Matching Items (6)
Description
Within recent years, metal-organic frameworks, or MOF’s, have gained a lot of attention in the materials research community. These micro-porous materials are constructed of a metal oxide core and organic linkers, and have a wide-variety of applications due to their extensive material characteristic possibilities. The focus of this study is the MOF-5 material, specifically its chemical stability in air. The MOF-5 material has a large pore size of 8 Å, and aperture sizes of 15 and 12 Å. The pore size, pore functionality, and physically stable structure makes MOF-5 a desirable material. MOF-5 holds applications in gas/liquid separation, catalysis, and gas storage. The main problem with the MOF-5 material, however, is its instability in atmospheric air. This inherent instability is due to the water in air binding to the zinc-oxide core, effectively changing the material and its structure. Because of this material weakness, the MOF-5 material is difficult to be utilized in industrial applications. Through the research efforts proposed by this study, the stability of the MOF-5 powder and membrane were studied. MOF-5 powder and a MOF-5 membrane were synthesized and characterized using XRD analysis. In an attempt to improve the stability of MOF-5 in air, methyl groups were added to the organic linker in order to hinder the interaction of water with the Zn4O core. This was done by replacing the terepthalic acid organic linker with 2,5-dimethyl terephthalic acid in the powder and membrane synthesis steps. The methyl-modified MOF-5 powder was found to be stable after several days of exposure to air while the MOF-5 powder exhibited significant crystalline change. The methyl-modified membrane was found to be unstable when synthesized using the same procedure as the MOF-5 membrane.
ContributorsAnderson, Anthony David (Author) / Lin, Jerry Y.S. (Thesis director) / Ibrahim, Amr (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
This paper intends to analyze the Phoenix Suns' shooting patterns in real NBA games, and compare them to the "NBA 2k16" Suns' shooting patterns. Data was collected from the first five Suns' games of the 2015-2016 season and the same games played in "NBA 2k16". The findings of this paper indicate that "NBA 2k16" utilizes statistical findings to model their gameplay. It was also determined that "NBA 2k16" modeled the shooting patterns of the Suns in the first five games of the 2015-2016 season very closely. Both, the real Suns' games and the "NBA 2k16" Suns' games, showed a higher probability of success for shots taken in the first eight seconds of the shot clock than the last eight seconds of the shot clock. Similarly, both game types illustrated a trend that the probability of success for a shot increases as a player holds onto a ball longer. This result was not expected for either game type, however, "NBA 2k16" modeled the findings consistent with real Suns' games. The video game modeled the Suns with significantly more passes per possession than the real Suns' games, while they also showed a trend that more passes per possession has a significant effect on the outcome of the shot. This trend was not present in the real Suns' games, however literature supports this finding. Also, "NBA 2k16" did not correctly model the allocation of team shots for each player, however, the differences were found only in bench players. Lastly, "NBA 2k16" did not correctly allocate shots across the seven regions for Eric Bledsoe, however, there was no evidence indicating that the game did not correctly model the allocation of shots for the other starters, as well as the probability of success across the regions.
ContributorsHarrington, John P. (Author) / Armbruster, Dieter (Thesis director) / Kamarianakis, Ioannis (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
Statistical process control (SPC) is an important quality application that is used throughout industry and is composed of control charts. Most often, it is applied in the final stages of product manufacturing. However it would be beneficial to apply SPC throughout all stages of the manufacturing process such as the beginning stages. This report explores the fundamentals of SPC, applicable programs, important aspects of implementation, and specific examples of where SPC was beneficial. Important programs for SPC are general statistical software such as JMP and Minitab, and some programs are made specifically for SPC such as SPACE: statistical process and control environment. Advanced programs like SPACE are beneficial because they can easily assist with creating control charts and setting up rules, alarms and notifications, and reaction mechanisms. After the charts are set up it is important to apply rules to the charts to see when a system is running off target which indicates the need to troubleshoot and investigate. This makes the notification part an integral aspect as well because attention and awareness must be brought to out of control situations. The next important aspect is ensuring there is a reaction mechanism or plan on what to do in the event of an out of control situation and what to do to get the system running back on target. Setting up an SPC system takes time and practice and requires a lot of collaboration with experts who know more about the system or the quality side. Some of the more difficult parts of implementation is getting everyone on board and creating trainings and getting the appropriate personnel trained.
ContributorsSennavongsa, Christy (Author) / Raupp, Gregory (Thesis director) / Dai, Lenore (Committee member) / Materials Science and Engineering Program (Contributor) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
Description
Metal-organic frameworks (MOFs) are a new set of porous materials comprised of metals or metal clusters bonded together in a coordination system by organic linkers. They are becoming popular for gas separations due to their abilities to be tailored toward specific applications. Zirconium MOFs in particular are known for their high stability under standard temperature and pressure due to the strength of the Zirconium-Oxygen coordination bond. However, the acid modulator needed to ensure long range order of the product also prevents complete linker deprotonation. This leads to a powder product that cannot easily be incorporated into continuous MOF membranes. This study therefore implemented a new bi-phase synthesis technique with a deprotonating agent to achieve intergrowth in UiO-66 membranes. Crystal intergrowth will allow for effective gas separations and future permeation testing. During experimentation, successful intergrown UiO-66 membranes were synthesized and characterized. The degree of intergrowth and crystal orientations varied with changing deprotonating agent concentration, modulator concentration, and ligand:modulator ratios. Further studies will focus on achieving the same results on porous substrates.
ContributorsClose, Emily Charlotte (Author) / Mu, Bin (Thesis director) / Shan, Bohan (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
Description
Polymer-nanoparticle composites (PNCs) show improved chemical and physical properties compared to pure polymers. However, nanoparticles dispersed in a polymer matrix tend to aggregate due to strong interparticle interactions. Electrospun nanofibers impregnated with nanoparticles have shown improved dispersion of nanoparticles. Currently, there are few models for quantifying dispersion in a PNC, and none for electrospun PNC fibers. A simulation model was developed to quantify the effects of nanoparticle volume loading and fiber to particle diameter ratios on the dispersion in a nanofiber. The dispersion was characterized using the interparticle distance along the fiber. Distributions of the interparticle distance were fit to Weibull distributions and a two-parameter empirical equation for the mean and standard deviation was found. A dispersion factor was defined to quantify the dispersion along the polymer fiber. This model serves as a standard for comparison for future experimental studies through its comparability with microscopy techniques, and as way to quantify and predict dispersion in polymer-nanoparticle electrospinning systems with a single performance metric.
ContributorsBalzer, Christopher James (Author) / Mu, Bin (Thesis director) / Armstrong, Mitchell (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
Description
The process of cooking a turkey is a yearly task that families undertake in order to deliver a delicious centerpiece to a Thanksgiving meal. While other dishes accompany and comprise the traditional Thanksgiving supper, focusing on creating a turkey that satisfies the tastes of all guests is difficult, as preferences vary. Over the years, many cooking methods and preparation variations have come to light. This thesis studies these cooking methods and preparation variations, as well as the effects on the crispiness of the skin, the juiciness of the meat, the tenderness of the meat, and the overall taste, to simplify the choices that home cooks have to prepare a turkey that best fits their tastes. Testing and evaluation reveal that among deep-frying, grilling, and oven roasting turkey, a number of preparation variations show statistically significant changes relative to a lack of these preparation variations. For crispiness, fried turkeys are statistically superior, scoring about 1.5 points higher than other cooking methods on a 5 point scale. For juiciness, the best preparation variation was using an oven bag, with the oven roasted turkey scoring about 4.5 points on a 5 point scale. For tenderness, multiple methods are excellent, with the best three preparation variations in order being spatchcocking, brining, and using an oven bag, each of these preparation variations are just under a 4 out of 5. Finally, testing reaffirms that judges tend to have different subjective tastes, with some having different perceptions and opinions on some criteria, while statistically agreeing on others: there was 67% agreement among judges on crispiness and tenderness, while there was only 17% agreement on juiciness. Evaluation of these cooking methods, as well as their respective preparation variations, addresses the question of which methods are worthwhile endeavors for cooks.
ContributorsVance, Jarod (Co-author) / Lacsa, Jeremy (Co-author) / Green, Matthew (Thesis director) / Taylor, David (Committee member) / Chemical Engineering Program (Contributor) / Computer Science and Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05