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- All Subjects: Moon
- All Subjects: Paleoweathering
- Creators: Christensen, Philip R. (Philip Russel)
Description
Amorphous phases are detected over large regions of the Martian surface from orbit and in more localized deposits by rovers on the surface. Amorphous silicates can be primary or secondary in origin, both having formed through very different processes, so the unambiguous identification of these phases is important for understanding the geologic history of Mars. Secondary amorphous silicates are poorly understood and underrepresented in spectral libraries because they lack the long-range structural order that makes their crystalline counterparts identifiable in most analytical techniques. Fortunately, even amorphous materials have some degree of short-range order so that distinctions can be made with careful characterization.
Two sets of laboratory experiments were used to produce and characterize amorphous weathering products under probable conditions for the Martian surface, and one global spectral analysis using thermal-infrared (TIR) data from the Thermal Emission Spectrometer (TES) instrument was used to constrain variations in amorphous silicates across the Martian surface. The first set of experiments altered crystalline and glassy basalt samples in an open system under strong (pH 1) and moderate (pH 3) acidic conditions. The second set of experiments simulated a current-day Martian weathering scenario involving transient liquid water where basalt glass weathering solutions, formed in circumneutral (pH ~5.5 and 7) conditions, were rapidly evaporated, precipitating amorphous silicates. The samples were characterized using visible and near-infrared (VNIR) spectroscopy, TIR spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD).
All experiments formed amorphous silicate phases that are new to spectral libraries. Moderately acidic alteration experiments produced no visible or spectral evidence of alteration products, whereas exposure of basalt glass to strongly acidic fluids produced silica-rich alteration layers that are spectrally consistent with VNIR and TIR spectra from the circum-polar region of Mars, indicating this region has undergone acidic weathering. Circum-netural pH basalt weathering solution precipitates are consistent with amorphous materials measured by rovers in soil and rock surface samples in Gale and Gusev Craters, suggesting transient water interactions over the last 3 billion years. Global spectral analyses determine that alteration conditions have varied across the Martian surface, and that alteration has been long lasting.
Two sets of laboratory experiments were used to produce and characterize amorphous weathering products under probable conditions for the Martian surface, and one global spectral analysis using thermal-infrared (TIR) data from the Thermal Emission Spectrometer (TES) instrument was used to constrain variations in amorphous silicates across the Martian surface. The first set of experiments altered crystalline and glassy basalt samples in an open system under strong (pH 1) and moderate (pH 3) acidic conditions. The second set of experiments simulated a current-day Martian weathering scenario involving transient liquid water where basalt glass weathering solutions, formed in circumneutral (pH ~5.5 and 7) conditions, were rapidly evaporated, precipitating amorphous silicates. The samples were characterized using visible and near-infrared (VNIR) spectroscopy, TIR spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD).
All experiments formed amorphous silicate phases that are new to spectral libraries. Moderately acidic alteration experiments produced no visible or spectral evidence of alteration products, whereas exposure of basalt glass to strongly acidic fluids produced silica-rich alteration layers that are spectrally consistent with VNIR and TIR spectra from the circum-polar region of Mars, indicating this region has undergone acidic weathering. Circum-netural pH basalt weathering solution precipitates are consistent with amorphous materials measured by rovers in soil and rock surface samples in Gale and Gusev Craters, suggesting transient water interactions over the last 3 billion years. Global spectral analyses determine that alteration conditions have varied across the Martian surface, and that alteration has been long lasting.
ContributorsSmith, Rebecca (Author) / Christensen, Philip R. (Philip Russel) (Thesis advisor) / Shock, Everett (Committee member) / Hartnett, Hilairy (Committee member) / Shim, Sang-Heon (Committee member) / Sharp, Thomas (Committee member) / Arizona State University (Publisher)
Created2016
Description
Water has shaped the surface of Mars, recording previous environments and inspiring the search for extinct life beyond Earth. While conditions on the Martian surface today are not conducive to the presence of liquid water, ancient erosional and depositional features indicate that this was not always so. Quantifying the regional and global history of water on Mars is crucial to understanding how the planet evolved, where to focus future exploration, and implications for water on Earth.
Many sites on Mars contain layered sedimentary deposits, sinuous valleys with delta shaped deposits, and other indications of large lakes. The Hypanis deposit is a unique endmember in this set of locations as it appears to be the largest ancient river delta identified on the planet, and it appears to have no topographic boundary, implying deposition into a sea. I have used a variety of high-resolution remote sensing techniques and geologic mapping techniques to present a new model of past water activity in the region.
I gathered new orbital observations and computed thermal inertia, albedo, elevation, and spectral properties of the Hypanis deposit. I measured the strike and dip of deposit layers to interpret the sedimentary history. My results indicate that Hypanis was formed in a large calm lacustrine setting. My geomorphic mapping of the deposit and catchment indicates buried volatile-rich sediments erupted through the Chryse basin fill, and may be geological young or ongoing. Collectively, my results complement previous studies that propose a global paleoshoreline, and support interpretations that Mars had an ocean early in its history. Future missions to the Martian surface should consider Hypanis as a high-value sampling opportunity.
Many sites on Mars contain layered sedimentary deposits, sinuous valleys with delta shaped deposits, and other indications of large lakes. The Hypanis deposit is a unique endmember in this set of locations as it appears to be the largest ancient river delta identified on the planet, and it appears to have no topographic boundary, implying deposition into a sea. I have used a variety of high-resolution remote sensing techniques and geologic mapping techniques to present a new model of past water activity in the region.
I gathered new orbital observations and computed thermal inertia, albedo, elevation, and spectral properties of the Hypanis deposit. I measured the strike and dip of deposit layers to interpret the sedimentary history. My results indicate that Hypanis was formed in a large calm lacustrine setting. My geomorphic mapping of the deposit and catchment indicates buried volatile-rich sediments erupted through the Chryse basin fill, and may be geological young or ongoing. Collectively, my results complement previous studies that propose a global paleoshoreline, and support interpretations that Mars had an ocean early in its history. Future missions to the Martian surface should consider Hypanis as a high-value sampling opportunity.
ContributorsAdler, Jacob (Author) / Bell, James (Thesis advisor) / Christensen, Philip R. (Philip Russel) (Committee member) / Robinson, Mark (Committee member) / Asphaug, Erik (Committee member) / Whipple, Kelin (Committee member) / Arizona State University (Publisher)
Created2019
Description
Both volcanism and impact cratering produce ejecta and associated deposits incorporating a molten rock component. While the heat sources are different (exogenous vs. endogenous), the end results are landforms with similar morphologies including ponds and flows of impact melt and lava around the central crater. Ejecta from both impact and volcanic craters can also include a high percentage of melted rock. Using Lunar Reconnaissance Orbiter Camera Narrow Angle Camera (LROC NAC) images, crucial details of these landforms are finally revealed, suggesting a much more dynamic Moon than is generally appreciated. Impact melt ponds and flows at craters as small as several hundred meters in diameter provide empirical evidence of abundant melting during the impact cratering process (much more than was previously thought), and this melt is mobile on the lunar surface for a significant time before solidifying. Enhanced melt deposit occurrences in the lunar highlands (compared to the mare) suggest that porosity, target composition, and pre-existing topography influence melt production and distribution. Comparatively deep impact craters formed in young melt deposits connote a relatively rapid evolution of materials on the lunar surface. On the other end of the spectrum, volcanic eruptions have produced the vast, plains-style mare basalts. However, little was previously known about the details of small-area eruptions and proximal volcanic deposits due to a lack of resolution. High-resolution images reveal key insights into small volcanic cones (0.5-3 km in diameter) that resemble terrestrial cinder cones. The cones comprise inter-layered materials, spatter deposits, and lava flow breaches. The widespread occurrence of the cones in most nearside mare suggests that basaltic eruptions occur from multiple sources in each basin and/or that rootless eruptions are relatively common. Morphologies of small-area volcanic deposits indicate diversity in eruption behavior of lunar basaltic eruptions driven by magmatic volatiles. Finally, models of polar volatile behavior during impact-heating suggest that chemical alteration of minerals in the presence of liquid water is one possible outcome that was previously not thought possible on the Moon.
ContributorsStopar, Julie D (Author) / Robinson, Mark S. (Thesis advisor) / Bell, James (Committee member) / Christensen, Philip R. (Philip Russel) (Committee member) / Clarke, Amanda (Committee member) / Scowen, Paul (Committee member) / Arizona State University (Publisher)
Created2016