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Thermodynamic development and balance of plant study is completed for a 30 MW solar thermochemical water splitting process that generates hydrogen gas and electric power. The generalized thermodynamic model includes 23 components and 45 states. Quasi-steady state simulations are completed for design point system sizing, annual performance analysis and sensitivity

Thermodynamic development and balance of plant study is completed for a 30 MW solar thermochemical water splitting process that generates hydrogen gas and electric power. The generalized thermodynamic model includes 23 components and 45 states. Quasi-steady state simulations are completed for design point system sizing, annual performance analysis and sensitivity analysis. Detailed consideration is given to water splitting reaction kinetics with governing equations generalized for use with any redox-active metal oxide material. Specific results for Ceria illustrate particle reduction in two solar receivers for target oxygen partial pressure of 10 Pa and particle temperature of 1773 K at a design point DNI of 900 W/m2. Sizes of the recuperator, steam generator and hydrogen separator are calculated at the design point DNI to achieve 100,000 kg of hydrogen production per day from the plant. The total system efficiency of 39.52% is comprised of 50.7% hydrogen fraction and 19.62% electrical fraction. Total plant capital costs and operating costs are estimated to equate a hydrogen production cost of $4.40 per kg for a 25-year plant life. Sensitivity analysis explores the effect of environmental parameters and design parameters on system performance and cost. Improving recuperator effectiveness from 0.7 to 0.8 is a high-value design modification resulting in a 12.1% decrease in hydrogen cost for a modest 2.0% increase in plant $2.85M. At the same time, system efficiency is relatively inelastic to recuperator effectiveness because 81% of excess heat is recovered from the system for electricity production 39 MWh/day and revenue is $0.04 per kWh. Increasing water inlet pressure up to 20 bar reduces the size and cost of super heaters but further pressure rises increasing pump at a rate that outweighs super heater cost savings.
ContributorsBudama, Vishnu Kumar (Author) / Johnson, Nathan (Thesis advisor) / Stechel, Ellen (Committee member) / Rykaczewski, Konrad (Committee member) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2018
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The concept of the microgrid is widely studied and explored in both academic and industrial societies. The microgrid is a power system with distributed generations and loads, which is intentionally planned and can be disconnected from the main utility grid. Nowadays, various distributed power generations (wind resource, photovoltaic resource, etc.)

The concept of the microgrid is widely studied and explored in both academic and industrial societies. The microgrid is a power system with distributed generations and loads, which is intentionally planned and can be disconnected from the main utility grid. Nowadays, various distributed power generations (wind resource, photovoltaic resource, etc.) are emerging to be significant power sources of the microgrid.

This thesis focuses on the system structure of Photovoltaics (PV)-dominated microgrid, precisely modeling and stability analysis of the specific system. The grid-connected mode microgrid is considered, and system control objectives are: PV panel is working at the maximum power point (MPP), the DC link voltage is regulated at a desired value, and the grid side current is also controlled in phase with grid voltage. To simulate the real circuits of the whole system with high fidelity instead of doing real experiments, PLECS software is applied to construct the detailed model in chapter 2. Meanwhile, a Simulink mathematical model of the microgrid system is developed in chapter 3 for faster simulation and energy management analysis. Simulation results of both the PLECS model and Simulink model are matched with the expectations. Next chapter talks about state space models of different power stages for stability analysis utilization. Finally, the large signal stability analysis of a grid-connected inverter, which is based on cascaded control of both DC link voltage and grid side current is discussed. The large signal stability analysis presented in this thesis is mainly focused on the impact of the inductor and capacitor capacity and the controller parameters on the DC link stability region. A dynamic model with the cascaded control logic is proposed. One Lyapunov large-signal stability analysis tool is applied to derive the domain of attraction, which is the asymptotic stability region. Results show that both the DC side capacitor and the inductor of grid side filter can significantly influence the stability region of the DC link voltage. PLECS simulation models developed for the microgrid system are applied to verify the stability regions estimated from the Lyapunov large signal analysis method.
ContributorsXu, Hongru (Author) / Chen, Yan (Thesis advisor) / Johnson, Nathan (Committee member) / Lei, Qin (Committee member) / Arizona State University (Publisher)
Created2018
Description
This honors thesis is focused on two separate catalysis projects conducted under the mentorship of Dr. Javier Pérez-Ramírez at ETH Zürich. The first project explored ethylene oxychlorination over supported europium oxychloride catalysts. The second project investigated alkyne semihydrogenation over nickel phosphide catalysts. This work is the subject of a publication

This honors thesis is focused on two separate catalysis projects conducted under the mentorship of Dr. Javier Pérez-Ramírez at ETH Zürich. The first project explored ethylene oxychlorination over supported europium oxychloride catalysts. The second project investigated alkyne semihydrogenation over nickel phosphide catalysts. This work is the subject of a publication of which I am a co-author, as cited below.

Project 1 Abstract: Ethylene Oxychlorination
The current two-step process for the industrial process of vinyl chloride production involves CuCl2 catalyzed ethylene oxychlorination to ethylene dichloride followed by thermal cracking of the latter to vinyl chloride. To date, no industrial application of a one-step process is available. To close this gap, this work evaluates a wide range of self-prepared supported CeO2 and EuOCl catalysts for one-step production of vinyl chloride from ethylene in a fixed-bed reactor at 623 773 K and 1 bar using feed ratios of C2H4:HCl:O2:Ar:He = 3:3 6:1.5 6:3:82 89.5. Among all studied systems, CeO2/ZrO2 and CeO2/Zeolite MS show the highest activity but suffer from severe combustion of ethylene, forming COx, while 20 wt.% EuOCl/γ-Al2O3 leads to the best vinyl chloride selectivity of 87% at 15.6% C2H4 conversion with complete suppression of CO2 formation and only 4% selectivity to CO conversion for over 100 h on stream. Characterization by XRD and EDX mapping reveals that much of the Eu is present in non-active phases such as Al2Eu or EuAl4, indicating that alternative synthesis methods could be employed to better utilize the metal. A linear relationship between conversion and metal loading is found for this catalyst, indicating that always part of the used Eu is available as EuOCl, while the rest forms inactive europium aluminate species. Zeolite-supported EuOCl slightly outperforms EuOCl/γ Al2O3 in terms of total yield, but is prone to significant coking and is unstable. Even though a lot of Eu seems locked in inactive species on EuOCl/γ Al2O3, these results indicate possible savings of nearly 16,000 USD per kg of catalyst compared to a bulk EuOCl catalyst. These very promising findings constitute a crucial step for process intensification of polyvinyl chloride production and exploring the potential of supported EuOCl catalysts in industrially-relevant reactions.

Project 2 Abstract: Alkyne Semihydrogenation
Despite strongly suffering from poor noble metal utilization and a highly toxic selectivity modifier (Pb), the archetypal catalyst applied for the three-phase alkyne semihydrogenation, the Pb-doped Pd/CaCO3 (Lindlar catalyst), is still being utilized at industrial level. Inspired by the very recent strategies involving the modification of Pd with p-block elements (i.e., S), this work extrapolates the concept by preparing crystalline metal phosphides with controlled stoichiometry. To develop an affordable and environmentally-friendly alternative to traditional hydrogenation catalysts, nickel, a metal belonging to the same group as Pd and capable of splitting molecular hydrogen has been selected. Herein, a simple two-step synthesis procedure involving nontoxic precursors was used to synthesize bulk nickel phosphides with different stoichiometries (Ni2P, Ni5P4, and Ni12P5) by controlling the P:Ni ratios. To uncover structural and surface features, this catalyst family is characterized with an array of methods including X-ray diffraction (XRD), 31P magic-angle nuclear magnetic resonance (MAS-NMR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). Bulk-sensitive techniques prove the successful preparation of pure phases while XPS analysis unravels the facile passivation occurring at the NixPy surface that persists even after reductive treatment. To assess the characteristic surface fingerprints of these materials, Ar sputtering was carried out at different penetration depths, reveling the presence of Ni+ and P-species. Continuous-flow three-phase hydrogenations of short-chain acetylenic compounds display that the oxidized layer covering the surface is reduced under reaction conditions, as evidenced by the induction period before reaching the steady state performance. To assess the impact of the phosphidation treatment on catalytic performance, the catalysts were benchmarked against a commercial Ni/SiO2-Al2O3 sample. While Ni/SiO2-Al2O3 presents very low selectivity to the alkene (the selectivity is about 10% at full conversion) attributed to the well-known tendency of naked nickel nanoparticles to form hydrides, the performance of nickel phosphides is highly selective and independent of P:Ni ratio. In line with previous findings on PdxS, kinetic tests indicate the occurrence of a dual-site mechanism where the alkyne and hydrogen do not compete for the same site.

This work is the subject of a publication of which I am a co-author, as cited below.

D. Albani; K. Karajovic; B. Tata; Q. Li; S. Mitchell; N. López; J. Pérez-Ramírez. Ensemble Design in Nickel Phosphide Catalysts for Alkyne Semi-Hydrogenation. ChemCatChem 2019. doi.org/10.1002/cctc.201801430
ContributorsTata, Bharath (Author) / Deng, Shuguang (Thesis director) / Muhich, Christopher (Committee member) / Chemical Engineering Program (Contributor, Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
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Description
The prevalence of renewable generation will increase in the next several decades and offset conventional generation more and more. Yet this increase is not coming without challenges. Solar, wind, and even some water resources are intermittent and unpredictable, and thereby create scheduling challenges due to their inherent “uncontrolled” nature. To

The prevalence of renewable generation will increase in the next several decades and offset conventional generation more and more. Yet this increase is not coming without challenges. Solar, wind, and even some water resources are intermittent and unpredictable, and thereby create scheduling challenges due to their inherent “uncontrolled” nature. To effectively manage these distributed renewable assets, new control algorithms must be developed for applications including energy management, bridge power, and system stability. This can be completed through a centralized control center though efforts are being made to parallel the control architecture with the organization of the renewable assets themselves—namely, distributed controls. Building energy management systems are being employed to control localized energy generation, storage, and use to reduce disruption on the net utility load. One such example is VOLTTRONTM, an agent-based platform for building energy control in real time. In this thesis, algorithms developed in VOLTTRON simulate a home energy management system that consists of a solar PV array, a lithium-ion battery bank, and the grid. Dispatch strategies are implemented to reduce energy charges from overall consumption ($/kWh) and demand charges ($/kW). Dispatch strategies for implementing storage devices are tuned on a month-to-month basis to provide a meaningful economic advantage under simulated scenarios to explore algorithm sensitivity to changing external factors. VOLTTRON agents provide automated real-time optimization of dispatch strategies to efficiently manage energy supply and demand, lower consumer costs associated with energy usage, and reduce load on the utility grid.
ContributorsCardwell, Joseph (Author) / Johnson, Nathan (Thesis advisor) / Rogers, Bradley (Committee member) / Macia, Narciso (Committee member) / Arizona State University (Publisher)
Created2015
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Description
This dissertation develops advanced controls for distributed energy systems and evaluates performance on technical and economic benefits. Microgrids and thermal systems are of primary focus with applications shown for residential, commercial, and military applications that have differing equipment, rate structures, and objectives. Controls development for residential energy heating and cooling

This dissertation develops advanced controls for distributed energy systems and evaluates performance on technical and economic benefits. Microgrids and thermal systems are of primary focus with applications shown for residential, commercial, and military applications that have differing equipment, rate structures, and objectives. Controls development for residential energy heating and cooling systems implement adaptive precooling strategies and thermal energy storage, with comparisons made of each approach separately and then together with precooling and thermal energy storage. Case studies show on-peak demand and annual energy related expenses can be reduced by up to 75.6% and 23.5%, respectively, for a Building America B10 Benchmark home in Phoenix Arizona, Los Angeles California, and Kona Hawaii. Microgrids for commercial applications follow after with increased complexity. Three control methods are developed and compared including a baseline logic-based control, model predictive control, and model predictive control with ancillary service control algorithms. Case studies show that a microgrid consisting of 326 kW solar PV, 634 kW/ 634 kWh battery, and a 350 kW diesel generator can reduce on-peak demand and annual energy related expenses by 82.2% and 44.1%, respectively. Findings also show that employing a model predictive control algorithm with ancillary services can reduce operating expenses by 23.5% when compared to a logic-based algorithm. Microgrid evaluation continues with an investigation of off-grid operation and resilience for military applications. A statistical model is developed to evaluate the survivability (i.e. probability to meet critical load during an islanding event) to serve critical load out to 7 days of grid outage. Case studies compare the resilience of a generator-only microgrid consisting of 5,250 kW in generators and hybrid microgrid consisting of 2,250 kW generators, 3,450 kW / 13,800 kWh storage, and 16,479 kW solar photovoltaics. Findings show that the hybrid microgrid improves survivability by 10.0% and decreases fuel consumption by 47.8% over a 168-hour islanding event when compared to a generator-only microgrid under nominal conditions. Findings in this dissertation can increase the adoption of reliable, low cost, and low carbon distributed energy systems by improving the operational capabilities and economic benefits to a variety of customers and utilities.
ContributorsNelson, James Robert (Author) / Johnson, Nathan (Thesis advisor) / Stadler, Michael (Committee member) / Zhang, Wenlong (Committee member) / Arizona State University (Publisher)
Created2019
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This work introduces self-organizing techniques to reduce the complexity and burden of coordinating distributed energy resources (DERs) and microgrids that are rapidly increasing in scale globally. Technical and financial evaluations completed for power customers and for utilities identify how disruptions are occurring in conventional energy business models. Analyses completed for

This work introduces self-organizing techniques to reduce the complexity and burden of coordinating distributed energy resources (DERs) and microgrids that are rapidly increasing in scale globally. Technical and financial evaluations completed for power customers and for utilities identify how disruptions are occurring in conventional energy business models. Analyses completed for Chicago, Seattle, and Phoenix demonstrate site-specific and generalizable findings. Results indicate that net metering had a significant effect on the optimal amount of solar photovoltaics (PV) for households to install and how utilities could recover lost revenue through increasing energy rates or monthly fees. System-wide ramp rate requirements also increased as solar PV penetration increased. These issues are resolved using a generalizable, scalable transactive energy framework for microgrids to enable coordination and automation of DERs and microgrids to ensure cost effective use of energy for all stakeholders. This technique is demonstrated on a 3-node and 9-node network of microgrid nodes with various amounts of load, solar, and storage. Results found that enabling trading could achieve cost savings for all individual nodes and for the network up to 5.4%. Trading behaviors are expressed using an exponential valuation curve that quantifies the reputation of trading partners using historical interactions between nodes for compatibility, familiarity, and acceptance of trades. The same 9-node network configuration is used with varying levels of connectivity, resulting in up to 71% cost savings for individual nodes and up to 13% cost savings for the network as a whole. The effect of a trading fee is also explored to understand how electricity utilities may gain revenue from electricity traded directly between customers. If a utility imposed a trading fee to recoup lost revenue then trading is financially infeasible for agents, but could be feasible if only trying to recoup cost of distribution charges. These scientific findings conclude with a brief discussion of physical deployment opportunities.
ContributorsJanko, Samantha Ariel (Author) / Johnson, Nathan (Thesis advisor) / Zhang, Wenlong (Committee member) / Herche, Wesley (Committee member) / Arizona State University (Publisher)
Created2019
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Rapid increases in the installed amounts of Distributed Energy Resources are forcing a paradigm shift to guarantee stability, security, and economics of power distribution systems. This dissertation explores these challenges and proposes solutions to enable higher penetrations of grid-edge devices. The thesis shows that integrating Graph Signal Processing with State

Rapid increases in the installed amounts of Distributed Energy Resources are forcing a paradigm shift to guarantee stability, security, and economics of power distribution systems. This dissertation explores these challenges and proposes solutions to enable higher penetrations of grid-edge devices. The thesis shows that integrating Graph Signal Processing with State Estimation formulation allows accurate estimation of voltage phasors for radial feeders under low-observability conditions using traditional measurements. Furthermore, the Optimal Power Flow formulation presented in this work can reduce the solution time of a bus injection-based convex relaxation formulation, as shown through numerical results. The enhanced real-time knowledge of the system state is leveraged to develop new approaches to cyber-security of a transactive energy market by introducing a blockchain-based Electron Volt Exchange framework that includes a distributed protocol for pricing and scheduling prosumers' production/consumption while keeping constraints and bids private. The distributed algorithm prevents power theft and false data injection by comparing prosumers' reported power exchanges to models of expected power exchanges using measurements from grid sensors to estimate system state. Necessary hardware security is described and integrated into underlying grid-edge devices to verify the provenance of messages to and from these devices. These preventive measures for securing energy transactions are accompanied by additional mitigation measures to maintain voltage stability in inverter-dominated networks by expressing local control actions through Lyapunov analysis to mitigate cyber-attack and generation intermittency effects. The proposed formulation is applicable as long as the Volt-Var and Volt-Watt curves of the inverters can be represented as Lipschitz constants. Simulation results demonstrate how smart inverters can mitigate voltage oscillations throughout the distribution network. Approaches are rigorously explored and validated using a combination of real distribution networks and synthetic test cases. Finally, to overcome the scarcity of real data to test distribution systems algorithms a framework is introduced to generate synthetic distribution feeders mapped to real geospatial topologies using available OpenStreetMap data. The methods illustrate how to create synthetic feeders across the entire ZIP Code, with minimal input data for any location. These stackable scientific findings conclude with a brief discussion of physical deployment opportunities to accelerate grid modernization efforts.
ContributorsSaha, Shammya Shananda (Author) / Johnson, Nathan (Thesis advisor) / Scaglione, Anna (Thesis advisor) / Arnold, Daniel (Committee member) / Boscovic, Dragan (Committee member) / Arizona State University (Publisher)
Created2021
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Desorption processes are an important part of all processes which involve utilization of solid adsorbents such as adsorption cooling, sorption thermal energy storage, and drying and dehumidification processes and are inherently energy-intensive. Here, how those energy requirements can be reduced through the application of ultrasound for three widely used

Desorption processes are an important part of all processes which involve utilization of solid adsorbents such as adsorption cooling, sorption thermal energy storage, and drying and dehumidification processes and are inherently energy-intensive. Here, how those energy requirements can be reduced through the application of ultrasound for three widely used adsorbents namely zeolite 13X, activated alumina and silica gel is investigated. To determine and justify the effectiveness of incorporating ultrasound from an energy-savings point of view, an approach of constant overall input power of 20 and 25 W was adopted. To measure the extent of the effectiveness of using ultrasound, the ultrasonic-power-to-total power ratios of 0.2, 0.25, 0.4 and 0.5 were investigated and the results compared with those of no-ultrasound (heat only) at the same total power. Duplicate experiments were performed at three nominal frequencies of 28, 40 and 80 kHz to observe the influence of frequency on regeneration dynamics. Regarding moisture removal, application of ultrasound results in higher desorption rate compared to a non-ultrasound process. A nonlinear inverse proportionality was observed between the effectiveness of ultrasound and the frequency at which it is applied. Based on the variation of desorption dynamics with ultrasonic power and frequency, three mechanisms of reduced adsorbate adsorption potential, increased adsorbate surface energy and enhanced mass diffusion are proposed. Two analytical models that describe the desorption process were developed based on the experimental data from which novel efficiency metrics were proposed, which can be employed to justify incorporating ultrasound in regeneration and drying processes.
ContributorsDaghooghi Mobarakeh, Hooman (Author) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Wang, Robert (Committee member) / Calhoun, Ronald (Committee member) / Deng, Shuguang (Committee member) / Arizona State University (Publisher)
Created2021
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Fossil fuels are currently the main source of energy in the world’s transportation sector. They are also the primary contributor to carbon emissions in the atmosphere, leading to adverse climate effects. The objective of the following research is to increase the yield and efficiency of algal biofuel in order to

Fossil fuels are currently the main source of energy in the world’s transportation sector. They are also the primary contributor to carbon emissions in the atmosphere, leading to adverse climate effects. The objective of the following research is to increase the yield and efficiency of algal biofuel in order to establish algal-derived fuel as a competitive alternative to predominantly used fossil fuels. Using biofuel commercially will reduce the cost of production and ultimately decrease additional carbon emissions. Experiments were performed using hydrothermal liquefaction (HTL) to determine which catalyst would enhance the algal biocrude oil and result in the highest quality biofuel product, as well as to find the optimal combination of processing temperature and manure co-liquefaction of biomass ratio. For the catalytic upgrading experiments, Micractenium Immerum algae was used in conjunction with pure H2, Pt/C, MO2C, and HZSM-5 catalysts at 350℃ and 400℃, 430 psi, and a 30-minute residence time to investigate the effects of catalyst choice and temperature on the crude oil yield. While all catalysts increased the carbon content of the crude oil, it was found that using HZSM-5 at 350℃ resulted in the greatest overall yield of about 75%. However, the Pt/C catalyst increased the HHV from 34.26 MJ/kg to 43.26 MJ/kg. Cyanidioschyzon merolae (CM) algae and swine manure were utilized in the co-liquefaction experiments, in ratios (algae to swine) of 80:20, 50:50, and 20:80 at temperatures of 300℃ and 330℃. It was found that a ratio of 80:20 at 330℃ produced the highest biocrude oil yield of 29.3%. Although the 80:20 experiments had the greatest biomass conversion and best supported the deacidification of the oil product, the biocrude oil had a HHV of 33.58 MJ/kg, the lowest between the three different ratios. However, all calorific values were relatively close to each other, suggesting that both catalytic upgrading and co-liquefaction can increase the efficiency and economic viability of algal biofuel.
ContributorsMurdock, Tessa A (Author) / Deng, Shuguang (Thesis director) / Varman, Arul (Committee member) / Chemical Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
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This paper analyzes Burkina Faso’s Souro Sanou University Hospital Center’s energy needs and discusses whether or not solar panels are a good investment. This paper also discusses a way to limit the damage caused by power outages. The hospital has a history of problems with power outages; in the summer

This paper analyzes Burkina Faso’s Souro Sanou University Hospital Center’s energy needs and discusses whether or not solar panels are a good investment. This paper also discusses a way to limit the damage caused by power outages. The hospital has a history of problems with power outages; in the summer they have power outages every other day lasting between one to four hours, and in the rainy season they have outages once every other week lasting the same amount of time.
The first step in this analysis was collecting relevant data which includes: location, electricity rates, energy consumption, and existing assets. The data was entered into a program called HOMER. HOMER is a program which analyzes an electrical system and determines the best configuration and usage of assets to get the lowest levelized cost of energy (LCOE). In HOMER, five different analyses were performed. They reviewed the hospital’s energy usage over 25 years: the current situation, one of the current situation with added solar panels, and another where the solar panels have single axis tracking. The other two analyses created incentives to have more solar panels, one situation with net metering, and one with a sellback rate of 0.03 $/kWh. The result of the analysis concluded that the ideal situation would have solar panels with a capacity of 300 kW, and the LCOE in this situation will be 0.153 $/kWh. The analysis shows that investing in solar panels will save the hospital approximately $65,500 per year, but the initial investment of $910,000 only allows for a total savings of $61,253 over the life of the project. The analysis also shows that if the electricity company, Sonabel, eventually buys back electricity then net metering would be more profitable than reselling electricity for the hospital.
Solar panels will help the hospital save money over time, but they will not stop power outages from happening at the hospital. For the outages to stop affecting the hospital’s operations they will have to invest in an uninterrupted power supply (UPS). The UPS will power the hospital for the time between when the power goes out and when their generators are turning on which makes it an essential investment. This will stop outages from affecting the hospital, and if the power goes out during the day then the solar panels can help supplement the energy production which will take some of the strain from their generators.
The results of this study will be sent to officials at the hospital and they can decide if the large initial investment justifies the savings. If the solar panels and UPS can save one life, then maybe the large initial investment is worth it.
ContributorsSchmidt, Evin Khalil (Author) / Johnson, Nathan (Thesis director) / Miner, Mark (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05