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A relatively simple subset of nanotechnology - nanofluids - can be obtained by adding nanoparticles to conventional base fluids. The promise of these fluids stems from the fact that relatively low particle loadings (typically <1% volume fractions) can significantly change the properties of the base fluid. This research

A relatively simple subset of nanotechnology - nanofluids - can be obtained by adding nanoparticles to conventional base fluids. The promise of these fluids stems from the fact that relatively low particle loadings (typically <1% volume fractions) can significantly change the properties of the base fluid. This research explores how low volume fraction nanofluids, composed of common base-fluids, interact with light energy. Comparative experimentation and modeling reveals that absorbing light volumetrically (i.e. in the depth of the fluid) is fundamentally different from surface-based absorption. Depending on the particle material, size, shape, and volume fraction, a fluid can be changed from being mostly transparent to sunlight (in the case of water, alcohols, oils, and glycols) to being a very efficient volumetric absorber of sunlight. This research also visualizes, under high levels of irradiation, how nanofluids undergo interesting, localized phase change phenomena. For this, images were taken of bubble formation and boiling in aqueous nanofluids heated by a hot wire and by a laser. Infrared thermography was also used to quantify this phenomenon. Overall, though, this research reveals the possibility for novel solar collectors in which the working fluid directly absorbs light energy and undergoes phase change in a single step. Modeling results indicate that these improvements can increase a solar thermal receiver's efficiency by up to 10%.
ContributorsTaylor, Robert (Author) / Phelan, Patrick E (Thesis advisor) / Adrian, Ronald (Committee member) / Trimble, Steve (Committee member) / Posner, Jonathan (Committee member) / Maracas, George (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Plasmon resonance in nanoscale metallic structures has shown its ability to concentrate electromagnetic energy into sub-wavelength volumes. Metal nanostructures exhibit a high extinction coefficient in the visible and near infrared spectrum due to their large absorption and scattering cross sections corresponding to their surface plasmon resonance. Hence, they can serve

Plasmon resonance in nanoscale metallic structures has shown its ability to concentrate electromagnetic energy into sub-wavelength volumes. Metal nanostructures exhibit a high extinction coefficient in the visible and near infrared spectrum due to their large absorption and scattering cross sections corresponding to their surface plasmon resonance. Hence, they can serve as an attractive candidate for solar energy conversion. Recent papers have showed that dielectric core/metallic shell nanoparticles yielded a plasmon resonance wavelength tunable from visible to infrared by changing the ratio of core radius to the total radius. Therefore it is interesting to develop a dispersion of core-shell multifunctional nanoparticles capable of dynamically changing their volume ratio and thus their spectral radiative properties. Nanoparticle suspensions (nanofluids) are known to offer a variety of benefits for thermal transport and energy conversion. Nanofluids have been proven to increase the efficiency of the photo-thermal energy conversion process in direct solar absorption collectors (DAC). Combining these two cutting-edge technologies enables the use of core-shell nanoparticles to control the spectral and radiative properties of plasmonic nanofluids in order to efficiently harvest and convert solar energy. Plasmonic nanofluids that have strong energy concentrating capacity and spectral selectivity can be used in many high-temperature energy systems where radiative heat transport is essential. In this thesis,the surface plasmon resonance effect and the wavelength tuning ranges for different metallic shell nanoparticles are investigated, the solar-weighted efficiencies of corresponding core-shell nanoparticle suspensions are explored, and a quantitative study of core-shell nanoparticle suspensions in a DAC system is provided. Using core-shell nanoparticle dispersions, it is possible to create efficient spectral solar absorption fluids and design materials for applications which require variable spectral absorption or scattering.
ContributorsLv, Wei (Author) / Phelan, Patrick E (Thesis advisor) / Dai, Lenore (Committee member) / Prasher, Ravi (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Waste heat energy conversion remains an inviting subject for research, given the renewed emphasis on energy efficiency and carbon emissions reduction. Solid-state thermoelectric devices have been widely investigated, but their practical application remains challenging because of cost and the inability to fabricate them in geometries that are easily compatible

Waste heat energy conversion remains an inviting subject for research, given the renewed emphasis on energy efficiency and carbon emissions reduction. Solid-state thermoelectric devices have been widely investigated, but their practical application remains challenging because of cost and the inability to fabricate them in geometries that are easily compatible with heat sources. An intriguing alternative to solid-state thermoelectric devices is thermogalvanic cells, which include a generally liquid electrolyte that permits the transport of ions. Thermogalvanic cells have long been known in the electrochemistry community, but have not received much attention from the thermal transport community. This is surprising given that their performance is highly dependent on controlling both thermal and mass (ionic) transport. This research will focus on a research project, which is an interdisciplinary collaboration between mechanical engineering (i.e. thermal transport) and chemistry, and is a largely experimental effort aimed at improving fundamental understanding of thermogalvanic systems. The first part will discuss how a simple utilization of natural convection within the cell doubles the maximum power output of the cell. In the second part of the research, some of the results from the previous part will be applied in a feasibility study of incorporating thermogalvanic waste heat recovery systems into automobiles. Finally, a new approach to enhance Seebeck coefficient by tuning the configurational entropy of a mixed-ligand complex formation of copper sulfate aqueous electrolytes will be presented. Ultimately, a summary of these results as well as possible future work that can be formed from these efforts is discussed.
ContributorsGunawan, Andrey (Author) / Phelan, Patrick E (Thesis advisor) / Buttry, Daniel A (Committee member) / Mujica, Vladimiro (Committee member) / Chan, Candace K. (Committee member) / Wang, Robert Y (Committee member) / Arizona State University (Publisher)
Created2015
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Description
The residential building sector accounts for more than 26% of the global energy consumption and 17% of global CO2 emissions. Due to the low cost of electricity in Kuwait and increase of population, Kuwaiti electricity consumption tripled during the past 30 years and is expected to increase by 20% by

The residential building sector accounts for more than 26% of the global energy consumption and 17% of global CO2 emissions. Due to the low cost of electricity in Kuwait and increase of population, Kuwaiti electricity consumption tripled during the past 30 years and is expected to increase by 20% by 2027. In this dissertation, a framework is developed to assess energy savings techniques to help policy-makers make educated decisions. The Kuwait residential energy outlook is studied by modeling the baseline energy consumption and the diffusion of energy conservation measures (ECMs) to identify the impacts on household energy consumption and CO2 emissions.



The energy resources and power generation in Kuwait were studied. The characteristics of the residential buildings along with energy codes of practice were investigated and four building archetypes were developed. Moreover, a baseline of end-use electricity consumption and demand was developed. Furthermore, the baseline energy consumption and demand were projected till 2040. It was found that by 2040, energy consumption would double with most of the usage being from AC. While with lighting, there is a negligible increase in consumption due to a projected shift towards more efficient lighting. Peak demand loads are expected to increase by an average growth rate of 2.9% per year. Moreover, the diffusion of different ECMs in the residential sector was modeled through four diffusion scenarios to estimate ECM adoption rates. ECMs’ impact on CO2 emissions and energy consumption of residential buildings in Kuwait was evaluated and the cost of conserved energy (CCE) and annual energy savings for each measure was calculated. AC ECMs exhibited the highest cumulative savings, whereas lighting ECMs showed an immediate energy impact. None of the ECMs in the study were cost effective due to the high subsidy rate (95%), therefore, the impact of ECMs at different subsidy and rebate rates was studied. At 75% subsidized utility price and 40% rebate only on appliances, most of ECMs will be cost effective with high energy savings. Moreover, by imposing charges of $35/ton of CO2, most ECMs will be cost effective.
ContributorsAlajmi, Turki (Author) / Phelan, Patrick E (Thesis advisor) / Kaloush, Kamil (Committee member) / Huang, Huei-Ping (Committee member) / Wang, Liping (Committee member) / Hajiah, Ali (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Just for a moment! Imagine you live in Arizona without air-conditioning systems!

Air-conditioning and refrigeration systems are one of the most crucial systems in anyone’s house and car these days. Energy resources are becoming more scarce and expensive. Most of the currently used refrigerants have brought an international concern about global

Just for a moment! Imagine you live in Arizona without air-conditioning systems!

Air-conditioning and refrigeration systems are one of the most crucial systems in anyone’s house and car these days. Energy resources are becoming more scarce and expensive. Most of the currently used refrigerants have brought an international concern about global warming. The search for more efficient cooling/refrigeration systems with environmental friendly refrigerants has become more and more important so as to reduce greenhouse gas emissions and ensure sustainable and affordable energy systems. The most widely used air-conditioning and refrigeration system, based on the vapor compression cycle, is driven by converting electricity into mechanical work which is a high quality type of energy. However, these systems can instead be possibly driven by heat, be made solid-state (i.e., thermoelectric cooling), consist entirely of a gaseous working fluid (i.e., reverse Brayton cycle), etc. This research explores several thermally driven cooling systems in order to understand and further overcome some of the major drawbacks associated with their performance as well as their high capital costs. In the second chapter, we investigate the opportunities for integrating single- and double-stage ammonia-water (NH3–H2O) absorption refrigeration systems with multi-effect distillation (MED) via cascade of rejected heat for large-scale plants. Similarly, in the third chapter, we explore a new polygeneration cooling-power cycle’s performance based on Rankine, reverse Brayton, ejector, and liquid desiccant cycles to produce power, cooling, and possibly fresh water for various configurations. Different configurations are considered from an energy perspective and are compared to stand-alone systems. In the last chapter, a new simple, inexpensive, scalable, environmentally friendly cooling system based on an adsorption heat pump system and evacuated tube solar collector is experimentally and theoretically studied. The system is destined as a small-scale system to harness solar radiation to provide a cooling effect directly in one system.
ContributorsAlelyani, Sami M (Author) / Phelan, Patrick E (Thesis advisor) / Wang, Liping (Committee member) / Stechel, Ellen B (Committee member) / Calhoun, Ronald J (Committee member) / Alalili, Ali R (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Thermal Energy Storage (TES) is of great significance for many engineering applications as it allows surplus thermal energy to be stored and reused later, bridging the gap between requirement and energy use. Phase change materials (PCMs) are latent heat-based TES which have the ability to store and release heat through

Thermal Energy Storage (TES) is of great significance for many engineering applications as it allows surplus thermal energy to be stored and reused later, bridging the gap between requirement and energy use. Phase change materials (PCMs) are latent heat-based TES which have the ability to store and release heat through phase transition processes over a relatively narrow temperature range. PCMs have a wide range of operating temperatures and therefore can be used in various applications such as stand-alone heat storage in a renewable energy system, thermal storage in buildings, water heating systems, etc. In this dissertation, various PCMs are incorporated and investigated numerically and experimentally with different applications namely a thermochemical metal hydride (MH) storage system and thermal storage in buildings. In the second chapter, a new design consisting of an MH reactor encircled by a cylindrical sandwich bed packed with PCM is proposed. The role of the PCM is to store the heat released by the MH reactor during the hydrogenation process and reuse it later in the subsequent dehydrogenation process. In such a system, the exothermic and endothermic processes of the MH reactor can be utilized effectively by enhancing the thermal exchange between the MH reactor and the PCM bed. Similarly, in the third chapter, a novel design that integrates the MH reactor with cascaded PCM beds is proposed. In this design, two different types of PCMs with different melting temperatures and enthalpies are arranged in series to improve the heat transfer rate and consequently shorten the time duration of the hydrogenation and dehydrogenation processes. The performance of the new designs (in chapters 2 and 3) is investigated numerically and compared with the conventional designs in the literature. The results indicate that the new designs can significantly enhance the time duration of MH reaction (up to 87%). In the fourth chapter, organic coconut oil PCM (co-oil PCM) is explored experimentally and numerically for the first time as a thermal management tool in building applications. The results show that co-oil PCM can be a promising solution to improve the indoor thermal environment in semi-arid regions.
ContributorsAlqahtani, Talal (Author) / Phelan, Patrick E (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Mellouli, Sofiene (Committee member) / Wang, Robert (Committee member) / Mu, Bin (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Water desalination has become one of the viable solutions to provide drinking water in regions with limited natural resources. This is particularly true in small communities in arid regions, which suffer from low rainfall, declining surface water and increasing salinity of groundwater. Yet, current desalination methods are difficult to be

Water desalination has become one of the viable solutions to provide drinking water in regions with limited natural resources. This is particularly true in small communities in arid regions, which suffer from low rainfall, declining surface water and increasing salinity of groundwater. Yet, current desalination methods are difficult to be implemented in these areas due to their centralized large-scale design. In addition, these methods require intensive maintenance, and sometimes do not operate in high salinity feedwater. Membrane distillation (MD) is one technology that can potentially overcome these challenges and has received increasing attention in the last 15 years. The driving force of MD is the difference in vapor pressure across a microporous hydrophobic membrane. Compared to conventional membrane-based technologies, MD can treat high concentration feedwater, does not need intensive pretreatment, and has better fouling resistance. More importantly, MD operates at low feed temperatures and so it can utilize low–grade heat sources such as solar energy for its operation. While the integration of solar energy and MD was conventionally indirect (i.e. by having two separate systems: a solar collector and an MD module), recent efforts were focused on direct integration where the membrane itself is integrated within a solar collector aiming to have a more compact, standalone design suitable for small-scale applications. In this dissertation, a comprehensive review of these efforts is discussed in Chapter 2. Two novel direct solar-powered MD systems were proposed and investigated experimentally: firstly, a direct contact MD (DCMD) system was designed by placing capillary membranes within an evacuated tube solar collector (ETC) (Chapter 3), and secondly, a submerged vacuum MD (S-VMD) system that uses circulation and aeration as agitation techniques was investigated (Chapter 4). A maximum water production per absorbing area of 0.96 kg·m–2·h–1 and a thermal efficiency of 0.51 were achieved. A final study was conducted to investigate the effect of ultrasound in an S-VMD unit (Chapter 5), which significantly enhanced the permeate flux (up to 24%) and reduced the specific energy consumption (up to 14%). The results add substantially to the understanding of integrating ultrasound with different MD processes.
ContributorsBamasag, Ahmad (Author) / Phelan, Patrick E (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Wang, Liping (Committee member) / Bocanegra, Luis (Committee member) / Roedel, Ronald (Committee member) / Arizona State University (Publisher)
Created2020
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Description
The colloidal solutions of nanoparticles have been seen as promising solutions forheat transfer enhancement. Additionally, there has been an accelerated study on the effects of ultrasound on heat transfer enhancement in recent years. A few authors have studied the combined impact of Al2O3 nanofluids and ultrasound on mini channels. This study focused on

The colloidal solutions of nanoparticles have been seen as promising solutions forheat transfer enhancement. Additionally, there has been an accelerated study on the effects of ultrasound on heat transfer enhancement in recent years. A few authors have studied the combined impact of Al2O3 nanofluids and ultrasound on mini channels. This study focused on the combined effects of Al2O3 nanofluids and ultrasound on heat transfer enhancement in a circular mini channel heat sink. Two concentrations of Al2O3-water nanofluids, i.e., 0.5% and 1%, were used for the experiments in addition to two heat input conditions, namely 40 W and 50 W providing a constant heat flux of 25000 W m-2 and 31250 W m-2 respectively. The effect on the nanofluids using 5 W ultrasound was analyzed. Experimental observations show that the usage of ultrasound increased the heat transfer coefficient. The heat transfer coefficient also increased with increasing nanoparticle concentration and high heat flux. The average heat transfer coefficient enhancement for 0.5% and 1% nanofluid due to increased heat flux in the absence of ultrasound was 12.4% and 9% respectively. At a constant heat input of 40 W, the induction of ultrasound enhanced the heat transfer coefficient by 22.8% and 23.9% for 0.5% and 1% nanofluid respectively. Similarly, for a constant heat input of 50 W, the usage of ultrasound enhanced the heat transfer coefficient by 19.8% and 22.9% for 0.5% and 1% nanofluid respectively Also, interesting findings are reported with low heat input with ultrasound vs. high heat input without ultrasound (i.e., 40 W with US vs. 50 W without US). The heat transfer coefficient and Nusselt number for 0.5% and 1% concentrations was enhanced by 9.2% and 13.6%, respectively. Furthermore, for fixed heat input powers of 40 W and 50 W, increasing the concentration from 0.5% to 1% along with ultrasound yielded an average enhancement in Nu of 38.3% and 32.4% respectively
ContributorsMastoi, Faisal Ali (Author) / Phelan, Patrick E (Thesis advisor) / Milcarek, Ryan (Committee member) / Kwon, Beomjin (Committee member) / Arizona State University (Publisher)
Created2022