating polymer heat exchangers and estimate their effectiveness as a heat transfer device. Fused Deposition Modeling (FDM), Selective Laser Sintering (SLS) and Stereolithography (SLA) are the three 3-d printing techniques that are explored for their feasibility in manufacturing heat exchangers. The research also explores a triply periodic minimal structure–the gyroid, as a heat exchanger design. The performance of the gyroid heat exchanger was studied using experiments. The main parameters considered for the experiments were heat transfer rate, effectiveness and pressure drop. From the results obtained it can be inferred that using polymers in heat exchangers helps reducing corrosion and fouling problems, but it affects the effectiveness of the heat exchangers. For our design, the maximum effectiveness achieved was 0.1. The pressure drop for the heat exchanger was observed to decrease with an increase in flow rate and the maximum pressure drop measured was 0.88 psi for a flow rate of 5 LPM.
ContributorsDanayat, Swapneel Shailesh (Author) / Phelan, Patrick (Thesis advisor) / Kwon, Beomjin (Committee member) / Azeredo, Bruno (Committee member) / Arizona State University (Publisher)
Created2019