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Description
The presence of huge amounts of waste heat and the constant demand for electric energy makes this an appreciable research topic, yet at present there is no commercially viable technology to harness the inherent energy resource provided by the temperature differential between the inside and outside of buildings. In a

The presence of huge amounts of waste heat and the constant demand for electric energy makes this an appreciable research topic, yet at present there is no commercially viable technology to harness the inherent energy resource provided by the temperature differential between the inside and outside of buildings. In a newly developed technology, electricity is generated from the temperature gradient between building walls through a Seebeck effect. A 3D-printed triply periodic minimal surface (TPMS) structure is sandwiched in copper electrodes with copper (I) sulphate (Cu2SO4) electrolyte to mimic a thermogalvanic cell. Previous studies mainly concentrated on mechanical properties and the electric power generation ability of these structures; however, the goal of this study is to estimate the thermal resistance of the 3D-printed TPMS experimentally. This investigation elucidates their thermal resistances which in turn helps to appreciate the power output associated in the thermogalvanic structure. Schwarz P, Gyroid, IWP, and Split P geometries were considered for the experiment with electrolyte in the thermogalvanic brick. Among these TPMS structures, Split P was found more thermally resistive than the others with a thermal resistance of 0.012 m2 K W-1. The thermal resistances of Schwarz D and Gyroid structures were also assessed experimentally without electrolyte and the results are compared to numerical predictions in a previous Mater's thesis.
ContributorsDasinor, Emmanuel (Author) / Phelan, Patrick (Thesis advisor) / Milcarek, Ryan (Committee member) / Bhate, Dhruv (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Energy is one of the wheels on which the modern world runs. Therefore, standards and limits have been devised to maintain the stability and reliability of the power grid. This research shows a simple methodology for increasing the amount of Inverter-based Renewable Generation (IRG), which is also known as Inverter-based

Energy is one of the wheels on which the modern world runs. Therefore, standards and limits have been devised to maintain the stability and reliability of the power grid. This research shows a simple methodology for increasing the amount of Inverter-based Renewable Generation (IRG), which is also known as Inverter-based Resources (IBR), for that considers the voltage and frequency limits specified by the Western Electricity Coordinating Council (WECC) Transmission Planning (TPL) criteria, and the tie line power flow limits between the area-under-study and its neighbors under contingency conditions. A WECC power flow and dynamic file is analyzed and modified in this research to demonstrate the performance of the methodology. GE's Positive Sequence Load Flow (PSLF) software is used to conduct this research and Python was used to analyze the output data.

The thesis explains in detail how the system with 11% of IRG operated before conducting any adjustments (addition of IRG) and what procedures were modified to make the system run correctly. The adjustments made to the dynamic models are also explained in depth to give a clearer picture of how each adjustment affects the system performance. A list of proposed IRG units along with their locations were provided by SRP, a power utility in Arizona, which were to be integrated into the power flow and dynamic files. In the process of finding the maximum IRG penetration threshold, three sensitivities were also considered, namely, momentary cessation due to low voltages, transmission vs. distribution connected solar generation, and stalling of induction motors. Finally, the thesis discusses how the system reacts to the aforementioned modifications, and how IRG penetration threshold gets adjusted with regards to the different sensitivities applied to the system.
ContributorsAlbhrani, Hashem A M H S (Author) / Pal, Anamitra (Thesis advisor) / Holbert, Keith E. (Committee member) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Research confirms that climate change is primarily due to the influx of greenhouse gases from the anthropogenic burning of fossil fuels for energy. Carbon dioxide (CO2) is the dominant greenhouse gas contributing to climate change. Although research also confirms that negative emission technologies (NETs) are necessary to stay within 1.5-2°C

Research confirms that climate change is primarily due to the influx of greenhouse gases from the anthropogenic burning of fossil fuels for energy. Carbon dioxide (CO2) is the dominant greenhouse gas contributing to climate change. Although research also confirms that negative emission technologies (NETs) are necessary to stay within 1.5-2°C of global warming, this dissertation proposes that the climate change problem has been ineffectively communicated to suggest that CO2 emissions reduction is the only solution to climate change. Chapter 1 explains that current United States (US) policies focus heavily on reducing CO2 emissions, but ignore the concentrations of previous CO2 emissions accumulating in the atmosphere. Through political, technological, and ethical lenses, this dissertation evaluates whether the management process of CO2 emissions and concentrations in the US today can effectively combat climate change.

Chapter 2 discusses the historical management of US air pollution, why CO2 is regulated as an air pollutant, and how the current political framing of climate change as an air pollution problem promotes the use of market-based solutions to reduce emissions but ignores CO2 concentrations. Chapter 3 argues for the need to reframe climate change solutions to include reducing CO2 concentrations along with emissions. It presents the scientific reasoning and technological needs for reducing CO2 concentrations, why direct air capture (DAC) is the most effective NET to do so, and existing regulatory systems that can inform future CO2 removal policy. Chapter 4 explores whether Responsible Innovation (RI), a framework that includes society in the innovation process of emerging technologies, is effective for the ethical research and deployment of DAC; reveals the need for increased DAC governance strategies, and suggests how RI can be expanded to allow continued research of controversial emerging technologies in case of a climate change emergency. Overall, this dissertation argues that climate change must be reframed as a two-part problem: preventing new CO2 emissions and reducing concentrations, which demands increased investment in DAC research, development, and deployment. However, without a national or global governance strategy for DAC, it will remain difficult to include CO2 concentration reduction as an essential piece to the climate change solution.
ContributorsMorton, Evvan (Author) / Lackner, Klaus S (Thesis advisor) / Allenby, Braden R. (Committee member) / Graffy, Elisabeth A. (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Performing the Electrical traces the histories and futures of electrical discovery and knowledge through cultural performances, socio-political assemblages, and the more-than-human worldmaking functions of energy in general and electricity in particular, or what I refer to as energy-as-electricity. This project seeks to transform how energy-as-electricity is perceived, and thereby to

Performing the Electrical traces the histories and futures of electrical discovery and knowledge through cultural performances, socio-political assemblages, and the more-than-human worldmaking functions of energy in general and electricity in particular, or what I refer to as energy-as-electricity. This project seeks to transform how energy-as-electricity is perceived, and thereby to re-vision the impact that energy-rich relationships might have ecologically—in both the social and environmental senses of the word. As a practice-led inquiry I use my scenographic sensibilities in combination with performance studies and energy humanities lenses to identify how energy-scapes form through social performances, material relations, and aesthetic/ritualistic interventions. This approach allows me to synthesize vastly different scales of energy-as-electricity performatives and spatialities and propose alternative framings which work towards decolonizing and re-feminizing energy-rich relationships. This research considers the way power flows, accumulates, and transforms through performance as embodied expression, practice and eventful doings of human and more-than-human agents. It asks: if place is practiced space (Henri Lefebvre), how can decolonizing and re-feminizing energy-rich relationships transform normative power relationships (or power geometries, as cultural geographer Doreen Massey refers to such globalized interconnections)—which are formed through electricity, technologies and colonial-capitalism? I ground this inquiry as an ecological intervention in order to investigate how performing with electricity differently (both in collective imaginations and quotidian interactions), can change the ways that electricity is produced and consumed in the time of the Anthropocene, Capitalocene, and Plasticene. The following study produces written and tacit knowledge that expands the framing of energy-rich relationships shared between human and more-than-human performatives. My provocation is that experiential encounters are critical for expanding the ontological plurality of energy-as-electricity with ecological a/effect. Drawing on the insights of performance scenographer Rachel Hann, I demonstrate that scenographic methodologies in an expanded field, along with embodied sensing, provide productive insights into this endeavor of expansion. This project both serves as a space making/space keeping provocation and offers a methodology for devising more desirable futures.
ContributorsFoster Gluck, Geneva (Author) / Underiner, Tamara (Thesis advisor) / Hunt, Kristin (Committee member) / McHugh, Kevin (Committee member) / Arizona State University (Publisher)
Created2020
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Description
The popularity of solar photovoltaic (PV) energy is growing across the globe with more than 500 GW installed in 2018 with a capacity of 640 GW in 2019. Improved PV module reliability minimizes the levelized cost of energy. Studying and accelerating encapsulant browning and solder bond degradation—two of the most

The popularity of solar photovoltaic (PV) energy is growing across the globe with more than 500 GW installed in 2018 with a capacity of 640 GW in 2019. Improved PV module reliability minimizes the levelized cost of energy. Studying and accelerating encapsulant browning and solder bond degradation—two of the most commonly observed degradation modes in the field—in a lab requires replicating the stress conditions that induce the same field degradation modes in a controlled accelerated environment to reduce testing time.

Accelerated testing is vital in learning about the reliability of solar PV modules. The unique streamlined approach taken saves time and resources with a statistically significant number of samples being tested in one chamber under multiple experimental stress conditions that closely mirror field conditions that induce encapsulant browning and solder bond degradation. With short circuit current (Isc) and series resistance (Rs) degradation data sets at multiple temperatures, the activation energies (Ea) for encapsulant browning and solder bond degradation was calculated.

Regular degradation was replaced by the wear-out stages of encapsulant browning and solder bond degradation by subjecting two types of field-aged modules to further accelerated testing. For browning, the Ea calculated through the Arrhenius model was 0.37 ± 0.17 eV and 0.71 ± 0.07 eV. For solder bond degradation, the Arrhenius model was used to calculate an Ea of 0.12 ± 0.05 eV for solder with 2wt% Ag and 0.35 ± 0.04 eV for Sn60Pb40 solder.

To study the effect of types of encapsulant, backsheet, and solder on encapsulant browning and solder bond degradation, 9-cut-cell samples maximizing available data points while minimizing resources underwent accelerated tests described for modules. A ring-like browning feature was observed in samples with UV pass EVA above and UV cut EVA below the cells. The backsheet permeability influences the extent of oxygen photo-bleaching. In samples with solder bond degradation, increased bright spots and cell darkening resulted in increased Rs. Combining image processing with fluorescence imaging and electroluminescence imaging would yield great insight into the two degradation modes.
ContributorsGopalakrishna, Hamsini (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Hacke, Peter (Committee member) / Arizona State University (Publisher)
Created2020
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Description
About 20-50% of industrial processes energy is lost as waste heat in their operations. The thermal hydraulic engine relies on the thermodynamic properties of supercritical carbon dioxide (CO2) to efficiently perform work. Carbon dioxide possesses great properties that makes it a safe working fluid for the engine’s applications. This research

About 20-50% of industrial processes energy is lost as waste heat in their operations. The thermal hydraulic engine relies on the thermodynamic properties of supercritical carbon dioxide (CO2) to efficiently perform work. Carbon dioxide possesses great properties that makes it a safe working fluid for the engine’s applications. This research aims to preliminarily investigate the actual efficiency which can be obtained through experimental data and compare that to the Carnot or theoretical maximum efficiency. The actual efficiency is investigated through three approaches. However, only the efficiency results from the second method are validated since the other approaches are based on a complete actual cycle which was not achieved for the engine. The efficiency of the thermal hydraulic engine is found to be in the range of 0.5% to 2.2% based on the second method which relies on the boundary work by the piston. The heating and cooling phases of the engine’s operation are viewed on both the T-s (temperature-entropy) and p-v (pressure-volume) diagrams. The Carnot efficiency is also found to be 13.7% from a temperature difference of 46.20C based on the measured experimental data. It is recommended that the thermodynamic cycle and efficiency investigation be repeated using an improved heat exchanger design to reduce energy losses and gains during both the heating and cooling phases. The temperature of CO2 can be measured through direct contact with the thermocouple and pressure measurements can be improved using a digital pressure transducer for the thermodynamic cycle investigation.
ContributorsManford, David (Author) / Phelan, Patrick (Thesis advisor) / Calhoun, Ronald (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Arizona State University (Publisher)
Created2020
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Description
As the global community raises concerns regarding the ever-increasing urgency of climate change, efforts to explore innovative strategies in the fight against this anthropogenic threat is growing. Along with other greenhouse gas mitigation technologies, Direct Air Capture (DAC) or the technology of removing carbon dioxide directly from the air has

As the global community raises concerns regarding the ever-increasing urgency of climate change, efforts to explore innovative strategies in the fight against this anthropogenic threat is growing. Along with other greenhouse gas mitigation technologies, Direct Air Capture (DAC) or the technology of removing carbon dioxide directly from the air has received considerable attention. As an emerging technology, the cost of DAC has been the prime focus not only in scientific society but also between entrepreneurs and policymakers. While skeptics are concerned about the high cost and impact of DAC implementation at scales comparable to the magnitude of climate change, industrial practitioners have demonstrated a pragmatic path to cost reduction. Based on the latest advancements in the field, this dissertation investigates the economic feasibility of DAC and its role in future energy systems. With a focus on the economics of carbon capture, this work compares DAC with other carbon capture technologies from a systemic perspective. Moreover, DAC’s major expenses are investigated to highlight critical improvements necessary for commercialization. In this dissertation, DAC is treated as a backstop mitigation technology that can address carbon dioxide emissions regardless of the source of emission. DAC determines the price of carbon dioxide removal when other mitigation technologies fall short in meeting their goals. The results indicate that DAC, even at its current price, is a reliable backup and is competitive with more mature technologies such as post-combustion capture. To reduce the cost, the most crucial component of a DAC design, i.e., the sorbent material, must be the centerpiece of innovation. In conclusion, DAC demonstrates the potential for not only negative emissions (carbon dioxide removal with the purpose of addressing past emissions), but also for addressing today’s emissions. The results emphasize that by choosing an effective scale-up strategy, DAC can become sufficiently cheap to play a crucial role in decarbonizing the energy system in the near future. Compared to other large-scale decarbonization strategies, DAC can achieve this goal with the least impact on our existing energy infrastructure.
ContributorsAzarabadi, Habib (Author) / Lackner, Klaus S (Thesis advisor) / Allenby, Braden R. (Committee member) / Dirks, Gary W (Committee member) / Reddy, Agami (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Lithium titanium oxide (LTO), is a crystalline (spinel) anode material that has recently been considered as an alternative to carbon anodes in conventional lithium-ion batteries (LIB), mainly due to the inherent safety and durability of this material. In this paper commercial LTO anode 18650 cells with lithium cobalt oxide (LCO)

Lithium titanium oxide (LTO), is a crystalline (spinel) anode material that has recently been considered as an alternative to carbon anodes in conventional lithium-ion batteries (LIB), mainly due to the inherent safety and durability of this material. In this paper commercial LTO anode 18650 cells with lithium cobalt oxide (LCO) cathodes have been cycled to simulate EV operating condition (temperature and drive profiles) in Arizona. The capacity fade of battery packs (pack #1 and pack#2), each consisting 6 such cells in parallel was studied. While capacity fades faster at the higher temperature (40°C), fading is significantly reduced at the lower temperature limit (0°C). Non-invasive techniques such as Electrochemical Impedance Spectroscopy (EIS) show a steady increase in the high-frequency resistance along with capacity fade indicating Loss of Active Material (LAM) and formation of co-intercalation products like Solid Electrolyte Interface (SEI). A two-stage capacity fade can be observed as previously reported and can be proved by differential voltage curves. The first stage is gradual and marks the slow degradation of the anode while the second stage is marked by a drastic capacity fade and can be attributed to the fading cathode. After an effective capacity fading of ~20%, the battery packs were disassembled, sorted and repackaged into smaller packs of 3 cells each for second-life testing. No major changes were seen in the crystal structure of LTO, establishing its electrochemical stability. However, the poor built of the 18650-cell appears to have resulted in failures like gradual electrolytic decomposition causing prominent swelling and failure in a few cells and LAM from the cathode along with cation dissolution. This result is important to understand how LTO batteries fail to better utilize the batteries for specific secondary-life applications.
ContributorsWadikar, Harshwardhan (Author) / Crozier, Peter (Thesis advisor) / Wang, Qing H (Committee member) / Nian, Qiong (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Accurate forecasting of electricity prices has been a key factor for bidding strategies in the electricity markets. The increase in renewable generation due to large scale PV and wind deployment in California has led to an increase in day-ahead and real-time price volatility. This has also led to prices going

Accurate forecasting of electricity prices has been a key factor for bidding strategies in the electricity markets. The increase in renewable generation due to large scale PV and wind deployment in California has led to an increase in day-ahead and real-time price volatility. This has also led to prices going negative due to the supply-demand imbalance caused by excess renewable generation during instances of low demand. This research focuses on applying machine learning models to analyze the impact of renewable generation on the hourly locational marginal prices (LMPs) for California Independent System Operator (CAISO). Historical data involving the load, renewable generation from solar and wind, fuel prices, aggregated generation outages is extracted and collected together in a dataset and used as features to train different machine learning models. Tree- based machine learning models such as Extra Trees, Gradient Boost, Extreme Gradient Boost (XGBoost) as well as models based on neural networks such as Long short term memory networks (LSTMs) are implemented for price forecasting. The focus is to capture the best relation between the features and the target LMP variable and determine the weight of every feature in determining the price.

The impact of renewable generation on LMP forecasting is determined for several different days in 2018. It is seen that the prices are impacted significantly by solar and wind generation and it ranks second in terms of impact after the electric load. The results of this research propose a method to evaluate the impact of several parameters on the day-ahead price forecast and would be useful for the grid operators to evaluate the parameters that could significantly impact the day-ahead price prediction and which parameters with low impact could be ignored to avoid an error in the forecast.
ContributorsVad, Chinmay (Author) / Honsberg, C. (Christiana B.) (Thesis advisor) / King, Richard R. (Committee member) / Kurtz, Sarah (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Demand for green energy alternatives to provide stable and reliable energy

solutions has increased over the years which has led to the rapid expansion of global

markets in renewable energy sources such as solar photovoltaic (PV) technology. Newest

amongst these technologies is the Bifacial PV modules, which harvests incident radiation

from both sides of

Demand for green energy alternatives to provide stable and reliable energy

solutions has increased over the years which has led to the rapid expansion of global

markets in renewable energy sources such as solar photovoltaic (PV) technology. Newest

amongst these technologies is the Bifacial PV modules, which harvests incident radiation

from both sides of the module. The overall power generation can be significantly increased

by using these bifacial modules. The purpose of this research is to investigate and maximize

the effect of back reflectors, designed to increase the efficiency of the module by utilizing

the intercell light passing through the module to increase the incident irradiance, on the

energy output using different profiles placed at varied distances from the plane of the array

(POA). The optimum reflector profile and displacement of the reflector from the module

are determined experimentally.

Theoretically, a 60-cell bifacial module can produce 26% additional energy in

comparison to a 48-cell bifacial module due to the 12 excess cells found in the 60-cell

module. It was determined that bifacial modules have the capacity to produce additional

energy when optimized back reflectors are utilized. The inverted U reflector produced

higher energy gain when placed at farther distances from the module, indicating direct

dependent proportionality between the placement distance of the reflector from the module

and the output energy gain. It performed the best out of all current construction geometries

with reflective coatings, generating more than half of the additional energy produced by a

densely-spaced 60-cell benchmark module compared to a sparsely-spaced 48-cell reference

module.ii

A gain of 11 and 14% was recorded on cloudy and sunny days respectively for the

inverted U reflector. This implies a reduction in the additional cells of the 60-cell module

by 50% can produce the same amount of energy of the 60-cell module by a 48-cell module

with an inverted U reflector. The use of the back reflectors does not only affect the

additional energy gain but structural and land costs. Row to row spacing for bifacial

systems(arrays) is reduced nearly by half as the ground height clearance is largely

minimized, thus almost 50% of height constraints for mounting bifacial modules, using

back reflectors resulting in reduced structural costs for mounting of bifacial modules
ContributorsMARTIN, PEDRO JESSE (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2019