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Many defense, healthcare, and energy applications can benefit from the development of surfaces that easily shed droplets of liquids of interest. Desired wetting properties are typically achieved via altering the surface chemistry or topography or both through surface engineering. Despite many recent advancements, materials modified only on their exterior are

Many defense, healthcare, and energy applications can benefit from the development of surfaces that easily shed droplets of liquids of interest. Desired wetting properties are typically achieved via altering the surface chemistry or topography or both through surface engineering. Despite many recent advancements, materials modified only on their exterior are still prone to physical degradation and lack durability. In contrast to surface engineering, this thesis focuses on altering the bulk composition and the interior of a material to tune how an exterior surface would interact with liquids. Fundamental and applied aspects of engineering of two material systems with low contact angle hysteresis (i.e. ability to easily shed droplets) are explained. First, water-shedding metal matrix hydrophobic nanoparticle composites with high thermal conductivity for steam condensation rate enhancement are discussed. Despite having static contact angle <90° (not hydrophobic), sustained dropwise steam condensation can be achieved at the exterior surface of the composite due to low contact angle hysteresis (CAH). In order to explain this observation, the effect of varying the length scale of surface wetting heterogeneity over three orders of magnitude on the value of CAH was experimentally investigated. This study revealed that the CAH value is primarily governed by the pinning length which in turn depends on the length scale of wetting heterogeneity. Modifying the heterogeneity size ultimately leads to near isotropic wettability for surfaces with highly anisotropic nanoscale chemical heterogeneities. Next, development of lubricant-swollen polymeric omniphobic protective gear for defense and healthcare applications is described. Specifically, it is shown that the robust and durable protective gear can be made from polymeric material fully saturated with lubricant that can shed all liquids irrespective of their surface tensions even after multiple contact incidences with the foreign objects. Further, a couple of schemes are proposed to improve the rate of lubrication and replenishment of lubricant as well as reduce the total amount of lubricant required in making the polymeric protective gear omniphobic. Overall, this research aims to understand the underlying physics of dynamic surface-liquid interaction and provides simple scalable route to fabricate better materials for condensers and omniphobic protective gear.
ContributorsDamle, Viraj (Author) / Rykaczewski, Konrad (Thesis advisor) / Phelan, Patrick (Committee member) / Lin, Jerry (Committee member) / Herrmann, Marcus (Committee member) / Wang, Robert (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2017
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Description
Passive flow control achieved by surface dimpling can be an effective strategy for reducing drag around bluff bodies - an example of substantial popular interest being the flow around a golf ball. While the general effect of dimples causing a delay of boundary layer separation is well known, the mechanisms

Passive flow control achieved by surface dimpling can be an effective strategy for reducing drag around bluff bodies - an example of substantial popular interest being the flow around a golf ball. While the general effect of dimples causing a delay of boundary layer separation is well known, the mechanisms contributing to this phenomena are subtle and not thoroughly understood. Numerical models offer a powerful approach for studying drag reduction, however simulation strategies are challenged by complex geometries, and in applications the introduction of ad hoc turbulence models which introduce additional uncertainty. These and other factors provide much of the motivation for the current study, which focused on the numerical simulations of the flow over a simplified configuration consisting of a dimpled flat plate. The principal goals of the work are to understand the performance of the numerical methodology, and gain insight into the underlying physics of the flow. Direct numerical simulation of the incompressible Navier-Stokes equations using a fractional step method was employed, with the dimpled flat plate represented using an immersed boundary method. The dimple geometry utilizes a fixed dimple aspect ratio, with dimples arranged in a single spanwise row. The grid sizes considered ranged from approximately 3 to 99 million grid points. Reynolds numbers of 3000 and 4000 based on the inlet laminar boundary layer thickness were simulated. A turbulent boundary layer was induced downstream of the dimples for Reynolds numbers which did not transition for the flow over an undimpled flat plate. First and second order statistics of the boundary layer that develops agree reasonably well with those for turbulent channel flow and flat plate boundary layers in the sublayer and buffer layers, but differ in the outer layer. Inspection of flow visualizations suggest that early transition is promoted by thinning of the boundary layer, initiation of shear layer instabilities over the dimples, flow separation and reattachment, and tripping of the boundary layer at the trailing edge of the dimples.
ContributorsMode, Jeffrey Michael (Author) / Squires, Kyle (Thesis advisor) / Herrmann, Marcus (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2010
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Description
Computing the fluid phase interfaces in multiphase flow is a challenging area of research in fluids. The Volume of Fluid andLevel Set methods are a few algorithms that have been developed for reconstructing the multiphase fluid flow interfaces. The thesis work focuses on exploring the ability of neural networks to reconstruct

Computing the fluid phase interfaces in multiphase flow is a challenging area of research in fluids. The Volume of Fluid andLevel Set methods are a few algorithms that have been developed for reconstructing the multiphase fluid flow interfaces. The thesis work focuses on exploring the ability of neural networks to reconstruct the multiphase fluid flow interfaces using a data-driven approach. The neural network model has liquid volume fraction stencils as an input, and it predicts the radius of the circle as an output of the network which represents a phase interface separating two immiscible fluids inside a fluid domain. The liquid volume fraction stencils are generated for randomly varying circle radii within a 1x1 domain using an open-source VOFI library. These datasets are used to train the neural network. Once the model is trained, the predicted circular phase interface from the neural network output is used to generate back the predicted liquid volume fraction stencils. Error norms values are calculated to assess the error in the neural network model’s predicted liquid volume fraction stencils with the actual liquid volume fraction stencils from the VOFI library. The neural network parameters are optimized by testing them for different hyper-parameters to reduce the error norms. So as to minimize the difference between the predicted and the actual liquid volume fraction stencils and errors in reconstructing the fluid phase interface geometry.
ContributorsPawar, Pranav Rajesh (Author) / Herrmann, Marcus (Thesis advisor) / Zhuang, Houlong (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Owing to the surge in development of endovascular devices such as coils and flow diverter stents, doctors are inclined to approach surgical cases non-invasively more often than before. Treating brain aneurysms as a bulging of a weakened area of a blood vessel is no exception. Therefore, promoting techniques that can

Owing to the surge in development of endovascular devices such as coils and flow diverter stents, doctors are inclined to approach surgical cases non-invasively more often than before. Treating brain aneurysms as a bulging of a weakened area of a blood vessel is no exception. Therefore, promoting techniques that can help surgeons have a better idea of treatment outcomes are of invaluable importance.

In order to investigate the effects of these devices on intra-aneurysmal hemodynamics, the conventional computational fluid dynamics (CFD) approach uses the explicit geometry of the device within an aneurysm and discretizes the fluid domain to solve the Navier-Stokes equations. However, since the devices are made of small struts, the number of mesh elements in the boundary layer region would be considerable. This cumbersome task led to the implementation of the porous medium assumption. In this approach, the explicit geometry of the device is eliminated, and relevant porous medium assumptions are applied. Unfortunately, as it will be shown in this research, some of the porous medium approaches used in the literature are over-simplified. For example, considering the porous domain to be homogeneous is one major drawback which leads to significant errors in capturing the intra-aneurysmal flow features. Specifically, since the devices must comply with the complex geometry of an aneurysm, the homogeneity assumption is not valid.

In this research, a novel heterogeneous porous medium approach is introduced. This results in a substantial reduction in the total number of mesh elements required to discretize the flow domain while not sacrificing the accuracy of the method by over-simplifying the utilized assumptions.
ContributorsYadollahi Farsani, Hooman (Author) / Herrmann, Marcus (Thesis advisor) / Frakes, David (Thesis advisor) / Chong, Brian (Committee member) / Peet, Yulia (Committee member) / Oswald, Jay (Committee member) / Arizona State University (Publisher)
Created2018
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Description
In this dissertation, two types of passive air freshener products from Henkel, the wick-based air freshener and gel-based air freshener, are studied for their wicking mechanisms and evaporation performances.The fibrous pad of the wick-based air freshener is a porous medium that absorbs fragrance by capillary force and releases the fragrance

In this dissertation, two types of passive air freshener products from Henkel, the wick-based air freshener and gel-based air freshener, are studied for their wicking mechanisms and evaporation performances.The fibrous pad of the wick-based air freshener is a porous medium that absorbs fragrance by capillary force and releases the fragrance into the ambient air. To investigate the wicking process, a two-dimensional multiphase flow numerical model using COMSOL Multiphysics is built. Saturation and liquid pressure inside the pad are solved. Comparison between the simulation results and experiments shows that evaporation occurs simultaneously with the wicking process. The evaporation performance on the surface of the wicking pad is analyzed based on the kinetic theory, from which the mass flow rate of molecules passing the interface of each pore of the porous medium is obtained. A 3D model coupling the evaporation model and dynamic wicking on the evaporation pad is built to simulate the entire performance of the air freshener to the environment for a long period of time. Diffusion and natural convection effects are included in the simulation. The simulation results match well with the experiments for both the air fresheners placed in a chamber and in the absent of a chamber, the latter of which is subject to indoor airflow. The gel-based air freshener can be constructed as a porous medium in which the solid network of particles spans the volume of the fragrance liquid. To predict the evaporation performance of the gel, two approaches are tested for gel samples in hemispheric shape. The first approach is the sessile drop model commonly used for the drying process of a pure liquid droplet. It can be used to estimate the weight loss rate and time duration of the evaporation. Another approach is to simulate the concentration profile outside the gel and estimate the evaporation rate from the surface of the gel using the kinetic theory. The evaporation area is updated based on the change of pore size. A 3D simulation using the same analysis is further applied to the cylindrical gel sample. The simulation results match the experimental data well.
ContributorsYuan, Jing (Author) / Chen, Kangping (Thesis advisor) / Herrmann, Marcus (Committee member) / Huang, Huei-Ping (Committee member) / Wang, Liping (Committee member) / Jiao, Yang (Committee member) / Arizona State University (Publisher)
Created2021
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Description
Spray flows are important in a myriad of practical applications including fuel injection, ink-jet printing, agricultural sprays, and industrial processes. Two-phase sprays find particular use for spot cooling applications with high heat fluxes as in casting processes and power electronics. Computability of sprays in a cost-effective manner provides a path

Spray flows are important in a myriad of practical applications including fuel injection, ink-jet printing, agricultural sprays, and industrial processes. Two-phase sprays find particular use for spot cooling applications with high heat fluxes as in casting processes and power electronics. Computability of sprays in a cost-effective manner provides a path to optimize the design of nozzles to tune the spray characteristics for the needs of a particular application. Significant research has so far been devoted to understand and characterize spray flows better, be it from a theoretical, experimental or computational standpoint. The current thesis discusses a methodology for modeling primary atomization using the Quadratic Formula which is derived from an integral formulation of the governing equations. The framework is then applied to different examples of flat-fan hydraulic sprays. For each case, the spray is first resolved as a continuous fluid using the volume of fluid method. Atomization criterion is then applied to the velocity flow-field to determine the sites for primary atomization. At each site, local diameters for particle injection is determined using the quadratic formula. The trajectory of injected particles are then monitored through a particle tracking algorithm. The results from the numerical analysis are compared with experimental data to validate the computational framework.
ContributorsBhardwaj, Angshuman (Author) / Lee, T.-W. (Thesis advisor) / Herrmann, Marcus (Committee member) / Rykaczewski, Konrad (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Contact angle goniometer is one of the most common tools in surfaces science. Since the introduction of this instrument by Fox and Zisman1 in 1950, dispensing the liquid using a syringe has generated pendant drops. However, using such approach at conditions significantly deviating from standard pressure and temperature would

Contact angle goniometer is one of the most common tools in surfaces science. Since the introduction of this instrument by Fox and Zisman1 in 1950, dispensing the liquid using a syringe has generated pendant drops. However, using such approach at conditions significantly deviating from standard pressure and temperature would require an elaborate and costly fluidic system. To this end, this thesis work introduces alternative design of a goniometer capable of contact angle measurement at wide pressure and temperature range. In this design, pendant droplets are not dispensed through a pipette but are generated through localized condensation on a tip of a preferentially cooled small metal wire encapsulated within a thick thermal insulator layer. This thesis work covers experimental study of the relation between the geometry of the condensation-based pendant drop generator geometry and subcooling, and growth rate of drops of representative high (water) and low (pentane) surface tension liquids. Several routes that the generated pendant drops can be used to measure static and dynamic contact angles of the two liquids on common substrates well as nanoengineered superhydrophobic and omniphobic surfaces are demonstrated.
ContributorsMohan, Ajay Roopesh (Author) / Rykaczewski, Konrad (Thesis advisor) / Herrmann, Marcus (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Deformable heat exchangers could provide a multitude of previously untapped advantages ranging from adaptable performance via macroscale, dynamic shape change (akin to dilation/constriction seen in blood vessels) to enhanced heat transfer at thermal interfaces through microscale, surface deformations. So far, making deformable, ‘soft heat exchangers’ (SHXs) has been limited by

Deformable heat exchangers could provide a multitude of previously untapped advantages ranging from adaptable performance via macroscale, dynamic shape change (akin to dilation/constriction seen in blood vessels) to enhanced heat transfer at thermal interfaces through microscale, surface deformations. So far, making deformable, ‘soft heat exchangers’ (SHXs) has been limited by the low thermal conductivity of materials with suitable mechanical properties. The recent introduction of liquid-metal embedded elastomers by Bartlett et al1 has addressed this need. Specifically, by remaining soft and stretchable despite the addition of filler, these thermally conductive composites provide an ideal material for the new class of “soft thermal systems”, which is introduced in this work. Understanding such thermal systems will be a key element in enabling technology that require high levels of stretchability, such as thermoregulatory garments, soft electronics, wearable electronics, and high-powered robotics. Shape change inherent to SHX operation has the potential to violate many conventional assumptions used in HX design and thus requires the development of new theoretical approaches to predict performance. To create a basis for understanding these devices, this work highlights two sequential studies. First, the effects of transitioning to a surface deformable, SHX under steady state static conditions in the setting of a liquid cooling device for thermoregulation, electronics and robotics applications was explored. In this study, a thermomechanical model was built and validated to predict the thermal performance and a system wide analysis to optimize such devices was carried out. Second, from a more fundamental perspective, the effects of SHXs undergoing transient shape deformation during operation was explored. A phase shift phenomenon in cooling performance dependent on stretch rate, stretch extent and thermal diffusivity was discovered and explained. With the use of a time scale analysis, the extent of quasi-static assumption viability in modeling such systems was quantified and multiple shape modulation regime limits were defined. Finally, nuance considerations and future work of using liquid metal-silicone composites in SHXs were discussed.
ContributorsKotagama, Praveen (Author) / Rykaczewski, Konrad (Thesis advisor) / Wang, Robert (Committee member) / Phelan, Patrick (Committee member) / Herrmann, Marcus (Committee member) / Green, Matthew (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Gas Dynamic Virtual Nozzles (GDVN) produce microscopic flow-focused liquid jets and are widely used for sample delivery in serial femtosecond crystallography (SFX) and time-resolved solution scattering. Recently, 2-photon polymerization (2PP) made it possible to produce 3D-printed GDVNs with submicron printing resolution. Comparing with hand- fabricated nozzles, reproducibility, and less developing

Gas Dynamic Virtual Nozzles (GDVN) produce microscopic flow-focused liquid jets and are widely used for sample delivery in serial femtosecond crystallography (SFX) and time-resolved solution scattering. Recently, 2-photon polymerization (2PP) made it possible to produce 3D-printed GDVNs with submicron printing resolution. Comparing with hand- fabricated nozzles, reproducibility, and less developing effort, and similarity of the performance of different 3D printed nozzles are among the advantages of using 3D printing techniques to develop GDVN’s. Submicron printing resolution also makes it possible to easily improve GDVN performance by optimizing the design of nozzles. In this study, 3D printed nozzles were developed to achieve low liquid and gas flow rates and high liquid jet velocities. A double-pulsed nanosecond laser imaging system was used to perform Particle Tracking Velocimetry (PTV) in order to determine jet velocities and assess jet stability/reproducibility. The testing results of pure water jets focused with He sheath gas showed that some designs can easily achieve stable liquid jets with velocities of more than 80 m/s, with pure water flowing at 3 microliters/min, and helium sheath gas flowing at less than 5 mg/min respectively. A numerical simulation pipeline was also used to characterize the performance of different 3D printed GDVNs. The results highlight the potential of making reproducible GDVNs with minimum fabrication effort, that can meet the requirements of present and future SFX and time-resolved solution scattering research.
ContributorsNazari, Reza (Author) / Adrian, Ronald (Thesis advisor) / Kirian, Richard (Thesis advisor) / Herrmann, Marcus (Committee member) / Phelan, Patrick (Committee member) / Weierstall, Uwe (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Compressible fluid flows involving multiple physical states of matter occur in both nature and technical applications such as underwater explosions and implosions, cavitation-induced bubble collapse in naval applications and Richtmyer-Meshkov type instabilities in inertial confinement fusion. Of particular interest is the atomization of fuels that enable shock-induced mixing of fuel

Compressible fluid flows involving multiple physical states of matter occur in both nature and technical applications such as underwater explosions and implosions, cavitation-induced bubble collapse in naval applications and Richtmyer-Meshkov type instabilities in inertial confinement fusion. Of particular interest is the atomization of fuels that enable shock-induced mixing of fuel and oxidizer in supersonic combustors. Due to low residence times and varying length scales, providing insight through physical experiments is both technically challenging and sometimes unfeasible. Numerical simulations can help provide detailed insight and aid in the engineering design of devices that can harness these physical phenomena.

In this research, computational methods were developed to accurately simulate phase interfaces in compressible fluid flows with a focus on targeting primary atomization. Novel numerical methods which treat the phase interface as a discontinuity, and as a smeared region were developed using low-dissipation, high-order schemes. The resulting methods account for the effects of compressibility, surface tension and viscosity. To aid with the varying length scales and high-resolution requirements found in atomization applications, an adaptive mesh refinement (AMR) framework is used to provide high-resolution only in regions of interest. The developed methods were verified with test cases involving strong shocks, high density ratios, surface tension effects and jumps in the equations of state, in one-, two- and three dimensions, obtaining good agreement with theoretical and experimental results. An application case of the primary atomization of a liquid jet injected into a Mach 2 supersonic crossflow of air is performed with the methods developed.
ContributorsKannan, Karthik (Author) / Herrmann, Marcus (Thesis advisor) / Huang, Huei-Ping (Committee member) / Lopez, Juan (Committee member) / Peet, Yulia (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2020