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- All Subjects: Mechanical Engineering
- All Subjects: Gas-turbine disks
- Creators: Solanki, Kiran
Description
Recently, the use of zinc oxide (ZnO) nanowires as an interphase in composite materials has been demonstrated to increase the interfacial shear strength between carbon fiber and an epoxy matrix. In this research work, the strong adhesion between ZnO and carbon fiber is investigated to elucidate the interactions at the interface that result in high interfacial strength. First, molecular dynamics (MD) simulations are performed to calculate the adhesive energy between bare carbon and ZnO. Since the carbon fiber surface has oxygen functional groups, these were modeled and MD simulations showed the preference of ketones to strongly interact with ZnO, however, this was not observed in the case of hydroxyls and carboxylic acid. It was also found that the ketone molecules ability to change orientation facilitated the interactions with the ZnO surface. Experimentally, the atomic force microscope (AFM) was used to measure the adhesive energy between ZnO and carbon through a liftoff test by employing highly oriented pyrolytic graphite (HOPG) substrate and a ZnO covered AFM tip. Oxygen functionalization of the HOPG surface shows the increase of adhesive energy. Additionally, the surface of ZnO was modified to hold a negative charge, which demonstrated an increase in the adhesive energy. This increase in adhesion resulted from increased induction forces given the relatively high polarizability of HOPG and the preservation of the charge on ZnO surface. It was found that the additional negative charge can be preserved on the ZnO surface because there is an energy barrier since carbon and ZnO form a Schottky contact. Other materials with the same ionic properties of ZnO but with higher polarizability also demonstrated good adhesion to carbon. This result substantiates that their induced interaction can be facilitated not only by the polarizability of carbon but by any of the materials at the interface. The versatility to modify the magnitude of the induced interaction between carbon and an ionic material provides a new route to create interfaces with controlled interfacial strength.
ContributorsGalan Vera, Magdian Ulises (Author) / Sodano, Henry A (Thesis advisor) / Jiang, Hanqing (Committee member) / Solanki, Kiran (Committee member) / Oswald, Jay (Committee member) / Speyer, Gil (Committee member) / Arizona State University (Publisher)
Created2013
Description
Derived from the necessity to increase testing capabilities of hybrid rocket motor (HRM) propulsion systems for Daedalus Astronautics at Arizona State University, a small-scale motor and test stand were designed and developed to characterize all components of the system. The motor is designed for simple integration and setup, such that both the forward-end enclosure and end cap can be easily removed for rapid integration of components during testing. Each of the components of the motor is removable allowing for a broad range of testing capabilities. While examining injectors and their potential it is thought ideal to obtain the highest regression rates and overall motor performance possible. The oxidizer and fuel are N2O and hydroxyl-terminated polybutadiene (HTPB), respectively, due to previous experience and simplicity. The injector designs, selected for the same reasons, are designed such that they vary only in the swirl angle. This system provides the platform for characterizing the effects of varying said swirl angle on HRM performance.
ContributorsSummers, Matt H (Author) / Lee, Taewoo (Thesis advisor) / Chen, Kangping (Committee member) / Wells, Valana (Committee member) / Arizona State University (Publisher)
Created2013
Description
Ingestion of high temperature mainstream gas into the rotor-stator cavities of a gas turbine is one of the major problems faced by the turbine designers. The ingested gas heats up rotor disks and induces higher thermal stresses on them, giving rise to durability concern. Ingestion is usually reduced by installing seals on the rotor and stator rims and by purging the disk cavity by secondary air bled from the compressor discharge. The geometry of the rim seals and the secondary air flow rate, together, influence the amount of gas that gets ingested into the cavities. Since the amount of secondary air bled off has a negative effect on the gas turbine thermal efficiency, one goal is to use the least possible amount of secondary air. This requires a good understanding of the flow and ingestion fields within a disk cavity. In the present study, the mainstream gas ingestion phenomenon has been experimentally studied in a model single-stage axial flow gas turbine. The turbine stage featured vanes and blades, and rim seals on both the rotor and stator. Additionally, the disk cavity contained a labyrinth seal radially inboard which effectively divided the cavity into a rim cavity and an inner cavity. Time-average static pressure measurements were obtained at various radial positions within the disk cavity, and in the mainstream gas path at three axial locations at the outer shroud spread circumferentially over two vane pitches. The time-average static pressure in the main gas path exhibited a periodic asymmetry following the vane pitch whose amplitude diminished with increasing distance from the vane trailing edge. The static pressure distribution increased with the secondary air flow rate within the inner cavity but was found to be almost independent of it in the rim cavity. Tracer gas (CO2) concentration measurements were conducted to determine the sealing effectiveness of the rim seals against main gas ingestion. For the rim cavity, the sealing effectiveness increased with the secondary air flow rate. Within the inner cavity however, this trend reversed -this may have been due to the presence of rotating low-pressure flow structures inboard of the labyrinth seal.
ContributorsThiagarajan, Jayanth kumar (Author) / Roy, Ramendra P (Thesis advisor) / Lee, Taewoo (Committee member) / Mignolet, Marc (Committee member) / Arizona State University (Publisher)
Created2013
Description
Modern day gas turbine designers face the problem of hot mainstream gas ingestion into rotor-stator disk cavities. To counter this ingestion, seals are installed on the rotor and stator disk rims and purge air, bled off from the compressor, is injected into the cavities. It is desirable to reduce the supply of purge air as this decreases the net power output as well as efficiency of the gas turbine. Since the purge air influences the disk cavity flow field and effectively the amount of ingestion, the aim of this work was to study the cavity velocity field experimentally using Particle Image Velocimetry (PIV). Experiments were carried out in a model single-stage axial flow turbine set-up that featured blades as well as vanes, with purge air supplied at the hub of the rotor-stator disk cavity. Along with the rotor and stator rim seals, an inner labyrinth seal was provided which split the disk cavity into a rim cavity and an inner cavity. First, static gage pressure distribution was measured to ensure that nominally steady flow conditions had been achieved. The PIV experiments were then performed to map the velocity field on the radial-tangential plane within the rim cavity at four axial locations. Instantaneous velocity maps obtained by PIV were analyzed sector-by-sector to understand the rim cavity flow field. It was observed that the tangential velocity dominated the cavity flow at low purge air flow rate, its dominance decreasing with increase in the purge air flow rate. Radially inboard of the rim cavity, negative radial velocity near the stator surface and positive radial velocity near the rotor surface indicated the presence of a recirculation region in the cavity whose radial extent increased with increase in the purge air flow rate. Qualitative flow streamline patterns are plotted within the rim cavity for different experimental conditions by combining the PIV map information with ingestion measurements within the cavity as reported in Thiagarajan (2013).
ContributorsPathak, Parag (Author) / Roy, Ramendra P (Thesis advisor) / Calhoun, Ronald (Committee member) / Lee, Taewoo (Committee member) / Arizona State University (Publisher)
Created2013
Description
Aluminum alloys and their composites are attractive materials for applications requiring high strength-to-weight ratios and reasonable cost. Many of these applications, such as those in the aerospace industry, undergo fatigue loading. An understanding of the microstructural damage that occurs in these materials is critical in assessing their fatigue resistance. Two distinct experimental studies were performed to further the understanding of fatigue damage mechanisms in aluminum alloys and their composites, specifically fracture and plasticity. Fatigue resistance of metal matrix composites (MMCs) depends on many aspects of composite microstructure. Fatigue crack growth behavior is particularly dependent on the reinforcement characteristics and matrix microstructure. The goal of this work was to obtain a fundamental understanding of fatigue crack growth behavior in SiC particle-reinforced 2080 Al alloy composites. In situ X-ray synchrotron tomography was performed on two samples at low (R=0.1) and at high (R=0.6) R-ratios. The resulting reconstructed images were used to obtain three-dimensional (3D) rendering of the particles and fatigue crack. Behaviors of the particles and crack, as well as their interaction, were analyzed and quantified. Four-dimensional (4D) visual representations were constructed to aid in the overall understanding of damage evolution. During fatigue crack growth in ductile materials, a plastic zone is created in the region surrounding the crack tip. Knowledge of the plastic zone is important for the understanding of fatigue crack formation as well as subsequent growth behavior. The goal of this work was to quantify the 3D size and shape of the plastic zone in 7075 Al alloys. X-ray synchrotron tomography and Laue microdiffraction were used to non-destructively characterize the volume surrounding a fatigue crack tip. The precise 3D crack profile was segmented from the reconstructed tomography data. Depth-resolved Laue patterns were obtained using differential-aperture X-ray structural microscopy (DAXM), from which peak-broadening characteristics were quantified. Plasticity, as determined by the broadening of diffracted peaks, was mapped in 3D. Two-dimensional (2D) maps of plasticity were directly compared to the corresponding tomography slices. A 3D representation of the plastic zone surrounding the fatigue crack was generated by superimposing the mapped plasticity on the 3D crack profile.
ContributorsHruby, Peter (Author) / Chawla, Nikhilesh (Thesis advisor) / Solanki, Kiran (Committee member) / Liu, Yongming (Committee member) / Arizona State University (Publisher)
Created2014
Description
In order to achieve higher gas turbine efficiency, the main gas temperature at turbine inlet has been steadily increased from approximately 900°C to about 1500°C over the last few decades. This temperature is higher than the maximum acceptable temperature for turbine internals. The hot main gas may get ingested into the space between rotor and stator, the rotor-stator disk cavity in a stage because of the pressure differential between main gas annulus and the disk cavity. To reduce this ingestion, the disk cavity is equipped with a rim seal; additionally, secondary (purge) air is supplied to the cavity. Since the purge air is typically bled off the compressor discharge, this reducing the overall gas turbine efficiency, much research has been carried out to estimate the minimum purge flow necessary (cw,min) for complete sealing of disk cavities.
In this work, experiments have been performed in a subscale single-stage axial turbine featuring vanes, blades and an axially-overlapping radial-clearance seal at the disk cavity rim. The turbine stage is also equipped with a labyrinth seal radially inboard. The stage geometry and the experimental conditions were such that the ingestion into the disk cavity was driven by the pressure asymmetry in the main gas annulus. In the experiments, time-averaged static pressure was measured at several locations in the main annulus and in the disk cavity; the pressure differential between a location on the vane platform close to lip (this being the rim seal part on the stator) and a location in the 'seal region' in the cavity is considered to be the driving potential for both ingestion and egress. Time-averaged volumetric concentration of the tracer gas (CO2) in the purge air supplied was measured at multiple radial locations on the stator surface. The pressure and ingestion data were then used to calculate the ingestion and egress discharge coefficients for a range of purge flow rates, employing a simple orifice model of the rim seal. For the experiments performed, the egress discharge coefficient increased and the ingestion discharge coefficient decreased with the purge air flow rate. A method for estimation of cw,min is also proposed.
In this work, experiments have been performed in a subscale single-stage axial turbine featuring vanes, blades and an axially-overlapping radial-clearance seal at the disk cavity rim. The turbine stage is also equipped with a labyrinth seal radially inboard. The stage geometry and the experimental conditions were such that the ingestion into the disk cavity was driven by the pressure asymmetry in the main gas annulus. In the experiments, time-averaged static pressure was measured at several locations in the main annulus and in the disk cavity; the pressure differential between a location on the vane platform close to lip (this being the rim seal part on the stator) and a location in the 'seal region' in the cavity is considered to be the driving potential for both ingestion and egress. Time-averaged volumetric concentration of the tracer gas (CO2) in the purge air supplied was measured at multiple radial locations on the stator surface. The pressure and ingestion data were then used to calculate the ingestion and egress discharge coefficients for a range of purge flow rates, employing a simple orifice model of the rim seal. For the experiments performed, the egress discharge coefficient increased and the ingestion discharge coefficient decreased with the purge air flow rate. A method for estimation of cw,min is also proposed.
ContributorsSingh, Prashant (Author) / Roy, Ramendra P (Thesis advisor) / Mignolet, Marc (Thesis advisor) / Lee, Taewoo (Committee member) / Arizona State University (Publisher)
Created2014
Description
Fission products in nuclear fuel pellets can affect fuel performance as they change the fuel chemistry and structure. The behavior of the fission products and their release mechanisms are important to the operation of a power reactor. Research has shown that fission product release can occur through grain boundary (GB) at low burnups. Early fission gas release models, which assumed spherical grains with no effect of GB diffusion, did not capture the early stage of the release behavior well. In order to understand the phenomenon at low burnup and how it leads to the later release mechanism, a microstructurally explicit model is needed. This dissertation conducted finite element simulations of the transport behavior using 3-D microstructurally explicit models. It looks into the effects of GB character, with emphases on conditions that can lead to enhanced effective diffusion. Moreover, the relationship between temperature and fission product transport is coupled to reflect the high temperature environment.
The modeling work began with 3-D microstructure reconstruction for three uranium oxide samples with different oxygen stoichiometry: UO2.00 UO2.06 and UO2.14. The 3-D models were created based on the real microstructure of depleted UO2 samples characterized by Electron Backscattering Diffraction (EBSD) combined with serial sectioning. Mathematical equations on fission gas diffusion and heat conduction were studied and derived to simulate the fission gas transport under GB effect. Verification models showed that 2-D elements can be used to model GBs to reduce the number of elements. The effect of each variable, including fuel stoichiometry, temperature, GB diffusion, triple junction diffusion and GB thermal resistance, is verified, and they are coupled in multi-physics simulations to study the transport of fission gas at different radial location of a fuel pellet. It was demonstrated that the microstructural model can be used to incorporate the effect of different physics to study fission gas transport. The results suggested that the GB effect is the most significant at the edge of fuel pellet where the temperature is the lowest. In the high temperature region, the increase in bulk diffusivity due to excess oxygen diminished the effect of GB diffusion.
The modeling work began with 3-D microstructure reconstruction for three uranium oxide samples with different oxygen stoichiometry: UO2.00 UO2.06 and UO2.14. The 3-D models were created based on the real microstructure of depleted UO2 samples characterized by Electron Backscattering Diffraction (EBSD) combined with serial sectioning. Mathematical equations on fission gas diffusion and heat conduction were studied and derived to simulate the fission gas transport under GB effect. Verification models showed that 2-D elements can be used to model GBs to reduce the number of elements. The effect of each variable, including fuel stoichiometry, temperature, GB diffusion, triple junction diffusion and GB thermal resistance, is verified, and they are coupled in multi-physics simulations to study the transport of fission gas at different radial location of a fuel pellet. It was demonstrated that the microstructural model can be used to incorporate the effect of different physics to study fission gas transport. The results suggested that the GB effect is the most significant at the edge of fuel pellet where the temperature is the lowest. In the high temperature region, the increase in bulk diffusivity due to excess oxygen diminished the effect of GB diffusion.
ContributorsLim, Harn Chyi (Author) / Peralta, Pedro (Thesis advisor) / Jiang, Hanqing (Committee member) / Solanki, Kiran (Committee member) / Arizona State University (Publisher)
Created2014
Description
The United States Department of Energy (DOE) has always held the safety and reliability of the nation's nuclear reactor fleet as a top priority. Continual improvements and advancements in nuclear fuels have been instrumental in maximizing energy generation from nuclear power plants and minimizing waste. One aspect of the DOE Fuel Cycle Research and Development Advanced Fuels Campaign is to improve the mechanical properties of uranium dioxide (UO2) for nuclear fuel applications.
In an effort to improve the performance of UO2, by increasing the fracture toughness and ductility, small quantities of oxide materials have been added to samples to act as dopants. The different dopants used in this study are: titanium dioxide, yttrium oxide, aluminum oxide, silicon dioxide, and chromium oxide. The effects of the individual dopants and some dopant combinations on the microstructure and mechanical properties are determined using indentation fracture experiments in tandem with scanning electron microscopy. Indentation fracture experiments are carried out at room temperature and at temperatures between 450 °C and 1160 °C.
The results of this work find that doping with aluminosilicate produces the largest favorable change in the mechanical properties of UO2. This sample exhibits an increase in fracture toughness at room temperature without showing a change in yield strength at elevated temperatures. The results also show that doping with Al2O3 and TiO2 produce stronger samples and it is hypothesized that this is a result of the sample containing dopant-rich secondary phase particles.
In an effort to improve the performance of UO2, by increasing the fracture toughness and ductility, small quantities of oxide materials have been added to samples to act as dopants. The different dopants used in this study are: titanium dioxide, yttrium oxide, aluminum oxide, silicon dioxide, and chromium oxide. The effects of the individual dopants and some dopant combinations on the microstructure and mechanical properties are determined using indentation fracture experiments in tandem with scanning electron microscopy. Indentation fracture experiments are carried out at room temperature and at temperatures between 450 °C and 1160 °C.
The results of this work find that doping with aluminosilicate produces the largest favorable change in the mechanical properties of UO2. This sample exhibits an increase in fracture toughness at room temperature without showing a change in yield strength at elevated temperatures. The results also show that doping with Al2O3 and TiO2 produce stronger samples and it is hypothesized that this is a result of the sample containing dopant-rich secondary phase particles.
ContributorsMcDonald, Robert (Author) / Peralta, Pedro (Thesis advisor) / Rajagopalan, Jagannathan (Committee member) / Solanki, Kiran (Committee member) / Arizona State University (Publisher)
Created2014
Description
Processed pyro-gel contains castor oil with solid component of boehmite (Al-OOH). The pyro-gel is synthesized by heat to convert boehmite to gamma-Al2O3 and to a certain extent alpha-Al2O3 nano-particles and castor oil into carbon residue. The effect of heat on pyro-gel is analyzed in a series of experiments using two burning chambers with the initial temperature as the main factor. The obtained temperature distribution profiles are studied and it is observed that the gel behaves very close to the theoretical prediction under heat. The carbon residue with Al2O3 is then processed for twelve hours and then analyzed to obtain the pore distribution of the Al2O3 nano-particles and the relation between the pore volume and the pre-heat temperature is analyzed. The obtained pore distribution shows the pore volume of Al2O3 nano-particles has direct relation to the pre-heat temperature. The experimental process involving the cylindrical reactor is simulated by using a finite rate chemistry eddy-dissipation model in a non-premixed and a porous mesh. The temperature distribution profile of the processed gel for both the meshes is obtained and a comparison is done with the data obtained in the experimental analysis. The temperature distribution obtained from the simulations show they follow a very similar profile to the temperature distribution obtained from experimental analysis, thus confirming the accuracy of both the models. The variation in numerical values between the experimental and simulation analysis is discussed. A physical model is proposed to determine the pore formation based on the temperature distribution obtained from experimental analysis and simulation.
ContributorsSagi, Varun (Author) / Lee, Taewoo (Thesis advisor) / Phelan, Patrick (Committee member) / Chen, Kangping (Committee member) / Arizona State University (Publisher)
Created2010
Description
ABSTRACT The heat recovery steam generator (HRSG) is a key component of Combined Cycle Power Plants (CCPP). The exhaust (flue gas) from the CCPP gas turbine flows through the HRSG − this gas typically contains a high concentration of NO and cannot be discharged directly to the atmosphere because of environmental restrictions. In the HRSG, one method of reducing the flue gas NO concentration is to inject ammonia into the gas at a plane upstream of the Selective Catalytic Reduction (SCR) unit through an injection grid (AIG); the SCR is where the NO is reduced to N2 and H2O. The amount and spatial distribution of the injected ammonia are key considerations for NO reduction while using the minimum possible amount of ammonia. This work had three objectives. First, a flow network model of the Ammonia Flow Control Unit (AFCU) was to be developed to calculate the quantity of ammonia released into the flue gas from each AIG perforation. Second, CFD simulation of the flue gas flow was to be performed to obtain the velocity, temperature, and species concentration fields in the gas upstream and downstream of the SCR. Finally, performance characteristics of the ammonia injection system were to be evaluated. All three objectives were reached. The AFCU was modeled using JAVA - with a graphical user interface provided for the user. The commercial software Fluent was used for CFD simulation. To evaluate the efficacy of the ammonia injection system in reducing the flue gas NO concentration, the twelve butterfly valves in the AFCU ammonia delivery piping (risers) were throttled by various degrees in the model and the NO concentration distribution computed for each operational scenario. When the valves were kept fully open, it was found that it led to a more uniform reduction in NO concentration compared to throttling the valves such that the riser flows were equal. Additionally, the SCR catalyst was consumed somewhat more uniformly, and ammonia slip (ammonia not consumed in reaction) was found lower. The ammonia use could be decreased by 10 percent while maintaining the NO concentration limit in the flue gas exhausting into the atmosphere.
ContributorsAdulkar, Sajesh (Author) / Roy, Ramendra (Thesis advisor) / Lee, Taewoo (Thesis advisor) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2011