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Description
Fluorine (F) is a volatile constituent of magmas and hydrous mantle minerals. Compared to other volatile species, F is highly soluble in silicate melts, allowing F to remain in the melt during magma differentiation and rendering F less subject to disturbance during degassing upon magma ascent. Hence, the association between

Fluorine (F) is a volatile constituent of magmas and hydrous mantle minerals. Compared to other volatile species, F is highly soluble in silicate melts, allowing F to remain in the melt during magma differentiation and rendering F less subject to disturbance during degassing upon magma ascent. Hence, the association between fluorine in basalts and fluorine in the mantle source region is more robust than for other volatile species. The ionic radius of F- is similar to that of OH- and O2-, and F may substitute for hydroxyl and oxygen in silicate minerals and melt. Fluorine is also incorporated at trace levels within nominally anhydrous minerals (NAMs) such as olivine, clinopyroxene, and plagioclase. Investigating the geochemical behavior of F in NAMs provides a means to estimate the pre-eruptive F contents of degassed magmas and to better understand the degassing behavior of H. The partition coefficients of F were determined for clinopyroxene, olivine, plagioclase, and hornblende within melts of olivine-minette, augite-minette, basaltic andesite, and latite compositions. The samples analyzed were run products from previously-published phase-equilibria experiments. Fluorine was measured by secondary ion mass spectrometry (SIMS) using an 16O- primary beam and detection of negative secondary ions (19F-, 18O-, 28Si-). SIMS ion intensities are converted to concentrations by analyzing matrix-matched microanalytical reference materials and constructing calibration curves. For robust F calibration standards, five basaltic glasses (termed Fba glasses) were synthesized in-house using a natural tholeiite mixed with variable amounts of CaF2. The Fba glasses were characterized for F content and homogeneity, using both SIMS and electron-probe microanalysis (EPMA), and used as F standards. The partition coefficients for clinopyroxene (0.04-028) and olivine (0.01-0.16) varied with melt composition such that DF (olivine-minette) < DF (augite-minette) < DF (basaltic andesite) < DF (latite). Crystal chemical controls were found to influence the incorporation of F into clinopyroxene, but none were found that affected olivine. Fluorine partitioning was compared with that of OH within clinopyroxenes, and the alumina content of clinopyroxene was shown to be a strong influence on the incorporation of both anions. Fluorine substitution into both olivine and clinopyroxene was found to be strongly controlled by melt viscosity and degree of melt polymerization.
ContributorsGuggino, Steve (Author) / Hervig, Richard L (Thesis advisor) / Donald, Burt M (Committee member) / Amanda, Clarke B (Committee member) / Lynda, Williams B (Committee member) / Stanley, Williams N (Committee member) / Arizona State University (Publisher)
Created2012
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Description
There are many outstanding questions regarding the petrologic processes that give rise to andesitic and basaltic magmas in subduction zones, including the specifics that govern their geographical distribution in a given arc segment. Here I investigate the genesis of calc-alkaline and tholeiitic basalts from the Lassen Volcanic Center in order

There are many outstanding questions regarding the petrologic processes that give rise to andesitic and basaltic magmas in subduction zones, including the specifics that govern their geographical distribution in a given arc segment. Here I investigate the genesis of calc-alkaline and tholeiitic basalts from the Lassen Volcanic Center in order to determine the pressure, temperature, source composition, and method of melting that lead to the production of melt in the mantle below Lassen. To this aim, a suite of primitive basalts (i.e. SiO2<52 and Mg#>65) are corrected for fractional crystallization by adding minerals back to the bulk rock composition with the goal of returning them to a primary composition in equilibrium with the mantle. Thermobarometry of the primary melt compositions is conducted to determine temperature and pressure of melting, in addition to a forward mantle modeling technique to simulate mantle melting at varying pressures to constrain source composition and method of melting (batch vs. fractional). The results from the two techniques agree on an average depth of melt extraction of 36 km and a source composition similar to that of depleted mantle melted by batch melting. Although attempted for both calc-alkaline and tholeiitic basalts, the fractional crystallization correction and thus the pressure-temperature calculations were only successful for tholeiitic basalts due to the hydrous nature of the calc-alkaline samples. This leaves an opportunity to repeat this study with parameters appropriate for hydrous basalts, allowing for the comparison of calc-alkaline and tholeiitic melting conditions.
ContributorsSheppard, Katherine Davis (Author) / Till, Christy (Thesis director) / Hervig, Richard (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2015-05
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Description

The Star Planet Activity Research CubeSat (SPARCS) will be a 6U CubeSat devoted to photometric monitoring of M dwarfs in the far-ultraviolet (FUV) and near-ultraviolet (NUV) (160 and 280 nm respectively), measuring the time-dependent spectral slope, intensity and evolution of M dwarf stellar UV radiation. The delta-doped detectors baselined for

The Star Planet Activity Research CubeSat (SPARCS) will be a 6U CubeSat devoted to photometric monitoring of M dwarfs in the far-ultraviolet (FUV) and near-ultraviolet (NUV) (160 and 280 nm respectively), measuring the time-dependent spectral slope, intensity and evolution of M dwarf stellar UV radiation. The delta-doped detectors baselined for SPARCS have demonstrated more than five times the in-band quantum efficiency of the detectors of GALEX. Given that red:UV photon emission from cool, low-mass stars can be million:one, UV observation of thes stars are susceptible to red light contamination. In addition to the high efficiency delta-doped detectors, SPARCS will include red-rejection filters to help minimize red leak. Even so, careful red-rejection and photometric calibration is needed. As was done for GALEX, white dwarfs are used for photometric calibration in the UV. We find that the use of white dwarfs to calibrate the observations of red stars leads to significant errors in the reported flux, due to the differences in white dwarf and red dwarf spectra. Here we discuss the planned SPARCS calibration model and the color correction, and demonstrate the importance of this correction when recording UV measurements of M stars taken by SPARCS.

ContributorsOsby, Ella (Author) / Shkolnik, Evgenya (Thesis director) / Ardila, David (Committee member) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Description
Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better

Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better understanding of their eruptions and associated hazards. I will approach this analysis by focusing on volcanic bombs and ballistics, which are large clots of lava that are launched from the volcanic vent, follow ballistic trajectories, and can travel meters to a few kilometers from their source (e.g. Fagents and Wilson 1993; Waitt et al. 1995).
Tecolote Volcano in the Pinacate Volcanic Field in Mexico contains multiple vents within a horseshoe-shaped crater that have all produced various ejecta (Zawacki et al. 2019). The objectives of this research are to map ballistic distribution to understand the relationship between the source vent or vents and the bombs and ballistics that litter the region around Tecolote, and interpret the eruption conditions that ejected those bombs by using their distributions, morphologies, and fine-scale textures.
The findings of this work are that these bombs are apparently from the last stages of the eruption, succeeding the final lava flows. The interiors and exteriors of the bombs display different cooling rates which can are indicated by the fabric found within. Using this, certain characteristics of the bombs during eruption were extrapolated. The ‘cow pie’ bombs were determined to be the least viscous or contained a higher gas content at the time of eruption. Whereas the ribbon/rope bombs were determined to be the most viscous or contained a lesser gas content. Looking at the Southern Bomb Field site, it is dominated by large bombs that were during flight were molded into aerodynamic shapes. The Eastern Rim site is dominated by smaller bombs that appeared to be more liquid during the eruption. This difference in the two sites is a probable indication of at least two different eruptive events of different degrees of explosivity. Overall, aerodynamic bombs are more common and extend to greater distances from the presumed vent (up to 800 m), while very fluidal bombs are uncommon beyond 500 meters. Fluidal bombs (‘cow pie’, ‘ribbon’, ‘rope/spindle’) show a clear trend in decreasing size with distance from vent, whereas the size-distance trend is less dramatic for the aerodynamic bombs.
ContributorsWest, Jacob Alexander (Co-author) / West, Jacob (Co-author) / Clarke, Amanda (Thesis director) / Arrowsmith, Ramon (Committee member) / Roggensack, Kurt (Committee member) / School of Earth and Space Exploration (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05