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The present understanding of the formation and evolution of the earliest bodies in the Solar System is based in large part on geochemical and isotopic evidences contained within meteorites. The differentiated meteorites (meteorites originating from bodies that have experienced partial to complete melting) are particularly useful for deciphering magmatic processes

The present understanding of the formation and evolution of the earliest bodies in the Solar System is based in large part on geochemical and isotopic evidences contained within meteorites. The differentiated meteorites (meteorites originating from bodies that have experienced partial to complete melting) are particularly useful for deciphering magmatic processes occurring in the early Solar System. A rare group of differentiated meteorites, the angrites, are uniquely suited for such work. The angrites have ancient crystallization ages, lack secondary processing, and have been minimally affected by shock metamorphism, thus allowing them to retain their initial geochemical and isotopic characteristics at the time of formation. The scarcity of angrite samples made it difficult to conduct comprehensive investigations into the formation history of this unique meteorite group. However, a dramatic increase in the number of angrites recovered in recent years presents the opportunity to expand our understanding of their petrogenesis, as well as further refine our knowledge of the initial isotopic abundances in the early Solar System as recorded by their isotopic systematics. Using a combination of geochemical tools (radiogenic isotope chronometers and trace element chemistry), I have investigated the petrogenetic history of a group of four angrites that sample a range of formation conditions (cooling histories) and crystallization ages. Through isotope ratio measurements, I have examined a comprehensive set of long- and short-lived radiogenic isotope systems (26Al-26Mg, 87Rb-87Sr, 146Sm-142Nd, 147Sm-143Nd, and 176Lu-176Hf) within these four angrites. The results of these measurements provide information regarding crystallization ages, as well as revised estimates for the initial isotopic abundances of several key elements in the early Solar System. The determination of trace element concentrations in individual mineral phases, as well as bulk rock samples, provides important constraints on magmatic processes occurring on the angrite parent body. The measured trace element abundances are used to estimate the composition of the parent melts of individual angrites, examine crystallization conditions, and investigate possible geochemical affinities between various angrites. The new geochemical and isotopic measurements presented here significantly expand our understanding of the geochemical conditions found on the angrite parent body and the environment in which these meteorites formed.
ContributorsSanborn, Matthew E (Author) / Wadhwa, Meenakshi (Thesis advisor) / Hervig, Richard (Committee member) / Sharp, Thomas (Committee member) / Clarke, Amanda (Committee member) / Williams, Lynda (Committee member) / Carlson, Richard (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Seismic observations have revealed two large low shear velocity provinces (LLSVPs) in the lowermost mantle beneath Pacific and Africa. One hypothesis for the origin of LLSVPs is that they are caused by accumulation of subducted oceanic crust on the core-mantle boundary (CMB). Here, I perform high resolution geodynamical calculations to

Seismic observations have revealed two large low shear velocity provinces (LLSVPs) in the lowermost mantle beneath Pacific and Africa. One hypothesis for the origin of LLSVPs is that they are caused by accumulation of subducted oceanic crust on the core-mantle boundary (CMB). Here, I perform high resolution geodynamical calculations to test this hypothesis. The result shows that it is difficult for a thin (~ 6 km) subducted oceanic crust to accumulate on the CMB, and the major part of it is viscously stirred into the surrounding mantle. Another hypothesis for the origin of LLSVPs is that they are caused by thermochemical piles of more-primitive material which is remnant of Earth's early differentiation. In such case, a significant part of the subducted oceanic crust would enter the more-primitive reservoir, while other parts are either directly entrained into mantle plumes forming on top of the more-primitive reservoir or stirred into the background mantle. As a result, mantle plumes entrain a variable combination of compositional components including more-primitive material, old oceanic crust which first enters the more-primitive reservoir and is later entrained into mantle plumes with the more-primitive material, young oceanic crust which is directly entrained into mantle plumes without contacting the more-primitive reservoir, and depleted background mantle material. The result reconciles geochemical observation of multiple compositional components and varying ages of oceanic crust in the source of ocean-island basalts. Seismic studies have detected ultra-low velocity zones (ULVZs) in some localized regions on the CMB. Here, I present 3D thermochemical calculations to show that the distribution of ULVZs provides important information about their origin. ULVZs with a distinct composition tend to be located at the edges of LLSVPs, while ULVZs solely caused by partial melting tend to be located inboard from the edges of LLSVPs. This indicates that ULVZs at the edges of LLSVPs are best explained by distinct compositional heterogeneity, while ULVZs located insider of LLSVPs are better explained by partial melting. The results provide additional constraints for the origin of ULVZs.
ContributorsLi, Mingming (Author) / McNamara, Allen K (Thesis advisor) / Garnero, Edward J (Committee member) / Shim, Sang-Heon (Committee member) / Tyburczy, James (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Impact cratering and volcanism are two fundamental processes that alter the surfaces of the terrestrial planets. Though well studied through laboratory experiments and terrestrial analogs, many questions remain regarding how these processes operate across the Solar System. Little is known about the formation of large impact basins (>300 km in

Impact cratering and volcanism are two fundamental processes that alter the surfaces of the terrestrial planets. Though well studied through laboratory experiments and terrestrial analogs, many questions remain regarding how these processes operate across the Solar System. Little is known about the formation of large impact basins (>300 km in diameter) and the degree to which they modify planetary surfaces. On the Moon, large impact basins dominate the terrain and are relatively well preserved. Because the lunar geologic timescale is largely derived from basin stratigraphic relations, it is crucial that we are able to identify and characterize materials emplaced as a result of the formation of the basins, such as light plains. Using high-resolution images under consistent illumination conditions and topography from the Lunar Reconnaissance Orbiter Camera (LROC), a new global map of light plains is presented at an unprecedented scale, revealing critical details of lunar stratigraphy and providing insight into the erosive power of large impacts. This work demonstrates that large basins significantly alter the lunar surface out to at least 4 radii from the rim, two times farther than previously thought. Further, the effect of pre-existing topography on the degradation of impact craters is unclear, despite their use in the age dating of surfaces. Crater measurements made over large regions of consistent coverage using LROC images and slopes derived from LROC topography show that pre-existing topography affects crater abundances and absolute model ages for craters up to at least 4 km in diameter.

On Mars, small volcanic edifices can provide valuable insight into the evolution of the crust and interior, but a lack of superposed craters and heavy mantling by dust make them difficult to age date. On Earth, morphometry can be used to determine the ages of cinder cone volcanoes in the absence of dated samples. Comparisons of high-resolution topography from the Context Imager (CTX) and a two-dimensional nonlinear diffusion model show that the forms observed on Mars could have been created through Earth-like processes, and with future work, it may be possible to derive an age estimate for these features in the absence of superposed craters or samples.
ContributorsMeyer, Heather (Author) / Robinson, Mark S (Thesis advisor) / Bell, Jim (Thesis advisor) / Denevi, Brett (Committee member) / Clarke, Amanda (Committee member) / Asphaug, Erik (Committee member) / Arizona State University (Publisher)
Created2018
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Description
The dynamic Earth involves feedbacks between the solid crust and both natural and anthropogenic fluid flows. Fluid-rock interactions drive many Earth phenomena, including volcanic unrest, seismic activities, and hydrological responses. Mitigating the hazards associated with these activities requires fundamental understanding of the underlying physical processes. Therefore, geophysical monitoring in combination

The dynamic Earth involves feedbacks between the solid crust and both natural and anthropogenic fluid flows. Fluid-rock interactions drive many Earth phenomena, including volcanic unrest, seismic activities, and hydrological responses. Mitigating the hazards associated with these activities requires fundamental understanding of the underlying physical processes. Therefore, geophysical monitoring in combination with modeling provides valuable tools, suitable for hazard mitigation and risk management efforts. Magmatic activities and induced seismicity linked to fluid injection are two natural and anthropogenic processes discussed in this dissertation.

Successful forecasting of the timing, style, and intensity of a volcanic eruption is made possible by improved understanding of the volcano life cycle as well as building quantitative models incorporating the processes that govern rock melting, melt ascending, magma storage, eruption initiation, and interaction between magma and surrounding host rocks at different spatial extent and time scale. One key part of such models is the shallow magma chamber, which is generally directly linked to volcano’s eruptive behaviors. However, its actual shape, size, and temporal evolution are often not entirely known. To address this issue, I use space-based geodetic data with high spatiotemporal resolution to measure surface deformation at Kilauea volcano. The obtained maps of InSAR (Interferometric Synthetic Aperture Radar) deformation time series are exploited with two novel modeling schemes to investigate Kilauea’s shallow magmatic system. Both models can explain the same observation, leading to a new compartment model of magma chamber. Such models significantly advance the understanding of the physical processes associated with Kilauea’s summit plumbing system with potential applications for volcanoes around the world.

The unprecedented increase in the number of earthquakes in the Central and Eastern United States since 2008 is attributed to massive deep subsurface injection of saltwater. The elevated chance of moderate-large damaging earthquakes stemming from increased seismicity rate causes broad societal concerns among industry, regulators, and the public. Thus, quantifying the time-dependent seismic hazard associated with the fluid injection is of great importance. To this end, I investigate the large-scale seismic, hydrogeologic, and injection data in northern Texas for period of 2007-2015 and in northern-central Oklahoma for period of 1995-2017. An effective induced earthquake forecasting model is developed, considering a complex relationship between injection operations and consequent seismicity. I find that the timing and magnitude of regional induced earthquakes are fully controlled by the process of fluid diffusion in a poroelastic medium and thus can be successfully forecasted. The obtained time-dependent seismic hazard model is spatiotemporally heterogeneous and decreasing injection rates does not immediately reduce the probability of an earthquake. The presented framework can be used for operational induced earthquake forecasting. Information about the associated fundamental processes, inducing conditions, and probabilistic seismic hazards has broad benefits to the society.
ContributorsZhai, Guang (Author) / Shirzaei, Manoochehr (Thesis advisor) / Garnero, Edward (Committee member) / Clarke, Amanda (Committee member) / Tyburczy, James (Committee member) / Li, Mingming (Committee member) / Arizona State University (Publisher)
Created2018
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Description
ABSTRACT

The Sentinel-Arlington Volcanic Field (SAVF) is the Sentinel Plains lava field and associated volcanic edifices of late Cenozoic alkali olivine basaltic lava flows and minor tephra deposits near the Gila Bend and Painted Rock Mountains, 65 km-100km southwest of Phoenix, Arizona. The SAVF covers ~600 km2 and consists of

ABSTRACT

The Sentinel-Arlington Volcanic Field (SAVF) is the Sentinel Plains lava field and associated volcanic edifices of late Cenozoic alkali olivine basaltic lava flows and minor tephra deposits near the Gila Bend and Painted Rock Mountains, 65 km-100km southwest of Phoenix, Arizona. The SAVF covers ~600 km2 and consists of 21+ volcanic centers, primarily low shield volcanoes ranging from 4-6 km in diameter and 30-200 m in height. The SAVF represents plains-style volcanism, an emplacement style and effusion rate intermediate between flood volcanism and large shield-building volcanism. Because of these characteristics, SAVF is a good analogue to small-volume effusive volcanic centers on Mars, such as those seen the southern flank of Pavonis Mons and in the Tempe Terra region of Mars. The eruptive history of the volcanic field is established through detailed geologic map supplemented by geochemical, paleomagnetic, and geochronological analysis.

Paleomagnetic analyses were completed on 473 oriented core samples from 58 sites. Mean inclination and declination directions were calculated from 8-12 samples at each site. Fifty sites revealed well-grouped natural remanent magnetization vectors after applying alternating field demagnetization. Thirty-nine sites had reversed polarity, eleven had normal polarity. Fifteen unique paleosecular variation inclination and declination directions were identified, six were represented by more than one site with resultant vectors that correlated within a 95% confidence interval. Four reversed sites were radiometrically dated to the Matuyama Chron with ages ranging from 1.08 ± 0.15 Ma to 2.37 ± 0.02 Ma; and one normal polarity site was dated to the Olduvai normal excursion at 1.91 ± 0.59 Ma. Paleomagnetic correlations within a 95% confidence interval were used to extrapolate radiogenic dates. Results reveal 3-5 eruptive stages over ~1.5 Ma in the early Pleistocene and that the SAVF dammed and possibly diverted the lower Gila River multiple times. Preliminary modeling of the median clast size of the terrace deposits suggests a maximum discharge of ~11300 cms (~400,000 cfs) was necessary to transport observed sediment load, which is larger than the historically recorded discharge of the modern Gila River.
ContributorsCave, Shelby Renee (Author) / Clarke, Amanda (Thesis advisor) / Burt, Donald (Committee member) / Reynolds, Stephen (Committee member) / Semken, Steven (Committee member) / Schmeeckle, Mark (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Among volcanic gases, sulfur dioxide (SO2) is by far the most commonly measured. More than a monitoring proxy for volcanic degassing, SO2 has the potential to alter climate patterns. Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day,

Among volcanic gases, sulfur dioxide (SO2) is by far the most commonly measured. More than a monitoring proxy for volcanic degassing, SO2 has the potential to alter climate patterns. Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day, spanning years to decades. SO2 emissions at those volcanoes are poorly constrained, in large part because the current satellite monitoring techniques are unable to detect or quantify plumes of low concentration in the troposphere. Eruption plumes also often show high concentrations of ash and/or aerosols, which further inhibit the detection methods. In this work I focus on quantifying volcanic gas emissions at persistently active explosive volcanoes and their variations over short timescales (minutes to hours), in order to document their contribution to natural SO2 flux as well as investigate the physical processes that control their behavior.

In order to make these measurements, I first develop and assemble a UV ground-based instrument, and validate it against an independently measured source of SO2 at a coal-burning power plant in Arizona. I establish a measurement protocol and demonstrate that the instrument measures SO2 fluxes with < 20 % error. Using the same protocol, I establish a record of the degassing patterns at Semeru volcano (Indonesia), a volcano that has been producing cycles of repeated explosions with periods of minutes to hours for the past several decades. Semeru produces an average of 21-71 tons of SO2 per day, amounting to a yearly output of 8-26 Mt.

Using the Semeru data, along with a 1-D transient numerical model of magma ascent, I test the validity of a model in which a viscous plug at the top of the conduit produces cycles of eruption and gas release. I find that it can be a valid hypothesis to explain the observed patterns of degassing at Semeru. Periodic behavior in such a system occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it.
ContributorsSmekens, Jean-François (Author) / Clarke, Amanda (Thesis advisor) / Christensen, Philip R. (Philip Russel) (Committee member) / Williams, Stanley (Committee member) / Burton, Michael (Committee member) / Fink, Jonathan (Committee member) / Moore, Gordon (Committee member) / Arizona State University (Publisher)
Created2015
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Description
On Mars, sedimentary deposits reveal a complex history of water- and wind-related geologic processes. Central mounds – kilometer-scale stacks of sediment located within craters – occur across Mars, but the specific processes responsible for mound formation and subsequent modification are still uncertain. A survey of central mounds within large craters

On Mars, sedimentary deposits reveal a complex history of water- and wind-related geologic processes. Central mounds – kilometer-scale stacks of sediment located within craters – occur across Mars, but the specific processes responsible for mound formation and subsequent modification are still uncertain. A survey of central mounds within large craters was conducted. Mound locations, mound offsets within their host craters, and relative mound heights were used to address various mound formation hypotheses. The results suggest that mound sediments once filled their host craters and were later eroded into the features observed today. Mounds offsets from the center of their host crater imply that wind caused the erosion of central mounds. An in depth study of a single central mound (Mt. Sharp within Gale crater) was also conducted. Thermal Emission Imaging System Visible Imaging Subsystem (THEMIS-VIS) mosaics in grayscale and false color were used to characterize the morphology and color variations in and around Gale crater. One result of this study is that dunes within Gale crater vary in false color composites from blue to purple, and that these color differences may be due to changes in dust cover, grain size, and/or composition. To further investigate dune fields on Mars, albedo variations at eight dune fields were studied based on the hypothesis that a dune’s ripple migration rate is correlated to its albedo. This study concluded that a dune’s minimum albedo does not have a simple correlation with its ripple migration rate. Instead, dust devils remove dust on slow-moving and immobile dunes, whereas saltating sand caused by strong winds removes dust on faster-moving dunes.

On the Moon, explosive volcanic deposits within Oppenheimer crater that were emplaced ballistically were investigated. Lunar Reconnaissance Orbiter (LRO) Diviner Radiometer mid-infrared data, LRO Camera images, and Chandrayaan-1 orbiter Moon Mineralogy Mapper near-infrared spectra were used to test the hypothesis that the pyroclastic deposits in Oppenheimer crater were emplaced via Vulcanian activity by constraining their composition and mineralogy. The mineralogy and iron-content of the pyroclastic deposits vary significantly (including examples of potentially very high iron compositions), which indicates variability in eruption style. These results suggest that localized lunar pyroclastic deposits may have a more complex origin and mode of emplacement than previously thought.
ContributorsBennett, Kristen Alicia (Author) / Bell, James F. (Thesis advisor) / Christensen, Phillip (Committee member) / Clarke, Amanda (Committee member) / Robinson, Mark (Committee member) / Whipple, Kelin (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Assessments for the threats posed by volcanic eruptions rely in large part on the accurate prediction of volcanic plume motion over time. That predictive capacity is currently hindered by a limited understanding of volcanic plume dynamics. While eruption rate is considered a dominant control on volcanic plume dynamics, the effects

Assessments for the threats posed by volcanic eruptions rely in large part on the accurate prediction of volcanic plume motion over time. That predictive capacity is currently hindered by a limited understanding of volcanic plume dynamics. While eruption rate is considered a dominant control on volcanic plume dynamics, the effects of variable eruption rates on plume rise and evolution are not well understood. To address this aspect of plume dynamics, I conducted an experimental investigation wherein I quantified the relationship between laboratory jet development and highly-variable discharge rates under conditions analogous to those which may prevail in unsteady, short-lived explosive eruptions. I created turbulent jets in the laboratory by releasing pressurized water into a tank of still water. I then measured the resultant jet growth over time using simple video images and particle image velocimetry (PIV). I investigated jet behavior over a range of jet Reynolds numbers which overlaps with estimates of Reynolds numbers for short-duration volcanic plumes. By analysis of the jet boundary and velocity field evolution, I discovered a direct relationship between changes in vent conditions and jet evolution. Jet behavior evolved through a sequence of three stages - jet-like, transitional, and puff-like - that correlate with three main injection phases - acceleration, deceleration and off. While the source was off, jets were characterized by relatively constant internal velocity distributions and flow propagation followed that of a classical puff. However, while the source was on, the flow properties - both in the flows themselves and in the induced ambient flow - changed abruptly with changes at the source. On the basis of my findings for unsteady laboratory jets, I conclude that variable eruption rates with characteristic time scales close to eruption duration have first-order control over volcanic plume evolution. Prior to my study, the significance of this variation was largely uncharacterized as the volcanology community predominately uses steady eruption models for interpretation and prediction of activity. My results suggest that unsteady models are necessary to accurately interpret behavior and assess threats from unsteady, short-lived eruptions.
ContributorsChojnicki, Kirsten (Author) / Clarke, Amanda (Thesis advisor) / Williams, Stanley (Committee member) / Adrian, Ronald (Committee member) / Phillips, Jeremy (Committee member) / Fernando, Harindra (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Chemical and physical interactions of flowing ice and rock have inexorably shaped planetary surfaces. Weathering in glacial environments is a significant link in biogeochemical cycles – carbon and strontium – on Earth, and may have once played an important role in altering Mars’ surface. Despite growing recognition of the importance

Chemical and physical interactions of flowing ice and rock have inexorably shaped planetary surfaces. Weathering in glacial environments is a significant link in biogeochemical cycles – carbon and strontium – on Earth, and may have once played an important role in altering Mars’ surface. Despite growing recognition of the importance of low-temperature chemical weathering, these processes are still not well understood. Debris-coated glaciers are also present on Mars, emphasizing the need to study ice-related processes in the evolution of planetary surfaces. During Earth’s history, subglacial environments are thought to have sheltered communities of microorganisms from extreme climate variations. On Amazonian Mars, glaciers such as lobate debris aprons (LDA) could have hosted chemolithotrophic communities, making Mars’ present glaciers candidates for life preservation. This study characterizes glacial processes on both Earth and Mars.

Chemical weathering at Robertson Glacier, a small alpine glacier in the Canadian Rocky Mountains, is examined with a multidisciplinary approach. The relative proportions of differing dissolution reactions at various stages in the glacial system are empirically determined using aqueous geochemistry. Synthesis of laboratory and orbital thermal infrared spectroscopy allows identification of dissolution rinds on hand samples and characterization of carbonate dissolution signals at orbital scales, while chemical and morphological evidence for thin, discontinuous weathering rinds at microscales are evident from electron microscopy. Subglacial dissolution rates are found to outpace those of the proglacial till plain; biologically-mediated pyrite oxidation drives the bulk of this acidic weathering.

Second, the area-elevation relationship, or hypsometry, of LDA in the midlatitudes of Mars is characterized. These glaciers are believed to have formed ~500 Ma during a climate excursion. Hypsometric measurements of these debris-covered glaciers enable insight into past flow regimes and drive predictions about past climate scenarios. The LDA in this study fall into three major groups, strongly dependent on basal elevation, implying regional and climatic controls on ice formation and flow.

I show that biologically-mediated mineral reactions drive high subglacial dissolution rates, such that variations within the valley can be detected with remote sensing techniques. In future work, these insights can be applied to examining Mars’ glacial regions for signs of chemical alteration and biosignatures.
ContributorsRutledge, Alicia Marie (Author) / Christensen, Philip R. (Thesis advisor) / Shock, Everett (Committee member) / Clarke, Amanda (Committee member) / Sharp, Thomas (Committee member) / Whipple, Kelin (Committee member) / Arizona State University (Publisher)
Created2015
Description
Rock traits (grain size, shape, orientation) are fundamental indicators of geologic processes including geomorphology and active tectonics. Fault zone evolution, fault slip rates, and earthquake timing are informed by examinations of discontinuities in the displacements of the Earth surface at fault scarps. Fault scarps indicate the structure of fault zones

Rock traits (grain size, shape, orientation) are fundamental indicators of geologic processes including geomorphology and active tectonics. Fault zone evolution, fault slip rates, and earthquake timing are informed by examinations of discontinuities in the displacements of the Earth surface at fault scarps. Fault scarps indicate the structure of fault zones fans, relay ramps, and double faults, as well as the surface process response to the deformation and can thus indicate the activity of the fault zone and its potential hazard. “Rocky” fault scarps are unusual because they share characteristics of bedrock and alluvial fault scarps. The Volcanic Tablelands in Bishop, CA offer a natural laboratory with an array of rocky fault scarps. Machine learning mask-Region Convolutional Neural Network segments an orthophoto to identify individual particles along a specific rocky fault scarp. The resulting rock traits for thousands of particles along the scarp are used to develop conceptual models for rocky scarp geomorphology and evolution. In addition to rocky scarp classification, these tools may be useful in many sedimentary and volcanological applications for particle mapping and characterization.
ContributorsScott, Tyler (Author) / Arrowsmith, Ramon (Thesis advisor) / Das, Jnaneshwar (Committee member) / DeVecchio, Duane (Committee member) / Arizona State University (Publisher)
Created2020