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Description
Thermal susceptibility is one of the biggest challenges that asphalt pavements must overcome. Asphalt mixture’s thermal susceptibility can increase problems related to permanent deformation, and the expansion-contraction phenomenon triggers thermal cracking. Furthermore, there is a common worldwide interest in environmental impacts and pavements. Saving energy and mitigating the urban heat island (UHI) effect have been drawing the attention of researchers, governments, and industrial organizations. Pavements have been shown to play an important role in the UHI effect. Globally, about 90% of roadways are made of asphalt mixtures. The main objective of this research study involves the development and testing of an innovative aerogel-based product in the modification of asphalt mixtures to function as a material with unique thermal resistance properties, and potentially providing an urban cooling mechanism for the UHI. Other accomplishments included the development of test procedures to estimate the thermal conductivity of asphalt binders, the expansion-contraction of asphalt mixtures, and a computational tool to better understand the pavement’s thermal profile and stresses. Barriers related to the manufacturing and field implementation of the aerogel-based product were overcome. Unmodified and modified asphalt mixtures were manufactured at an asphalt plant to build pavement slabs. Thermocouples installed at top and bottom collected data daily. This data was valuable in understanding the temperature fluctuation of the pavement. Also, the mechanical properties of asphalt binders and mixtures with and without the novel product were evaluated in the laboratory. Fourier transform infrared (FTIR) and scanning electron microscope (SEM) analyses were also used to understand the interaction of the developed product with bituminous materials.
The modified pavements showed desirable results in reducing overall pavement temperatures and suppressing the temperature gradient, a key to minimize thermal cracking. The comprehensive laboratory tests showed favorable outcomes for pavement performance. The use of a pavement design software, and life cycle/cost assessment studies supported the use of this newly developed technology. Modified pavements would perform better than control in distresses related to permanent deformation and thermal cracking; they reduce tire/pavement noise, require less raw material usage during their life cycle, and have lower life cycle cost compared to conventional pavements.
ContributorsObando Gamboa, Carlos Javier (Author) / Kaloush, Kamil (Thesis advisor) / Mamlouk, Michael (Committee member) / Ozer, Hasan (Committee member) / Fini, Elham (Committee member) / Zapata, Claudia (Committee member) / Arizona State University (Publisher)
Created2022
Description
This research focused on the structure-property relationships of a rejuvenator to understand the comprehensive rejuvenation mechanism of aged asphalt binder. Aged asphalt such as recycled asphalt shingles (RAS) and reclaimed asphalt pavement (RAP) contain various amounts of asphalt binder. However, the asphalt binder in RAS and RAP is severely aged and inferior in properties compared to a virgin binder. To address this issue, liquid additives have been used under the general title of rejuvenators. That poses an additional challenge associated with the lack of clear metrics to differentiate between softeners and rejuvenators. Therefore, there is a need for a thorough study of rejuvenators. In this study, diverse-sourced rejuvenators have been used in RAS and RAP-modified binders as well as laboratory-prepared aged binders. The properties of the rejuvenated aged binder were characterized at a macro-level and molecular level. The study showed that the performance of the RAS-modified binder was significantly improved after bio-modification by a bio-rejuvenator.
This study further evaluated laboratory-prepared aged asphalt rejuvenated with different rejuvenators. The results found that oxidized bitumen became soft after adding rejuvenators, regardless of their source. Molecular dynamics simulation showed that the effective rejuvenator restored the molecular conformation and reduced the size of asphaltene nanoaggregates.
The study results showed that due to the specific chemical composition of certain rejuvenators, they may negatively impact the durability of the mixture, especially about its resistance to moisture damage and aging. Computational analysis showed that while the restoration capacity of rejuvenators is related to their penetration into and peptizing of asphaltene nanoaggregates, the durability of the restored aged asphalt is mainly related to the polarizability values of the rejuvenator. Rejuvenators with lower polarizability showed better resistance to aging and moisture damage.
In summary, this study develops the rheology-based indicators which relate to the molecular level phenomenon in the rejuvenation mechanism. The rheology-based indicators, for instance, crossover modulus and crossover frequency differentiated the rejuvenators from recycling agents. Moreover, the study found that rejuvenation efficiency and durability are depended on the chemistry of rejuvenators. Finally, based on the learning of chemistry, a chemically balanced rejuvenator is synthesized with superior rejuvenation properties.
This study further evaluated laboratory-prepared aged asphalt rejuvenated with different rejuvenators. The results found that oxidized bitumen became soft after adding rejuvenators, regardless of their source. Molecular dynamics simulation showed that the effective rejuvenator restored the molecular conformation and reduced the size of asphaltene nanoaggregates.
The study results showed that due to the specific chemical composition of certain rejuvenators, they may negatively impact the durability of the mixture, especially about its resistance to moisture damage and aging. Computational analysis showed that while the restoration capacity of rejuvenators is related to their penetration into and peptizing of asphaltene nanoaggregates, the durability of the restored aged asphalt is mainly related to the polarizability values of the rejuvenator. Rejuvenators with lower polarizability showed better resistance to aging and moisture damage.
In summary, this study develops the rheology-based indicators which relate to the molecular level phenomenon in the rejuvenation mechanism. The rheology-based indicators, for instance, crossover modulus and crossover frequency differentiated the rejuvenators from recycling agents. Moreover, the study found that rejuvenation efficiency and durability are depended on the chemistry of rejuvenators. Finally, based on the learning of chemistry, a chemically balanced rejuvenator is synthesized with superior rejuvenation properties.
ContributorsRajib, Amirul Islam (Author) / Fini, Elham (Thesis advisor) / Yin, Huiming (Committee member) / Kaloush, Kamil (Committee member) / Parast, Mahour (Committee member) / Mamlouk, Michael (Committee member) / El Asmar, Mounir (Committee member) / Arizona State University (Publisher)
Created2020
Description
It is common to use crumb rubber as modifier in bitumen. Good performance of crumb rubber in bitumen has been reported in terms of improving characteristics like higher skid resistance, reducing noise, higher rutting resistance and longevity. However, due to the vulcanization, the polymeric crosslinked structure of crumb rubber suffers from inadequate dispersion and incompatibility in bitumen where storage stability becomes an issue. To solve this problem, partial surface devulcanization of the rubber via chemical and microbial surface activation was examined in this study showing both method can be effective to enhance rubber-bitumen interactions and subsequently storage stability of the rubberized bitumen. To ensure proper surface activation, it is important to thoroughly understand chemo-mechanics of bitumen containing rubber particles as well as underlying interaction mechanism at the molecular level. Therefore, this study integrates a multi-scale approach using density functional theory based computational modeling and laboratory experiments to provide an in-depth understanding of the mechanisms of interaction between surface activated rubber and bitumen. To do so, efficacy of various bio-modifiers was examined and compared it terms of both surface activation capability and durability of resulting rubberized bitumen. It was found that biomodifiers with various compositions can have either synergistic or antagonistic effect onchemo-mechanics of rubberized bitumen. The study was further extended to study the interplay of Polyphosphoric Acid (PPA) and these biomodified rubberized bitumens showing not all modifiers have high synergy with PPA in bitumens. Finally, durability of rubberized bitumen was studied in terms of its resistance to Ultraviolet (UV) aging. It was shown that there is a strong relation between composition of biomodified rubberized bitumen and its resistance to UV-aging.
ContributorsKabir, Sk Faisal (Author) / Fini, Elham (Thesis advisor) / Kaloush, Kamil (Committee member) / Lamanna, Anthony (Committee member) / Delgado, Anca (Committee member) / Poulikakos, Lily (Committee member) / Arizona State University (Publisher)
Created2020