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Description
Soft polymer composites with improved thermal conductivity are needed for the thermal management of electronics. Interfacial thermal boundary resistance, however, prevents the efficient use of many high thermal conductivity fill materials. Magnetic alignment of ferrous fill material enforces percolation of the high thermal conductivity fill, thereby shifting the governing boundary

Soft polymer composites with improved thermal conductivity are needed for the thermal management of electronics. Interfacial thermal boundary resistance, however, prevents the efficient use of many high thermal conductivity fill materials. Magnetic alignment of ferrous fill material enforces percolation of the high thermal conductivity fill, thereby shifting the governing boundary resistance to the particle- particle interfaces and increasing the directional thermal conductivity of the polymer composite. Magnetic alignment maximizes the thermal conductivity while minimizing composite stiffening at a fill fraction of half the maximum packing factor. The directional thermal conductivity of the composite is improved by more than 2-fold. Particle-particle contact engineering is then introduced to decrease the particle- particle boundary resistance and further improve the thermal conductivity of the composite.

The interface between rigid fill particles is a point contact with very little interfacial area connecting them. Silver and gallium-based liquid metal (LM) coatings provide soft interfaces that, under pressure, increase the interfacial area between particles and decrease the particle-particle boundary resistance. These engineered contacts are investigated both in and out of the polymer matrix and with and without magnetic alignment of the fill. Magnetically aligned in the polymer matrix, 350nm- thick silver coatings on nickel particles produce a 1.8-fold increase in composite thermal conductivity over the aligned bare-nickel composites. The LM coatings provide similar enhancements, but require higher volumes of LM to do so. This is due to the rapid formation of gallium oxide, which introduces additional thermal boundaries and decreases the benefit of the LM coatings.

The oxide shell of LM droplets (LMDs) can be ruptured using pressure. The pressure needed to rupture LMDs matches closely to thin-walled pressure vessel theory. Furthermore, the addition of tungsten particles stabilizes the mixture for use at higher pressures. Finally, thiols and hydrochloric acid weaken the oxide shell and boost the thermal performance of the beds of LMDs by 50% at pressures much lower than 1 megapascal (MPa) to make them more suitable for use in TIMs.
ContributorsRalphs, Matthew (Author) / Rykaczewski, Konrad (Thesis advisor) / Wang, Robert Y (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Devasenathipathy, Shankar (Committee member) / Arizona State University (Publisher)
Created2019
Description
The traditional understanding of robotics includes mechanisms of rigid structures, which can manipulate surrounding objects, taking advantage of mechanical actuators such as motors and servomechanisms. Although these methods provide the underlying fundamental concepts behind much of modern technological infrastructure, in fields such as manufacturing, automation, and biomedical application, the robotic

The traditional understanding of robotics includes mechanisms of rigid structures, which can manipulate surrounding objects, taking advantage of mechanical actuators such as motors and servomechanisms. Although these methods provide the underlying fundamental concepts behind much of modern technological infrastructure, in fields such as manufacturing, automation, and biomedical application, the robotic structures formed by rigid axels on mechanical actuators lack the delicate differential sensors and actuators associated with known biological systems. The rigid structures of traditional robotics also inhibit the use of simple mechanisms in congested and/or fragile environments. By observing a variety of biological systems, it is shown that nature models its structures over millions of years of evolution into a combination of soft structures and rigid skeletal interior supports. Through technological bio-inspired designs, researchers hope to mimic some of the complex behaviors of biological mechanisms using pneumatic actuators coupled with highly compliant materials that exhibit relatively large reversible elastic strain. This paper begins the brief history of soft robotics, the various classifications of pneumatic fluid systems, the associated difficulties that arise with the unpredictable nature of fluid reactions, the methods of pneumatic actuators in use today, the current industrial applications of soft robotics, and focuses in large on the construction of a universally adaptable soft robotic gripper and material application tool. The central objective of this experiment is to compatibly pair traditional rigid robotics with the emerging technologies of sort robotic actuators. This will be done by combining a traditional rigid robotic arm with a soft robotic manipulator bladder for the purposes of object manipulation and excavation of extreme environments.
ContributorsShuster, Eden S. (Author) / Thanga, Jekan (Thesis director) / Asphaug, Erik (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
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Description
The energy crisis in the past decades has greatly boosted the search for alternatives to traditional fossil foils, and solar energy stands out as an important candidate due to its cleanness and abundance. However, the relatively low conversion efficiency and energy density strongly hinder the utilization of solar energy in

The energy crisis in the past decades has greatly boosted the search for alternatives to traditional fossil foils, and solar energy stands out as an important candidate due to its cleanness and abundance. However, the relatively low conversion efficiency and energy density strongly hinder the utilization of solar energy in wider applications. This thesis focuses on employing metamaterials and metafilms to enhance the conversion efficiency of solar thermal, solar thermophotovoltaic (STPV) and photovoltaic systems.

A selective metamaterial solar absorber is designed in this thesis to maximize the absorbed solar energy and minimize heat dissipation through thermal radiation. The theoretically designed metamaterial solar absorber exhibits absorptance higher than 95% in the solar spectrum but shows emittance less than 4% in the IR regime. This metamaterial solar absorber is further experimentally fabricated and optically characterized. Moreover, a metafilm selective absorber with stability up to 600oC is introduced, which exhibits solar absorptance higher than 90% and IR emittance less than 10%.

Solar thermophotovoltaic energy conversion enhanced by metamaterial absorbers and emitters is theoretically investigated in this thesis. The STPV system employing selective metamaterial absorber and emitter is investigated in this work, showing its conversion efficiency between 8% and 10% with concentration factor varying between 20 and 200. This conversion efficiency is remarkably enhanced compared with the conversion efficiency for STPV system employing black surfaces (<2.5%).

Moreover, plasmonic light trapping in ultra-thin solar cells employing concave grating nanostructures is discussed in this thesis. The plasmonic light trapping inside an ultrathin GaAs layer in the film-coupled metamaterial structure is numerically demonstrated. By exciting plasmonic resonances inside this structure, the short-circuit current density for the film-coupled metamaterial solar cell is three times the short-circuit current for a free-standing GaAs layer.

The dissertation is concluded by discussing about the future work on selective solar thermal absorbers, STPV/TPV systems and light trapping structures. Possibilities to design and fabricate solar thermal absorber with better thermal stability will be discussed, the experimental work of TPV system will be conducted, and the light trapping in organic and perovskite solar cells will be looked into.
ContributorsWang, Hao (Author) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Dai, Lenore (Committee member) / Rykaczewski, Konrad (Committee member) / Arizona State University (Publisher)
Created2016
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Description
“Smart” materials are used for a broad range of application including electronics, bio-medical devices, and smart clothing. This work focuses on development of smart self-sealing and breathable protective gear for soldiers against Chemical Weapon Agents (CWA). Specifically, the response of chemo-mechanical swelling polymer modified meshes to contact with stimuli droplets

“Smart” materials are used for a broad range of application including electronics, bio-medical devices, and smart clothing. This work focuses on development of smart self-sealing and breathable protective gear for soldiers against Chemical Weapon Agents (CWA). Specifically, the response of chemo-mechanical swelling polymer modified meshes to contact with stimuli droplets was studied. Theoretical discussion of the mechanism of smart materials is followed by development and experimental analysis of different modified mesh designs. A multi-physics model is proposed based on experimental data and the prototype of the fabric is tested in aerosol impingement conditions to confirm the barrier formed by rapid-self-sealing feature of the design.
ContributorsUppal, Aastha (Author) / Rykaczewski, Konrad (Thesis advisor) / Hildreth, Owen (Committee member) / Marvi, Hamidreza (Committee member) / Arizona State University (Publisher)
Created2016
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Description
It is well known that the geckos can cling to almost any surface using highly dense micro
ano fibrils found on the feet that rely on Van Der Waals forces to adhere. A few experimental and theoretical approaches have been taken to understand the adhesion mechanism of gecko feet. This work

It is well known that the geckos can cling to almost any surface using highly dense micro
ano fibrils found on the feet that rely on Van Der Waals forces to adhere. A few experimental and theoretical approaches have been taken to understand the adhesion mechanism of gecko feet. This work explains the building procedure of custom experimental setup to test the adhesion force over a temperature range and extends its application in space environment, potentially unsafe working condition.



This study demonstrates that these adhesive capable of switching adhesive properties not only at room environment but also over a temperature range of -160 degC to 120 degC in vacuum conditions. These conditions are similar to the condition experienced by a satellite in a space orbiting around the earth. Also, this study demonstrated various detachment and specimen patch preparation methods. The custom-made experimental setup for adhesion test can measure adhesion force in temperature and pressure controlled environment over specimen size of 1 sq. inch. A cryogenic cooling system with liquid nitrogen is used to achieve -160 degC and an electric resistive heating system are used to achieve 120 degC in controlled volume. Thermal electrodes, infrared thermopile detectors are used to record temperature at sample and pressure indicator to record vacuum condition in controlled volume. Reversibility of the switching behaviour of the specimen in controlled environment confirms its application in space and very high or very low-temperature conditions.

The experimental setup was developed using SolidWorks as a design tool, Ansys as simulation tool and the data acquisition utilizes LabVIEW available in the market today.
ContributorsMate, Sunil (Author) / Marvi, Hamidreza (Thesis advisor) / Rykaczewski, Konrad (Committee member) / Lee, Hyunglae (Committee member) / Arizona State University (Publisher)
Created2016
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Description
This paper details ink chemistries and processes to fabricate passive microfluidic devices using drop-on-demand printing of tetraethyl-orthosilicate (TEOS) inks. Parameters space investigation of the relationship between printed morphology and ink chemistries and printing parameters was conducted to demonstrate that morphology can be controlled by adjusting solvents selection, TEOS concentration,

This paper details ink chemistries and processes to fabricate passive microfluidic devices using drop-on-demand printing of tetraethyl-orthosilicate (TEOS) inks. Parameters space investigation of the relationship between printed morphology and ink chemistries and printing parameters was conducted to demonstrate that morphology can be controlled by adjusting solvents selection, TEOS concentration, substrate temperature, and hydrolysis time. Optical microscope and scanning electron microscope images were gathered to observe printed morphology and optical videos were taken to quantify the impact of morphology on fluid flow rates. The microscopy images show that by controlling the hydrolysis time of TEOS, dilution solvents and the printing temperature, dense or fracture structure can be obtained. Fracture structures are used as passive fluidic device due to strong capillary action in cracks. At last, flow rate of passive fluidic devices with different thickness printed at different temperatures are measured and compared. The result shows the flow rate increases with the increase of device width and thickness. By controlling the morphology and dimensions of printed structure, passive microfluidic devices with designed flow rate and low fluorescence background are able to be printed.
ContributorsHuang, Yiwen (Author) / Hildreth, Owen (Thesis advisor) / Wang, Robert (Committee member) / Rykaczewski, Konrad (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Analytical solution of the pressure field for water uptake through a composite root, coupled with fully saturated soil is derived by using the slender body approximation. It is shown that in general, the resistance of the root and soil are not additive. This result can play a very important role

Analytical solution of the pressure field for water uptake through a composite root, coupled with fully saturated soil is derived by using the slender body approximation. It is shown that in general, the resistance of the root and soil are not additive. This result can play a very important role in modelling water uptake through plant roots and determination of hydraulic resistances of plant roots. Optimum plant root structure that minimizes a single root’s hydraulic resistance is also studied in this work with the constraint of prescribed root volume. Hydraulic resistances under the slender body approximation and without such a limitation are considered. It is found that for large stele-to-cortex permeability ratio, there exists an optimum root length-to-base-radius ratio that minimizes the hydraulic resistance. A remarkable feature of the optimum root structure is that the optimum dimensionless stele conductivity depends only on a single geometrical parameter, the stele-to-root base-radius ratio. Once the stele-to-root base-radius ratio and the stele-to-cortex permeability ratio are given, the optimum root length-to-radius ratio can be found. While these findings remain to be verified by experiments for real plant roots, they offer theoretical guidance for the design of bio-inspired structures that minimizes hydraulic resistance for fluid production from porous media.
ContributorsChandrashekar, Sriram (Author) / Chen, Kang-Ping (Thesis advisor) / Huang, Huei-Ping (Committee member) / Rykaczewski, Konrad (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Durable, cost-effective, and environmentally friendly anti-icing methods are desired to reduce the icing hazard in many different industrial areas including transportation systems, power plants, power transmission, as well as offshore oil and gas production. In contrast to traditional passive anti-icing surfaces, this thesis work introduces an anti-icing coating that responds

Durable, cost-effective, and environmentally friendly anti-icing methods are desired to reduce the icing hazard in many different industrial areas including transportation systems, power plants, power transmission, as well as offshore oil and gas production. In contrast to traditional passive anti-icing surfaces, this thesis work introduces an anti-icing coating that responds to different icing conditions by releasing an antifreeze liquid. It consists of an outer porous superhydrophobic epidermis and a wick-like underlying dermis that is infused with the antifreeze liquid. This bi-layer coating prevents accumulation of frost, freezing fog, and freezing rain, while conventional anti-icing surfaces typically work only in one of these conditions. The bi-layer coating also delays condensation on the exterior surface at least ten times longer than identical system without antifreeze.

It is demonstrated that the significant delay in condensation onset is due to the integral humidity sink effect posed by the hygroscopic antifreeze liquid infused in the porous structure. This effect significantly alters the water vapor concentration field at the coating surface, which delays nucleation of drops and ice. It was demonstrated that with a proper design of the environmental chamber the size of the region of inhibited condensation and condensation frosting around an isolated pore, as well as periodically spaced pores, filled by propylene glycol can be quantitatively predicted from quasi-steady state water vapor concentration field. Theoretical analysis and experiments revealed that the inhibition of nucleation is governed by only two non-dimensional geometrical parameters: the pore size relative to the unit cell size and the ratio of the unit cell size to the thickness of the boundary layer. It is demonstrated that by switching the size of the pores from millimeters to nanometers, a dramatic depression of the nucleation onset temperature, as well as significantly greater delay in nucleation onset can be achieved.
ContributorsSun, Xiaoda (Author) / Rykaczewski, Konrad (Thesis advisor) / Lin, Jerry (Committee member) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Herrmann, Marcus (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2017
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Description
Many defense, healthcare, and energy applications can benefit from the development of surfaces that easily shed droplets of liquids of interest. Desired wetting properties are typically achieved via altering the surface chemistry or topography or both through surface engineering. Despite many recent advancements, materials modified only on their exterior are

Many defense, healthcare, and energy applications can benefit from the development of surfaces that easily shed droplets of liquids of interest. Desired wetting properties are typically achieved via altering the surface chemistry or topography or both through surface engineering. Despite many recent advancements, materials modified only on their exterior are still prone to physical degradation and lack durability. In contrast to surface engineering, this thesis focuses on altering the bulk composition and the interior of a material to tune how an exterior surface would interact with liquids. Fundamental and applied aspects of engineering of two material systems with low contact angle hysteresis (i.e. ability to easily shed droplets) are explained. First, water-shedding metal matrix hydrophobic nanoparticle composites with high thermal conductivity for steam condensation rate enhancement are discussed. Despite having static contact angle <90° (not hydrophobic), sustained dropwise steam condensation can be achieved at the exterior surface of the composite due to low contact angle hysteresis (CAH). In order to explain this observation, the effect of varying the length scale of surface wetting heterogeneity over three orders of magnitude on the value of CAH was experimentally investigated. This study revealed that the CAH value is primarily governed by the pinning length which in turn depends on the length scale of wetting heterogeneity. Modifying the heterogeneity size ultimately leads to near isotropic wettability for surfaces with highly anisotropic nanoscale chemical heterogeneities. Next, development of lubricant-swollen polymeric omniphobic protective gear for defense and healthcare applications is described. Specifically, it is shown that the robust and durable protective gear can be made from polymeric material fully saturated with lubricant that can shed all liquids irrespective of their surface tensions even after multiple contact incidences with the foreign objects. Further, a couple of schemes are proposed to improve the rate of lubrication and replenishment of lubricant as well as reduce the total amount of lubricant required in making the polymeric protective gear omniphobic. Overall, this research aims to understand the underlying physics of dynamic surface-liquid interaction and provides simple scalable route to fabricate better materials for condensers and omniphobic protective gear.
ContributorsDamle, Viraj (Author) / Rykaczewski, Konrad (Thesis advisor) / Phelan, Patrick (Committee member) / Lin, Jerry (Committee member) / Herrmann, Marcus (Committee member) / Wang, Robert (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2017
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Description
In convective heat transfer processes, heat transfer rate increases generally with a large fluid velocity, which leads to complex flow patterns. However, numerically analyzing the complex transport process and conjugated heat transfer requires extensive time and computing resources. Recently, data-driven approach has risen as an alternative method to solve physical

In convective heat transfer processes, heat transfer rate increases generally with a large fluid velocity, which leads to complex flow patterns. However, numerically analyzing the complex transport process and conjugated heat transfer requires extensive time and computing resources. Recently, data-driven approach has risen as an alternative method to solve physical problems in a computational efficient manner without necessitating the iterative computations of the governing physical equations. However, the research on data-driven approach for convective heat transfer is still in nascent stage. This study aims to introduce data-driven approaches for modeling heat and mass convection phenomena. As the first step, this research explores a deep learning approach for modeling the internal forced convection heat transfer problems. Conditional generative adversarial networks (cGAN) are trained to predict the solution based on a graphical input describing fluid channel geometries and initial flow conditions. A trained cGAN model rapidly approximates the flow temperature, Nusselt number (Nu) and friction factor (f) of a flow in a heated channel over Reynolds number (Re) ranging from 100 to 27750. The optimized cGAN model exhibited an accuracy up to 97.6% when predicting the local distributions of Nu and f. Next, this research introduces a deep learning based surrogate model for three-dimensional (3D) transient mixed convention in a horizontal channel with a heated bottom surface. Conditional generative adversarial networks (cGAN) are trained to approximate the temperature maps at arbitrary channel locations and time steps. The model is developed for a mixed convection occurring at the Re of 100, Rayleigh number of 3.9E6, and Richardson number of 88.8. The cGAN with the PatchGAN based classifier without the strided convolutions infers the temperature map with the best clarity and accuracy. Finally, this study investigates how machine learning analyzes the mass transfer in 3D printed fluidic devices. Random forests algorithm is hired to classify the flow images taken from semi-transparent 3D printed tubes. Particularly, this work focuses on laminar-turbulent transition process occurring in a 3D wavy tube and a straight tube visualized by dye injection. The machine learning model automatically classifies experimentally obtained flow images with an accuracy > 0.95.
ContributorsKang, Munku (Author) / Kwon, Beomjin (Thesis advisor) / Phelan, Patrick (Committee member) / Ren, Yi (Committee member) / Rykaczewski, Konrad (Committee member) / Sohn, SungMin (Committee member) / Arizona State University (Publisher)
Created2022