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This report analyzes the potential for accumulation of boron in direct potable reuse. Direct potable reuse treats water through desalination processes such as reverse osmosis or nanofiltration which can achieve rejection rates of salts sometimes above 90%. However, boron achieves much lower rejection rates near 40%. Because of this low

This report analyzes the potential for accumulation of boron in direct potable reuse. Direct potable reuse treats water through desalination processes such as reverse osmosis or nanofiltration which can achieve rejection rates of salts sometimes above 90%. However, boron achieves much lower rejection rates near 40%. Because of this low rejection rate, there is potential for boron to accumulate in the system to levels that are not recommended for potable human consumption of water. To analyze this issue a code was created that runs a steady state system that tracks the internal concentration, permeate concentration, wastewater concentration and reject concentration at various rejection rates, as well as all the flows. A series of flow and mass balances were performed through five different control volumes that denoted different stages in the water use. First was mixing of clean water with permeate; second, consumptive uses; third, addition of contaminant; fourth, wastewater treatment; fifth, advanced water treatments. The system cycled through each of these a number of times until steady state was reached. Utilities or cities considering employing direct potable reuse could utilize this model by estimating their consumption levels and input of contamination, and then seeing what percent rejection or inflow of makeup water they would need to obtain to keep boron levels at a low enough concentration to be fit for consumption. This code also provides options for analyzing spikes and recovery in the system due to spills, and evaporative uses such as cooling towers and their impact on the system.
ContributorsDoidge, Sydney (Author) / Fox, Peter (Thesis director) / Perreault, Francois (Committee member) / Civil, Environmental and Sustainable Engineering Program (Contributor) / School of International Letters and Cultures (Contributor) / Barrett, The Honors College (Contributor)
Created2017-12
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Access to clean drinking water has been identified by the National Academy of Engineering as one of the Grand Challenges of the 21st century. This thesis investigated clean drinking water access in the greater Phoenix area, specifically with regards to drinking water quality standards and management strategies. This research report

Access to clean drinking water has been identified by the National Academy of Engineering as one of the Grand Challenges of the 21st century. This thesis investigated clean drinking water access in the greater Phoenix area, specifically with regards to drinking water quality standards and management strategies. This research report provides an introduction to water quality, treatment, and management; a background on the Salt River Project; and an analysis on source water mix and drinking water quality indicators for water delivered to Tempe, Arizona water treatment facilities.
ContributorsMercer, Rebecca Nicole (Author) / Ganesh, Tirupalavanam (Thesis director) / Trowbridge, Amy (Committee member) / Industrial, Systems (Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
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The goal of this research study was to empirically study a poster-based messaging campaign in comparison to that of a project-based learning approach in assessing the effectiveness of these methods in conveying the scope of biomedical engineering to upper elementary school students. For the purpose of this honors thesis, this

The goal of this research study was to empirically study a poster-based messaging campaign in comparison to that of a project-based learning approach in assessing the effectiveness of these methods in conveying the scope of biomedical engineering to upper elementary school students. For the purpose of this honors thesis, this research paper specifically reflects and analyzes the first stage of this study, the poster-based messaging campaign. 6th grade students received socially relevant messaging of juniors and seniors at ASU achieving their biomedical aspirations, and received information regarding four crucial themes of biomedical engineering via daily presentations and a website. Their learning was tracked over the course of the weeklong immersion program through a pre/post assessment. This data was then analyzed through the Wilcoxon matched pairs test to determine whether the change in biomedical engineering awareness was statistically significant. It was determined that a poster-based messaging campaign indeed increased awareness of socially relevant themes within biomedical engineering, and provided researchers with tangible ways to revise the study before a second round of implementation. The next stage of the study aims to explain biomedical engineering through engaging activities that stimulate making while emphasizing design-aesthetic appeal and engineering habits of mind such as creativity, teamwork, and communication.
ContributorsSwaminathan, Swetha Anu (Author) / Ganesh, Tirupalavanam (Thesis director) / Shrake, Scott (Committee member) / Harrington Bioengineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
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Description

Much of Nepal lacks access to clean drinking water, and many water sources are contaminated with arsenic at concentrations above both World Health Organization and local Nepalese guidelines. While many water treatment technologies exist, it is necessary to identify those that are easily implementable in developing areas. One simple treatment

Much of Nepal lacks access to clean drinking water, and many water sources are contaminated with arsenic at concentrations above both World Health Organization and local Nepalese guidelines. While many water treatment technologies exist, it is necessary to identify those that are easily implementable in developing areas. One simple treatment that has gained popularity is biochar—a porous, carbon-based substance produced through pyrolysis of biomass in an oxygen-free environment. Arizona State University’s Engineering Projects in Community Service (EPICS) has partnered with communities in Nepal in an attempt to increase biochar production in the area, as it has several valuable applications including water treatment. Biochar’s arsenic adsorption capability will be investigated in this project with the goal of using the biochar that Nepalese communities produce to remove water contaminants. It has been found in scientific literature that biochar is effective in removing heavy metal contaminants from water with the addition of iron through surface activation. Thus, the specific goal of this research was to compare the arsenic adsorption disparity between raw biochar and iron-impregnated biochar. It was hypothesized that after numerous bed volumes pass through a water treatment column, iron from the source water will accumulate on the surface of raw biochar, mimicking the intentionally iron-impregnated biochar and further increasing contaminant uptake. It is thus an additional goal of this project to compare biochar loaded with iron through an iron-spiked water column and biochar impregnated with iron through surface oxidation. For this investigation, the biochar was crushed and sieved to a size between 90 and 100 micrometers. Two samples were prepared: raw biochar and oxidized biochar. The oxidized biochar was impregnated with iron through surface oxidation with potassium permanganate and iron loading. Then, X-ray fluorescence was used to compare the composition of the oxidized biochar with its raw counterpart, indicating approximately 0.5% iron in the raw and 1% iron in the oxidized biochar. The biochar samples were then added to batches of arsenic-spiked water at iron to arsenic concentration ratios of 20 mg/L:1 mg/L and 50 mg/L:1 mg/L to determine adsorption efficiency. Inductively coupled plasma mass spectrometry (ICP-MS) analysis indicated an 86% removal of arsenic using a 50:1 ratio of iron to arsenic (1.25 g biochar required in 40 mL solution), and 75% removal with a 20:1 ratio (0.5 g biochar required in 40 mL solution). Additional samples were then inserted into a column process apparatus for further adsorption analysis. Again, ICP-MS analysis was performed and the results showed that while both raw and treated biochars were capable of adsorbing arsenic, they were exhausted after less than 70 bed volumes (234 mL), with raw biochar lasting 60 bed volumes (201 mL) and oxidized about 70 bed volumes (234 mL). Further research should be conducted to investigate more affordable and less laboratory-intensive processes to prepare biochar for water treatment.

ContributorsLaird, Ashlyn (Author) / Schoepf, Jared (Thesis director) / Westerhoff, Paul (Committee member) / Chemical Engineering Program (Contributor) / School of International Letters and Cultures (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05