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- All Subjects: Leachate
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Description
The computation of the fundamental mode in structural moment frames provides valuable insight into the physical response of the frame to dynamic or time-varying loads. In standard practice, it is not necessary to solve for all n mode shapes in a structural system; it is therefore practical to limit the system to some determined number of r significant mode shapes. Current building codes, such as the American Society of Civil Engineers (ASCE), require certain class of structures to obtain 90% effective mass participation as a way to estimate the accuracy of a solution for base shear motion. A parametric study was performed from the collected data obtained by the analysis of a large number of framed structures. The purpose of this study was the development of rules for the required number of r significant modes to meet the ASCE code requirements. The study was based on the implementation of an algorithm and a computer program developed in the past. The algorithm is based on Householders Transformations, QR Factorization, and Inverse Iteration and it extracts a requested s (s<< n) number of predominate mode shapes and periods. Only the first r (r < s) of these modes are accurate. To verify the accuracy of the algorithm a variety of building frames have been analyzed using the commercially available structural software (RISA 3D) as a benchmark. The salient features of the algorithm are presented briefly in this study.
ContributorsGrantham, Jonathan (Author) / Fafitis, Apostolos (Thesis advisor) / Attard, Thomas (Committee member) / Houston, Sandra (Committee member) / Hjelmstad, Keith (Committee member) / Arizona State University (Publisher)
Created2014
Description
Expansive clay soils, when subjected to substantial moisture change, can be extremely problematic causing various types of damage to lightly-loaded structures. Solving these problems requires an understanding of unsaturated soil mechanics. Soil suction, related to moisture content change, is important in the development of unsaturated soil properties and in the assessment of initial and final stress for heave computation. Direct measurement of soil suction on expansive clays to determine field suction profiles is quite limited due primarily to tradition and cost-driven geotechnical field investigation practices prioritizing water content measurement over soil suction measurement. This study employs a surrogate to estimate soil suction profiles for various sites consisting of clay soils with a Plasticity Index of greater than 15. The soil suction surrogate was used to determine suction profiles from existing geotechnical engineering expansive clay field investigations and a limited amount of directly measured suction profiles were also used. Equilibrium suction magnitudes and the depths to constant suction were obtained from the field suction profiles and results were compared to data found in the existing literature. Thornthwaite Moisture Index (TMI) is a climatic index to describe climatic conditions for a given region. Surface flux boundary conditions (i.e. covered and uncovered and irrigated and non-irrigated) were investigated and comparisons were made to the extent possible. Previous studies have presented correlations between TMI and equilibrium suction and TMI and depth to constant suction. Relationships within this study are presented and comparisons are made to existing relationships. Results and recommendations for further research are discussed.
ContributorsCuzme, Alan (Author) / Houston, Sandra (Thesis advisor) / Zapata, Claudia (Committee member) / Paassen, Leon van (Committee member) / Arizona State University (Publisher)
Created2018
Description
Currently conventional Subtitle D landfills are the primary means of disposing of our waste in the United States. While this method of waste disposal aims at protecting the environment, it does so through the use of liners and caps that effectively freeze the breakdown of waste. Because this method can keep landfills active, and thus a potential groundwater threat for over a hundred years, I take an in depth look at the ability of bioreactor landfills to quickly stabilize waste. In the thesis I detail the current state of bioreactor landfill technologies, assessing the pros and cons of anaerobic and aerobic bioreactor technologies. Finally, with an industrial perspective, I conclude that moving on to bioreactor landfills as an alternative isn't as simple as it may first appear, and that it is a contextually specific solution that must be further refined before replacing current landfills.
ContributorsWhitten, George Avery (Author) / Kavazanjian, Edward (Thesis director) / Allenby, Braden (Committee member) / Houston, Sandra (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2013-05
Description
Zero-Valent Metals (ZVM) are highly reactive materials and have been proved to be effective in contaminant reduction in soils and groundwater remediation. In fact, zero-Valent Iron (ZVI) has proven to be very effective in removing, particularly chlorinated organics, heavy metals, and odorous sulfides. Addition of ZVI has also been proved in enhancing the methane gas generation in anaerobic digestion of activated sludge. However, no studies have been conducted regarding the effect of ZVM stimulation to Municipal Solid Waste (MSW) degradation. Therefore, a collaborative study was developed to manipulate microbial activity in the landfill bioreactors to favor methane production by adding ZVMs. This study focuses on evaluating the effects of added ZVM on the leachate generated from replicated lab scale landfill bioreactors. The specific objective was to investigate the effects of ZVMs addition on the organic and inorganic pollutants in leachate. The hypothesis here evaluated was that adding ZVM including ZVI and Zero Valent Manganese (ZVMn) will enhance the removal rates of the organic pollutants present in the leachate, likely by a putative higher rate of microbial metabolism. Test with six (4.23 gallons) bioreactors assembled with MSW collected from the Salt River Landfill and Southwest Regional Landfill showed that under 5 grams /liter of ZVI and 0.625 grams/liter of ZVMn additions, no significant difference was observed in the pH and temperature data of the leachate generated from these reactors. The conductivity data suggested the steady rise across all reactors over the period of time. The removal efficiency of sCOD was highest (27.112 mg/lit/day) for the reactors added with ZVMn at the end of 150 days for bottom layer, however the removal rate was highest (16.955 mg/lit/day) for ZVI after the end of 150 days of the middle layer. Similar trends in the results was observed in TC analysis. HPLC study indicated the dominance of the concentration of heptanoate and isovalerate were leachate generated from the bottom layer across all reactors. Heptanoate continued to dominate in the ZVMn added leachate even after middle layer injection. IC analysis concluded the chloride was dominant in the leachate generated from all the reactors and there was a steady increase in the chloride content over the period of time. Along with chloride, fluoride, bromide, nitrate, nitrite, phosphate and sulfate were also detected in considerable concentrations. In the summary, the addition of the zero valent metals has proved to be efficient in removal of the organics present in the leachate.
ContributorsPandit, Gandhar Abhay (Author) / Cadillo – Quiroz, Hinsby (Thesis advisor) / Olson, Larry (Thesis advisor) / Boyer, Treavor (Committee member) / Arizona State University (Publisher)
Created2019